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1.
The Al‐Jawf area of northern Saudi Arabia provides spectacular outcrops of Early Devonian carbonate bioherms in the Wadi Murayr and Dumat Al‐Jandal areas. These carbonate bioherms belong to the Qasr Member of the Late Pragian–Early Emsian Jauf Formation (~405 Ma) and are surrounded by a bioclastic carbonate succession. The Qasr Member is the first major carbonate unit of the Palaeozoic succession in Saudi Arabia that mainly consists of microbialite carbonates and metazoan reefs exhibiting distinct mound features. These bioherm complexes and their associated carbonate facies are pervasively dolomitized. Stratigraphic, petrographic and geochemical analyses were conducted to determine the facies distribution and interpret their depositional and diagenetic processes. A total of 11 facies are identified from a range of depositional environments within a carbonate platform system, ranging from tidal flats, lagoon, shoal, patch reefs to reef front. The main diagenetic processes are carbonate cementation and dolomitization. Dolomitization occurred as both fabric preserved (mostly in grain‐dominated facies) and fabric destructive (mud‐dominated facies). The microbialites and coralline sponges facies show poor reservoir with visual porosity less than 5%, but this succession may have a potential to serve as a good source for the underlying and overlying facies. Ooid and peloidal grainstone facies show fair to good visual porosity that locally exceeds 10% with intergranular porosity as the dominant type. However, in the most studied samples, vuggy and intraparticle porosities are observed as the dominant type. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

2.
The upper Kimmeridgian outcrops in Jabaloyas (NE Spain) studied here have significant similarity in terms of carbonate ramp morphology and its facies architecture with Member D of the Upper Jurassic Arab Formation reservoirs in the Middle East. Geological models from analogue outcrops enhance or challenge the understanding of multi-scale sedimentological and diagenetic heterogeneities in the subsurface hydrocarbon reservoir models by providing morphometric parameters. For this purpose, conventional diagenetic studies (petrographic microscopy analysis and cathodoluminescence) have been performed to assess the impact of diagenetic modifications through burial. More than 50 thin sections have been used to define a full paragenetic sequence. Additional mineralogical mapping (Qemscan®) on a selection of thin sections serves as a calibration tool for semiquantitative analytic studies of every mineral phases and the proposed porosity evolution. This work unravels the whole paragenetic diagenetic processes and focused on those that occurred right after deposition to shallow burial (eogenesis). High-sequence stratigraphy allows linking these events to variations of the environmental domains that, in fact, respond most likely to sea-level fluctuations. In particular, it provides key parameters to frame the diagenetic overprint such as cementation processes plugging primary interparticle porosity and selective dissolution linked to master bounding surfaces: calcite meniscus cements in vadose zones and selective dissolution processes linked to firmgrounds. Ultimately, they offer valuable trends that would be potentially relevant to decipher and characterize reservoir parameters for the upscaling workflow of fabrics from microscopic to inter-well scale in carbonate hydrocarbon reservoirs.  相似文献   

3.
A mineralogical and geochemical study of clay lithologies and a biostratigraphic analysis of the carbonates from the deep-sea Lagonegro Basin (Southern Apennines—Italy) have been carried out to deduce in general the provenance of clay sediments and their paleoenvironmental conditions and particular to recognize the signature of the Paleocene–Eocene climatic global warming. The analysed succession comprising a wide stratigraphic interval of the Sannio Unit, spanning between Albian to the upper Oligocene–lower Miocene, is exposed near Accettura and Stigliano villages. Eighteen clay samples were analysed by XRD, XRF, SEM, TG-DTA. Their age was framed by biostratigraphic analyses carried out on carbonate sediments. Mineral assemblage of the clay sediments includes quartz, carbonates (calcite and dolomite), feldspars (plagioclase and k-feldspars), hematite, randomly illite/smectite mixed layers with a low illite percentage, kaolinite, discrete illite–muscovite, chlorite, palygorskite and sepiolite. The low illite percentage in randomly illite/smectite mixed layers indicates low diagenetic conditions for the studied successions. These features are unique for the Cretaceous–Tertiary successions of the Lagonegro domain and are particularly significant for the preservation of the native mineralogical assemblage useful to determine the provenance and paleoenvironmental conditions of the clayey sediments. Palygorskite and sepiolite are concentrated in the upper Paleocene–middle Eocene stratigraphic interval and particularly in the upper part of the early Eocene—lower part of the middle Eocene (biozone of Blow P 9–12). Clay sediments rich in palygorskite and sepiolite show a higher P2O5 amount and a lower kaolinite percentage, compatible with warm and arid climatic conditions typical of the global warming event well recorded in the southern tethyan margin. Likely palygorskite and sepiolite formed in lagoonal environment in nearby carbonate platform margins and then they were transported into the Lagonegro Basin as indicated by the well developed habitus of palygorskite. During the Paleogene the Lagonegro Basin and the nearby carbonate platforms represented a key sector the southern paleodomains of the Tethys. The discovery of these minerals gives a contribution to the reconstruction paleoenvironmental conditions of the Tethian paleo-margin during the early–middle Eocene.  相似文献   

4.
Ridge sandstone of Jurassic Jumara dome of Kachchh was studied in an attempt to quantify the effects of diagenetic process such as compaction, cementation and dissolution on reservoir properties. The average framework composition of Ridge sandstone is Q80F17L3, medium-to coarse grained and subarkose to arkose. Syndepositional silty to clayey matrix (3% average) is also observed that occurs as pore filling. The diagenetic processes include compaction, cementation and precipitation of authigenic cements, dissolution of unstable grains and grain replacement and development of secondary porosity. The major cause of intense reduction in primary porosity of Ridge sandstone is early cementation which include silica, carbonate, iron, kaolinite, illite, smectite, mixed layer illite-smectite and chlorite, which prevents mechanical compaction. The plots of COPL versus CEPL and IGV versus total cement suggest the loss of primary porosity in Ridge sandstone is due to cementation. Cements mainly iron and carbonate occurs in intergranular pores of detrital grains and destroys porosity. The clay mineral occurs as pore filling and pore lining and deteriorates the porosity and permeability of the Ridge sandstone. The reservoir quality of the studied sandstone is reduced by clay minerals (kaolinite, illite, smectite, mixed layer illitesmectite, chlorite), carbonate, iron and silica cementation but on the other hand, it is increased by alteration and dissolution of the unstable grain, in addition to partial dissolution of carbonate cements. The potential of the studied sandstone to serve as a reservoir is strongly related to sandstone diagenesis.  相似文献   

5.
Most of hydrocarbon accumulations within the Gulf of Hammamet foreland basins in eastern Tunisia are reservoired within the Upper Miocene Birsa and Saouaf sandstones. It is the case of Birsa, Tazarka, Oudna, Baraka, Maamoura, Cosmos and Yasmine fields. These sandstones constitute oil and gas fields located on folded and faulted horst anticline highs and described as varying from shoreface to shallow marine and typically exhibit excellent reservoir quality of 30 to 35% porosity and good permeability from 500 to 1100 md. In addition, the fracturing of faults enhanced their reservoir quality potential. However, due to the lack of seismic stratigraphic studies to highlight depositional environment reservoir characterization and distribution, petroleum exploration faces structural and stratigraphic trap types and remains on targeting only high fold closures with limited reserve volumes of hydrocarbons. As an example of the Birsa concession case, syn-sedimentary tectonic structuring and geodynamic evolution during Middle to Upper Miocene Birsa reservoir sequences have guided the distribution of depositional environment of sandstone channel systems around horst and grabens by E-W, NE-SW and N-S strike slip flower faults controlling the subsidence distribution combined with the eustatic sea level variations. Seismic sequence stratigraphy study of Miocene Birsa reservoir horizons, based on the analysis and interpretations of E-W and N-S 3D selected regional lines that were compared and correlated to outcrops and calibrated by well data, permitted to highlight the basin configuration and sequence deposit nature and distribution. Sedimentary infilling of the basin from Langhian Ain Ghrab carbonate to Serravallian Tortonian Birsa and Saouaf sandstone and shale formations is organized in four third-order seismic sequences, limited by regional erosional toplap, onlap and downlap unconformity surfaces and by remarkable chronostratigraphic horizons of forced and normal erosive lowstand and highstand system tracts separated by transgressive and maximum flooding surfaces. Reconstructed sedimentary paleo-environment distribution vary from deltaic fluvial proximal deposits in the northern part of the high central Birsa horst to a delta front and prodelta coastal and shelf shore face and shore line channelized deposits in the surrounding borders of grabens. Distal deposits seem to be distributed from upper to lower slope fans and probably to the basin floor on the flanks of the subsiding grabens. Synthetic predictive paleogeographic depositional reservoir fairway map distribution of Lower, Middle and Upper Birsa sandstone reservoirs highlights four main domains of channelized superposed and shifted reservoirs to explore.  相似文献   

6.
Comparison of Upper Guadalupian fore-reef, reef and back-reef strata from outcrops in the Guadalupe Mountains with equivalent subsurface cores from the northern and eastern margins of the Delaware Basin indicates that extensive evaporite diagenesis has occurred in both areas. In both surface and subsurface sections, the original sediments were extensively dolomitized and most primary and secondary porosity was filled with anhydrite. These evaporites were emplaced by reflux of evaporitic fluids from shelf settings through solution-enlarged fractures and karstic sink holes into the underlying strata. Outcrop areas today, however, contain no preserved evaporites in reef and fore-reef sections and only partial remnants of evaporites are retained in back-reef settings. In their place, these rocks contain minor silica, very large volumes of coarse sparry calcite and some secondary porosity. The replacement minerals locally form pseudomorphs of their evaporite precursors and, less commonly, contain solid anhydrite inclusions. Some silicification, dissolution of anhydrite and conversion of anhydrite to gypsum have occurred in these strata where they are still buried at depths in excess of 1 km; however, no calcite replacements were noted from any subsurface core samples. Subsurface alteration has also led to the widespread, late-stage development of large- and small-scale dissolution breccias. The restriction of calcite cements to very near-surface sections, petrographic evidence that the calcites post-date hydrocarbon emplacement, and the highly variable but generally ‘light’carbon and oxygen isotopic signatures of the spars all indicate that calcite precipitation is a very late diagenetic (telogenetic) phenomenon. Evaporite dissolution and calcitization reactions have only taken place where Permian strata were flushed with meteoric fluids as a consequence of Tertiary uplift, tilting and breaching of regional hydrological seals. A typical sequence of alteration involves initial corrosion of anhydrite, one or more stages of hydration/dehydration during conversion to gypsum, dissolution of gypsum and precipitation of sparry calcite. Such evaporite dissolution and replacement processes are probably continuing today in near-outcrop as well as deeper settings. This study emphasizes the potential importance of telogenetic processes in evaporite diagenesis and in the precipitation of carbonate cements. The extensive mineralogical and petrophysical transformations which these strata have undergone during their uplift indicates that considerable caution must be exercised in using surface exposures to interpret subsurface reservoir parameters in evaporitic carbonate rocks.  相似文献   

7.
A previous study (Disnar et al., 1986a) indicated significant volatile hydrocarbon compounds (nC1 to C5) in mineralized carbonate rocks of the Trèves Pb-Zn deposit (Gard Dept., France) as well as an accumulation of methane, ethylene and ethane in the hanging wall of the deposit. The present study analyzed rock samples taken from outcrops vertically above and at a distance from the deposit and identified three anomalous zones indicating the presence of concealed mineralization. The first zone is due to methane (radius about 3 km), the second, to alkenes (about 2 km) and the third, to alkanes, higher homologues of methane (about 1 km). These anomalies are interpreted as resulting from migration of these compounds through the sedimentary cover from the deposit where they could have been generated during mineralizing events, or during subsequent diagenesis. Their specific signature with regard to that given by samples taken at a distance from the orebodies can be attributed to the hydrothermal and biological processes responsible for the deposition of the ore.  相似文献   

8.
研究深部碳酸盐岩力学特性参数分布规律,对于预防碳酸盐岩地层钻井事故的发生具有十分重要的意义。采集对应地层埋深从3 568～5 983 m的20组不同层系的碳酸盐岩露头岩芯,借助MTS815.03和RMT150C岩石力学试验系统、RSM-SYS5非金属声波测试仪等,完成显微电镜分析、单轴压缩、三轴压缩和围压声波测试等试验。试验结果表明,（1）南方海相碳酸盐岩主要以生物碎屑白云岩、泥晶灰岩为主,粒径范围在0.01～0.20 mm之间,孔隙类型以粒内溶蚀孔隙、粒间孔隙、晶间溶孔为主,孔隙率范围为2%～12%;（2）单轴抗压强度在空间分布上有一定的规律性,三轴抗压强度在空间上为无序分布,表现出某种混沌的特征;（3）碳酸盐岩纵波速度随围压的增加而增大,在低围压下纵波速度增加明显;高围压下纵波速度变化相对较小,围压下纵波速度增幅,白云岩大于灰岩,获得白云岩、灰岩的抗压强度与其纵波波速不同的相关关系。其结论可为深部碳酸盐岩地层安全钻进提供技术参数。  相似文献   

9.
Palygorskite is a fibrous, magnesium‐bearing clay mineral commonly associated with Late Mesozoic and Early Cenozoic dolomites. The presence of palygorskite is thought to be indicative of warm, alkaline fluids rich in Si, Al and Mg. Palygorskite has been interpreted to form in peritidal diagenetic environments, either as a replacement of detrital smectite clay during a dissolution–precipitation reaction or solid‐state transformation, or as a direct precipitate from solution. Despite a lack of evidence, most diagenetic studies involving these two minerals posit that dolomite and palygorskite form concurrently. Here, petrological evidence is presented from the Umm er Radhuma Formation (Palaeocene–Eocene) in the subsurface of central Qatar for an alternative pathway for palygorskite formation. The Umm er Radhuma is comprised of dolomitized subtidal to peritidal carbonate cycles that are commonly capped by centimetre‐scale beds rich in palygorskite. Thin section, scanning electron microscopy and elemental analyses demonstrate that palygorskite fibres formed on both the outermost surfaces of dissolved euhedral dolomite crystals and within partially to completely dissolved dolomite crystal cores. These observations suggest that dolomite and palygorskite formed sequentially, and support a model by which the release of Mg2+ ions and the buffering of solution pH during dolomite dissolution promote the formation of palygorskite. This new diagenetic model explains the co‐occurrence of palygorskite and dolomite in the rock record, and provides valuable insight into the specific diagenetic conditions under which these minerals may form.  相似文献   

10.
Fifteen percent of the exploration wells drilled in the Kutai Basin region were targeted for stratigraphic play-types. Carbonate reservoirs comprise almost 70% of the objectives in these stratigraphic plays. There was need for a better understanding of the carbonate reservoir potential in the region. Accordingly, this study was carried out. The distribution, depositional environment as well as factors controlling the quality of carbonate reservoirs are reviewed and analyzed. Carbonate reservoirs in the study area can be found sparsely throughout the Kutai Basin. Carbonates range in age from Oligocene (Bebulu limestone) to Late Miocene (Dian limestone). The main constituents of these carbonate build-ups are platy-corals, encrusting red algae and larger benthonic foraminifera. Most of the carbonates were deposited in a shallow marine environment (inner to middle shelf) during rises in relative sea level. Highstand system tracts are characterized by well-developed carbonate facies-belts. The carbonate build-ups generally occur as isolated bedded mounds, from a few feet up to 1000 ft in thickness. The preservation of primary porosity is generally poor due to diagenetic processes during burial history, particularly the infilling of pores by non-ferroan calcite cement. The development of secondary porosity is limited, due to the retardation of subsurface fluid flow by non-permeable layers, and the absence of solution effects due to sub-aerial exposure and karstification. Preserved porosities are mainly present as vugs, best developed in coarse-grained shelf-margin facies, which may not have subsequently been completely filled by calcite cement. Early hydrocarbon migration may retard the diagenetic processes and preserve the primary carbonate porosity.  相似文献   

11.
The area of the Dolomites in the Southern Alps exhibits some of the best outcrops of carbonate platforms and platform-to-basin transitions in the world. The region has attracted geologists since the early 19th Century and has been a centre of stratigraphic and sedimentological research ever since. The interpretation of the platforms in the Dolomites as coral reefs dates back to the 1850s and was inspired by the work on modern reefs in the Pacific and Indian Oceans at that time. Very soon, however, studies in the Dolomites triggered developments of their own. Fieldwork on these Triassic atolls led to a first understanding of the dramatic facies changes at the periphery of reefs and atolls, including the recognition of slope facies and basinward transport of platform material by gravity. In addition, the platforms were used to prove long-term syndepositional subsidence on the scale of kilometres as early as 1860. After World War II, the study of modern reefs and platforms led to process-based facies models and this, in turn, guided the sedimentological analysis of the Alpine–Mediterranean belt. Repeatedly, however, the roles became reversed and the Alpine–Mediterranean platforms contributed to the fundamental underpinnings of sedimentology. In the 1980s, mountain-size outcrops in the Alps and the Apennines were recognized as models for the interpretation of shoal-water carbonates in seismic data. Seismic models of outcrops in the Dolomites, for instance, gave rise to the concept of pseudo-unconformities, i.e. rapid lateral facies changes that appear as unconformities in seismic images. In the 1990s, the Alpine–Mediterranean Mesozoic along with the North American and European Palaeozoic revealed the significance of microbially induced carbonate precipitation in constructing large limestone bodies. Studies of ancient rocks led this development because this particular carbonate factory is far less prominent now than it was at certain times in the past.  相似文献   

12.
The Linok Formation is made up of clayey and carbonate strata, 180–300 m thick, formed at the terminal Middle Riphean on the northwestern margin of the Siberian Platform. In the modern structure, it is exposed in the lower part of the Turukhansk Uplift section. The sediments accumulated in the distal part of the epiplatformal basin as a symmetrical transgressive–regressive cycle. Its lower part represents a deep-water basin environment with the mixed carbonate–clayey sedimentation, whereas the upper part reflects the origination and evolution of a carbonate platform. Microstructures discussed in this work suggest not only the ancient existence of benthic microbial assemblages (mats) but their active influence upon the facies pattern of sediments as well. The influence was determined by the ability of mat-forming communities to produce carbonate sediments under certain environmental conditions. The analysis of the facies succession suggested the absence of an appreciable influx of carbonate material to the basin from other sources. Based on the carbonate generation ability, one can distinguish three (carbonate-free, low-productive, and high-productive) groups of microbial communities. Groups 1 and 2 represent deep-water basin mats, whereas group 3 represents relatively shallow-water platformal microbial–mineral systems. The carbonate productivity of communities is inversely proportional to the depth of their dwelling and the relative rate of clayey sedimentation. The morphological reconstruction of microbiolite structures showed that the structures in basins and platforms greatly differed in terms of the size of elements. The ability of microbial communities to generate carbonate could be realized only within large ecosystems.  相似文献   

13.
The behavior of stable carbon and oxygen isotopes in carbonates during the deposition and diagenesis of sediments in the bioproductive Upper Famennian Pripyat Trough (southern Belarus) is discussed. Limestones and clayey limestones (Corg 0.92 ± 0.11%) are characterized by very low δ13C values (–9.6 ± 0.3‰). Parental sediments of these rocks were deposited in the shallow-water zone during slow downwarping episodes of the seafloor. Lithification of the sediments took place in oxidative conditions of the diagenesis zone. Organic matter was actively oxidized by free oxygen. Carbon dioxide with isotopically light organic carbon formed in this process was used during the crystallization of diagenetic carbonates that are visually indiscernible from the sedimentational variety. Marls, clayey marls, and carbonate-bearing clays (Corg 6.02 ± 0.80%) are characterized by δ13C values as high as –3.5 ± 0.6‰. In combustible shales (Corg >10%), δ13C value is ‒1.2 ± 0.6‰). The clayey rocks mark the episodes of sedimentation in relatively deep-water conditions that appear during the uncompensated sagging of the basin floor. The diagenetic zone with free oxygen was significantly decreased or absent at all. Here, oxygen of marine sulfates was the main or single oxidizer of organic matter (sulfate reduction). The sulfate oxygen is a weaker oxidizing agent than free oxygen. Therefore, much more organic matter was retained and fossilized in clayey rocks than in carbonate rocks. Organic carbon released during the sulfate reduction and mobilized later for the diagenetic carbonate formation was insufficient for the significant decrease of δ13C values relative to the marine carbonate standard. Isotopic composition of carbonate oxygen in the studied rocks is invariable and does not depend on the content of clay and organic matter. In these rocks, δ18O values are at the level (approximately –5‰) shown for the Famennian in the Global Chemostratigraphic Chart. This fact is consistent with the supposition that oxygen isotope composition of atmospheric precipitates, which influenced the rock formation via continental flow, is close to that of sea water in low latitudes where the territory of Belarus was located in the Late Devonian.  相似文献   

14.
Major ion concentrations in 404 springs in carbonate strata were found to exhibit a wide range in sulfate values. Sulfate concentrations are often much larger than would be expected from the analysis of samples from surface outcrops. Springs in the Sierra Madre Oriental (Mexico), the Rocky Mountains Front Range (Canada), and the Peak District (England) show similarities in sulfate concentration and in spatial distribution. Springs with high sulfate concentrations are found close to base level and are thermal. Springs with low sulfate concentration are found at higher elevations above base level and are not thermal. There is a direct relationship between sulfate concentration and spring temperature, and an inverse relationship with discharge. The results from the three areas described support a model of local and regional flow patterns, with deep regional flow providing the warm sulfate-rich water. The initial fracture porosity development in these aquifers may owe as much to the removal of sulfur minerals as to the removal of carbonate minerals. High sulfate values are frequently found in carbonate aquifers, so this model may be of widespread applicability.  相似文献   

15.
《Chemical Geology》2003,193(3-4):273-293
The El Berrocal granite/U-bearing quartz vein (UQV) system has been studied as a natural analogue of a high-level radioactive waste repository. The main objective was to understand the geochemical behaviour of natural nuclides under different physicochemical conditions. Within this framework, the argillization processes related to fracturing and formation of the uranium–quartz vein were studied from a mineralogical and isotopic standpoint in order to establish their temperatures of formation and thus complete the geothermal history of the system. For this purpose, δ18O values were determined for pure mineral from the unaltered granite and quartz from the uranium–quartz vein, as well as for mixture samples from the hydrothermally altered granite (sericitised granite) and clayey samples from fracture fillings, including the clayey walls of the uranium–quartz vein. The isotopic signature of quartz from the uranium–quartz vein and the monophasic nature of its fluid inclusions led us to conclude that the isotopic signature of water in equilibrium with quartz was approximately in the range from −8.3‰ to −5.7‰ V-SMOV, its temperature of formation being around 85–120 °C. The δ18O values of pure sericite from the hydrothermally altered granite, calculated by means of the oxygen fraction molar method, indicate that its temperature of formation, in equilibrium with the aforementioned waters, is also in the range from 70 °C to approximately 120 °C. Clays from fracture fillings and clayey walls of the uranium–quartz vein are usually mixtures, in different proportions, of illite, approximately formed between 70 and 125 °C; two generations of kaolinite formed at approximately 90–130 °C and at around 25 °C, respectively; smectite, formed at ≤25 °C; and occasionally palygorskite, formed either between 30 and 45 °C or 19 and 32 °C, depending on the fractionation equation used. These data suggest that sericite from the hydrothermally altered granite, quartz from the uranium–quartz vein, illite and the first generation of kaolinite from the fracture fillings resulted from the same hydrothermal process affecting the El Berrocal granite in relation to fracturing. Under certain physicochemical conditions (T≈100 °C, pH≈8 and log [H4SiO4] between −4 and −3), illite and kaolinite can be paragenetic. As a result of weathering processes, smectite was formed from hydrothermal illite and inherited albite under alkaline weathering, while the second generation of kaolinite was formed from smectite, under acid conditions and close to the sulphide-rich uranium–quartz vein. Palygorskite is an occasional mineral formed probably either during the thermal tail of the above-described hydrothermal process or during weathering processes. In both cases, palygorskite must have formed from alkaline Si–Mg-rich solutions. Finally, these data and processes are discussed in terms of natural analogue processes, drawing some implications for the performance assessment of a deep geological radwaste repository (DGRR).  相似文献   

16.
Jhilmili intertrappean bed (～13 m thick) attains its significance with the recent discovery of brackish water ostrocod and planktonic foraminifera fossils (Keller et al. 2009; Khosala et al. 2009). Present XRD data revealed abundance of montmorillonite > montmorillonite/chlorite mixed layer > palygorskite in five physically distinct lithounits namely: (a) lower chocolate brown siltstone with green patches, followed by (b) brick red clayey siltstone, (c) greenish grey clay, (d) yellowish brown clay and (e) uppermost olive grey to dark brown silt layers in the successionrepresent higher weathering indices and annual precipitation, reflecting cyclic, but longer spells of weathering. Occurrence of M/C mixed layer with the smectite in Jhilmili area is suggestive of their derivation from the later, whilst montmorillonite to palygorskite transformation is ascribed to the drastic changes in the humid to arid climate, where former served as a source of Al and some of the Si and Mg ions for the later. Jhilmili and Anjar clays represent similar charge occupancies at different sites, but later contains relatively higher amount of palygorskite, formed in the arid environment. Majority of the trace elemental data plots for Jhilmili clays lie within the upper and lower limits of infra (Lametas)-/inter-trappeans clays. The continuous release of Cu throughout the succession (mainly in the palygorskite dominated clays) indicates oxidizing conditions. PAAS normalized REE data plots for these clays show progressive enrichment in the HREE contents in the lower part, but, upper part of the succession is marked by positive cerium anomaly, reflecting oxidizing conditions prevailed at the later stage of the succession. These conditions continued, but, were not conducive to HREE enrichment as evidenced by their depletion in the upper part of the succession. The Ce anomaly observed in the middle part of the succession is similar to that form by continental weathering of the basalt, ascribed to Ce precipitation in the oxic environment, thus suggestive of drastic changes in the oxidizing conditions. Thermodynamic data-sets for Jhilmili clays show I/S mixed layer and celadonite compositions, whereas, Jabalpur infra-/inter-trappean clays correspond to Mg smectites and celadonite end members, thus, representing compositional commonality with those of the other clays derived from the continental weathering of basalt protolith. Jhilmili smectites and smectite-chlorite mixtures show compositional similarity with the dioctahedral and trioctahedral smectites and the smectites formed at 250°C, having compositions between trioctahedral smectite and chlorite, thus, assigning high temperatures for their formation, where the heat required for the formation of these clays was possibly derived from the hydrothermal fluids, associated with the Deccan volcanism.  相似文献   

17.
非饱和黏性土的电阻率特性及其试验研究   总被引：9，自引：0，他引：9  
在讨论黏性土导电特性的基础上,假定非饱和黏性土中存在3种电流流通路径,针对已有的非饱和土电阻率结构模型存在的缺陷,推导了适用于非饱和黏性土的电阻率结构模型,探讨了土电阻率的主要影响因素,并将其归纳为3类。最后,通过对合肥膨胀土相关试验研究,分析了含水率、孔隙水电阻率、温度以及孔隙率对膨胀土的电阻率的影响特征,探讨了非饱和膨胀土的电阻率基本特性。  相似文献   

18.
The Upper Paleozoic preflysch sedimentary rocks in the Türkstan-Alay ranges are combined in a common section with limestone of autochthon and synsedimentation carbonate nappes, thus forming the upper-most layers of the stratigraphic section of the latter. By their lithology, relatively small thickness, facies variability, and position at the boundary between carbonate and flysch-olistostrome sequences (in the autochthon), these rocks correspond to a certain extent to preflysch of the Urals and the Mediterranean Alpine Belt. This association of clayey, carbonate, and terrigenous rocks is strictly constrained in stratigraphy (the upper portion of the lower Moscovian substage and the lower portion of the upper Moscovian substage) and localization (the southern slopes of carbonate platforms). The formation of this rock association immediately predated the Late Paleozoic overthrusting and deposition of terrigenous flysch. In paleotectonic terms, preflysch is an indicator of the initial stage of tectonic and magmatic activation that led to the replacement of carbonate sedimentation with deposition of terrigenous and clayey sediments, coeval volcanism, and stratiform ore formation. The following sequence of events has been outlined in the Early and Middle Carboniferous: (1) thrusting of volcanic-sedimentary rocks filling troughs over the northern margins of carbonate platforms, (2) lateritic weathering and deposition of marine bauxite in the Bashkirian and early Moscovian, (3) repeated overthrusting and deposition of preflysch on southern slopes of platforms, (4) invasion of the frontal flysch trough from the south, (5) scouring of preflysch and the underlying limestone, and (6) formation of flysch-olistostrome sequences and tectonic and gravity nappes in the late Moscovian time. This interpretation takes into account the southward vergence of thrust sheets and nappes, the structure and localization of allochthonous fragments of marginal zones of carbonate platforms, and the pre-Bashkirian thrusting of volcanic and sedimentary rocks over the condensed pelagic deposits of the Shalan Group. It is suggested that bauxite and preflysch materials had the same source and were deposited in the Middle Carboniferous on the offshore carbonate shoals.  相似文献   

19.
During Late Proterozoic times, the Archaean Central African craton was affected by trough faulting which led to the formation of grabens, the Sangha aulacogen being the main structure of this type in the studied area. This transverse basin connects with other basins on the northern and south-western borders of the craton. During the Cryogenian, this network of basins was filled with fluvio-deltaic and lacustrine periglacial deposits. The glacio-eustatic transgression in Neoproterozoic III (end-Proterozoic) times flooded extensive areas of shelf on the northern edge of the craton, leading to the development of carbonate sedimentation in a broad outer shelf environment associated with nearshore barriers and evaporitic lagoons. These facies are similar to those developed in the West Congolian Schisto-calcaire (shale-limestone) ramp succession. The North-Central African ramp succession (sediment slope) contains an example of tidal rhythmites in vertical accretion, which occurs beneath the barrier deposits on the subtidal outer shelf. Mathematical analysis of the bedding pattern yields a period of 29–30 days for the lunar month, a result which is in agreement with astrophysical evidence for this epoch (i.e. 650 Ma ago). Major subsidence and seismic activity on this gently sloping platform, associated with the proximity of the Sangha aulacogen, caused the triggering of carbonate turbidites and mass flow deposits. The proliferation of microbial mats under euphotic conditions on an extensive shelf led to the build-up of a carbonate platform. During early Neoproterozoic III times, the West Congolian and North-Central African ramps prograded northwards and southwards, respectively, into the Sangha aulacogen. The sea at that time was restricted to a long graben-like basin, while a remaining area of marine sedimentation persisted into the Palaeozoic. Thus the pattern of end-Proterozoic carbonate sedimentation on the borders of the Central African craton can be interpreted in terms of an overall gently sloping ramp model with progradation converging towards the Sangha aulacogen.  相似文献   

20.
A small calcareous basin in central Spain was studied to establish the role of groundwater in the Pareja Limno-reservoir. Limno-reservoirs aim to preserve a constant water level in the riverine zone of large reservoirs to mitigate the impacts arising from their construction. Groundwater flow contribution (mean 60 %) was derived by recharge estimation. In situ measurements (spring discharge, electrical conductivity and sulfate) were undertaken and spring discharge was compared with a drought index. Twenty-eight springs were monitored and three hydrogeological units (HGUs) were defined: a carbonate plateau (HGU1), the underlying aquitard (HGU2), and the gypsum-enriched HGU3. HGU1 is the main aquifer and may play a role in the preservation of the limno-reservoir water level. Hydrogeochemical sampling was conducted and the code PHREEQC used to describe the main geochemical processes. Weathering and dissolution of calcite and gypsum seem to control the hydrogeochemical processes in the basin. Water progresses from Ca2+–HCO3 – in the upper basin to Ca2+–SO4 2– in the lower basin, where HGU3 outcrops. A clear temporal pattern was observed in the limno-reservoir, with salinity decreasing in winter and increasing in summer. This variation was wider at the river outlet, but the mixing of the river discharge with limno-reservoir water buffered it.  相似文献   

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