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1.
钙华是一种特殊的化学或生物化学沉积,它们在大陆内部广泛地分布且含有重要的地质信息,是一种特殊的油气储集体。影响钙华沉积的因素复杂多样,在调研钙华的形成过程及分类的基础上,从气候环境、水文地质条件、水体物理化学条件、生物活动及构造活动五个方面讨论钙华形成的控制因素;并从沉积环境与模式、沉积速率等方面将新疆塔北地区的钙华与国外钙华沉积体进行类比,发现塔北钙华沉积体在温暖湿润的环境下表现出良好的季节性分层,五道班地区钙华在沉积时汇入了大量的陆源碎屑,受生物活动影响较大;硫磺沟地区的钙华沉积则是伴随断裂活动所形成热液上涌的产物。通过对比发现,塔北露头缝洞内充填的钙华内部孔隙发达、连通性较好,并有良好的含油显示,故钙华具备一定的储集能力。 相似文献
2.
云南西部兰坪—思茅盆地位于藏南—滇西地热带和羌北—滇西盐类成矿带东南部,红层分布广泛,盆地内温泉、盐泉和咸泉数量众多,有些温泉沉积钙华。分析了红层的岩性特征和地下水类型,出露于红层泉水的成因机制以及钙华的成因和控制因素,盆地盐泉或咸泉的找钾特征系数及其在预测找钾远景中的应用。盆地内红层地下水的分布受到岩性、构造和地貌的控制,风化裂隙水分布局限,以夹层型层间裂隙水和溶孔水为主。温泉均为深循环泉,盐泉或咸泉多为溶滤成因的浅循环泉。影响温泉附近钙华沉积的水化学因素主要包括pH、CO_2含量或CO_2分压、Ca~(2+)和HCO_3~-含量,可以用Ca~(2+)/HCO_3~-毫克当量比值和方解石饱和指数判断钙华沉积趋势。盐泉或咸泉的比例系数有助于预测找钾远景。 相似文献
3.
在地表环境下,钙华沉积常常是物理化学和生物沉积过程共同作用的结果。藻类因其在钙华沉积环境中具有较大的生物量及其自身拥有多样的代谢方式,对钙华沉积过程和形态具有重要影响。本研究以四川黄龙钙华为例,通过对典型沉积点的水化学、藻类群落组成和现代钙华微岩相结构进行综合分析,来揭示藻类在钙华沉积中的作用。研究发现,黄龙钙华沉积环境中分布的藻类主要包括蓝藻、绿藻和硅藻等。这些藻类代谢活动会在一定程度上改变沉积水体水化学环境,但在快速流动的水体中,其影响有限。不同藻类群落常常形成几百微米至1~2 mm厚的微生物席或生物膜层,作为碳酸钙沉积发生的重要场所,即钙华沉积活动层。在该活动层内,藻体及其分泌的胞外聚合物（EPS）能够为碳酸钙晶体生长提供大量成核位点和生长模板,从而极大地促进钙华沉积。同时,EPS可以控制或影响碳酸钙结晶形态及钙华微岩相结构。准确认识和量化藻类在钙华沉积中的作用还需要继续开展更多微观尺度方面的研究,以便更好地理解钙华沉积机制,并为准确解译古老钙华岩相结构和地球化学特征奠定基础,同时为预测钙华景观演化和保育提供更多科学依据。 相似文献
4.
弄清钙华生物沉积作用有助于更好地理解钙华微岩相结构和地球化学特征的气候环境指示意义。总结和综述了与钙华沉积相关的生物群落、生物成因钙华微岩相结构、钙华生物沉积作用过程及其对钙华地球化学特征影响的研究进展,并展望了未来的研究重点。细菌、藻类和苔藓等广泛参与到钙华沉积中,形成了许多不同类型的孔隙结构、晶体结构和纹层结构。生物沉积过程主要包括:①生物生长扰动水流使得CO2逸出;②代谢作用(如光合作用)过程诱导碳酸钙沉积;③"表面控制"过程影响晶体成核及生长。生物沉积作用驱动了元素的迁移转化,对沉积水体和钙华地球化学特征具有重要影响。钙华在地球生物学研究中具有重要潜力,未来需要加强现代钙华沉积中的物理化学和生物过程相互作用机制及其各自贡献的量化研究,以便准确地解译钙华沉积记录。 相似文献
5.
四川黄龙沟景区钙华的起源和形成机理研究 总被引：36，自引：5，他引：36
对四川黄龙沟钙华景区的水化学测试发现，形成黄龙沟钙华的泉水具有很高的Ca^2 和HC03^-离子浓度，相应地，泉水的C02分压显著高于大气和土壤生物成因所能产生的C02分压。结合泉水出露的地质条件和泉口C02气体碳稳定同位素组成(δ^13C＝—6．8‰)的分析，进一步发现，高C02分压与深部成因的C02有关。可见，黄龙沟钙华属于热成因类钙华，而非原来普遍认为的“是气候岩溶作用的产物”。此外，黄龙沟钙华的大量出现与水中方解石的迅速沉积、Ca^2 和HC03^-浓度的大量降低有关。随着地下水自泉口出露，由于水的C02分压远高于大气，水中C02大量释放于大气，结果水的pH值迅速升高，方解石饱和指数由泉口的负值很快转变为高的正值，为方解石的沉积奠定了必要的物理化学基础。放置于水中的大理岩石片观测表明，流速较快的边石坝处的方解石沉积速率是其附近水池内的2—5倍，这清楚地显示了水动力条件对沉积速率的控制。进一步根据DBL理论模型分析发现，水动力条件对方解石沉积速率的控制在于其对固液界面间扩散边界层(DBL)厚度的影响，流速愈快，DBL厚度愈薄。且DBL厚度最终制约着沉积表面的化学组成浓度，即厚度愈小，表面H^ 浓度愈低(或pH愈高)、方解石饱和指数愈高，进而方解石沉积愈快。 相似文献
6.
董发勤 李刚 代群威 周琳 王富东 赵学钦 蒋忠诚 张强 李博文 Enrico Capezzuoli Mike O''Driscoll Andelka Plenkovic-Moraj 《中国岩溶》2021,40(1):11-18
钙华不仅具有重要的景观旅游价值,而且对确定区内碳酸盐沉积特征、环境演化规律及同期环境生物的作用与贡献有重要的研究意义。本文在对比国内外典型钙华特征的基础上,以黄龙和九寨沟为例,对雪宝顶区块流域内钙华的沉积特征、环境化学与生物作用进行阐述,指出了雪宝顶区块流域冷水型钙华的形成与演化是化学沉积-溶解作用、生物沉积与溶蚀作用等共同作用的结果,并受非生物、生物因素影响。在雪宝顶冷水型钙华的形成过程中,微生物协同参与了钙华的沉积与溶蚀过程,通过自身新陈代谢促活动促使使钙离子结晶,并诱导晶型变化;其他生物体如植物、藻类等或以间接的方式促进或加快了钙华形成,或为钙华生长提供模板和体量。 相似文献
7.
象牙泉地处青藏高原高寒地区,因其钙华沉积酷似“象牙”而闻名。开展象牙泉形成机理的研究,有助于钙华景观的地质环境保护,对雅鲁藏布江构造带古环境演化、新构造活动的研究具有重要意义。文章以象牙源泉及其钙华沉积为研究对象,通过钙华成分、泉水水化学组分、氢氧同位素及相关性分析,探讨了象牙泉及钙华景观的形成机制,估算了钙华形成年代,讨论了钙华景观演化趋势。结果表明:象牙泉出露高程3 208 m,温度16.1 ℃,pH值6.06～6.64,溶解性总固体1 521.1～1 524.2 mg/L,为中偏弱酸性微咸水;阳离子以钠和钙为主,阴离子以碳酸氢根和氯离子为主,水化学类型为重碳酸钙型水;象牙泉具有较高的氯、钠及稍高的溶解性总固体特征,其氢氧同位素分布于全球大气降水方程线附近,说明象牙泉主要为大气降水补给,具有较长的径流途径和缓慢的循环速度,水岩作用强烈。象牙泉为溶解沉淀型,其化学组分来源于水岩相互作用过程碳酸盐岩矿物、硅酸盐岩矿物的溶解。象牙泉钙华沉积的化学成分主要为碳酸钙,占63.07%;次要成分为二氧化硅,占10.19%;属钙华为主、硅华次之的常温泉类钙华。钙均衡估算表明,象牙泉钙华形成于1.38万年前,其沉积速率约为0.27 mm/a。 相似文献
8.
钙华是第四纪研究中的重要标志物,它记录了地质构造活动和气候变化信息.钙华沉积和气候变化之间可能存在联系,但它们之间的确切关系还不清楚.本文收集了中国的50处钙华地理坐标及98个已发表的钙华年龄数据,并使用钙华数量出现峰值的年龄与第四纪典型气候事件发生的时间进行比较分析,以检验钙华沉积受气候变化调节的假设.数据分析表明,中国钙华在空间上主要分布在水量充足气候温暖且地势起伏大、水动力强的西南地区;在时间上钙华数量出现峰值的频率大致对应于气候的10万年(100 ka)冰期旋回,每100 ka的最大峰值均出现在间冰期或过渡期(冰川期向间冰期过渡时期)这两个较温暖时期.并得出中国钙华在气候温暖且降水或地下水丰富的时期沉积速率更高,而在气温降低水量减少时期沉积速率较低. 相似文献
9.
陆地热泉钙华研究进展与展望 总被引：1，自引：1，他引：0
陆地热泉钙华是沉淀于富Ca2+和HCO3-热泉（普遍T≥30℃）的陆地碳酸盐沉积物/岩。热泉钙华独特的形成环境、岩石矿物学特征、地球化学特征和流体性质对古环境、古气候、早期生命起源、新构造运动、陆相热水沉积学、地热资源等方面研究具有重要指示意义。尽管相关学者对陆地热泉钙华开展了相关研究,但由于热泉钙华沉积-成岩过程中受复杂外界条件控制,其时空分布、沉积特征、矿物组成、地球化学特征、微生物作用、流体来源、成岩作用、古气候记录等系列科学问题有待深入研究。在国内外大量文献的基础上,结合研究团队对云南腾冲火山地热区热泉钙华的认识,综述了目前国内外学者对陆地热泉钙华的研究进展,总结了热泉钙华研究意义,提出了当前热泉钙华研究存在的问题及下步研究方向,为更加全面地认识陆地热泉钙华沉积及未来研究提供启示。 相似文献
10.
贵州乌江渡水电站帷幕灌浆廊道中的钙华及其成因 总被引：1，自引：1，他引：0
基于水化学和钙华、水碳稳定同位素特征的分析,作者发现贵州乌江渡水电站帷幕灌浆廊道中的钙华可分为两大类:一类与人类活动有关,即是帷幕或混凝土中的Ｃａ（ＯＨ）＿２溶解、迁移并吸收空气中的ＣＯ＿２产生碳酸钙沉积的结果;另一类属于天然条件下岩溶作用的产物,即由于地下水中的ＣＯ＿２,逸出发生碳酸钙沉积的结果。 相似文献
11.
ROBIN W. RENAUT R. BERNHART OWEN BRIAN JONES JEAN‐JACQUES TIERCELIN CORINNE TARITS JOHN K. EGO KURT O. KONHAUSER 《Sedimentology》2013,60(2):428-468
Travertine is present at 20% of the ca 60 hot springs that discharge on Loburu delta plain on the western margin of saline, alkaline Lake Bogoria in the Kenya Rift. Much of the travertine, which forms mounds, low terraces and pool‐rim dams, is sub‐fossil (relict) and undergoing erosion, but calcite‐encrusted artefacts show that carbonate is actively precipitating at several springs. Most of the springs discharge alkaline (pH: 8·3 to 8·9), Na‐HCO3 waters containing little Ca (<2 mg l?1) at temperatures of 94 to 97·5°C. These travertines are unusual because most probably precipitated at temperatures of >80°C. The travertines are composed mainly of dendritic and platy calcite, with minor Mg‐silicates, aragonite, fluorite and opaline silica. Calcite precipitation is attributed mainly to rapid CO2 degassing, which led to high‐disequilibrium crystal morphologies. Stratigraphic evidence shows that the travertine formed during several stages separated by intervals of non‐deposition. Radiometric ages imply that the main phase of travertine formation occurred during the late Pleistocene (ca 32 to 35 ka). Periods of precipitation were influenced strongly by fluctuations in lake level, mostly under climate control, and by related changes in the depth of boiling. During relatively arid phases, meteoric recharge of ground water declines, the lake is low and becomes hypersaline, and the reduced hydrostatic pressure lowers the level of boiling in the plumbing system of the hot springs. Any carbonate precipitation then occurs below the land surface. During humid phases, the dilute meteoric recharge increases, enhancing geothermal circulation, but the rising lake waters, which become relatively dilute, flood most spring vents. Much of the aqueous Ca2+ then precipitates as lacustrine stromatolites on shallow firm substrates, including submerged older travertines. Optimal conditions for subaerial travertine precipitation at Loburu occur when the lake is at intermediate levels, and may be favoured during transitions from humid to drier conditions. 相似文献
12.
A preliminary analysis of the formation of travertine and travertine cones in the Jifei hot spring,Yunnan, China 总被引：3，自引：2，他引：1
Yaping Liu Xun Zhou Bin Fang Haiyan Zhou Tsutomu Yamanaka 《Environmental Earth Sciences》2012,66(7):1887-1896
The Jifei hot spring emerges in the form of a spring group in the Tibet–Yunnan geothermal zone, southwest of Yunnan Province, China. The temperatures of spring waters range from 35 to 81°C and are mainly of HCO3–Na·Ca type. The total discharge of the hot spring is about 10 L/s. The spring is characterized by its huge travertine terrace with an area of about 4,000 m2 and as many as 18 travertine cones of different sizes. The tallest travertine cone is as high as 7.1 m. The travertine formation and evolution can be divided into three periods: travertine terrace deposition period, travertine cone formation period and death period. The hydrochemical characteristics of the Jifei hot spring was analyzed and compared with a local non-travertine hot spring and six other famous travertine springs. The results indicate that the necessary hydrochemical conditions of travertine and travertine cones deposition in the Jifei area are (1) high concentration of HCO3 − and CO2; (2) about 52.9% deep source CO2 with significantly high value; (3) very high milliequivalent percentage of HCO3 − (97.4%) with not very high milliequivalent percentage of Ca2+ (24.4%); and (4) a large saturation index of calcite and aragonite of the hot water. 相似文献
13.
Late Pleistocene travertines up to 40 m thick near Rapolano Terme in Tuscany, central Italy, were precipitated by hot water issuing from springs on hillsides and flowing into adjacent depressions to mix with rainwater. Proximal light-coloured slope and terrace travertines pass distally into darker reed mound and depression-fill travertines. Lithotypes include crystalline crust, shrub, pisoid, paper-thin raft, coated bubble, reed, and lithoclast-breccia. High precipitation rates resulted in rapid slope aggradation and progradation. Dilution by rainwater likely lowered precipitation rates in depressions, but deposition was augmented by allochthonous material eroded from upslope travertines. Slope Depositional Systems consist of Smooth and Terrace Slope facies characterized by white crystalline crusts, with diverse additional lithotypes in terrace pools. Depression Depositional Systems have mixed light and dark travertines with horizontal to gently concave stratification. Extensive light-coloured Shrub Flat travertine is dominant; darker Marsh-Pool Facies composed of fine lithoclast and reed travertine is localized. Reed Mounds composed of mixed light and dark travertines localized by abundant reed growth, formed where spring water emerged near the bases of low angle slopes. Distal reduction in accretion rate was the major influence on sequence development. Light-coloured slope travertines interdigitate with darker depression deposits. Vertical aggradation of slope deposits, mound progradation, and filling of topographic depressions is expressed by advance and retreat of facies. Evolution from depression to slope or mound sequences is termed ‘steepening up’. Up-sequence change from slope or mound to depression facies is termed ‘levelling up’. Exposure surfaces associated with palaeosols are common in all facies and often constitute sequence boundaries. They are more closely spaced in depression sequences, reflecting slower and possibly also more discontinuous accumulation at sites furthest from hot springs. 相似文献
14.
Rapid facies changes in Holocene fissure ridge hot spring travertines, Rapolano Terme, Italy 总被引：1，自引：0，他引：1
Holocene hot water travertine continues to form at Terme San Giovanni, near Rapolano Terme, central Italy, although artificial diversion of the water has reduced deposition. Mesothermal water (≈38–39 °C) emerging from fault-controlled vents located on a hilltop has created a linear fissure ridge 240 m long and up to 10 m high. Active parts of the ridge crest are covered by small cones; inactive parts are locally neotectonically fissured and have small pools. Ridge deposits include crystalline crust, paper-thin raft and shrub lithotypes. The ridge has both smooth and terraced marginal slopes, dominated by crystalline crusts with small shrubs in terrace pools. At the base of the ridge, there is a rapid transition to lateral flats and depressions, where water from the ridge collects and deposits shrub, irregular pisoid, reed, paper-thin raft and fine-grained and organic-rich travertines. Water channelled to nearby valley sides deposits thick crystalline crusts on valley slopes and waterfall overhangs, locally with small pools filled by smooth spherical pisoids. On the valley floor, mixing of waters forms varied stream-fill deposits that include micritic reed, paper-thin raft and coated bubble travertines. The diversity of travertine facies observed results from the location of the Terme San Giovanni hot springs on a hill crest, thus providing a wide array of downslope locations for further deposition. The abrupt facies transitions observed are characteristic of hot spring carbonates and result from a combination of rapid decrease in precipitation away from vents, variations in local surface topography and the feedback effect of travertine deposition itself, which dams and diverts water flow. 相似文献
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16.
《Journal of Structural Geology》1999,21(8-9):903-916
Late Quaternary travertines deposited from hot springs can reveal much about the neotectonic attributes and histories of structures. On the basis of field studies in the Aegean region (Turkey and Greece), the northern Apennines (Italy) and the Basin and Range province (USA) we conclude that the following relationships are of predictive value: (i) travertine deposits are preferentially located along fracture traces, either immediately above extensional fissures or in the hanging walls of normal faults; (ii) the locations of many travertine fissure-ridge deposits coincide with step-over zones (relay ramps) between fault segments; networks of intersecting tensional fissures reflecting the complex strains experienced in such settings are probably responsible for enhancing hydrothermal flow; (iii) the morphology of travertine deposits overlying extensional fissures is controlled by the rheology of the underlying materials; tufa cones (towers, pinnacles) form on former and present lake floors where fissures underlie unconsolidated sediments, whereas fissure-ridges develop where fissures cut bedrocks at the surface; (iv) fissure-ridges comprise outwardly dipping bedded travertine flanking a central tensional fissure filled by vertically banded travertines; fissures can be used to infer local stretching directions; (v) where there are travertines datable by the U-series method it is possible to calculate time-averaged dilation and lateral propagation rates for individual fissures; (vi) most fissures cutting fissure-ridges comprise self-similar angular segments with fractal dimensions in the range 1.00–1.12, the properties of bedded travertine combined with stress perturbations at fissure tips probably being responsible for such similar fractal dimensions being inferred from such a wide range of locations. Fissures gradually increasing in width with depth are products of continuous fracture dilation in contrast to those that form during episodic dilation which display stepped increases of width with depth; (vii) travertine deposited from springs along fault zones accumulate in terraced-mounds sited down slope of the spring line; (viii) many post-depositional fractures cutting travertine deposits are locally oriented at right angles to deposit margins; and (ix) systematic joints in travertines are restricted to those parts of eroded sheet deposits that have been exhumed. 相似文献
17.
《Russian Geology and Geophysics》2007,48(8):659-667
The subject of study was the chemical composition of common fresh-water springs precipitating travertines in tectonically passive regions of the Kolyvan'-Tomsk folded area and northwestern Salair. Attention was paid to the specific character of manifestation, mineralogy, and petrography of the produced travertines. Results of the study of isotopic composition of carbon in hydrocarbonate ion of waters and carbonate travertines are reported. It is shown that the genetic type of CO2 accompanying the formation of travertines is biogenic. Study of the equilibrium of the underground waters with aluminosilicate and carbonate minerals has shown that the travertines are the product of evolution of an equilibrium-nonequilibrium water-rock system. New mechanisms of travertine formation from cool fresh waters are proposed. 相似文献