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1.
内蒙古西乌旗地区大石寨组火山岩时代及地球化学特征 总被引：4，自引：1，他引：3
西乌旗地区大石寨组火山岩以流纹岩为主,LA-ICP-MS锆石U-Pb同位素测定结果及全岩主量、微量和稀土元素分析结果表明,本区流纹岩的年龄为280.3Ma±1.4Ma,形成于早二叠世;大石寨组火山岩属高钾过铝质钙碱性火山岩,其中SiO2、K2O、Al2O3含量均较高。稀土元素配分曲线总体向右缓倾斜,轻稀土元素相对于重稀土元素富集,Eu呈明显的负异常,重稀土元素亏损不明显。Rb、Th、U、K等大离子亲石元素富集明显,Ba表现为弱亏损,高场强元素具有明显的Ta、Sr、P及Ti亏损,Zr、Hf相对富集。研究认为,该地区流纹岩可能是由玄武岩、安山岩等中基性火山岩分离结晶作用形成的,且形成的构造环境为大陆边缘弧。 相似文献
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LA-ICP-MS锆石U-Pb年龄表明,突泉地区碱性流纹岩锆石的~(206)Pb/~(238)U年龄分别为135±1Ma、133±1Ma,属于早白垩世岩浆活动的产物。岩石地球化学资料表明,碱性流纹岩具富SiO_2、K_2O和高TFeO/MgO值,低Al_2O_3、CaO和MgO的特征,属于高钾钙碱性系列岩石,稀土元素总量较高,轻、重稀土元素分馏明显,具右倾的稀土元素分布模式,负Eu异常明显,相对富集Rb、U、Zr、Hf,亏损Sr、Ti、Nb、Ta等元素,花岗岩判别图解上,样品分布在A型花岗岩区;在Nb-Y-3Ga图解上,显示拉张构造环境的A_2型花岗岩的特征;元素地球化学示踪指出,突泉地区碱性流纹岩可能起源于下地壳的部分熔融,结合区域上分布的同时代火山岩及A型花岗岩类,可以限定碱性流纹岩形成于伸展构造背景,并可能与北部蒙古-鄂霍茨克缝合带的演化有关。锆石Hf同位素研究显示,本区早白垩世流纹岩ε_(Hf)(t)值为+4.2～+10.7,其二阶模式年龄平均为0.74～0.76Ga,结合松嫩地块、兴安地块Hf同位素资料,表明兴安地块与松嫩地块具有相似的地壳增生过程。 相似文献
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大兴安岭中段索伦地区满克头鄂博组火山岩年龄、地球化学特征及其构造环境 总被引：2，自引：2，他引：0
对大兴安岭中段索伦地区满克头鄂博组火山岩进行了岩石地球化学、锆石U-Pb及Hf同位素研究,讨论该地区火山岩的形成时代和构造背景。用LA-ICP-MS测得索伦地区满克头鄂博组2个流纹岩样品的锆石206Pb/238U年龄分别为138.0±1.5Ma和139.9±2.5Ma,表明火山岩的形成时代是早白垩世早期,而非晚侏罗世;地球化学数据显示其具有高硅、富碱、弱过铝质-过铝质(A/CNK=0.99~1.34)、分异程度高的特点,属于高钾钙碱性系列,相对富集轻稀土元素和部分大离子亲石元素(Rb、Th、U、K),亏损高场强元素(Nb、Ta、Ti、P)。锆石Hf同位素组成表明,该区满克头鄂博组火山岩具有较高的εHf(t)值(+4.06~+8.24),二阶段模式年龄为936~664Ma,暗示其可能起源于从亏损地幔增生的年轻地壳物质的部分熔融。结合区域地质资料分析,满克头鄂博组火山岩形成于造山后伸展环境,可能与蒙古-鄂霍茨克洋闭合后造山带的垮塌密切相关。 相似文献
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本文对内蒙古克什克腾旗长岭子地区大石寨组安山质岩屑晶屑凝灰岩进行了锆石LA-ICP-MS U-Pb年代学、锆石原位Hf同位素分析及地球化学研究。测年结果表明样品中锆石年龄主要分七组:3140±19～2826±36 Ma、2761±36～2273±23 Ma、2025±27～1673±89 Ma、1036±144～673±17 Ma、574±19～422±11 Ma、392±11～312±10 Ma和224±18～133±2 Ma。结合锆石的原位微区Hf同位素结果ε_(Hf)(t)值介于-18.0～16.8,n(~(176)Lu)/n(~(177)Hf)和n(~(176)Hf)/n(~(177)Hf)分别为0.000235～0.005759和0.280524～0.283022,T_(DM2)=4291～293 Ma,我们认为大石寨组岩屑晶屑凝灰岩中第一组锆石(3140～2826 Ma)指示东北地区或其邻区可能发育过中太古代—古太古代的古老基底。第二组锆石(2761～2273 Ma)记录了Kenorland超大陆汇聚的地质事件,揭示了大兴安岭地区太古代—古元古代古老结晶基底的信息。第三组锆石(2025～1673 Ma)则是Columbia超大陆形成地质事件的响应。第四、五组锆石(1036～673 Ma、574～422 Ma)来源于东北地区,分别记录了区域新元古代Rondinia和泛非期Gondwana两期重大地质事件。第六组锆石(392～312 Ma)峰值年龄为347 Ma,加权平均年龄为350.0±6.5Ma(MSWD=4.0,n=43),占总数48%,代表凝灰岩的形成时代,属于早石炭世。第七组锆石(224～133 Ma)可能与后期流体改造有关。岩石地球化学分析表明,大石寨组岩屑晶屑凝灰岩大部分样品属于偏铝质(A/CNK=0.65～1.95)、钙碱性(δ=0.88～2.50)火山岩,具有轻稀土富集,重稀土相对亏损,无明显Eu异常,富集Ba、Rb、K等大离子亲石元素,亏损Nb、Ta、Ti、P等高场强元素的特点,与安第斯型活动大陆边缘火山岩相似。结合前人已发表地质资料,我们认为克什克腾旗大石寨组安山质岩屑晶屑凝灰岩为古亚洲洋俯冲过程中洋壳脱水产生的流体与上覆地幔楔相互作用后形成的。形成于活动大陆边缘弧环境,指示古亚洲洋在早石炭世尚未闭合。 相似文献
5.
西昆仑奥东布拉克地区阿羌岩组火山岩平均含量Si O2为49.49%,Ti O2为1.07%,Al2O3为14.96%,ALK均值为3.38%,Na2O/K2O均值为1.46,表明岩石属于钙碱性向碱性(偏碱性)系列过渡的岩石类型。稀土元素配分模式图显示岩石轻稀土元素(LREE)相对富集,重稀土元素(HREE)相对亏损,具有弱正Eu异常,指示岩浆没有经历明显的分异作用。微量元素显示,岩石富集Rb、Ba、K等大离子亲石元素,而相对亏损Ta、Nb、Hf等活动性弱的高场强元素,指示岩石形成于岛弧的构造环境。锆石U-Pb定年结果显示火山岩锆石206Pb/238U加权平均年龄为474.2±4.3 Ma,表明阿羌岩组火山岩形成于奥陶世而不是前人认为的石炭纪。 相似文献
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赣东北中元古界铁沙街组石英角斑岩和流纹岩锆石SHRIMP U-Pb年龄、Hf同位素及地球化学特征 总被引：1，自引：0，他引：1
本文首次测得江西弋阳中元古界铁沙街组石英角斑岩SHRIMP锆石U-Pb年龄为1154±5 Ma。测定发现铁沙街组石英角斑岩和流纹岩高SiO_2(73.53%~81.11%),低CaO(0.06%~0.11%)、Na_2O(0.05%~2.77%),K_2O为2.16%~6.43%和Al_2O_3为11.06%~13.96%;在Zr/TiO_2—Nh/Y微量元素分类图解上绝大多数样品落于碱性流纹岩区域;在SiO_2—FeO/MgO图解中绝大多数样品位于钙碱性岩石系列区域;稀土总量(ΣREE)为182.48×10~(-6)~818.82×10~(-6),轻稀土较富集,铕明显负异常(δEu=0.20~O.45);在原始地幔标准化图解中,表现出亏损大离子亲石元素(Ba、Sr、Ti、P)和富集高场强元素(Nb、Ta、La、Ce、Zr、Hf、Sm)。铁沙街组石英角斑岩和流纹岩的锆石的ε_(Hf)(t)值分别为-6.1~5.3和-2.3~4.8,两阶段Hf模式年龄分别为1653~2380 Ma和1675~2132 Ma。锆石Hf同位素特征显示铁沙街组石英角斑岩、流纹岩的成因主要为岩石圈拆沉,深部地幔物质上涌,并由此造成的古元古代晚期下地壳物质的部分熔融。综上认为,铁沙街组石英角斑岩和流纹岩形成于中元古界后造山阶段的板内环境,可能与华夏陆块板内裂谷减薄开裂阶段的地幔物质上涌有关。 相似文献
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中河花岗斑岩体位于河南省崤山东部,该岩体是最近发现的中河大型银铅锌矿床的成矿母岩。选取2件花岗斑岩样品进行LA-ICP-MS锆石U-Pb定年,获得2件样品的~(206)Pb/~(238)U年龄加权平均值分别为(129±0.7)Ma(MSWD=0.78)和(131±1.5)Ma(MSWD=1.70),表明中河岩体形成于早白垩世。岩石地球化学特征显示,中河岩体具有高的w(SiO_2)和w(K_2O)、低的w(Na_2O),其A/CNK比值为1.03~1.63,Mg#值介于25~50,总体上属于过铝质-强过铝质的高钾钙碱性系列。岩石具有低的w(Yb),中等-弱的铕负异常,稀土元素配分曲线为轻稀土元素富集型,轻稀土元素分馏相对强烈,但重稀土元素分馏不明显。中河岩体有相对低的w(Sr)和w(Y),且富集大离子亲石元素Rb、Ba、U、K和轻稀土元素,亏损高场强元素Nb、Ta、P、Zr、Hf、Ti和重稀土元素。中河岩体锆石εHf(t)值为-34.4~-23.2,平均为-26.9,Hf同位素二阶段模式年龄介于2485~3182 Ma,平均为2714 Ma。岩石地球化学特征及Hf同位素组成表明中河岩体的岩浆源区主要为新太古代地壳物质,并有少量的中太古代地壳物质,中-新太古代增生的具有弧岩浆特征的地壳物质部分熔融形成了早白垩世的中河岩体。 相似文献
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内蒙古科右前旗大石寨组火山岩锆石LA—ICP—MSU—Pb年龄及其形成背景 总被引：4，自引：0，他引：4
对大石寨组火山岩的形成时代和形成背景的认识存在较大的分歧。对采自建组剖面底部英安岩样品中的锆石进行阴极发光照相、微区原位LA—ICP—MS微量元素分析和U-Pb测年。锆石U—Pb同位素分析结果显示,锆石发育典型的岩浆震荡环带,高Th／U（0．51～1．57）,轻稀土元素亏损,重稀土元素富集,具有强烈的正Ce异常和强烈的负Eu异常等特征,表明锆石均属于岩浆成因。22个分析点获得的谐和年龄为（314±1）Ma（MSWD=0．88）,代表了大石寨组火山岩的形成时代。结合前人的资料,认为大石寨组火山岩为裂陷早期的产物,而晚古生代的沉积岩石组合为在这一基础上发展起来的具有裂陷盆地性质的沉积组合。 相似文献
9.
新疆西天山铁木里克铁矿床火山岩锆石U-Pb年代学、岩石地球化学特征及地质意义 总被引：1，自引：0，他引：1
铁木里克铁矿位于西天山阿吾拉勒铁铜成矿带中段,矿床围岩为一套以粗面安山岩、安山岩和流纹岩为主的连续变化的中酸性火山岩。本文通过对铁木里克铁矿床火山岩进行LA-ICP-MS锆石U-Pb定年,并且结合Hf同位素和岩石地球化学研究,对火山岩的形成时代以及大地构造背景进行探讨。锆石LA-ICP-MS测年结果显示,粗面安山岩、安山岩以及流纹岩的测年结果分别是318.8±2.3Ma、320.8±2.5Ma和319.1±3.5Ma。地球化学分析表明该套火山岩属于高钾钙碱性-钾玄岩系列,富集轻稀土元素(LREE)和大离子亲石元素(LILE;如Rb、Th、K),重稀土元素(HREE)配分平坦,同时具有Nb、Ta的强烈亏损,具有明显的岛弧火山岩地球化学特征。在火山岩的大地构造判别图解上,样品点都落在了大陆弧部分。锆石的Hf同位素显示εHf(t)具有一致的变化范围(+6.2~+12.0),指示火山岩具有相同的岩浆来源,都是来源于早古生代新生陆壳的重熔,形成于相同的构造岩浆背景下。结合区域地质资料,本文认为铁木里克铁矿床出露的这套高钾钙碱性-钾玄岩系列火山岩可能是南天山洋闭合末期到陆陆碰撞早期大陆弧岩浆作用的产物。 相似文献
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西昆仑乌孜别里山口南侧一带火山岩地层的时代归属一直存有争议.该套地层虽普遍发育以流纹岩为主的火山岩系,但尚未有人对其开展系统的年代学与地球化学研究.本次研究对该套地层中的流纹岩进行元素地球化学、锆石U-Pb定年及Hf同位素的研究.流纹岩激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)锆石U-Pb年龄为(521.0±2.8)Ma,表明其形成于早寒武世.流纹岩具有高硅富碱的特点,为过铝质、高钾钙碱性系列,岩石明显富集大离子亲石元素(Rb、K)、轻稀土元素和不相容元素U,相对亏损重稀土元素、高场强元素(P、Ti),具有中等Eu负异常,流纹岩具有高分异S型花岗岩的特征.锆石Hf同位素初始比值 εHf(t)变化范围在?0.9～4.1之间,主要为正值,两阶段Hf模式年龄(tDM2)介于1533～1229 Ma之间,显示乌孜别里地区流纹岩为中元古代新生地壳物质重熔形成的岩浆,经较高程度的分异演化而成.结合前人研究成果,推断研究区流纹岩形成于原特提斯洋俯冲背景下岩浆弧构造环境. 相似文献
11.
新疆阿尔泰南缘康布铁堡组钾-钠质流纹岩锆石U-Pb年龄和地球化学 总被引：4，自引：3，他引：1
阿尔泰南缘分布着大量的晚古生代康布铁堡组火山岩系,是许多铁矿、铜矿以及铅锌矿的赋矿围岩。阿尔泰南缘麦兹和克朗火山-沉积盆地内的钾-钠质流纹岩的年龄分别为396.7±1.4Ma和394.0±6.0Ma,结合近期研究成果,进一步表明阿尔泰南缘火山岩主要形成于晚古生代早期,锆石U-Pb年龄峰期在400Ma左右。钾-钠质流纹岩具有高硅(SiO2的含量范围为73%~82%)、高碱(总碱含量介于4%~7%)和过铝质(高A/CNK值>1)的特征,并见有白云母和黑云母的矿物组合,属于高硅高碱过铝质的钙碱性火山岩。此外,它们的Sr和Nd同位素分别为87Sr/86Sr=0.7074~0.7144,143Nd/144Nd=0.512072~0.512252,具有上地壳来源的特征,说明其岩石成因与初生地壳的部分熔融作用有着密切关系。结合区域地质背景分析,它们都产在与俯冲消减作用有关的陆缘岛弧的地质环境中。因此,我们推断本区钾-钠质流纹岩的原始岩浆为高硅高碱的花岗质岩浆,是由进入陆壳的高侵位玄武岩浆的底侵作用导致其上部地壳近固相线的低程度部分熔融的产物。 相似文献
12.
内蒙古扎鲁特旗地区中侏罗统塔木兰沟组的厘定 总被引：1，自引：0，他引：1
扎鲁特旗地区发育的一套中性火山岩,前人曾将其置于二叠纪“大石寨组”、“青凤山组”,缺少古生物资料和测年数据.本次1：25万区域地质调查,在原1：20万划分的“大石寨组”、“青凤山组”的安山岩中采集了同位素测年样品,采用全岩激光40Ar/39Ar法测年,对火山岩样品进行了年代学研究,结果表明火山岩年龄为（172.7±2.0）~（165.2±1.3）Ma.鉴于这套火山岩地层岩石组合特征清楚,时代依据充分,在区域上具有一定的延展性和可填图性,故将这套火山岩地层重新厘定为中侏罗统塔木兰沟组. 相似文献
13.
内蒙古中部红格尔地区白音高老组主要由流纹岩组成, 含少量英安岩和粗安岩。流纹岩具有高硅、铝和钾,低钙镁的特点;富集大离子亲石元素K、Rb、Th和U, 高场强元素Nb、Ta、Ti和P强烈亏损, 具负异常;高w(Sr)/w(Y)和w(La)/w(Yb), 低w(Y)和w(Yb)。稀土元素总量较低, 轻重稀土元素分馏强烈, 具有中等的铕负异常。εNd(t)值为正值(+088~+266), tDM变化于5883~7164 Ma之间。主量、微量元素地球化学和Sr Nd Pb同位素组成显示红格尔地区白音高老组流纹岩为高钾钙碱性C型埃达克质岩, 其形成与蒙古—鄂霍茨克洋的闭合碰撞有关, 形成于早白垩世造山后加厚岩石圈跨塌阶段的板内伸展环境, 是加厚下地壳部分熔融的产物。岩浆源区部分熔融残留相为石榴子石, 在岩浆上升演化过程中经历了斜长石、钛铁矿和磷灰石的分离结晶作用。 相似文献
14.
The Rooiberg Group is a 6-km-thick sequence of mostly volcanic rocks, which represent the first phase of magmatic activity associated with the Bushveld Complex. These strata include, in ascending stratigraphic order, the Dullstroom, Damwal, Kwaggasnek, and Schrikkloof Formations. Units of the lower Dullstroom Formation range from basalts to andesites and comprise two compositional suites: high Ti and low Ti. Compositional data indicate that melts represented by the overlying, more siliceous volcanic rocks, which include dacites and rhyolites, were derived from low Ti melts by fractional crystallization and assimilation of crustal material (AFC processes).
Rb–Sr isotopic data (28 samples) for units of the Dullstroom and Damwal Formations loosely constrain a crystallization age of 2071+94/−65 Ma (these errors and those below: 95% confidence limits), which agrees with previously reported age data. These data suggest an initial value for 87Sr/86Sr of 0.70655+0.00087/−0.00051 for the Rooiberg Group. In contrast, Rb–Sr isotopic compositions of six samples of the Kwaggasnek Formation indicate post-crystallization alteration, which was probably associated with the Lebowa Granite Suite of the Bushveld Complex. Sm–Nd isotopic data (29 samples) for volcanic units of the Rooiberg Group provide a poorly constrained age of 1837+360/−320 Ma with an initial value for 143Nd/144Nd of 0.50976+0.00026/−0.00035. These Rb–Sr and Sm–Nd isotopic compositions are similar to those indicated for melts that crystallized to form the Rustenburg Layered Suite (RLS) of the Bushveld Complex. Extruded and intruded melts probably were derived from the same or similar sources and may have resided in the same magma chambers before emplacement. 相似文献
15.
黑龙江西部龙江地区位于中亚造山带东段,黑河-贺根山缝合带与西拉木伦缝合带之间,地层记录了两大古板块之间古亚洲洋闭合过程的信息。本文对龙江地区乐平统林西组和下-中三叠统老龙头组的砂岩样品进行碎屑重矿物和碎屑锆石U-Pb同位素年代学研究。碎屑重矿物组合以锆石+磷灰石+金红石+角闪石+绿帘石+重晶石的组合为特征,表明物源主要来自于中酸性岩浆岩,并有少量变质岩及沉积岩组分。林西组样品最年轻的锆石年龄为278±3Ma,老龙头组样品最年轻的锆石年龄为247±3Ma、243±4Ma及237±3Ma,结合前人的研究,限定了林西组沉积于乐平世,老龙头组沉积于早三叠世-中三叠世。碎屑锆石年龄谱明显分为五组:237～258Ma、270～329Ma、357～558Ma、680～1633Ma及1893～1966Ma。其中237～258Ma的碎屑锆石主要来自与古亚洲洋洋壳消亡前的俯冲增生过程相关的火山活动,270～329Ma的碎屑锆石主要来自大石寨组火山岩及其同期侵入岩,357～558Ma的碎屑锆石来自早古生代-晚古生代早期岩浆弧,680～1633Ma的碎屑锆石可能来自兴安及额尔古纳地块的变质基底,而较古老的～1800Ma的锆石年龄暗示了华北克拉通基底的物源信息。通过研究发现林西组及老龙头组样品前30%年轻的碎屑锆石年龄与地层沉积年龄之差都小于100Ma,结合对砂岩碎屑组成、重矿物组合及盆地与火山弧位置关系的研究,认为研究区乐平世-中三叠世沉积盆地具有汇聚背景,为弧前盆地。 相似文献
16.
In this paper we present geochemical, zircon U–Pb and Hf isotopic data on the late Paleozoic volcanic rocks of the Dashizhai Formation, which are exposed along the northwestern margin of the Songnen terrane in eastern Inner Mongolia. Our aim is to constrain the petrogenesis and tectonic setting of the volcanic rocks and to unravel the late Paleozoic tectonic evolution of the northwestern part of the Songnen terrane, along the eastern segment of the Central Asian Orogenic Belt. Lithologically, the Dashizhai Formation is composed mainly of rhyolitic tuff, rhyolite, dacite, andesite, basaltic andesite and basalt, with minor basaltic trachyandesite. The zircons separated from these rocks are euhedral–subhedral, have high Th/U ratios (0.2–1.6), and display broad oscillatory growth zoning, indicating a magmatic origin. The results of zircon U–Pb dating indicate the volcanic rocks formed during the early Permian (295–283 Ma). Geochemically, these volcanic rocks belong to the mid-K to high-K calc-alkaline series and are characterized by an enrichment in large ion lithophile elements (LILEs) and a depletion in high field strength elements (HFSEs, such as Nb, Ta, and Ti), similar to igneous rocks that form in active continental margin settings. Most magmatic zircons of the rhyolites show positive εHf(t) values (+ 3.65 to + 13.0) and two-stage model ages (TDM2) of 1396–551 Ma. These geochemical characteristics indicate that the acidic volcanic rocks of the Dashizhai Formation were most likely derived from the partial melting of dominantly juvenile crustal components with a possible addition of “old” materials. In contrast, the basic to intermediate volcanic rocks were derived from the partial melting of a depleted lithospheric mantle that had been metasomatized by fluids derived from a subducted slab. These data, together with regional geological investigations, suggest that the generation of the early Permian volcanic rocks of the Dashizhai Formation was related to the southward subduction of the Paleo–Asian oceanic plate beneath the Songnen terrane. This also implies that the terminal collision between the Songnen and Xing'an terranes did not occur before the early Permian. 相似文献
17.
Whole‐rock geochemistry, zircon U–Pb and molybdenite Re–Os geochronology, and Sr–Nd–Hf isotopes analyses were performed on ore‐related dacite porphyry and quartz porphyry at the Yongping Cu–Mo deposit in Southeast China. The geochemical results show that these porphyry stocks have similar REE patterns, and primitive mantle‐normalized spectra show LILE‐enrichment (Ba, Rb, K) and HFSE (Th, Nb, Ta, Ti) depletion. The zircon SHRIMP U–Pb geochronologic results show that the ore‐related porphyries were emplaced at 162–156 Ma. Hydrothermal muscovite of the quartz porphyry yields a plateau age of 162.1 ± 1.4 Ma (2σ). Two hydrothermal biotite samples of the dacite porphyry show plateau ages of 164 ± 1.3 and 163.8 ± 1.3 Ma. Two molybdenite samples from quartz+molybdenite veins contained in the quartz porphyry yield Re–Os ages of 156.7 ± 2.8 Ma and 155.7 ± 3.6 Ma. The ages of molybdenite coeval to zircon and biotite and muscovite ages of the porphyries within the errors suggest that the Mo mineralization was genetically related to the magmatic emplacement. The whole rocks Nd–Sr isotopic data obtained from both the dacite and quartz porphyries suggest partial melting of the Meso‐Proterozoic crust in contribution to the magma process. The zircon Hf isotopic data also indicate the crustal component is the dominated during the magma generation. 相似文献
18.
内蒙古西乌旗大石寨组火山岩年代学和地球化学特征及地质意义 总被引：1，自引：0，他引：1
中亚造山带南缘二叠纪火山岩的成因及形成环境一直存在争议。本文以内蒙古西乌旗罕乌拉地区发育的大石寨组火山岩为研究对象,对其开展了野外地质、岩石学、锆石U-Pb同位素年代学、地球化学研究。大石寨组火山岩为一套中酸性火山熔岩-碎屑岩组合,岩性以流纹岩为主。锆石LA-ICP-MS U-Pb同位素定年结果显示,2件流纹岩样品的~(206)Pb/~(238)U年龄加权平均值分别为276±0.81Ma(MSWD=1.3)和280±0.76Ma(MSWD=0.69),说明大石寨组流纹岩喷发于早二叠世,反映了早二叠世的构造岩浆作用事件。岩石地球化学研究表明,大石寨组火山岩为一套中酸性火山岩,以高硅、富碱为特征,Ti、Mg、Fe、Ca等元素含量较低;微量元素总体含量较高,具有一致的配分曲线,Rb、Th、U、K、LREE等大离子亲石元素相对于Nb、Ta、HREE等高场强元素明显富集;稀土元素总量偏高,具一致的右倾"海鸥式"配分型式。在微量元素原始地幔标准化蛛网图上显示明显的Ba、Sr、P、Eu和Ti的负异常。10000Ga/Al平均值3.6。地球化学特征显示该套火山岩具有岛弧火山岩的属性,类似A型花岗岩的地球化学特征,为高温低压下长英质地壳部分熔融的产物。结合地球化学特征及区域地质资料,大石寨组火山岩最可能形成于弧后扩张环境,是早二叠世古亚洲洋闭合前洋壳俯冲消减作用的产物。 相似文献
19.
We report U-Pb crystallization ages from four metavolcanic rocks and two granitic gneiss samples as well as whole-rock chemical analyses and Sm-Nd isotopic ratios from 25 metaigneous and metasedimentary rocks from the Chopawamsic and Milton terranes, southern Appalachian Orogen. A metarhyolite sample from the Chopawamsic Formation and a metabasalt sample from the Ta River Formation in the Chopawamsic terrane have indistinguishable U-Pb crystallization ages of 471.4+/-1.3 Ma and 470.0+1.3/-1.5 Ma, respectively. A sample from the Prospect granite that intruded metavolcanic rocks of the Ta River Formation yields a younger U-Pb date of 458.0+/-1 Ma. Metarhyolite and granitic gneiss samples from the northern part of the Milton terrane yield U-Pb dates of 458.5+3.8/-1.0 Ma and 450+/-1.8 Ma, respectively. Metavolcanic and metaplutonic rocks from both terranes span a range in major element composition from basalt to rhyolite. Trace element concentrations in these samples show enrichment in large-ion lithophile elements K, Ba, and Rb and depletion in high field strength elements Ti and Nb, similar to those from island arc volcanic rocks. Initial epsilon(Nd) values and T(DM) ages of the metaigneous and metasedimentary samples range from 0.2 to -7.2 and from 1200 to 1700 Ma for the Chopawamsic terrane and from 3.7 to -7.2 and from 850 to 1650 Ma for the Milton terrane. The crystallization ages for the metavolcanic and metaplutonic samples from both terranes indicate that Ordovician magmatism occurred in both. Similar epsilon(Nd) values from representative samples from both terranes suggest that both were generated from an isotopically similar source. Xenocrystic zircons from metavolcanic rocks in the Chopawamsic terrane have predominately Mesoproterozoic (207)Pb/(206)Pb ages (600-1300 Ma), but a single Archean (2.56 Ga) core was also present. The xenocrystic zircons and the generally negative epsilon(Nd) values indicate that both terranes are composed of isotopically evolved continental crust. 相似文献
20.
Abstract: The Bidjovagge gold-copper deposit, northern Norway occurs in the lower Proterozoic Kautokeino greenstone belt, and consists of ten ore bodies in albite felsite, graphite schist and meta-diabase sills, along with a series of syenodiorite dykes. Calcite is one of the most important gangue minerals occurring within the ore veins. The early primary calcite samples from A, C and D ore bodies (copper–rich) show almost flat chondrite-normalised REE curves, and slightly positive Eu anomalies. A Sm-Nd isotope age of 1858 ± 72 Ma (2ρ) has been given based on fifteen primary calcite samples. The Sm-Nd age of calcite is in well agreement with previously published U-Pb davidite age of 1885 ±18 Ma (2ρ) and Sm-Nd davidite age of 1886 ± 88 Ma (2ρ). All these isotopic age data indicate that the gold-copper mineralisation may occur during or slightly after the peak of the Svecokarelian orogeny. Two late primary calcite samples from C and D ore bodies have flat chondrite-normalised LREE curves, positive HREE curves, and negative Eu anomalies. In contrast, most of the early primary calcite samples from B ore body (gold–rich) show an overall negative chondrite-normalised REE slope and negative Eu anomalies. Sm-Nd data on seven primary calcite samples from the B ore body are relatively scattered, and gave an isochrone age of 1809 ± 150 Ma (2ρ), identical to the age of the calcite samples from A, C and D ore bodies. Two late primary calcite samples from the B ore body have almost flat chondrite-normalised REE slope and negative Eu anomalies. REE patterns and eNd (T) values of calcites suggest that the ore fluids for the calcites from the A, C and D ore bodies derived their metals from mafic igneous rocks (diabase sills). For the secondary calcites from the C ore body, their relative high initial Nd (T) values at 1858 Ma imply that much more radiogenic Nd-component were incorporated during calcite crystallisation when another ore fluid emplaced. Combined Nd isotope data and REE geochemical features suggest that the isotopically more evolved source such as albite felsite and syn-genetic high level syenodiorite dykes were probably metal source for these calcites in the B ore body. Three samples of secondary calcite from the B ore body, which obviously deviated from 1809 Ma isochron are easily explained as products of post-ore hydrothermal events. 相似文献