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This paper investigated the geotechnical properties of smectite-rich shale, and its implications as foundation material. Ten expansive shale samples were collected from foundation materials at Akpugo in Nkanu West L.G.A. of Enugu State, southeast Nigeria. Samples were subjected to grading, Atterberg limits-cum-compaction tests, slake durability, specific gravity, permeability, undrained triaxial tests and x-ray diffraction scan. Fines and sand contents of the soil samples range from 51–97% and 3–49% respectively. Liquid limit, plastic limit and plasticity index have average values of 60.7, 19.1 and 43.3% respectively. Linear shrinkage and free swell showed average of 16.3% and 76%. These results are indicative of predominant clay soil with high plasticity, compressibility and water holding capacity. XRD scan established presence of smectite and illite clay minerals, confirming soil high plasticity, capable of causing instability in foundation soil. The shale achieved maximum dry density range between 1.79 and 1.94 kg/m3 at optimum moisture content range of 6.9–12.8%, indicating poor to fair foundation materials. The shale cohesion ranges from 15 to 30 kPa while the angle of friction ranges between 10° and 18°, signifying an average strength soil material. Samples slake durability index and specific gravity fall within 24–55% and 2.50–2.58 respectively, suggesting non-durable and weak soil. Permeability of the samples ranges between 7.36 ×10?6 and 4.77 ×10?8 cm/s which suggested low drainage capable of causing water-log at sites. Therefore, the shale could be generally classified as poor to fair foundation material, which on moisture influx experience reduction in strength due to deterioration of its constituent minerals, especially clay and cement materials during the lifespan of engineering structures. Authors therefore recommend modification of foundation soil, appropriate foundation design and good drainage control as ways of improving stability of engineering structures underlain by expansive shale.  相似文献   

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氧化还原条件是控制页岩岩性特征和有机质保存的重要因素之一,可以使用多种地球化学方法对其进行评估。为了探讨相关地球化学指标对海相页岩沉积环境氧化还原条件的适用性,对四川盆地长宁地区N208井筇竹寺组和龙马溪组20个岩心样品进行的总有机碳含量(TOC)、硫元素化学种和主微量元素含量测试结果显示:筇竹寺组和龙马溪组底部层段的有机碳含量总体较高,平均值分别为3.73%和3.50%;向上有机碳含量普遍变低,平均值分别为0.410%和1.70%。筇竹寺组页岩的硫元素化学种以还原态硫为主,揭示其沉积水体还原程度高;相较而言,龙马溪组页岩的还原态硫含量相对较低,表明其沉积水体的还原性比筇竹寺组弱,为相对的弱还原环境。结合微量元素富集系数构建的S-MoEF-TOC体系判识结果显示:筇竹寺组页岩整体上属于贫硫酸盐的厌氧环境,其底部为厌氧环境,向上还原程度变低;龙马溪组页岩总体为含硫酸盐的厌氧—贫氧环境,向上还原程度变低,表现为贫氧环境。这些分析结果可以为加深认识筇竹寺组和龙马溪组页岩层系的地球化学特征及页岩气资源潜力评价提供新的参考。  相似文献   

4.
蒙脱石的成岩演变与石油的初次运移   总被引:1,自引:1,他引:1  
王行信 《沉积学报》1985,3(1):81-91
自从鲍尔斯提出成岩过程中蒙脱石脱水对油气初次运移的重要性以后,许多学者对成岩过程中蒙脱石的脱水反应特征及在油气初次运移中的意义进行了研究和讨论。一般认为成岩过程中蒙脱石的脱水为石油初次运移创造了下列有利条件: 1.提供水介质来源; 2.重新产生孔隙度; 3.促进泥岩异常高压带的形成; 4.由于蒙脱石层间水的加入,提高了烃类和脂肪酸在水中的溶解度,促进了石油的运移。 成岩过程中蒙脱石析出层间水只是蒙脱石成岩演变的一个方面,如果仅以脱水量的多少和烃类在水中溶解度的概念来评价蒙脱石的成岩演变对油气运移的影响,这显然是不够的。 关于松辽盆地白垩系泥岩粘土矿物成岩演变特征与有机变质作用和油气分布的关系,可参阅作者的有关论文[1][2],这里不再赘述。  相似文献   

5.
中国南方奥陶纪-志留纪之交广泛沉积了以五峰组和龙马溪组为代表的笔石页岩。基于对重庆巫溪地区五峰组-龙马溪组底部页岩段中近400件页岩样品中笔石丰度的统计及100件页岩样品有机碳含量(TOC,%)的分析测试结果,选择其中23件不同笔石丰度与TOC的页岩样品开展页岩中笔石体与围岩(非笔石体部分)TOC的对比实验,并结合能谱分析测试结果,探讨笔石与有机质富集的关系。初步研究认为:①五峰组-龙马溪组页岩中笔石体的C、O等元素含量较高,其TOC明显高于围岩,是页岩有机质的贡献者之一;②五峰组-龙马溪组页岩全岩TOC与笔石丰度及笔石体TOC相关性均较差,而与围岩TOC相关性较好,这指示着页岩中笔石丰度对有机质富集影响较小。  相似文献   

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针对页岩油开展了广泛文献调研,在页岩油概念的提出、演化及研究历程基础上,对陆相页岩油资源量分布、类型和潜力及若干关键问题等研究进展进行了综述,提出了陆相页岩油效益开发面临的关键开发地质问题。具体如下:1)阐述了页岩油概念的由来及最新定义。国内外页岩油均历经三个发展阶段,对页岩油的理论认识不断深入,开发效果和水平逐渐提升。我国陆相页岩油资源丰富、潜力巨大,是今后一个时期的重点攻关对象。2)陆相页岩油可按不同方式进行分类。按成熟度演化阶段划分固态有机质阶段、滞留烃阶段、液态烃阶段、液态烃裂解天然气阶段等四类;按源储组合类型划分源储共存型、源储分离型和纯页岩型三类;按开发方式分为夹层型、混积型、页岩型和裂缝型四类。3)陆相页岩油在细粒岩分类及沉积模式、源储岩石微观特征、富集机制、“七性特征”和工业化开采技术等方面取得了较大的进展。4)陆相页岩油源储结构表现出极强的非均质性,亟待加强细粒页岩沉积超高频基准面旋回对比模式、半深湖—深湖相低级次构型单元成因及分布模式、相控储层质量差异分布模式和地质工程一体化及甜点快速评价等开发地质方面的研究,以提高页岩油开发经济效益和采收率。  相似文献   

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阿尔金山前侏罗系出露大套厚层的暗色泥页岩,生烃潜力优越,具备陆相页岩气形成条件,是有利的勘探接替区。通过野外地质调查、样品采集和测试分析,研究下—中侏罗统泥页岩的沉积展布、有机地球化学特征及储集性能,并探讨了该区页岩气的勘探潜力。研究表明: 富有机质泥页岩主要处于滨浅湖—半深湖相、沼泽相沉积环境中,其在平面上呈NE向展布,单层厚度和累计厚度均较大; 泥页岩的有机质类型主要为Ⅱ1、Ⅱ2型干酪根; TOC含量为0.55%~10%,平均为2.28%; 镜质体反射率(Ro)为1.0%~1.6%,平均为1.269%,处于成熟—高成熟阶段,为页岩气藏形成提供良好的生烃条件; 其矿物特征表现为脆性矿物含量高,大于51%,有利于后期的水力压裂改造和页岩气开采; 通过扫描电镜观察,泥页岩储层发育微孔隙及微裂缝,为页岩气提供了良好的储集空间和运移通道。初步预测,后期改造相对较弱的月牙山地区为页岩气勘探的有利目标区。  相似文献   

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阿尔金山前侏罗系出露大套厚层的暗色泥页岩,生烃潜力优越,具备陆相页岩气形成条件,是有利的勘探接替区。通过野外地质调查、样品采集和测试分析,研究下—中侏罗统泥页岩的沉积展布、有机地球化学特征及储集性能,并探讨了该区页岩气的勘探潜力。研究表明: 富有机质泥页岩主要处于滨浅湖—半深湖相、沼泽相沉积环境中,其在平面上呈NE向展布,单层厚度和累计厚度均较大; 泥页岩的有机质类型主要为Ⅱ1、Ⅱ2型干酪根; TOC含量为0.55%~10%,平均为2.28%; 镜质体反射率(Ro)为1.0%~1.6%,平均为1.269%,处于成熟—高成熟阶段,为页岩气藏形成提供良好的生烃条件; 其矿物特征表现为脆性矿物含量高,大于51%,有利于后期的水力压裂改造和页岩气开采; 通过扫描电镜观察,泥页岩储层发育微孔隙及微裂缝,为页岩气提供了良好的储集空间和运移通道。初步预测,后期改造相对较弱的月牙山地区为页岩气勘探的有利目标区。  相似文献   

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Airborne geophysical (aeromagnetic and gravity) data of Nsukka area was interpreted qualitatively and quantitatively with the aim of determining the susceptibilities of rock types, depth/mass of the anomalous bodies, possible cause of the anomalies and type of mineralization prevalent in the area. The estimated depths from forward and inverse modeling of aeromagnetic data for profiles 1, 2, 3, 4 and 5 were 1200m, 1644m, 1972m, 2193m and 2285m respectively. The respective susceptibility values were 0.0031, 0.0073, 1.4493, 0.0069 and 0.0016. These indicate dominance of iron rich minerals like limonite, hematite, pyrrhotite, and pyrite and forms lateritic caps on sandstones. SPI depth result ranges from 151.6m minimum (shallow magnetic bodies) to 3082.7 m maximum (deep lying magnetic bodies). Euler depths for the four different structural index (SI = 0.5, 1, 2, 3) ranges from 7.99 to 128.93m which are depths of shallow magnetic sources resulting from lateritic bodies in the outcrops in the study area. From the gravity data interpretation, Euler depth estimation reveals that depth to anomalous bodies ranges from 89.13 to 2296.92m. Density of the causative body obtained from modeling results for profile 1 was 1498kg/m3, which is in the range of clay material and the depth was about 923m. From models 2, 4 and 5, the densities of the causative bodies were 3523, 4127 and 3707kg/m3, while depths to the surface were about 604, 815 and 1893m respectively. These density ranges correspond to that of ironstone. From model three, the density of causative body obtained was 2508kg/m3, located at a depth of about 268m below the surface. This work has shown that Nsukka area is underlain by thick strata of shales, sandstones and ironstones, which together are suitable for ceramic production, and sufficiently thick sediments suitable for hydrocarbon accumulation.  相似文献   

10.
Four organic-rich shale units of the Proterozoic Vindhyan sedimentary succession have been scanned to reveal their origin and hydrocarbon potential. The wavy-crinkly nature of the carbonaceous laminae is suggestive of a microbial mat origin of the shales. These shales are thus different from Phanerozoic black shales which typically exhibit planar laminae. The hydrocarbon potential of the black shale units has been evaluated by Rock-Eval pyrolysis. Total organic carbon content of many of the shales exceeds 1%. The meanT max for the black shales translate to a vitrinite reflectance range of 2.05-2.40% Rm based on standard conversion techniques. These shales have reached the catagenetic stage near the beginning of anthracite formation.  相似文献   

11.
扬子地台寒武系泥页岩甲烷吸附特征   总被引:4,自引:0,他引:4  
宋敍  王思波  曹涛涛  宋之光 《地质学报》2013,87(7):1041-1048
对采自扬子地区寒武系黄柏岭组、幕府山组和牛蹄塘组的泥页岩进行了甲烷吸附性能及影响因素研究。所分析页岩的TOC含量在1.08%~4.16%之间;粘土矿物含量在36.7%~62.3%之间。页岩样品甲烷吸附量测定结果显示,寒武系页岩甲烷最大理论吸附量与页岩TOC含量之间总体上呈正相关性,表明有机质丰度是控制页岩甲烷吸附能力的重要因素。而粘土矿物总含量与页岩甲烷最大理论吸附量之间缺乏相关性,仅蒙脱石含量与页岩甲烷最大理论吸附量呈正相关性,显示个别粘土矿物具有较强的甲烷吸附及影响页岩吸附性能的作用。寒武系不同地区页岩吸附性能存在显著差异,遵义牛蹄塘组页岩甲烷最大理论吸附量在2.76~5.30mL/g之间;南京幕府山组页岩甲烷最大理论吸附量在1.36~4.35mL/g之间;池州黄柏岭组泥页岩甲烷最大理论吸附量在1.63~2.72mL/g之间。此外,寒武系不同地区页岩有机碳含量与甲烷吸附量之间关系变化很大,显示页岩吸附量不仅受有机质丰度类型的影响,而且受有机质成熟度、区域地质演化以及粘土矿物吸附等多种因素制约。  相似文献   

12.
The Upper Ordovician Wufeng-Lower Silurian Longmaxi and the Lower Cambrian Qiongzhusi shales are the major targets for shale gas exploration and development in China. Although the two organic-rich shales share similar distribution ranges and thicknesses, they exhibit substantially different exploration and development results. This work analyzed the nanopore structures of the shale reservoirs in this region. Pore development of 51 shale samples collected from various formations and locations was compared using the petromineralogical, geochemical, structural geological and reservoir geological methods. The results indicate that the reservoir space in these shales is dominated by organic pores and the total pore volume of micropores, mesopores, macropores in different tectonic areas and formations show different trends with the increase of TOC. It is suggested that organic pores of shale can be well preserved in areas with simple structure and suitable preservation conditions, and the shale with smaller maximum ancient burial depth and later hydrocarbon-generation-end-time is also more conducive to pore preservation. Organic pore evolution models are established, and they are as follows: ① Organic matter pore development stage, ② Early stage of organic matter pore destruction, and ③ late stage of organic matter pore destruction. The areas conducive to pore development are favorable for shale gas development. Research results can effectively guide the optimization and evaluation of favorable areas of shale gas.  相似文献   

13.
鄂尔多斯盆地下寺湾地区延长组页岩气储层非均质性特征   总被引:1,自引:0,他引:1  
王香增  张丽霞  高潮 《地学前缘》2016,23(1):134-145
鄂尔多斯盆地三叠系延长组长7、长9页岩是页岩油气勘探的重要层位,本文在岩心观测、薄片观察、脉冲渗透率测试、有机碳含量测试、气体组分分析、测井解释方法的基础上,对陆相页岩层内岩性、地化参数、微观孔隙结构、力学参数的非均质特征进行研究。研究认为陆相页岩储层砂质纹层发育密度和频率值较高,纹层中的大孔隙与页岩中的中孔和微孔构成复杂的孔隙体系,造成页岩储层层内非均质性极强,可有效改善页岩层系的物性,为游离气的富集和运移提供有利空间和有效通道,对游离气的渗流和富集具有积极意义。非均质程度较弱的页岩段,砂质纹层发育程度低,物性致密,排烃能力最弱,富集较多的吸附气。陆相页岩成储机制受控于其较强的非均质性,同时页岩强非均质性段,脆性矿物含量高,有利于页岩储层的压裂开采。  相似文献   

14.
In this article, we describe the geological features of the Ediacaran (upper Sinian), lower Cambrian and lower Silurian shale intervals in the Upper Yangtze Platform, South China, and report on the gas potential of 53 samples from these major marine shale formations. Reflected light microscopy, total organic carbon (TOC) measurement, Rock-Eval, carbon isotope ratio analysis, thermovaporization gas chromatography (Tvap-GC), and open pyrolysis gas chromatography (open py-GC) were used to characterize the organic matter. Measured TOC in this research is normally >2% and averages 5%. TOC contents are roughly positively correlated with increasing geological age, i.e. lower Silurian shales exhibit generally lower TOC contents than lower Cambrian shales, which in turn commonly have lower TOC contents than Ediacaran shales. Kerogen has evolved to the metagenesis stage, which was demonstrated by the abundant pyrobitumen on microphotographs, the high calculated vitrinite reflectance (Ro = 3%) via bitumen reflectance (Rb), as well as δ13 C of gas (methane) inclusions. Pyrolysates from Tvap-GC and open py-GC are quantitatively low and only light hydrocarbons were detected. The lower Silurian shale generally exhibits higher generation of hydrocarbon than the lower Cambrian and Ediacaran shale. Cooles’ method and Claypool’s equations were used to reconstruct the original TOC and Rock-Eval parameters of these overmature samples. Excellent original hydrocarbon generation was revealed in that the original TOC (TOCo) is between 5% and 23%, and original S1+S2 (S1o+S2o) is ranging from 29 to 215 mg HC/g rock.  相似文献   

15.
以湘中坳陷涟源凹陷上二叠统龙潭组和大隆组海陆过渡相泥页岩为研究对象,重点选取12块典型泥页岩钻井岩心样品开展有机碳含量、岩石热解、X射线衍射、密度法孔隙度、高压压汞、二氧化碳和氮气吸附等测试分析,利用氩离子抛光-场发射扫描电镜(FE-SEM)观察了泥页岩孔隙特征,通过定性描述和定量测定相结合的方法研究了海陆过渡相泥页岩纳-微米级孔隙结构特征及孔隙发育影响因素.研究结果表明:龙潭组和大隆组泥页岩有机碳含量均较高,热演化程度处在凝析油和湿气生成阶段早期,对应Ro为1.22%~1.43%;泥页岩孔隙类型主要为粒间孔、粒内孔、有机孔和微纳米缝.龙潭组与大隆组样品在孔隙形态、孔隙大小和影响因素上均有差异:龙潭组样品氮气吸附滞回环开口宽,有机孔形态多为圆形和椭圆形,孔径较大;大隆组样品氮气吸附滞回环开口窄,有机孔形态多为不规则状,孔径较小;龙潭组泥岩和大隆组泥页岩样品有机碳含量与黏土矿物含量呈正相关关系,2套样品的微孔孔隙积体与有机碳和黏土矿物含量均呈正相关性;龙潭组样品介孔+宏孔的孔隙体积与有机碳和黏土矿物含量呈正相关性,与石英+长石含量呈负相关性;大隆组样品中的碳酸盐矿物对其孔隙性有明显影响,大隆组样品介孔+宏孔孔隙体积与有机碳、黏土矿物和石英+长石含量相关性不明显.   相似文献   

16.
页岩油分类与评价   总被引:11,自引:1,他引:10       下载免费PDF全文
页岩油是以游离(含凝析态)、吸附及溶解(可溶解于天然气、干酪根和残余水等)态等多种方式赋存于有效生烃泥页岩地层层系中且具有勘探开发意义的非气态烃类。根据泥页岩地层中所含烃类相态、成因机理及勘探开发等特点,将页岩类油气划分为页岩气和页岩油等两类八种。结合页岩油特点,指出了我国页岩油形成条件和分布规律,即规模分布的有效生烃泥页岩、形成于深水-半深水相的富有机质泥页岩、较高的有机质丰度和适当的热演化程度以及较好的基质物性条件等是页岩油形成的主要条件。建立了中国陆相断陷湖盆页岩油发育模式,指出概率体积法可以作为页岩油资源评价的主要方法,提出了页岩油远景区、有利区及目标区优选的参数体系和标准。作为非常规油气能源的主要类型之一,页岩油将会对我国能源结构产生重要影响。  相似文献   

17.
目前针对桂中坳陷早石炭世富有机质泥页岩的生烃潜力方面研究很少,严重制约了该区以页岩气为主的非常规油气勘探.本研究对鹿寨县城西石炭系鹿寨组泥页岩系统取样分析,从有机碳含量、岩石热解、有机碳同位素组成、抽提物正构烷烃组成特征及泥岩镜质体反射率多个方面讨论了该套泥页岩的生烃潜力;结合区域构造演化史总结了与下石炭统岩关阶泥页岩密切相关的3种近源气藏赋存模式.研究结果表明:泥页岩的TOC值分布于0.25%~15.67%,其中强制海退前沉积的泥页岩富含有机质,TOC值均大于2%,TOC值与氯仿沥青"A"、生烃潜量及总烃呈弱正相关关系.泥页岩的有机质类型主体为Ⅱ型;泥页岩的Ro值分布于1.72%~2.78%,处于过成熟阶段.泥页岩上下岩性组合特征及桂中坳陷现今所处的构造位置表明,坳陷中部对冲构造区为有利的近源气藏形成区,背冲构造区为较差区;坳陷边缘逆冲推覆构造区为存在岩性圈闭的近源气藏形成区.   相似文献   

18.
Shale gas has been the exploration focus for future energy supply in South Africa in recent time. Specifically, the Permian black shales of the Prince Albert, Whitehill, Collingham, Ripon and Fort Brown Formations are considered to be most prospective rocks for shale gas exploration. In this study,outcrop and core samples from the Ecca Group were analyzed to assess their total organic carbon(TOC), organic matter type, thermal maturity and hydrocarbon generation potential. These rocks have TOC ranging from 0.11 to 7.35 wt%. The genetic potential values vary from 0.09 to 0.53 mg HC/g,suggesting poor hydrocarbon generative potential. Most of the samples have Hydrogen Index(HI) values of less than 50 mg HC/g TOC, thus suggesting Type-Ⅳ kerogen. Tmax values range from 318℃ to601℃, perhaps indicating immature to over-maturity of the samples. The vitrinite reflectance values range from 2.22% to 3.93%, indicating over-maturity of samples. Binary plots of HI against Oxygen Index(OI), and HI versus Tmax show that the shales are of Type II and mixed Type Ⅱ-Ⅲ kerogen.Based on the geochemical data, the potential source rocks are inferred as immature to over-matured and having present-day potential to produce gas.  相似文献   

19.
Sa'ar–Nayfa reservoir is mainly made up of carbonate sediments with bands of shale that contain a substantial amount of proven oil in the Hiswah Oilfield, Sayun–Masila Basin, eastern Yemen. Several vertical wells have been drilled and penetrated these sequences. This study is concerned on the petrophysical evaluation and well log analysis of the Lower Cretaceous of 11 wells at the Hiswah Oilfield, Hadramawt Governorate, eastern Yemen. Computer-assisted log analyses were used to evaluate the petrophysical parameters such as shale volume, total porosity, effective porosity, water saturation, hydrocarbon saturation, flushed zone saturation and reservoir and pay flags. Cross-plots of the petrophysical parameters versus depth were illustrated. The Lower Cretaceous Sa'ar–Nayfa reservoir reflects that the matrix components are mainly carbonates and shales. Moreover, the lithological-geologic model reflected that these shales are strongly affecting the porosity and, consequently, the fluid saturation in the Sa'ar–Nayfa reservoir. In this study, the thickness of the Sa'ar–Nayfa reservoir increases from central toward north-eastern and north-western parts within the Hiswah Oilfield. The porosities analyses of the investigation of the Sa'ar–Nayfa reservoir for the 11 studied wells concluded that the average total porosity ranges from 5.4 % to 16.8 % while the effective porosity ranges from 5.2 % to 14.8 %. Water saturation of the Sa'ar–Nayfa reservoir ranges from 6.9 % to 75.8 %. On the other hand, hydrocarbon saturation matches with water saturation in a reverse relationship. Sa'ar–Nayfa reservoir is interpreted as good quality reservoir rocks with high average effective porosity reaching to 20 % and high hydrocarbon saturation exceeding 93 %. The Sa'ar–Nayfa reservoir reveals promising reservoir characteristics especially the upper reservoir unit, which should be taken into consideration during future development of the oilfields area. The hydrocarbon saturation map of the Sa'ar–Nayfa reservoir shows a regular pattern of distribution with a general increasing to the northeast, northwest and east directions while decreasing southwest wards, recording the maximum value of 93.1 % at the Hiswah-21 well.  相似文献   

20.
页岩微观孔隙结构是影响页岩气储层储集能力的重要因素。为评价川南地区下寒武统筇竹寺组页岩性质,基于井下 岩心样品、钻井资料,运用普通扫描电镜和氩离子抛光-场发射扫描电镜观测、Image J2x软件分析、低温CO2和N2 吸附、 高压压汞实验方法,对川南地区筇竹寺组页岩气微观孔隙成因类型、孔隙结构特征及其影响因素进行了研究。研究结果表 明,川南地区下寒武统筇竹寺组页岩孔隙度为0.25%~5.80%,平均为2.49%;发育多种成因类型微观孔隙,以粒间孔为 主,粒内孔、有机质孔和微裂缝次之,页岩微观孔隙总面孔率为3.58%~5.92%;川南地区筇竹寺组页岩总孔容为(2.86~ 12.55)×10-3 mL/g,总比表面积为2.727~21.992 m2/g,孔径主要分布于0.30~1.00 nm、2.5~4.7 nm和55~70 nm这三个区间,微 孔(<2 nm)和介孔(2~50 nm)是筇竹寺组页岩气储集空间的主体,孔隙结构形态主要为圆孔、楔形孔、平板狭缝型孔和混合 型孔结构。页岩孔隙度及总比表面积与TOC、脆性矿物含量呈正相关关系,页岩微孔孔容及比表面积与TOC呈正相关关 系,页岩孔隙度、总孔容及总比表面积与R0、粘土矿物含量呈负相关关系。  相似文献   

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