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本提出了不采用同位素示踪剂测定铀，钍同位素比活度的方法。用标准方法准确的测定地质样品中的铀，钍含量及＾２３４Ｕ／＾２３８Ｕ，＾２３０Ｔｈ／＾２３２Ｔｈ的活度比值，再应用铀，钍系的衰变特性，推导出计算样品中＾２３４Ｕ，＾２３８Ｕ，＾２３０Ｔｈ和＾２３２Ｔｈ经活度的方法，本方法计算所得之结果与＾２３２Ｕ示踪法对比。均在１σ范围内，符合很好。 相似文献
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薩卡文曾在1959年合成了铀试剂Ⅲ,并建议用光电比色法测定釷、铀、锆。在著作中提出了于鋯石中不用分离居外元素(包括锆元素)而测定钍的方法。在论文中叙述了在岩石中使钍呈氟化物分出后进行钍的测定。在著作中詳细地阐明了铀试剂Ⅲ与钍的反应操作条件,并提出了用这些试剂以萃取光电比色法测定钍。文章也谈到使钍吸附在阳极上分离后测定少量钍。 相似文献
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铀系组分法是测定火山岩不同组分中的２３０Ｔｈ／２３２Ｔｈ值和２３８Ｕ／２３２Ｔｈ值、计算年龄的方法。岩石中的各组分是用磁选或浮选分离的。经过论证，组分法与等时线方法是等价的，但不需要从全岩中精选纯的单矿物，不会发生铀和钍同位素的分馏。根据组分法模式测定了云南腾冲盆地北来凤山、老龟坡山和马鞍山火山岩样品的年龄，分别为０．１１ＭａＢ．Ｐ．、５１０００。Ｂ．Ｐ．和２５０００ａＢ．Ｐ，与地层顺序相吻合。组分法对于年青火山岩定年有着极大的潜力。 相似文献
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贵州某些层控铀矿成矿时代 总被引：2，自引：0，他引：2
近几年,作者及其他一些地质工作者先后于贵州6504、6151、6915、6916及6760l等层控铀矿床、矿点内采集了同位素分析样品数十个,获得了一批U-Th-Pb法同位素地质年龄数据。本文简述了各矿床、矿点的基本地质概况,并对所有同位素地质年龄数据进行了综台整理。用于同位素地质年龄测定的样品主要为沥青铀矿或含沥青铀矿的寓铀矿石。经钍含量检查测定,多数样品内含钍量极低。为了避免扣除普通铅含量对单样年龄计算带来的影响,多数矿床、矿点的铀矿化年龄值用U-Pb等时线法求得。 相似文献
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本文推荐一种用萃取色谱法测定地质样品中的铀和钍的方法。溶样后，用Fe(OH)3沉淀法预富集铀和钍，再用UTEVA树脂分离，使分离的铀和钍电沉积在不锈钢圆盘上，再用α能谱法测定。用晶质铀矿、珊瑚和花岗岩标准物质评价该法。测得的铀和钍含量及^234U/^238U和^230Th/^234U活性比值与标准值十分一致。发现钚的存在会干扰分离，但利用氨基磺酸亚铁还原就可解决此问题。该法的化学回收率与阴离子交换法相近，但萃取色谱法能用较少试剂进行较快分离。 相似文献
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本文介绍了测定锰结核中铀和钍的方法。样品用高氯酸和氢氟酸混合酸溶解后,铀从6M盐酸中被吸附在Dowex-1(氯型)强碱性阴离子交换树脂上。淋洗液蒸干后,残渣溶解在7M硝酸-0.25M草酸中,然后用Dowex-1(硝酸根型)阴离子交换树脂定量分离钍。用6M盐酸淋洗钍,并用铀试剂Ⅲ分光光度测定之。用1M盐酸将铀从氯型树脂上淋洗下来,然后再和铁、钼以及其它在Dowex-1柱(氯型)上共同被淋洗出的元素分离。介质由50％(V/V)四氢呋喃,40％(V/V)甲基乙二醇和6M盐酸组成。用相同组成的混合液和纯6M盐酸溶液洗涤树脂除去铁和钼后,被吸附的铀用1M盐酸淋洗出,再用荧光法测定之。本法已非常成功地用于太平洋中60个锰结核样品中PPm量级铀和钍的测定。 相似文献
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一直以来,利用铀、钍、钾同位素的γ能谱寻找铀矿是铀矿地质重要的放射性物探手段。同样,水系沉积物化探中铀、钍、钾元素作为铀矿化探重要指示元素,在铀矿资源潜力预测评价中亦发挥了重要作用。笔者论述了水系沉积物铀、钍、钾元素在铀矿预测评价中的指示作用和异常特点,以及中国铀、钍、钾元素地球化学场分布特点和规律,将铀、钍、钾异常按累频占比划分为特高异常(异常内带)、高异常(异常中带)、异常(异常外带)和高背景,同时,论证了铀、钍、钾异常分布与铀成矿关系。可以看出,铀、钍、钾异常分布有明显的区域特征,现有的异常分布区与我国四大类型铀矿产区高度一致,其异常分布对我国铀、钍矿资源预测评价具有重要意义。 相似文献
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460火山岩盆地的地质发展与铀,钍演化 总被引：2，自引：0，他引：2
在总结460火山岩盆地地质特征和构造-岩浆活动发展历史的基础上。研究了各时代岩石中铀、钍的演化规律。提出该区晚太古代基底岩石的钾质混合岩化所引起的铀、钍增量是影响其后盖屋火山岩演化和铀成矿的物质基础;具有壳源重熔成因的上侏罗统酸性火山岩盖层,由于分布广泛,厚度巨大,有多种告石组台和多样的岩性序列,以及铀、钍含量高,构成了该区铀成矿有利的地层背景;燕山晚期沿区域断裂侵入的高铀酸性次火山岩或小侵入体,是该区成矿定位的决定因崇,它本身常成为赋矿的有刊围岩;后期热液铀成矿是使地层和岩体中铀和钍最终发生分离的主要地质作用。 相似文献
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Gregory J. Holk T. Kurtis Kyser Don Chipley Eric E. Hiatt Jim Marlatt 《Journal of Geochemical Exploration》2003,80(2-3):297-320
Lead isotope ratios and associated trace element concentrations (U, Th and Pb) extracted by partial-leaching with 2% nitric acid from Proterozoic sandstones and basement rocks reveal much about the fluid evolution of sedimentary basins hosting unconformity-type uranium deposits. In addition, these techniques have great potential as a guide for exploration of uranium and other types of deposits in basins of any age. Isotope ratios of Pb in Proterozoic sandstones from basins known to contain high-grade uranium deposits are radiogenic at key geological localities and settings distal to known mineralization and particularly in altered zones proximal to mineralization. Sandstones completely cemented by quartz overgrowths typically have non-radiogenic Pb isotope ratios, indicating early closure of porosity and isolation of these rocks from later fluid events. Alternatively, the unconformity served as both a source of uranium and radiogenic Pb as well as an avenue for late-stage (<250–900 Ma) fluid flow. The mafic volcanic units, which are relatively reducing lithologies and therefore have removed uranium from basinal brines, have uranium-supported radiogenic Pb isotope ratios. Comparison of 238U/206Pb and 206Pb/204Pb ratios is useful in determining the timing and nature of U and Pb migration before, during and after mineralization in these basins. This comparison can be used to delineate the presence of radiogenic Pb isotope ratios that are not internally supported by uranium and thorium in rocks, eventually providing the explorationist with geochemical vectors that point toward sites of high potential for economic uranium mineralization. 相似文献
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相山火山塌陷盆地基底变质岩U的地球化学研究 总被引：7，自引：0，他引：7
本文对相山火山塌陷盆地基底变质岩U的丰度及赋存形式进行了研究。基底变质岩中U主要以分散吸附状态的非结构U存在于基质或矿物粒间,少量的U以微粒、超微粒的独立铀矿物形式存在于矿物的裂隙中或粒间。U－Pb同位素的研究表明变质岩中的U在变质作用及后期的其它地质作用中发生了重新分配,并有不同程度的丢失,原始U含量较高。火山岩与变质岩的地球化学特征有许多相似之处。因此,作者认为基底变质岩有可能为成矿提供U源。 相似文献
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陈蔡群变质岩铀的地球化学特征 总被引：1，自引：0，他引：1
本文对陈蔡群变质岩铀的丰度及其赋存形式进行了研究。铀主要以分散吸附状态的方式存在。少量的铀以微粒、超微粒的铀矿物或含铀矿物的方式赋存在矿物裂隙或粒间,铀在变质作用中发生了重新分配。U-Pb同位素的研究表明岩石中的铀在变质作用及后期的其它地质作用中有大量的丢失,原始铀含量高。含矿火山岩与陈蔡群变质岩的地球化学特征对比表明,两者的地球化学特征有许多相似之处。作者认为,陈蔡群是形成铀矿床的可能铀源层之一。 相似文献
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M. Th. S. Heikal B. T. El-Dosuky M. F. Ghoneim M. I. Sherif 《Arabian Journal of Geosciences》2013,6(9):3229-3239
The present study examines the natural radioactivity in basements rocks including granites and associated dikes besides stream sediments in Sharm El Sheikh area. Two main rock units are concerned; granites pertaining to Younger Granites of Precambrian age and clastic sedimentary rocks related to Miocene and Pliocene ages. This area is traversed by two shear zones that were delineated as the master fractures trending NW and NNE and controlling uranium and thorium enrichment in granites and dikes. The field and laboratory radiometric measurements revealed radiometric anomalies, in particular, along shear zones. The results of radiometric analyses including concentrations of equivalent uranium (eU), equivalent thorium (eTh), Ra, and K radionuclides as well as the calculated ratios eTh/eU and eU/Ra for representative samples belonging to all rock varieties, revealed that the felsic dikes have the highest values of the average radionuclides potential followed by the alkali feldspar granites, while the mafic dikes display the lowest radioactivity potential. On the other hand, the trends defined in the variation of uranium and thorium reflects the amount of remobilization of uranium that has occurred within the plutons. The eTh and eU/eTh ratios shows a negative correlation, suggesting that distribution of uranium and thorium was at least controlled by magmatic differentiation, while, the positive correlation between eU and eU/eTh ratios indicates enrichment of uranium through post magmatic processes. Some precautions and recommendations are proposed to avoid any possible environmental impacts from shear zone areas with high intensity of natural radiation sources. 相似文献
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Accurate assessment of deep geothermal resources remains a challenge from the practical point of view. Parameter uncertainties and partial knowledge of initial conditions limit the prediction of subsurface temperatures using a variety of thermal models strongly unreliable, and the temperature is highly dependent on the radiogenic heat production in the geological layers mainly affected by a number of factors including the concentrations of uranium, thorium and potassium, and rock density. In this paper, geostatistical methods were applied to investigate the spatial distribution of radiogenic elements (e.g., uranium, thorium, potassium) and their corresponding concentrations and radiogenic heat production. A representative region measuring 35 km?×?80 km in the southwestern Québec, and covering the domains of Portneuf-Mauricie, Morin Terrane and Parc des Laurentides in the Grenville Province was selected for this study because of its easy accessibility. Analysis results show that the concentrations of uranium, thorium and potassium for most rocks of the Grenville basement in the research region are in the range of 1–2 ppm, 3–10 ppm and 1–4%, respectively. Furthermore, 90% of the total samples analysed in this study show a uranium concentration of less than 3 ppm, 64% of the samples show a thorium concentration of less than 5 ppm, and 56% of the samples show a potassium concentration of less than 3%. This paper engaged both the ordinary kriging interpolation and sequential Gaussian simulation (SGS) methods to study the spatial distribution of radiogenic elements. Using density data for specific rocks, the distribution of radiogenic heat production in the study area of the southwestern Grenville Province was also simulated using the SGS method. Conclusively, results show that the difference between the minimum and the maximum value of radiogenic heat production is 30%, considering a significant proportion of heterogeneity in rock density. 相似文献