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1.
The thermal waters at the Heybeli (K?z?lkirse) low-temperature geothermal field located in the Afyonkarahisar Province (western Turkey) are discharged from Paleozoic recrystallized limestone. The temperature, specific electrical conductivity, and pH values of the thermal waters are within the range of 28.9 to 54.7 °C, 587 to 3580 μS/cm, and 6.32 to 7.37, respectively. The Heybeli geothermal system is fed by meteoric waters. The waters are heated at depth by high geothermal gradient caused by the neotectonic activity in the deep and ascend to the surface through fractures and faults by convection. The thermal waters are of Na-Ca-HCO3-SO4 type and their chemical composition of the waters is mainly controlled by water-rock interaction and mixing processes. The δ18O, δ2H and tritium compositions show that the thermal waters are of meteoric origin and the residence time at the reservoir is longer than 50 years. Isotope data (δ34S and δ13C) indicate recrystallized limestones as origin of CO2 and structural substitution of sulfate into marine carbonates (CAS) as origin of sulfur. Chemical, \( {\updelta}^{18}{\mathrm{O}}_{\left({\mathrm{SO}}_4-{\mathrm{H}}_2\mathrm{O}\right)} \) isotope geothermometers and mineral equilibrium diagrams applied to thermal waters gave reservoir temperatures between 62 and 115 °C. Saturation index calculations show that the most expected minerals causing scaling at outflow conditions during the production and utilization of Heybeli geothermal waters are calcite, aragonite, dolomite, quartz, and chalcedony. 相似文献
2.
The deep water feeding wet-steam wells in four high-temperature geothermal areas in Iceland have highly variable salinity as reflected in the chlorine concentrations which vary from 20 to 19000 ppm. Using available values for equilibrium constants, the activities of 26 chemical species involving the major components of the reservoir water have been calculated and quantitative evaluations of solute/ solute, mineral/solute chemical equilibria in these geothermal systems have been made.The unflashed reservoir water is just saturated with calcite. The saline geothermal waters, which represent heated sea-water, are just saturated with anhydrite, but the dilute waters, which are of meteoric origin, are somewhat undersaturated with this mineral. The fluoride mobility is thought to be limited by an ionic exchange reaction where F? replaces some of the OH? in the layered silicates. The pH of the unflashed reservoir water is governed by ionic exchange equilibrium in which all the major cations participitate. At a given temperature it seems likely that the activity of one cation fixes the activities of all the other major cations and hydrogen ion. If this is so and we take all the other chemical equilibria which have been demonstrated to exist for granted, it turns out that the major element composition of the unflashed high-temperature geothermal waters is controlled by two independent variables only. These variables are the temperature and the supply to the water of the incompatible element chlorine, incompatible indicating that this element is not incorporated in the geothermal minerals. 相似文献
3.
Aysen Davraz 《Environmental Geology》2008,54(3):615-628
Thermal waters of the Usak area have temperatures ranging from 33 to 63°C and different chemical compositions. These waters
hosted by the Menderes Metamorphic rocks emerge along fault lineaments from two geothermal reservoirs in the area. The first
reservoir consists of gneiss, schists, and marbles of the Menderes Metamorphic rocks. The recorded reservoir is Pliocene lacustrine
limestone. Hydrogeochemical studies indicate that thermal waters were mixed with surface waters before and/or after heating
at depth. The results of mineral equilibrium modeling indicate that all the thermal waters are undersaturated at discharge
temperatures for gypsum, anhydrite, and magnesite minerals. Calcite, dolomite, aragonite, quartz, and chalcedony minerals
are oversaturated in all of the thermal waters. Water from the reservoir temperatures of the Usak area can reach upto120°C.
According to δ18O and δ2H values, all thermal and cold groundwater are of meteoric origin. 相似文献
4.
《International Geology Review》2012,54(9):1032-1058
Subsurface reservoir temperatures of two important Mexican geothermal systems (Los Azufres and Las Tres Vírgenes) were estimated by applying all available solute geothermometers for 88 and 56 chemical data measurements of the spring waters and fluids of the deep geothermal wells, respectively. Most of the chemical data for spring water of these two geothermal fields are for HCO3 water, followed by SO4 and Cl types. For the Los Azufres geothermal field (LAGF), the reservoir temperatures estimated by Na-K geothermometers for springs of HCO3 and SO4 waters, and by Na-Li and Li-Mg geothermometers for Cl water, are close to the average bottom-hole temperature (BHT) of the geothermal wells. However, all reservoir temperatures for spring waters from the Las Tres Vírgenes geothermal field (LTVGF) estimated by all solute geothermometers indicated significantly large differences (low temperatures) compared to the BHT. Evaluation of inferred reservoir temperatures for spring waters of the LAGF and LTVGF suggests that not all springs nor all solute geothermometers provide reliable estimation of the reservoir temperatures. Even though chemical equilibrium probably was not achieved in the water–rock system, Na-K geothermometers for HCO3 water (peripheral water mainly of meteoric origin with little geothermal component) and SO4 water (geothermal steam heated) and Na-Li and Li-Mg geothermometers for Cl-rich spring water (fully mature geothermal water) of the LAGF indicated reservoir temperatures close to the BHT. However, in comparison with the geothermometry of spring water of the LAGF and LTVGF, fluid measurements from geothermal wells of these two fields indicated reservoir temperatures in close agreement with their respective BHTs. For the best use of the solute geothermometry for spring water, it is advisable to: (1) chemically classify the springs based on water types; (2) identify and eliminate the discordant outlier observations by considering each water type as a separate sampled population; (3) apply all available solute geothermometers employing a suitable computer program such as SolGeo instead of using some specific, arbitrarily chosen geothermometers; and (4) evaluate the temperatures obtained for each solute geothermometer by considering the subsurface lithology, hydrological conditions, and BHTs or static formation temperatures whenever available. 相似文献
5.
The reservoir temperature and conceptual model of the Pasinler geothermal area, which is one of the most important geothermal areas in Eastern Anatolia, are determined by considering its hydrogeochemical and isotope properties. The geothermal waters have a temperature of 51 °C in the geothermal wells and are of Na–Cl–HCO3 type. The isotope contents of geothermal waters indicate that they are of meteoric origin and that they recharge on higher elevations than cold waters. The geothermal waters are of immature water class and their reservoir temperatures are calculated as 122–155 °C, and their cold water mixture rate is calculated as 32%. According to the δ13CVPDB values, the carbon in the geothermal waters originated from the dissolved carbon in the groundwaters and mantle-based CO2 gases. According to the δ34SCDT values, the sources of sulfur in the geothermal waters are volcanic sulfur, oil and coal, and limestones. The sources of the major ions (Na+, Ca2+, Mg2+, Cl?, and HCO3 ?) in the geothermal waters are ion exchange and plagioclase and silicate weathering. It is determined that the volcanic rocks in the area have effects on the water chemistry and elements like Zn, Rb, Sr, and Ba originated from the rhyolite, rhyolitic tuff, and basalts. The rare earth element (REE) content of the geothermal waters is low, and according to the normalized REE diagrams, the light REE are getting depleted and heavy REE are getting enriched. The positive Eu and negative Ce anomalies of waters indicate oxygen-rich environments. 相似文献
6.
《Applied Geochemistry》2001,16(6):633-649
Water inflows in the Gotthard Highway Tunnel and in the Gotthard Exploration Tunnel are meteoric waters infiltrating at different elevations, on both sides of an important orographic divide. Limited interaction of meteoric waters with gneissic rocks produces Ca–HCO3 and Na–Ca–HCO3 waters, whereas prolonged interaction of meteoric waters with the same rocks generates Na–HCO3 to Na–SO4 waters. Waters circulating in Triassic carbonate-evaporite rocks have a Ca–SO4 composition. Calcium-Na–SO4 waters are also present. They can be produced through interaction of either Na–HCO3 waters with anhydrite or Ca–SO4 waters with a local gneissic rock, as suggested by reaction path modeling. An analogous simulation indicates that Na–HCO3 waters are generated through interaction of Ca–HCO3 waters with a local gneissic rock. The two main SO4-sources present in the Alps are leaching of upper Triassic sulfate minerals and oxidative dissolution of sulfide minerals of crystalline rocks. Values of δ34SSO4 < ∼+9‰ are due to oxidative dissolution of sulfide minerals, whereas δ34SSO4 >∼+9‰ are controlled either by bacterial SO4 reduction or leaching of upper Triassic sulfate minerals. Most waters have temperatures similar to the expected values for a geothermal gradient of 22°C/km and are close to thermal equilibrium with rocks. However relatively large, descending flows of cold waters and ascending flows of warm waters are present in both tunnels and determine substantial cooling and heating, respectively, of the interacting rocks. The most import upflow zone of warm, Na-rich waters is below Guspisbach, in the Gotthard Highway Tunnel, at 6.2–9.0 km from the southern portal. These warm waters have equilibrium temperatures of 65–75°C and therefore constitute an important low-enthalpy geothermal resource. 相似文献
7.
在实际案例分析中,采用传统地球化学温标计算的温度与实测温度往往有一定的差距,研究系统中矿物-流体的平衡状态、判断作为估算热交换温度的地热温标是否使用、选出最合适的计算结果非常重要.在讨论热水与矿物的平衡状态时,采用Na-K-Mg三角图解法和PHREEQCI程度模拟计算矿物饱和指数的方法进行研究,结果表明:(1) 粤西沿海地热系统采集的23组水样的分析发现其热水水化学特征为热水呈中低温弱碱性、氟含量较高源于热水与花岗岩的水岩相互作用、由内陆至沿海地区水化学类型由HCO3·Cl-Ca·Na型向Cl-Na型转化;(2) 浅层水的混合使得硅温标的估算值低于实测温度;只有21号水样适合用阳离子温标,其热交换平衡温度为150~170 ℃;1号和19号样可用K-Mg温标计算其热交换温度下限值,分别为136.2和151.6 ℃,其余水样则适合用log(Q/K)-T平衡法估算,深部热水在经历深循环后上升至地表,在浅层受到冷水混合. 相似文献
8.
Calculation of pH and mineral equilibria in hydrothermal waters with application to geothermometry and studies of boiling and dilution 总被引：1，自引：0，他引：1
Using chemical analyses and 25° pH measurements of quenched high-temperature waters, we calculate in situ pH and distribution of aqueous species at high temperature. This is accomplished by solving simultaneous mass action equations for complexes and redox equilibria and mass balance equations, on all components, including a H+ equation with as many as 60 terms (depending on water composition). This calculation provides accurate values for the activities of aqueous ions in a given water at high temperature, which are used to calculate an ion activity product (Q) for each of more than 100 minerals. The value of log(Q/K) for each mineral, where K is the equilibrium constant, provides a measure of proximity of the aqueous solution to equilibrium with the mineral. By plotting log Q/Kvs. T for natural waters, it is possible to determine: a) whether the water was in equilibrium with a host rock mineral assemblage, b) probable minerals in the equilibrium assemblage and c) the temperature of equilibrium. In cases where the fluid departs from equilibrium with a host rock assemblage, it is possible to determine whether this may result from boiling or dilution, and an estimate of amount of lost gas or diluting water can be determined.The calculation is illustrated by application to geothermal waters from Iceland, Broadlands, and Sulphur Bank, hot spring waters from Jemez, Yellowstone and Blackfoot Reservoir (Idaho) and fluid inclusions from the Sunnyside Mine, Colorado. It is shown that most geothermal waters approach equilibrium with a subsurface mineral assemblage at a temperature close to measured temperatures and that some hot springs also approach equilibrium with the host rock at temperatures above outlet temperatures but commonly below the Na-K-Ca temperatures. The log Q/K plots show that some discrepancies between Na-K-Ca temperatures on spring waters and actual temperatures result from a failure of alkali feldspars to equilibrate with the fluid and with each other.Calculations on Sulphur Bank fluids show that boiling probably caused cinnabar precipitation near 150°C and that the boiled fluids equilibrated with secondary minerals near 150° even though temperatures up to 185° have been measured at depth. For the fluid inclusions, the measured bubble temperatures are close to those calculated for equilibration of the fluid with the observed sulfide mineral assemblage.New estimates of stability constants for aluminum hydroxide complexes are included at the end of the paper. 相似文献
9.
《Chemie der Erde / Geochemistry》2016,76(1):63-75
Geothermal resources are very rich in Yunnan, China. However, source of dissolved solutes in geothermal water and chemical evolution processes remain unclear. Geochemical and isotopic studies on geothermal springs and river waters were conducted in different petrological-tectonic units of western Yunnan, China. Geothermal waters contain Ca–HCO3, Na–HCO3, and Na (Ca)–SO4 type, and demonstrate strong rock-related trace elemental distributions. Enhanced water–rock interaction increases the concentration of major and trace elements of geothermal waters. The chemical compositions of geothermal waters in the Rehai geothermal field are very complicated and different because of the magma chamber developed at the shallow depth in this area. In this geothermal field, neutral-alkaline geothermal waters with high Cl, B, Li, Rb Cs, As, Sb, and Tl contents and acid–sulfate waters with high Al, Mn, Fe, and Pb contents are both controlled by magma degassing and water–rock interaction. Geothermal waters from metamorphic, granite, and sedimentary regions (except in the Rehai area) exhibit varying B contents ranging from 3.31 mg/L to 4.49 mg/L, 0.23 mg/L to 1.24 mg/L, and <0.07 mg/L, respectively, and their corresponding δ11B values range from −4.95‰ to −9.45‰, −2.57‰ to −8.85‰, and −4.02‰ to +0.06‰. The B contents of these geothermal waters are mainly controlled by leaching host rocks in the reservoir, and their δ11B values usually decrease and achieve further equilibrium with its surrounding rocks, which can also be proven by the positive δ18O-shift. In addition to fluid–rock reactions, the geothermal waters from Rehai hot springs exhibit higher δ11B values (−3.43‰ to +1.54‰) than those yielded from other areas because mixing with the magmatic fluids from the shallow magma. The highest δ11B of steam–heated waters (pH 3.25) from the Zhenzhu spring in Rehai is caused by the fractionation induced by pH and the phase separation of coexisting steam and fluids. Given the strong water–rock interaction, some geothermal springs in western Yunnan show reservoir temperatures higher than 180 °C, which demonstrate potential for electricity generation and direct-use applications. The most potential geothermal field in western Yunnan is located in the Rehai area because of the heat transfer from the shallow magma chamber. 相似文献
10.
The Diyadin Geothermal area, located in the eastern part of Anatolia (Turkey) where there has been recent volcanic activity, is favorable for the formation of geothermal systems. Indeed, the Diyadin geothermal system is located in an active geodynamic zone, where strike-slip faults and tensional cracks have developed due to N–S regional compression. The area is characterized by closely spaced thermal and mineralized springs, with temperatures in the range 30–64 °C, and flowrates 0.5–10 L/s. Thermal spring waters are mainly of Ca(Na)-HCO3 and Ca(Mg)-SO4 types, with high salinity, while cold groundwater is mostly of Ca(Na, Mg)-HCO3 type, with lower salinity. High contents of some minor elements in thermal waters, such as F, B, Li, Rb, Sr and Cs probably derive from enhanced water–rock interaction.Thermal water samples collected from Diyadin are far from chemical equilibrium as the waters flow upward from reservoirs towards spring vents and possibly mix with cooler waters. The temperatures of the deep geothermal reservoirs are estimated to be between 92 and 156 °C in Diyadin field, based on quartz geothermometry, while slightly lower estimates are obtained using chalcedony geothermometers. The isotopic composition of thermal water (δ18O, δ2H, δ3H) indicates their deep-circulating meteoric origin. The waters are likely to have originated from the percolation of rainwater along fractures and faults to the deep hot reservoir. Subsequent heating by conduction due to the presence of an intrusive cupola associated with the Tendurek volcano, is followed by the ascent of deep waters to the surface along faults and fractures that act as hydrothermal conduits.Modeling of the geothermal fluids indicates that the fluid is oversaturated with calcite, aragonite and dolomite, which matches travertine precipitation in the discharge area. Likewise, the fluid is oversaturated with respect to quartz, and chalcedony indicating the possibility of siliceous precipitation near the discharge areas. A conceptual hydro-geochemical model of the Diyadin thermal waters based on the isotope and chemical analytical results, has been constructed. 相似文献
11.
Badia Chulli Aysen Davraz Jalila Makni Mourad Bedir Hamed Ben Dhia 《Environmental Earth Sciences》2012,66(1):1-16
The Sfax Basin in eastern Tunisia is bounded to the east by the Mediterranean Sea. Thermal waters of the Sfax area have measured
temperatures of 23–36°C, and electrical conductivities of 3,200 and 14,980 μS/cm. Most of the thermal waters are characterized
as Na–Cl type although there are a few Na–SO4–Cl waters. They issue from Miocene units which are made up sands and sandstones interbedded with clay. The Quaternary sediments
cap the system. The heat source is high geothermal gradient which are determined downhole temperature measurements caused
by graben tectonics of the area. The results of mineral equilibrium modeling indicate that the thermal waters of the Sfax
Basin are undersaturated with respect to gypsum, anhydrite and fluorite, oversaturated with respect to kaolinite, dolomite,
calcite, microcline, quartz, chalcedony, and muscovite. Assessments from various chemical geothermometers, Na–K–Mg ternary
and mineral equilibrium diagrams suggest that the reservoir temperature of the Sfax area can reach up to 120°C. According
to δ18O and δ2H values, all thermal and cold groundwater is of meteoric origin. 相似文献
12.
A detailed study on the solute geothermometry of thermal water (18 springs and 8 drilled wells) of La Primavera geothermal field (LPGF) in Mexico has been carried out by employing a geochemical database compiled from the literature and by applying all the available solute geothermometers. The performance of these geothermometers in predicting the reservoir temperatures has been evaluated by applying a geochemometrics (geochemical and statistical) method. The springs of the LPGF are of bicarbonate type and the majority have attained partial-equilibrium chemical conditions and the remaining have shown non-equilibrium conditions. In the case of geothermal wells, water is dominantly of chloride-type and, among the studied eight geothermal wells, four have shown full-equilibrium chemical conditions and another four have indicated partial-equilibrium conditions. All springs of HCO3− type water have provided unreliable reservoir temperatures, whereas the only one available spring of SO42− type water has provided the reservoir temperature nearer to the average BHT of the wells. Contrary to the general expected behavior, spring water of non-equilibrium and geothermal well water of partial-equilibrium chemical conditions have indicated more reliable reservoir temperatures than those of partially-equilibrated and fully-equilibrated water, respectively. Among the chemical concentration data, Li and SiO2 of two springs, SO42− and Mg of four springs, and HCO3 and Na concentrations of two geothermal wells were identified as outliers and this has been reflected in very low reservoir temperatures predicted by the geothermometers associated with them (Li–Mg, Na–Li, Na–K–Mg, SiO2 etc.). Identification of the outlier data points may be useful in differentiating the chemical characteristics, lithology and the physico-chemical and geological processes at the sample locations of the study area.In general, the solute geothermometry of the spring waters of LPGF indicated a dominantly (94%) of underestimated deep reservoir temperatures, whereas in the case of the geothermal wells, many temperatures (54%) are underestimated, some are (43%) overestimated and a very small number (3%) are similar to an average bottom-hole temperatures (BHT) of the wells. 28 out of the total applied 29 geothermometers for spring waters have predicted the deep reservoir temperatures that are characterized by statistically significant large differences compared to the average BHTs of the geothermal wells. In the case of waters of the geothermal wells, 23 out of the total applied 28 geothermometers have predicted the reservoir temperatures similar (statistically no significant differences) to the BHTs of the corresponding geothermal wells. 相似文献
13.
This study focuses on the water and gas chemistry of the northeastern Algerian thermal waters. The helium gas was used to detect the origin of the geothermal fluid. In the Guelma Basin, the heat flow map shows an anomaly of 120 ± 20 mW/m2 linked to the highly conductive Triassic extrusion. The chemical database reveals the existence of three water types, Ca-SO4/Na-Cl, which are related to evaporites and rich in halite and gypsum minerals. The third type is Ca (Na)-HCO3, which mostly characterizes the carbonated Tellian sector. The origin of thermal waters using a gas-mixing model indicates a meteoric origin, except for the El Biban hot spring (W10), which shows a He/Ar ratio of 0.213, thus suggesting the presence of batholith. The helium distribution map indicates a lower 3He/4He ratio between 0 Ra and 0.04 Ra in the W10 and W15 samples, which is compatible with the crustal ratio. Reservoir temperatures estimated by silica geothermometers give temperatures less than 133 °C. The geothermal conceptual model suggests that a geothermal system was developed by the deep penetration of infiltrated cold waters to a depth of 2.5 km and then heated by a conductive heat source (batholith for El Biban case). The thermal waters rise up to the surface through the deep-seated fractures. During their ascension, they are mixed with shallow cold groundwater, which increase the Mg content and cause the immature classification of the water samples. 相似文献
14.
The chemistry of geothermal waters in Iceland. II. Mineral equilibria and independent variables controlling water compositions 总被引：1，自引：0，他引：1
Stefán Arnórsson Einar Gunnlaugsson Hördur Svavarsson 《Geochimica et cosmochimica acta》1983,47(3):547-566
The major element chemistry of Icelandic geothermal waters is predictable provided two parameters are known. This follows from an attainment of, or a close approach to, an overall chemical equilibrium in the geothermal systems at temperatures as low as 50°C. It is considered that the geothermal system composition, temperature and kinetic factors determine which alteration minerals form. The system composition is not so much fixed by rock composition as by the rate of leaching of the various constituents from the fresh rock and the composition of inflowing water. The water chemistry is determined by the system composition and the external variables acting on the system. They include temperature and the mobility of chloride. Pressure, which theoretically should be regarded as an external variable, has insignificant effect on water compositions in the range (1–200 bars) occurring in the geothermal systems. 相似文献
15.
Thermal mineral waters and extractable geothermal energy are an important and still underestimated natural wealth of Bulgaria. Their diversity is due to the complex geological structure, intense neotectonic activity, and the resulting complex character of meteoric water circulation. Reproductive hydrogeothermal systems with low-mineralized thermal waters of meteoric origin and resrvoir temperatures ranging between 30 and 100 (maximum 120) °C occur in the southern and north-eastern part of the country. Their total reproductive potential is estimated at 14–15 m3s–1. In the northern part (Moesian platform), regional hydrogeothermal reservoir with connate (marine) and mixed (marine and meteoric) mineral waters and brines are identified, the temperatures varying from 40 to 140 (maximum 150) °C. Huge resources of geothermal energy with commercial importance are accumulated in them. The hydrogeothermal wealth of Bulgaria provides as important basis for the development of balneological and multi-seasonal tourism, bottling industries, geothermal heating of buildings and greenhouses, aquaculture and other related activities. 相似文献
16.
Chaves thermal waters (76°C) are the most important external manifestations of low-temperature geothermal systems occurring in Portuguese mainland. They are related to crystalline granitic rocks. This paper describes the use of the environmental isotopic composition (oxygen-18, deuterium, and tritium) of hot and cold waters of the Chaves area as an important hydrogeological tool to solve specific problems arising in the appraisal of the geothermal resources of the area (e.g., origin and age of waters, recharge area, and underground flow paths).18O and D analyses seem to confirm the meteoric origin of Chaves thermal waters. The local altitude dependence of meteoric waters was determined by18O and D analyses of superficial and shallow groundwaters of the Chaves plain and its bordering mountains. Chaves thermal waters seem to be related to meteoric waters, infiltrated on the highest topography areas (Bolideira granitic outcrop NE Chaves), that percolate at great depth and emerge in a discharge area at lower altitude (Chaves plain). Chaves thermal waters showing little oxygen-18 shift and low tritium concentrations could be considered external manifestations of an old geothermal system in which the isotopic water-rock interaction is adjusted to equilibrium. 相似文献
17.
Molybdenum concentrations in Icelandic geothermal waters lie in the range 1–70 ppb. Warm waters and dilute high-temperature waters which contain high concentrations of sulphide are lowest in molybdenum. No correlation is otherwise observed between molybdenum concentrations and temperature. Surface waters and cold ground waters do not contain detectable molybdenum (<1 ppb). It seems likely that leaching rate is the prime factor in limiting molybdenum levels in these waters. Within individual geothermal fields molybdenum concentrations are either approximately constant or they vary regularly across the field. This regular variation may often be correlated with variations in other solute concentrations and subsurface temperatures and is taken to indicate a control of molybdenum mobility by a temperature dependent equilibrium. The evidence suggests that the solubility of molybdenite is responsible. Molybdenite has not been found in active geothermal systems in Iceland but is known to occur in some New Zealand geothermal systems and it has been identified in hydrothermally altered Tertiary basalt formations at Reydarártindur in southeast Iceland. Boiling and mixing with cold water leads to molybdenite undersaturation and thus these processes favour leaching of molybdenum from the rock. On the other hand, conductive cooling leads to supersaturation which favours removal of molybdenum from solution. 相似文献
18.
Tekkehamam geothermal field is located in the South of Menderes Graben (Aegean region) and is one of the most important geothermal sites of Western Anatolia. Umut geothermal field is a part of the Tekkehamam field. This study was conducted in order to determine the origin and hydrogeochemical properties of the geothermal waters. For this purpose, sampling was done in order to check the chemistry of the water, and 18O, 2H isotope analyses done at four wells, nine natural springs and three cold water sources. According to the results of the chemical analysis, the geothermal waters were determined to be of Na + K-SO4 type. Additionally, 14C and 3H analyses were done in selected well and spring waters for the purpose of age determination of groundwater; most of the waters were determined to be submodern. Geothermometer calculations show that the reservoir temperature for the Umut geothermal field ranges between 148 and 180 °C. Stable isotope results indicate that Umut geothermal waters are meteoric in origin. Mixing between shallow and deep waters is the dominant subsurface process that determines the physical and chemical character of the waters. 相似文献
19.
Boron geochemistry from some typical Tibetan hydrothermal systems: Origin and isotopic fractionation
The Tibetan plateau is characterized by intense hydrothermal activity and abnormal enrichment of trace elements in geothermal waters. Hydrochemistry and B isotope samples from geothermal waters in Tibet were systematically measured to describe the fractionation mechanisms and provide constraints on potential B reservoirs. B concentrations range from 0.35 to 171.90 mg/L, and isotopic values vary between −16.57 ‰ and +0.52 ‰. Geothermal fields along the Indus-Yarlung Zangbo suture zone and N–S rifts are observed with high B concentrations and temperatures. The similar hydrochemical compositions of high-B geothermal waters with magmatic fluid and consistent modeling of B isotopic compositions with present δ11B values imply that the B in high-B geothermal waters is mainly contributed by magmatic sources, probably through magma degassing. In contrast, geothermal fields in other regions of the Lhasa block have relatively low B concentrations and temperatures. After considering the small fractionation factor and representative indicators of Na/Ca, Cl/HCO3, Na + K and Si, the conformity between modeling results and the isotopic compositions of host rocks suggests that the B in low-temperature geothermal fields is mainly sourced from host rocks. According to simulated results, the B in some shallow geothermal waters not only originated from mixing of cold groundwater with deep thermal waters, but it was also contributed by equilibration with marine sedimentary rocks with an estimated proportion of 10%. It was anticipated that this study would provide useful insight into the sources and fractionation of B as well as further understanding of the relationships between B-rich salt lakes and geothermal activities in the Tibetan plateau. 相似文献
20.
A hydrochemical study of the Hammam Righa geothermal waters in north-central Algeria 总被引：1，自引：0，他引：1
Mohamed Belhai Yasuhiro Fujimitsu Fatima Zohra Bouchareb-Haouchine Abdelhamid Haouchine Jun Nishijima 《中国地球化学学报》2016,35(3):271-287
This study focuses on the hydrochemical characteristics of 47 water samples collected from thermal and cold springs that emerge from the Hammam Righa geothermal field, located in north-central Algeria. The aquifer that feeds these springs is mainly situated in the deeply fractured Jurassic limestone and dolomite of the Zaccar Mount. Measured discharge temperatures of the cold waters range from 16.0 to 26.5 °C and the hot waters from 32.1 to 68.2 °C. All waters exhibited a near-neutral pH of 6.0–7.6. The thermal waters had a high total dissolved solids (TDS) content of up to 2527 mg/l, while the TDS for cold waters was 659.0–852.0 mg/l. Chemical analyses suggest that two main types of water exist: hot waters in the upflow area of the Ca–Na–SO4 type (Hammam Righa) and cold waters in the recharge zone of the Ca–Na–HCO3 type (Zaccar Mount). Reservoir temperatures were estimated using silica geothermometers and fluid/mineral equilibria at 78, 92, and 95 °C for HR4, HR2, and HR1, respectively. Stable isotopic analyses of the δ18O and δD composition of the waters suggest that the thermal waters of Hammam Righa are of meteoric origin. We conclude that meteoric recharge infiltrates through the fractured dolomitic limestones of the Zaccar Mount and is conductively heated at a depth of 2.1–2.2 km. The hot waters then interact at depth with Triassic evaporites located in the hydrothermal conduit (fault), giving rise to the Ca–Na–SO4 water type. As they ascend to the surface, the thermal waters mix with shallower Mg-rich groundwater, resulting in waters that plot in the immature water field in the Na–K–Mg diagram. The mixing trend between cold groundwaters from the recharge zone area (Zaccar Mount) and hot waters in the upflow area (Hammam Righa) is apparent via a chloride-enthalpy diagram that shows a mixing ratio of 22.6 < R < 29.2 %. We summarize these results with a geothermal conceptual model of the Hammam Righa geothermal field. 相似文献