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1.
对冈底斯中部地区二云母花岗岩和花岗闪长岩进行了LA-ICP-MS锆石U-Pb定年、主量元素、微量元素和锆石Hf同位素组成的测定.结果表明, 二云母花岗岩的岩浆结晶年龄为(205± 1)Ma, 岩石属于强过铝质花岗岩, A/CNK= 1.16~ 1.20, K2O/Na2O= 1.67~ 1.95.岩石富Rb、Th和U等元素, Eu/Eu* = 0.29~ 0.41, (La/Yb)N= 22.62~ 35.08.锆石εHf(t)= -12.4~ -1.8.二云母花岗岩的岩浆产生于地壳中泥质岩类在无外来流体加入的情况下云母类矿物脱水反应所诱发的部分熔融作用, 其岩石形成机制类似于喜马拉雅新生代淡色花岗岩.花岗闪长岩的岩浆结晶年龄为(202± 1)Ma, 岩石属于准铝质(A/CNK= 0.96~ 0.98), K2O/Na2O= 1.42~ 1.77, Eu/Eu* = 0.54~ 0.65, (La/Yb)N= 6.76~ 13.35.锆石εHf(t)= -8.2~ -5.5.根据花岗闪长岩的地球化学特征和锆石Hf同位素组成, 花岗闪长岩的岩浆来自于地壳中基性岩类的部分熔融.冈底斯印支晚期强过铝质花岗岩的确定, 表明了冈底斯在印支晚期以前曾发生地壳的缩短与加厚作用, 从而进一步明确了冈底斯印支早期的造山事件及冈底斯经历了多期造山作用的演化.   相似文献   

2.
北拉萨地体广泛发育白垩纪岩浆岩,但是对其岩石成因及其动力学背景仍存在争议。本次研究选取西藏洛隆地区冻错岩体为研究对象,在野外地质调查基础上进行了岩石学、岩石地球化学、锆石U-Pb年代学和Hf同位素研究。结果表明：冻错岩体主要为花岗闪长岩和二长花岗岩,且发育暗色闪长质包体;锆石U-Pb测年结果显示花岗闪长岩(127.6±1.0 Ma, 129.9±0.9 Ma)和二长花岗岩(131.7±1.1 Ma)的形成时代为早白垩世;花岗闪长岩具有负的εHf(t)值(-12.9～-10.3)和古老的二阶段模式年龄(1 809～1 977 Ma);岩体花岗岩类的SiO2,Al2O3和全碱(Na2O+K2O)质量分数分别为67.01%～72.35%,14.37%～16.55%和6.49%～8.11%,里特曼指数(σ)为1.52～2.30,铝饱和指数A/CNK值为0.90～1.12,属准铝质-弱过铝质I型花岗岩类。闪长质包体SiO2,Al2  相似文献   

3.
海南岛地处东古特提斯构造域东缘,是研究古特提斯东缘演化的重要地区.对海南岛东南部长征和陵水花岗闪长岩的LA-ICP-MS锆石U-Pb定年结果显示两者的结晶年龄分别为251±2 Ma和256±1 Ma,指示其形成于晚二叠世.样品的K2O/Na2O比值较低（0.2~0.9）,铝饱和指数（A/CNK）为0.74~0.96,FeOT/MgO约为0.90,CIPW计算结果中标准矿物刚玉分子含量0.00~0.18%,小于1%,岩石薄片镜下可见大量角闪石,而未见白云母、堇青石和石榴子石,并具有相对负的εNd（t）值（-6.0~-3.2）和锆石原位εHf（t）值（-4.4~+0.2）,属于准铝质钙碱性I型花岗岩.长征和陵水花岗闪长岩源岩为亚碱性变基性岩,其形成与金沙江-哀牢山-松马-邦溪-晨星古特提斯弧后盆地的闭合有关.   相似文献   

4.
祁连造山带分为南祁连、中祁连和北祁连构造带.赛支寺岩体位于中祁连与南祁连构造带的结合部位.首次发现了赛支寺花岗闪长岩及其暗色包体,然而对于暗色包体的成因机理以及与寄主岩石之间的成因联系仍存在很多争议.并对其进行了系统的锆石U-Pb年代学、Lu-Hf同位素、岩石地球化学以及Sr-Nd同位素地球化学研究,探讨赛支寺岩体及其暗色包体的成因及动力学背景.LA-ICP-MS锆石U-Pb年代学表明,赛支寺花岗闪长岩形成于446.1±1.3 Ma,包体形成于446.0±1.0 Ma,两者在误差范围内一致,排除了包体为捕虏体成因.暗色包体具较低的SiO2含量、较高的Na2O/K2O比值,低Sr/Y、La/Yb比值,与寄主岩稀土配分曲线基本一致,但LREE相对较低;86Sr/87Sr=0.706 4~0.706 7,εNd(t)=-7.38~-7.97;发育针状磷灰石,形成于岩浆混合作用.寄主岩SiO2=66.45%~68.12%,Na2O/K2O=0.80~0.97,A/CNK=0.91~1.03,显示准铝质-弱过铝质岩浆特点;富集大离子亲石元素Rb、Th、U、K,亏损Nb、Ta等元素,高Sr/Y、La/Yb比值,轻稀土富集,弱负Eu异常;86Sr/87Sr=0.709 3~0.709 5,εNd(t)=-1.75~-1.03,与祁连造山带I型花岗岩相似;锆石εHf(t)=1.7~6.8,TDM2=995~1 750 Ma.综上所述认为,寄主花岗闪长岩形成于壳幔岩浆混合.结合区域地质背景,赛支寺花岗闪长岩形成于俯冲背景下,幔源岩浆上涌,侵入到下地壳中,造成下地壳物质熔融,由这种既有幔源物质又有古老地壳物质的花岗岩岩浆形成.   相似文献   

5.
武功山造山带位于华夏地块与扬子地块碰撞缝合带南侧,记录了新元古代以来的多次构造运动。本文对其中的黑云母二长花岗岩和二云母二长花岗岩进行了全面的矿物学、岩石地球化学、锆石U-Pb同位素年代学及Lu—Hf同位素研究。LA-ICP-MS锆石U-Pb同位素年代学研究指示武功山黑云母二长花岗岩和二云母二长花岗岩结晶于早志留世(441.6～442.2 Ma)。武功山早志留世花岗岩具有富硅(SiO2含量为67.43%～73.06%)、富碱(Na2O+K2O含量为6.47%～8.46%)、贫钙(CaO=0.78%～2.64%)、贫镁(MgO=0.46%～1.61%)等特征,为强过铝质高钾钙碱性花岗岩(A/CNK=1.09～1.35)。同时,岩相学和地球化学指示岩石属于亚碱性系列,分异程度较低,ΣREE较低,轻重稀土分异程度较高,为S型花岗岩且岩浆源区物相为角闪石+斜长石+石榴子石。结合花岗岩锆石fLu/Hf值均小于-0.9,εHf(t)均为负值(-6.7到-4.8),指示岩浆来源于古元古代古老...  相似文献   

6.
辽东半岛是华北克拉通胶-辽-吉古元古代活动带的重要组成部分,古元古代经历了复杂的构造演化过程,并记录了多期岩浆-变质作用,约2.2 Ga的辽吉A型花岗岩和1.89～1.85 Ga的巨斑状花岗岩、正长岩分别标志着辽东古元古代造山作用的开端和结束。最新研究显示,2.20～2.15 Ga的岩浆作用形成了2种不同类型的花岗岩,它们可能具有不同的岩石成因和构造意义。在青城子铅锌矿集区北部采集的兰花岭、白砬子花岗闪长岩和黄泊辉绿岩,锆石U-Pb年龄分别为2177±19 Ma、2129±36 Ma、1876±29 Ma。花岗闪长岩的岩石成因类型、地球化学特征与典型的约2.2 Ga的辽吉A型花岗岩明显不同,属于弱过铝质、低钾钙碱性一碱性岩石,Zr、Hf、Nb、Rb含量较低,K2O/Na2O值、稀土元素总量极低,为典型的Ⅰ型花岗岩类。根据锆石Lu-Hf同位素分析,εHf(t)值为-5.1～9.0,二阶段Hf模式年龄tDM2为2089～2817 Ma,岩浆源区为约2.5 Ga的太古宙地壳物质和少量软流圈地幔物质。兰花岭...  相似文献   

7.
位于柴北缘西段的小赛什腾山分布大量海西晚期中酸性岩浆岩,其形成时代和成因类型对揭露区域构造演化具有十分重要的意义。本研究以小赛什腾山二叠纪黑云母二长花岗岩和石英闪长岩作为研究对象,对其进行岩相学、锆石U-Pb年代学、岩石地球化学及Lu-Hf同位素研究。结果表明,黑云母二长花岗岩和石英闪长岩的成岩年龄分别为272±3 Ma和273±2 Ma,指示两者均形成于早—中二叠世。地球化学结果显示,黑云母二长花岗岩属弱过铝质钾玄岩系列I型花岗岩,石英闪长岩为准铝质钙碱性系列I型花岗岩,两者均不同程度富集大离子亲石元素Rb、Th、K等,亏损Nb、Ta、Ti等高场强元素,具有典型的弧岩浆地球化学特征。锆石Lu-Hf同位素表明黑云母二长花岗岩具正的εHf(t)值(2.04～8.16)和较年轻的二阶段Hf模式年龄(tDM2=0.77～1.16 Ga)。结合前人研究成果,认为小赛什腾山早—中二叠世黑云母二长花岗岩和石英闪长岩均为宗务隆洋俯冲消减的产物,石英闪长岩为玄武质洋壳板片发生部分熔融产生的熔体遭受地幔橄榄岩混染而成,而黑云母二长花岗岩为洋壳熔融产生的岩浆底侵...  相似文献   

8.
为确定东昆仑马尼特地区片麻状花岗闪长岩的形成时代、源区性质和构造背景,对其进行了锆石U-Pb年代学、地球化学和锆石Hf同位素研究.本次测试的片麻状花岗闪长岩锆石LA-ICP-MS(laser ablation inductively coupled plasma mass spectrometry) U-Pb加权平均年龄为495.6±1.1 Ma(MSWD=0.13),属于晚寒武世.马尼特片麻状花岗闪长岩SiO2含量为61.47%~63.99%,Na2O、K2O和CaO含量分别为2.91%~3.64%、0.93%~2.31%和4.29%~6.52%,全碱ALK=3.92%~5.69%,铝饱和指数A/CNK=0.83~0.97,属准铝质钙碱性系列岩石.岩石具有富集大离子亲石元素(Rb、K)和不相容元素(Th、U),相对亏损Nb、Ta、Zr、Ti高场强元素的特征,Nb/Ta、La/Nb、Th/Nb、Th/La等比值显示出岩石具有壳源特征.岩石具有高的εHf(t)值(12.2~15.0),Hf两阶段模式年龄在506~662 Ma范围内,其岩浆源区初始物质主要来源于新生地壳.岩石在微量元素Rb-(Y+Nb)构造判别图落入火山弧花岗岩区域,在R1-R2构造判别图落入板块碰撞前消减区花岗岩区域.结合岩石成岩年龄、地球化学特征以及区域构造演化,推测其应形成于原特提斯洋俯冲的构造环境,属于大洋洋壳向南俯冲的产物,即柴达木地块和万宝沟大洋玄武岩高原之间的洋壳同时向南、北发生双向俯冲消减.   相似文献   

9.
对大磊山片麻状花岗岩的研究可以为新元古代罗迪尼亚超大陆在扬子克拉通北缘裂解提供约束.在详细野外地质调查和岩相学工作基础上,对该片麻状花岗岩进行了系统的锆石U-Pb定年、全岩地球化学和锆石原位Lu-Hf同位素分析,研究发现,这些片麻状花岗岩富硅(SiO2=73.18%~77.40%)、碱(Na2O+K2O=8.07%~8.70%)、贫铝(Al2O3=12.11%~13.92%)和镁(MgO=0.10%~0.34%),富集LILE、Ga、Rb、Th,Zr和Hf元素具明显正异常,Nb、Sr、P、Ti等元素具明显负异常,表现出后造山A型花岗岩(A2型)的特征.这些花岗岩中,锆石均具典型的震荡环带,Th/U比值均大于0.5,为岩浆成因;两个样品的LA-ICP-MS(laser ablation inductively coupled plasma mass spectrometry)锆石的谐和分别是:801.3±3.0 Ma(MSWD=0.62,n=21) 和796.1±6.3 Ma(MSWD=1.70,n=15),其中一个样品继承锆石谐和年龄为845.0±12.0 Ma(MSWD=1.30,n=6),表示他们是新元古代岩浆结晶产物.锆石εHf(t)值变化于-7.5~+8.0,正εHf(t)值对应的亏损地幔单阶段模式年龄(tDM1)为1 242~1 059 Ma,负εHf(t)值对应的地壳两阶段模式年龄(tDM2)为1 636~1 981 Ma,显示该地区存在的最古老物质是古元古代(老至1 981 Ma).这些数据结果表明形成大磊山A型花岗岩的初始物质主要为元古代古老地壳物质,暗示该岩浆源自于壳幔混合作用,幔源端元可能源自于伸展拉张背景下地幔岩浆上涌.结合区域研究成果认为,该A型花岗岩的形成与罗迪尼亚超大陆聚合后-裂解中的陆缘弧后拉张环境所引起的深部古元古代地壳拉张垮塌有关.   相似文献   

10.
东昆仑中灶火地区的石英闪长岩—花岗闪长岩—二长花岗岩具有连续的成分变化。岩石具有中等到高的Si O_2含量(58.15%~71.12%),适度的高铝和全碱含量,为中—高钾钙碱性的准铝质Ⅰ型花岗岩。岩石相对富集大离子亲石元素和轻稀土元素,并亏损高场强元素,显示出弧岩浆岩的一般地球化学特征。锆石地质年代学分析获得石英闪长岩和花岗闪长岩的锆石结晶年龄约为243Ma,表明本文研究的花岗岩类为中三叠世岩浆岩。结合地质、地球化学研究,这套花岗岩形成于陆缘弧环境,是古特提斯洋俯冲晚期的岩浆记录。其成因为俯冲动力学背景下,幔源岩浆的底侵作用导致下地壳部分熔融,随后壳源熔体与幔源熔体发生不同程度的混合形成母岩浆,又经历了较高程度的结晶分异形成石英闪长岩—花岗闪长岩—二长花岗岩序列。  相似文献   

11.
In an effort to constrain the mechanism of dolomitization in Neogene dolomites in the Bahamas and improve understanding of the use of chemostratigraphic tracers in shallow‐water carbonate sediments the δ34S, Δ47, δ13C, δ18O, δ44/40Ca and δ26Mg values and Sr concentrations have been measured in dolomitized intervals from the Clino core, drilled on the margin of Great Bahama Bank and two other cores (Unda and San Salvador) in the Bahamas. The Unda and San Salvador cores have massively dolomitized intervals that have carbonate associated sulphate δ34S values similar to those found in contemporaneous seawater and δ44/40Ca, δ26Mg values, Sr contents and Δ47 temperatures (25 to 30°C) indicating relatively shallow dolomitization in a fluid‐buffered system. In contrast, dolomitized intervals in the Clino core have elevated values of carbonate associated sulphate δ34S values indicating dolomitization in a more sediment‐buffered diagenetic system where bacterial sulphate reduction enriches the residual in 34S, consistent with high sediment Sr concentrations and low δ44/40Ca and high δ26Mg values. Only dolomites associated with hardgrounds in the Clino core have carbonate associated δ34S values similar to seawater, indicating continuous flushing of the upper layers of the sediment by seawater during sedimentary hiatuses. This interpretation is supported by changes to more positive δ44/40Ca values at hardground surfaces. All dolomites, whether they formed in an open fluid‐buffered or closed sediment‐buffered diagenetic system have similar δ26Mg values suggesting that the HMC transformed to dolomite. The clumped isotope derived temperatures in the dolomitized intervals in Clino yield temperatures that are higher than normal, possibly indicating a kinetic isotope effect on dolomite Δ47 values associated with carbonate formation through bacterial sulphate reduction. The findings of this study highlight the utility of applying multiple geochemical proxies to disentangle the diagenetic history of shallow‐water carbonate sediments and caution against simple interpretations of stratigraphic variability in these geochemical proxies as indicating changes in the global geochemical cycling of these elements in seawater.  相似文献   

12.
Iron is one of the most abundant transition metal in higher plants and variations in its isotopic compositions can be used to trace its utilization. In order to better understand the effect of plant-induced isotopic fractionation on the global Fe cycling, we have estimated by quantum chemical calculations the magnitude of the isotopic fractionation between different Fe species relevant to the transport and storage of Fe in higher plants: Fe(II)-citrate, Fe(III)-citrate, Fe(II)-nicotianamine, and Fe(III)-phytosiderophore. The ab initio calculations show firstly, that Fe(II)-nicotianamine is ～3‰ (56Fe/54Fe) isotopically lighter than Fe(III)-phytosiderophore; secondly, even in the absence of redox changes of Fe, change in the speciation alone can create up to ～1.5‰ isotopic fractionation. For example, Fe(III)-phytosiderophore is up to 1.5‰ heavier than Fe(III)-citrate2 and Fe(II)-nicotianamine is up to 1‰ heavier than Fe(II)-citrate. In addition, in order to better understand the Fe isotopic fractionation between different plant components, we have analyzed the iron isotopic composition of different organs (roots, seeds, germinated seeds, leaves and stems) from six species of higher plants: the dicot lentil (Lens culinaris), and the graminaceous monocots Virginia wild rye (Elymus virginicus), Johnsongrass (Sorghum halepense), Kentucky bluegrass (Poa pratensis), river oat (Uniola latifolia), and Indian goosegrass (Eleusine indica). The calculations may explain that the roots of strategy-II plants (Fe(III)-phytosiderophore) are isotopically heavier (by about 1‰ for the δ56Fe) than the upper parts of the plants (Fe transported as Fe(III)-citrate in the xylem or Fe(II)-nicotianamine in the phloem). In addition, we suggest that the isotopic variations observed between younger and older leaves could be explained by mixing of Fe received from the xylem and the phloem.  相似文献   

13.
Pelagic deposits at Abadeh represent a complete biostratigraphic record across the Permian/Triassic boundary (PTB). The presumed water depth during deposition of these sediments was between 60 and 90 m. Similar to other Permian/Triassic boundary sections, the succession at Abadeh is characterised by a negative carbon isotope shift of approximately 4. The values start to decrease in the lower C. changxingensis - C. deflecta s.l. Zone, reach –0.12 (V-PDB) in the uppermost Permian just below the PTB, remain low to the early I. isarcica Zone (–0.32) and increase subsequently in the upper I. isarcica Zone. For the time interval of the PTB negative carbon isotope excursion, between the C. iranica and the I. isarcica Zones, no correlation exists between the 13Ccarb and the 18Ocarb. The above observations argue against the conclusion of Heydari et al. (2001) that the carbon isotope event at the P/T transition is an alteration artefact and not a global signal. The decrease in 13Ccarb is accompanied by a ~5 (and potentially up to 10) increase in 34SSSS. Together, these features are thought to reflect a complex global event, notably the development of widespread anoxic oceans with anoxic bottom layers rising onto the shelves. For the carbon isotope drop, other factors, such as the collapse of ocean primary productivity may also have played a role. The 87Sr/86Sr ratios of Dzhulfian seawater show only a minor increase from 0.70705 to 0.70710, reaching 0.70720 in the Dorashamian. The increase becomes steeper in the Early Triassic reaching 0.70754 in the N. dieneri Zone. The rise of the strontium isotope values is thought to be related to enhanced continental weathering under humid climatic conditions in the uppermost Permian (C. meishanensis - H. praeparvus Zone) and the lack of a dense land vegetation in the Early Triassic, prior to the Spathian (Upper Olenekian).  相似文献   

14.
Modelling of tree-ring δ13C and δ18O data from the Columbia Icefield area in the eastern Rocky Mountains of western Canada provides fuller understanding of climatic and hydrologic variability over the past 1000 yr in this region, based on reconstruction of changes in growth season atmospheric relative humidity (RHgrs), winter temperature (Twin) and the precipitation δ18O-Twin relation. The Little Ice Age (~ AD 1530s-1890s) is marked by low RHgrs and Twin and a δ18O-Twin relation offset from that of the present, reflecting enhanced meridional circulation and persistent influence of Arctic air masses. Independent proxy hydrologic evidence suggests that snowmelt sustained relatively abundant streamflow at this time in rivers draining the eastern Rockies. In contrast, the early millennium was marked by higher RHgrs and Twin and a δ18O-Twin relation like that of the 20th century, consistent with pervasive influence of Pacific air masses because of strong zonal circulation. Especially mild conditions prevailed during the “Medieval Climate Anomaly” ~ AD 1100-1250, corresponding with evidence for reduced discharge in rivers draining the eastern Rockies and extensive hydrological drought in neighbouring western USA.  相似文献   

15.
The analytical capabilities of the ims 1270 ion microprobe (SIMS) in determining O and C isotope compositions in biogenic carbonate samples have been tested. Results indicated that, with a spot size of ≊ 30 μm, the average reproducibility at the 1s level was 0.3‰ for oxygen isotopes and 0.6‰ for carbon isotopes. Nevertheless, this reproducibility can reach 0.2‰ for oxygen isotope determinations during some sessions. These reproducibilities allowed us to perform analyses on biogenic carbonate samples for environmental studies. In this paper, examples of oxygen and carbon isotope measurements are presented for a modern coral and the Holocene scleractinian coral, Porites lutea.  相似文献   

16.
康定杂岩Rb-Sr、Sm-Nd同位素系统及其意义   总被引：1，自引：0，他引：1  
通过对康定—冕宁地区出露的英云闪长岩、黑云角闪斜长片麻岩、角闪变粒岩全岩及其中所分离出的角闪石、黑云母、斜长石、钾长石的Rb-Sr、Sm-Nd同位素的系统测定,结合岩石的锆石U-Pb年龄结果,确定这些变质杂岩由于经历了复杂的形成过程与变质历史,Rb-Sr、Sm-Nd同位素体系难以确定其结晶年龄。由单矿物与全岩Rb-Sr、Sm-Nd体系拟合的~700 M a的等时线年龄反映了角闪岩相-高角闪岩相的变质作用年龄。Sm-Nd同位素体系由于在变质作用过程中的部分开放性,很容易给出无意义的较老的混合年龄。康定杂岩结晶后并没有经历麻粒岩相变质作用,区域上所含的麻粒岩透镜体可能是新元古代(773~721 M a)期间由Rod in ia超大陆裂解产生的新生洋壳向扬子克拉通陆块俯冲消减过程的变质产物。俯冲到一定深度后,由于板片被拉断,软流圈上涌导致变质洋壳板片岩石、先前底侵变质的镁铁质岩石及扬子陆块长英质基底岩石发生部分熔融,以镁铁质岩石熔融产生的熔浆为主(>70%),与长英质基底岩石熔融产生的熔浆混合形成w(Na2O)/w(K2O)>1的TTG组合。  相似文献   

17.
Mineralogical, textural and geochemical investigations were made to determine the post-depositional evolution of Devonian and Early Carboniferous carbonates from Valle de Tena. The carbonate association is made up of low-Mg calcite, which occurs as micrite, spar cements, neomorphic patches and spar filling veinlets. Non-stoichiometric dolomite and ankerite occur as cements (dolomite also as replacements) in the Middle Devonian, post-dating calcite types. All these phases pre-date tectonic stylolites, indicating compaction after stabilization of the carbonate minerals. Strontium concentrations indicate that Early Devonian and Early Carboniferous micrites initially precipitated as aragonite; Middle and Late Devonian micrites precipitated as high-Mg calcites. Both precursors were diagenetically stabilized to low-Mg calcites through interaction with meteoric waters in phreatic environments. Trace elements in dolomite and ankerite indicate precipitation from Sr-enriched meteoric water. All studied carbonates, except Middle Devonian limestones, precipitated in reducing environments, which favoured incorporation of Fe and Mn. Late calcite generations precipitated from more saline waters than micrites. Light 18O values in micrites suggest alteration mainly in meteoric-phreatic environments. The dolomites and ankerites precipitated from more 18O-depleted fluids than the calcites, suggesting a greater contribution from meteoric waters. Variations in 13C of micrites represent primary secular trends, according to published 13C variations. The 13C oscillations within each succession probably relate to sea-level oscillations. Strontium isotopes also point to a meteoric origin of diagenetic fluids. Model calculations suggest that O and Sr isotopes equilibrated between calcites and fluid at relatively low water/rock ratios, whereas C isotopic signatures are inherited from limestones.  相似文献   

18.
镁同位素地球化学研究新进展及其应用   总被引：7，自引：3，他引：4  
作为一种新兴的地质示踪剂,Mg同位素正受到国际地学界日益广泛的关注。Mg同位素地球化学研究已取得了巨大的进展,近期研究工作主要包括两个方面。首先,调查了地球各主要储库和陨石的Mg同位素组成特征,结果表明陨石和地球地幔具有均一并且相似的Mg同位素组成,平均δ26Mg值分别为-0.28±0.06‰和-0.25±0.07‰;相反,上地壳和水圈的Mg同位素组成很不均一,δ26Mg值变化范围分别为-4.84‰~+0.92‰和-2.93‰~+1.13‰。其次,对一些地质和物理化学过程中Mg同位素的分馏行为进行研究,结果表明:(1)地表风化作用可以造成大的Mg同位素分馏,导致重Mg同位素残留在风化产物中而轻Mg同位素进入水圈;(2)岩浆分异过程中Mg同位素平衡分馏很小;(3)高温化学扩散和热扩散过程中Mg同位素会发生显著的动力学分馏。基于这些研究成果,Mg同位素体系已经被初步应用于示踪早期地球形成和壳内物质再循环等过程,并有望在不久的将来应用于示踪大陆地壳的化学演化和地质温度计等研究领域。  相似文献   

19.
Iron, Cu and Zn stable isotope systems are applied in constraining a variety of geochemical and environmental processes. Secondary reference materials have been developed by the Institute of Geology, Chinese Academy of Geological Sciences (CAGS), in collaboration with other participating laboratories, comprising three solutions (CAGS‐Fe, CAGS‐Cu and CAGS‐Zn) and one basalt (CAGS‐Basalt). These materials exhibit sufficient homogeneity and stability for application in Fe, Cu and Zn isotopic ratio determinations. Reference values were determined by inter‐laboratory analytical comparisons involving up to eight participating laboratories employing MC‐ICP‐MS techniques, based on the unweighted means of submitted results. Isotopic compositions are reported in per mil notation, based on reference materials IRMM‐014 for Fe, NIST SRM 976 for Cu and IRMM‐3702 for Zn. Respective reference values of CAGS‐Fe, CAGS‐Cu and CAGS‐Zn solutions are as follows: δ56Fe = 0.83 ± 0.07 and δ57Fe = 1.20 ± 0.13, δ65Cu = 0.57 ± 0.06, and δ66Zn = ?0.79 ± 0.12 and δ68Zn = ?1.65 ± 0.24, respectively. Those of CAGS‐Basalt are δ56Fe = 0.15 ± 0.07, δ57Fe = 0.22 ± 0.10, δ65Cu = 0.12 ± 0.08, δ66Zn = 0.17 ± 0.13, and δ68Zn = 0.34 ± 0.26 (2s).  相似文献   

20.
文章简述了二次离子探针质谱(SIMS)、激光剥蚀等离子体质谱(LA-ICP-MS)和激光剥蚀多接受等离子体质谱(LA-MC-ICP-MS)等3种锆石微区原位同位素和微量元素测定方法的原理和优缺点;针对U-Pb定年、铪同位素、锂同位素、多种元素的同时测定,以及仪器改进、测试方法创新、标样研发等方面的新进展进行了评述。  相似文献   

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