Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

Estimation of the 3D correlation structure of an alluvial aquifer from surface-based multi-frequency ground-penetrating radar reflection data     

Zhiwei Xu  James Irving  Kyle Lindsay  John Bradford  Peimin Zhu  Klaus Holliger 《Geophysical Prospecting》2020,68(2):678-689

Knowledge about the stochastic nature of heterogeneity in subsurface hydraulic properties is critical for aquifer characterization and the corresponding prediction of groundwater flow and contaminant transport. Whereas the vertical correlation structure of the heterogeneity is often well constrained by borehole information, the lateral correlation structure is generally unknown because the spacing between boreholes is too large to allow for its meaningful inference. There is, however, evidence to suggest that information on the lateral correlation structure may be extracted from the correlation statistics of the subsurface reflectivity structure imaged by surface-based ground-penetrating radar measurements. To date, case studies involving this approach have been limited to 2D profiles acquired at a single antenna centre frequency in areas with limited complementary information. As a result, the practical reliability of this methodology has been difficult to assess. Here, we extend previous work to 3D and consider reflection ground-penetrating radar data acquired using two antenna centre frequencies at the extensively explored and well-constrained Boise Hydrogeophysical Research Site. We find that the results obtained using the two ground-penetrating radar frequencies are consistent with each other, as well as with information from a number of other studies at the Boise Hydrogeophysical Research Site. In addition, contrary to previous 2D work, our results indicate that the surface-based reflection ground-penetrating radar data are not only sensitive to the aspect ratio of the underlying heterogeneity, but also, albeit to a lesser extent, to the so-called Hurst number, which is a key parameter characterizing the local variability of the fine-scale structure.  相似文献   

Characterization of sudden and sustained base flow jump hydrologic behaviour in the humid seasonal tropics of the Panama Canal Watershed     

Yanyan Cheng  Fred L. Ogden  Jianting Zhu 《水文研究》2020,34(3):569-582

Base flows are important for tropical regions with pronounced dry seasons, which are facing increasing water demands. Base flow generation, however, is one of the most challenging hydrological processes to characterize in the tropics. In many years during the May–December wet season in the Panama Canal Watershed (PCW), base flows in rivers abruptly increase. This increase persists until the start of the December–April dry season. Understanding this unusual base flow jump (BFJ) behaviour is critical to improve water provisioning in the seasonal tropics, especially during droughts and extended dry seasons. This study developed an integrated approach combining piecewise regression on cumulative average base flow and sensitivity analysis to calculate the timing and magnitude of BFJ. Rainfall, forest cover, mean land surface slope, catchment area, and estimated subsurface storage were tested as predictors for the occurrence and magnitude of the BFJs in seven subcatchments of the PCW. Sensitivity analysis on correlated predictors allowed ranking of predictor contributions due to isolated and cross-correlation effects. Correlations between observed BFJs and BFJs predicted by watershed and rainfall-related predictors were 0.92 and 0.65 for BFJ timing and magnitude, respectively. Forest cover was the second most significant predictor after cumulative rainfall for jump magnitude, owing to larger subsurface storage and groundwater recharge in forests than pastures. Catchments in the mountainous eastern PCW always generated larger jumps due to their higher rainfall and greater forest cover than the western PCW catchments. The cross-correlations between predictors contributed to more than 50% of the jump variances. The results demonstrate the importance of rainfall gradient and catchment characteristics in affecting the sudden and sustained BFJs, which can help inform land management decisions intended to enhance water supplies in the tropics. This study underscores the need for more research to further understand the hydrological processes involved in the BFJ phenomenon, including better BFJ models and field characterizations, to help improve tropical ecosystem services under a changing environment.  相似文献   

毛乌素沙地东南缘全新世气候不稳定性     

李想  苏志珠  马义娟  张彩霞  柳苗苗 《中国沙漠》2020,40(2):109-117

毛乌素沙地处于中国季风区的西北边缘,对气候变化敏感,是古气候演化和古环境变迁研究的理想场所。全新世气温回暖期,气候整体稳定但存在暖湿冷干的次级波动,不同类型沉积相组成的地层序列记录了全新世千年、百年尺度的气候不稳定性。对毛乌素沙地不同沉积序列的研究表明:(1)毛乌素沙地东南缘的沙漠/黄土边界带DLT、NB剖面粒度及Rb/Sr比值可作为气候变化的代用指标。>63 μm砂含量增加,Rb/Sr比值降低,揭示东亚冬季风增强,风成砂堆积,风沙活动加剧,气候干冷;反之,东亚夏季风增强,降水增多,风化成壤程度加大,气候暖湿。(2)毛乌素沙地东南缘沙漠/黄土边界带及低洼沟谷区年代概率密度函数的分析显示,全新世早期~8\^5 ka BP风成砂堆积,风沙活动加剧,气候表现为干冷;全新世中期8\^5 ka~3\^0 ka BP地势较高处古土壤广泛发育,地势低洼处发育湖沼相/泥炭层,但在6.0 ka BP左右存在气候转冷过程;全新世晚期3\^0 ka BP以来气候波动频繁。(3)毛乌素沙地气候变化与北大西洋冰筏冷事件、董哥洞石笋、季风边缘区湖泊、东部沙地等记录具有可对比性和相对一致性,反映出全新世千年和百年尺度上的气候变化主要受全球变化的影响,这对预测和模拟未来气候变化具有借鉴意义。  相似文献   

社会网络视角中世界文化遗产地旅游村寨的利益关系治理     

时少华  李享 《热带地理》2020,40(4):625-635

以云南省红河州元阳县哈尼梯田核心区域2个典型的旅游村寨（大鱼塘村和普高老寨）为例，对两村寨利益相关者从网络凝聚性、网络互惠性、网络核心边缘、网络传递性、网络经纪人等5个方面展开关系数据分析，结果显示：1）大鱼塘村压力集团内部、压力集团与社区、企业与政府之间的利益关联性和联系的紧密性不足；2）两村当地政府和压力集团与社区之间的互惠性低于整体平均互惠性；3）两村利益网络中边缘结构较核心结构更加明显，这导致了利益关系的不平衡；4）两村当地政府利益集团传递性相对较低，当地社区传递性最高；5）两村中利益集团间缺少部分协调人、守门人、代理人、联络人等角色。最后提出相应建议：1）提升哈尼梯田利益关系由弱利益关系转变为强利益关系，改变利益集团间核心边缘利益关系格局；2）进一步加强各利益集团内部及之间的关联性；3）加强以企业和政府机构为顶点的组间利益传递，让利益流动逐步打破哈尼梯田利益集团之间的核心边缘关系结构；4）重点加强社区在利益关系网络中的参与机会与权力，对社区进行增权；5）利益集团内部要重点培育协调人和顾问角色，利益集团之间要重点培育企业与政府、社区、压力集团之间的守门人、代理人和联络人角色，以及社区与政府和企业之间的守门人、代理人角色。  相似文献   

新冠肺炎疫情扩散与人口流动的空间关系及对中国城市公共卫生分类治理启示     

向云波  王圣云 《热带地理》2020,40(3):408-421

人口流动影响新冠肺炎疫情传播与风险扩散。基于百度迁徙大数据和各省市区卫生健康委员会数据，结合地理信息技术，研究了2020年1月1日至3月5日136个城市新冠肺炎疫情扩散与武汉市人口流出的空间关系及其对我国城市公共卫生治理启示。研究表明：1）中国新冠肺炎疫情扩散过程具有阶段性特征，经历了疫情发生与隐性扩散、快速扩散与暴发、扩散遏制和扩散衰减4个阶段。2）研究时间段武汉市人口主要流向湖北省境内以及周边省市和北京、上海、广州、深圳等一线城市，具有地理邻近性和倾向区域中心城市的人口流入特征。受地理距离、时间成本、社会经济联系、境外输入等因素的影响，新冠肺炎疫情空间分布的不平衡性明显，长江中游城市群、京津冀城市群、长三角城市群、粤港澳大湾区和成渝城市群成为新冠肺炎疫情集中分布的重点区域，一些重点出入境口岸城市的新冠疫情扩散风险较大。3）新冠肺炎疫情扩散与人口流出之间具有较强的正向等级相关性。两者之间的空间关系可以分为8种调控类型，近90%的城市具有人口流入多、确诊病例数高或人口流入少、确诊病例数低的特征。其中，人口流入多、确诊病例数高的城市主要集中分布在湖北省境内以及中国重点城市群的中心城市，其防控压力来自人口流入多、确诊病例数高带来的疫情扩散风险；而人口流入少、确诊病例数低的城市分布较为分散，其防控的难点在于提高防控对策的精准性。我国疫情防控取得了显著成效，但随着时间的演进全球疫情形势反弹的不确定性仍然存在，外防输入、内防反弹的压力依然很重，现阶段乃至未来一段时期，疫情防控将伴随中国经济社会发展成为新常态。建议针对8种调控类型，从人口流动、交通和资源等引导与管控方面分类提出精细化的疫情防控策略，提升城市公共卫生治理能力。  相似文献   

游客-环境互动视角下旅游者目的地环境恢复性效应     

朱芳  苏勤  陶云  沈惊宏 《热带地理》2020,40(4):636-648

日常生活环境和旅游目的地环境都可以为个体提供恢复的机会，不同环境的属性特征导致不同程度的恢复。为了探究环境类型与恢复性效应之间的关系及停留时间的调节作用，文章采用问卷调查方式，利用配对样本t检验和混合设计方差分析相结合的方法，探讨游客在不同环境中的恢复性效应，并对这一现象提供心理上的解释。结果表明：1）恢复体验的4个维度（放松体验、心理脱离、掌握体验、控制体验）在旅游目的地环境中的得分均高于日常生活环境。2）掌握和控制体验维度在城市旅游目的地中的变化程度高于乡村旅游目的地，两种类型目的地的放松和心理脱离维度差异较小。3）随着在目的地停留时间的延长，乡村旅游目的地放松体验和心理脱离维度变化程度高于城市旅游目的地，两种类型目的地环境恢复性效应会相互靠近。因此，游客的环境恢复性效应不仅受到环境和目的地类型的影响，同时还与游客的适应程度有关，且受到其停留时间的调节作用。  相似文献   

Analysis of city centrality based on entropy weight TOPSIS and population mobility:A case study of cities in the Yangtze River Economic Belt     

罗静  陈四云  孙璇  朱媛媛  曾菊新  陈广平 《地理学报(英文版)》2020,30(4):515-534

Based on statistical data and population flow data for 2016,and using entropy weight TOPSIS and the obstacle degree model,the centrality of cities in the Yangtze River Economic Belt(YREB)together with the factors influencing centrality were measured.In addition,data for the population flow were used to analyze the relationships between cities and to verify centrality.The results showed that:(1)The pattern of centrality conforms closely to the pole-axis theory and the central geography theory.Two axes,corresponding to the Yangtze River and the Shanghai-Kunming railway line,interconnect cities of different classes.On the whole,the downstream cities have higher centrality,well-defined gradients and better development of city infrastructure compared with cities in the middle and upper reaches.(2)The economic scale and size of the population play a fundamental role in the centrality of cities,and other factors reflect differences due to different city classes.For most of the coastal cities or the capital cities in the central and western regions,factors that require long-term development such as industrial facilities,consumption,research and education provide the main competitive advantages.For cities that are lagging behind in development,transportation facilities,construction of infrastructure and fixed asset investment have become the main methods to achieve development and enhance competitiveness.(3)The mobility of city populations has a significant correlation with the centrality score,the correlation coefficients for the relationships between population mobility and centrality are all greater than 0.86(P<0.01).The population flow is mainly between high-class cities,or high-class and low-class cities,reflecting the high centrality and huge radiating effects of high-class cities.Furthermore,the cities in the YREB are closely linked to Guangdong and Beijing,reflecting the dominant economic status of Guangdong with its geographical proximity to the YREB and Beijing's enormous influence as the national political and cultural center,respectively.  相似文献   

Influence of Stress on Void Ratios of Compacted Crushed Rock Masses in Coal Mine Gobs     

Hu  Shengyong  Han  Dandan  Feng  Guorui  Zhang  Ao  Hao  Guocai  Hu  Lanqing  Zhu  Liping  Li  Bo 《Natural Resources Research》2020,29(2):1361-1373

The transfer and evolution of stress among rock blocks directly change the void ratios of crushed rock masses and affect the flow of methane in coal mine gobs. In this study, a Lagrange framework and a discrete element method, along with the soft-sphere model and EDEM numerical software, were used. The compaction processes of rock blocks with diameters of 0.6, 0.8, and 1.0 m were simulated with the degrees of compression set at 0%, 5%, 10%, 15%, 20%, and 25%. This study examines the influence of stress on void ratios of compacted crushed rock masses in coal mine gobs. The results showed that stress was mainly transmitted downward through strong force chains. As the degree of compression increased, the strong force chains extended downward, which resulted in the stress at the upper rock mass to become significantly higher than that at the lower rock mass. It was determined that under different degrees of compression, the rock mass of coal mine gobs could be divided, from the bottom to the top, into a lower insufficient compression zone (ICZ) and an upper sufficient compression zone (SCZ). From bottom to top, the void ratios in the ICZ sharply decreased and those in the SCZ slowly decreased. Void ratios in the ICZ were 1.2–1.7 times higher than those in the SCZ.

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3D Mineral Prospectivity Mapping with Random Forests: A Case Study of Tongling,Anhui, China     

Xiang  Jie  Xiao  Keyan  Carranza  Emmanuel John M.  Chen  Jianping  Li  Shi 《Natural Resources Research》2020,29(1):395-414

Natural Resources Research - In the past few decades, a variety of data-driven predictive modeling techniques has led to a dramatic advancement in mineral prospectivity mapping (MPM). The random...  相似文献