Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

A nearly analytic symplectic partitioned Runge–Kutta method based on a locally one-dimensional technique for solving two-dimensional acoustic wave equations     

Chol Sim  Chunyou Sun  Nam Yun 《Geophysical Prospecting》2020,68(4):1253-1269

In this paper, we develop a new nearly analytic symplectic partitioned Runge–Kutta method based on locally one-dimensional technique for numerically solving two-dimensional acoustic wave equations. We first split two-dimensional acoustic wave equation into the local one-dimensional equations and transform each of the split equations into a Hamiltonian system. Then, we use both a nearly analytic discrete operator and a central difference operator to approximate the high-order spatial differential operators, which implies the symmetry of the discretized spatial differential operators, and we employ the partitioned second-order symplectic Runge–Kutta method to numerically solve the resulted semi-discrete Hamiltonian ordinary differential equations, which results in fully discretized scheme is symplectic unlike conventional nearly analytic symplectic partitioned Runge–Kutta methods. Theoretical analyses show that the nearly analytic symplectic partitioned Runge–Kutta method based on locally one-dimensional technique exhibits great higher stability limits and less numerical dispersion than the nearly analytic symplectic partitioned Runge–Kutta method. Numerical experiments are conducted to verify advantages of the nearly analytic symplectic partitioned Runge–Kutta method based on locally one-dimensional technique, such as their computational efficiency, stability, numerical dispersion and long-term calculation capability.  相似文献   

美国出口管制下中国外贸风险的省域地理差异     

姜辉 《地理科学》2020,40(10):1618-1626

从总贸易、出口、进口、外资和人员5个视角构建对美风险系数，测度和比较各省区市对美外贸风险的地理差异。结果表明：上海、浙江和福建与美国的进出口贸易规模最大，对美国市场的依赖程度最高，面临的综合外贸风险最大；河南尤其需要防范对美国的出口风险；海南、新疆、天津和西藏等需要加强从美国进口的风险管理；重庆除了需要防范对美出口风险外，还因为实际利用美资最多且依赖程度最大，亟需加强外资风险管理。宁夏和山西虽然从美国的引资规模不大，但是对美资的依赖程度最高，亟需提升外资多元化水平。从人员跨境流动风险来看，上海、北京和浙江面临的风险最大。中国各省区市在应对美国出口管制时应该加强外贸风险的识别和管理，针对不同的风险采取差别化的防范和化解措施。  相似文献   

滨海城市竖向避难场所选址可靠性评价与若干问题探讨     

张威涛  任利剑  运迎霞 《地理科学》2020,40(11):1899-1908

关注滨海城市竖向避难场所的选址可靠性问题，首先深化确立“竖向避难场所”概念；然后构建竖向避难场所选址可靠性评价模型，综合自然地理要素和建成环境要素，从与灾害直接作用相关的选址暴露性、与应急交通相关的选址敏感性、与应急服务相关的选址适应性3个维度展开，搭建3级评价指标体系；再以天津滨海新区为例、聚焦滨海城市潮洪灾害和人口安全矛盾的集核——临港城区展开实证研究，借助ArcGIS分类与可视化发现：高低可靠性选址之间具有明显的空间分异，可以分解为灾害暴露性的“近岸高?远岸低”分异、交通敏感性的“外围高?中心低”分异、服务适应性的“中心与沿河高?外围低”兼“近港高?远港低”分异。同时发现：商业设施用地选址价值较高，在高可靠性选址中占比第一；中小学和社会福利设施用地选址价值最高，在高可靠性选址中占比第二；文化科研和娱乐康体设施用地在高可靠性选址中占比最小。针对临港城区实证研究结果，提出滨海城市竖向避难场所选址及可靠性提升对策。  相似文献   

农机投入对农业GTFP影响及门槛效应的区域差异分析     

刘敏  姜会明  姜天龙 《地理科学》2020,40(12):2037-2045

按照粮食的产销情况，将全国划分为3类粮食功能区域，利用固定效应模型和门槛效应模型分析了农机投入对农业绿色全要素生产率（GTFP）的影响及门槛效应的区域差异。结果表明：农机投入对农业GTFP的影响程度存在区域异质性，农机投入对粮食主销区农业GTFP提升的促进作用最大，粮食产销平衡区次之，粮食主产区最小；农机投入对农业GTFP的影响路径亦存在区域差异，粮食主产区和产销平衡区的农机投入通过促进农业技术效率和农业技术进步进而推动农业GTFP提升，粮食主销区的农机投入通过促进农业技术进步推动农业GTFP提升；农机投入对粮食主产区农业GTFP的影响存在双门槛效应，对粮食主销区和产销平衡区农业GTFP的影响存在单门槛效应。  相似文献   

通过课堂观察提升教师课程知行力的探究     

秦江 《地理教学》2020,(4):57-58,32

课堂是实施课程育人的主阵地,教师的教育观、课程观、课堂观、学生观等在课堂中的具体体现,反映了教师课程知行力的水平。本文以课程知行力的视角,探讨课堂观察的目的、内容和方法,并通过案例剖析的方式,为一线教师开展课堂观察,更新教育观念和教学方式,提升课程知行力提供参考。  相似文献   

游客-环境互动视角下旅游者目的地环境恢复性效应     

朱芳  苏勤  陶云  沈惊宏 《热带地理》2020,40(4):636-648

日常生活环境和旅游目的地环境都可以为个体提供恢复的机会，不同环境的属性特征导致不同程度的恢复。为了探究环境类型与恢复性效应之间的关系及停留时间的调节作用，文章采用问卷调查方式，利用配对样本t检验和混合设计方差分析相结合的方法，探讨游客在不同环境中的恢复性效应，并对这一现象提供心理上的解释。结果表明：1）恢复体验的4个维度（放松体验、心理脱离、掌握体验、控制体验）在旅游目的地环境中的得分均高于日常生活环境。2）掌握和控制体验维度在城市旅游目的地中的变化程度高于乡村旅游目的地，两种类型目的地的放松和心理脱离维度差异较小。3）随着在目的地停留时间的延长，乡村旅游目的地放松体验和心理脱离维度变化程度高于城市旅游目的地，两种类型目的地环境恢复性效应会相互靠近。因此，游客的环境恢复性效应不仅受到环境和目的地类型的影响，同时还与游客的适应程度有关，且受到其停留时间的调节作用。  相似文献   

Salinivibrio sp.YH4胞外丝氨酸蛋白酶EYHS耐盐性及生物信息学分析          下载免费PDF全文

武翠玲  宋英达  高慧芳  张廉芸  任晨霞 《盐湖研究》2020,28(1)

摘要：目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性，属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高，α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高，且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸，并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示，α螺旋和β片层围成了蛋白酶的催化腔，EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体，且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性，并有助于其催化功能的发挥，为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。  相似文献   

Geological Control of Fold Structure on Gas Occurrence and Its Implication for Coalbed Gas Outburst: Case Study in the Qinan Coal Mine,Huaibei Coalfield,China     

Zhang  Kaizhong  Wang  Liang  Cheng  Yuanping  Li  Wei  Kan  Jin  Tu  Qingyi  Jiang  Jingyu 《Natural Resources Research》2020,29(2):1375-1395

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Modeling studies of tidal dynamics and the associated responses to coastline changes in the Bohai Sea,China     

Longhai Zhu  Rijun Hu  Haijun Zhu  Shenghui Jiang  Yongchen Xu  Nan Wang 《Ocean Dynamics》2018,68(12):1625-1648

Over the past 30 years, reclamation projects and related changes have impacted the hydrodynamics and sediment transport in the Bohai Sea. Three-dimensional tidal current models of the Bohai Sea and the Yellow Sea were constructed using the MIKE 3 model. We used a refined grid to simulate and analyze the effects of changes in coastline, depth, topography, reclamation, the Yellow River estuary, and coastal erosion on tidal systems, tide levels, tidal currents, residual currents, and tidal fluxes. The simulation results show that the relative change in the amplitude of the half-day tide is greater than that of the full-day tide. The changes in the tidal amplitudes of M₂, S₂, K₁, and O₁ caused by coastline changes accounted for 27.76–99.07% of the overall change in amplitude from 1987 to 2016, and water depth changes accounted for 0.93–72.24% of the overall change. The dominant factor driving coastline changes is reclamation, accounting for 99.55–99.91% of the amplitude changes in tidal waves, followed by coastal erosion, accounting for 0.05–0.40% of the tidal wave amplitude changes. The contribution of changes in the Yellow River estuary to tidal wave amplitude changes is small, accounting for 0.01–0.12% of the amplitude change factor. The change in the highest tide level (HTL) is mainly related to the amplitude change, and the correlation with the phase change is small. The dominant factor responsible for the change in the HTL is the tide amplitude change in M2, followed by S2, whereas the influence of the K1 and O1 tides on the change in the HTL is small. Reclamation resulted in a decrease in the vertical average maximum flow velocity (V_VAM) in the Bohai Sea. Shallower water depths have led to an increase in the V_VAM; deeper water depths have led to a decrease in the maximum flow velocity. The absolute value of the maximum flow velocity gradually decreases from the surface to the bottom, but the relative change value is basically constant. The changes in the tidal dynamics of the Bohai Sea are proportional to the degree of change in the coastline. The maximum and minimum changes in the tidal flux appear in Laizhou Bay (P-LZB) and Liaodong Bay (P-LDB), respectively. The changes in the tidal flux are related to the change in the area of the bay. Due to the reduced tidal flux, the water exchange capacity of the Bohai Sea has decreased, impacting the ecological environment of the Bohai Sea. Strictly controlling the scale of reclamation are important measures for reducing the decline in the water exchange capacity of the Bohai Sea and the deterioration of its ecological environment.  相似文献