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1.
刘丙祥  聂虎  齐玥  杨力  祝禧艳  陈福坤 《岩石学报》2013,29(7):2437-2455
北秦岭地体中新元古代花岗岩类岩石是秦岭造山带的重要组成部分,记录了造山带基底前寒武纪地壳形成和演化历史。本文报道方庄和德河花岗岩岩体的锆石U-Pb年龄和O同位素组成、全岩元素和Sr-Nd同位素地球化学组成,探讨其岩石成因和地壳演化意义。结果表明,方庄花岗质糜棱岩的锆石结晶年龄为933.4±9.2Ma,δ18O值8.3‰~11.9‰,初始87Sr/86Sr比值0.72455,初始εNd值-6.0,Nd模式年龄2.09Ga(tDM2);德河黑云斜长片麻岩的锆石结晶年龄为948.1±8.9Ma,初始87Sr/86Sr比值变化较大,初始εNd值-5.0,Nd模式年龄2.02Ga。结合已报道的新元古代花岗岩类岩体的年龄和地球化学数据,北秦岭地体新元古代岩浆作用可以划分为980~870Ma挤压碰撞作用和~844Ma伸展裂解作用两大阶段,包括~940Ma强烈变形S型同碰撞花岗岩、~880Ma弱-无变形后碰撞I型花岗岩和~844Ma板内A型碱性岩三类花岗岩体。地球化学组成显示,这些花岗岩类岩石可能源自不同时期形成的秦岭群基底杂岩的部分熔融,但在后碰撞阶段幔源物质或年轻地壳物质的加入明显增加。北秦岭地体中新元古代岩浆活动与Rodinia超大陆演化基本同时代,可能记录超大陆形成过程中的地壳响应。在新元古代之前,北秦岭地体或许具有不同于华北陆块和华南陆块的演化历史。  相似文献   

2.
丹东地区是中国重要的金矿集中区,到目前为止还没有较准确的成岩成矿年代数据报道.本文采用Rb-8r等时线法和单颗粒锆石U-Pb法分别测出了丹东三股流花岗岩成岩年龄为131±5 Ma和129±3 Ma,因此三股流花岗岩综合同位素年龄定为130 Ma.五龙金矿主成矿阶段石英流体包裹体Rb-Sr等时线年龄为120±3 Ma.这一组年龄数据理顺了该地区构造-岩浆-成矿的时序关系,对中国东部金矿成矿对比研究提供了有效的年龄数据.8r、Nd同位素的示踪结果表明三股流花岗岩的成岩物质与下地壳物质有关.三股流花岗岩和矿体(含金石英脉)相似的Sr同位素初始比值,说明成矿和成岩物质可能来自深部同一岩浆源区.  相似文献   

3.
杨晓松  金振民 《地质论评》2001,47(3):294-300
对西藏亚东淡色花岗岩Rb-Sr和Sm-Nd同位素的详细研究表明,亚东淡色花岗岩Rb-Sr和Sm-Nd同位素组成十分不均匀,其初始Sr值和ε-(Nd)(13 Ma)分别介于0.756~0.775和-11.6~-16.3。由于存在着显著的同位素变异,而难以获得其全岩Rb-Sr等时线年龄。但研究获得了12.9±0.95Ma矿物—全岩Rb-Sr等时线年龄,其锶初始值为0.7744±0.0008,该年龄可以与高喜马拉雅带其他淡色花岗岩的年龄对比。Rb-Sr和Sm-Nd同位素组成显示亚东淡色花岗岩的源岩很可能是聂拉木群副变质岩。年龄统计分析表明,喜马拉雅淡色花岗岩是在地壳伸展和快速隆起背景下形成的,因此它的形成年龄是碰撞造山后地壳强烈活动和快速隆起的重要标志。  相似文献   

4.
赣南陂头花岗岩体Nd-Sr同位素特征及其意义   总被引:14,自引:1,他引:13  
对赣南陂头花岗岩岩体进行 Rb- Sr同位素定年研究 ,确定了其 Rb- Sr等时线年龄为(178.2± 0 .84 ) Ma,表明其形成于中侏罗世早期。并研究了陂头花岗岩 Sm- Nd组成 ,计算出其 εNd(t)值 (- 5.4~ - 6 .4 )和 T2 DM值 (140 6~ 1482 Ma) ,确定其物质来源为较年轻的地壳。  相似文献   

5.
本文对新县花岗岩岩基进行了系统的锆石U-Pb定年,全岩元素地球化学、Sr-Nd-Pb-Hf同位素测试,研究探讨其成岩年龄、岩石成因、物质来源以及地球化学动力学背景。锆石U-Pb年龄为125.5±1.5Ma,属于早白垩世产物。全岩元素地球化学成分表现为高硅、富碱,贫镁、铁和钙,富集轻稀土元素、大离子亲石元素(Rb、K、Th、U)和Pb,亏损重稀土元素、高场强元素(Nb、Ta、Ti)和Sr、Ba。全岩同位素具有中等略偏高的Sr 初始比值(87Sr/86Sr)i=0.706949~0.707086;低的放射性Pb同位素组成[ (206Pb/204Pb)i=16.611~17.152,(207Pb/204Pb)i=15.304~15.432,(208Pb/204Pb)i=37.316~37.702]; 低的Nd初始比值(εNd(t)=-13.65~-13.51)和老的Nd模式年龄(TDM2=2.12~2.13Ga)。锆石原位Hf同位素具有较低的初始比值(εHf(t)=-22.92~-19.40)和老的Hf二阶段模式年龄(TDM2=2.39~2.61 Ga)。综合以上元素地球化学特征、锆石U-Pb定年结果及Sr-Nd-Pb-Hf同位素组成,新县花岗岩岩基应属于分异的高钾钙碱性I型花岗岩,是化学成分类似于扬子板块北缘新元古代TTG型岩浆岩的扬子下地壳在非加厚下地壳(深度小于35km)环境下部分熔融的产物。  相似文献   

6.
论河北丰宁牛圈银(金)矿床的成矿时限问题   总被引:2,自引:0,他引:2  
对河北牛圈银(金)矿区细粒钾长花岗岩株和含矿隐爆角砾岩墙钾长石样品进行了详细的40Ar/39Ar同位素年龄测定。细粒钾长花岗岩株钾长石样品主要加热阶段所获得数据构成一条相关性很好的直线,其对应的同位素等时线年龄值为(216.6±3.2)Ma(2σ),40Ar/39Ar初始比值为297±28。相比之下,含矿隐爆角砾岩墙钾长石样品特定加热阶段(1200~1300℃和1360~1450℃)所获数据同样也构成两条直线,其对应的同位素等到时线年龄值分别为(227.9±4.8)Ma(2σ)和(216.7±6.1)Ma(2σ),40Ar/39Ar初始比值分别为307±41和269±39。考虑到所测样品均采自未受到明显后期构造-岩浆活动或其他热事件影响的岩(矿)体,因此,细粒钾长花岗岩株和含矿隐爆角砾岩墙的形成时代为216Ma,与印支期富钾岩浆作用具有密切成因联系。根据含矿隐爆角砾岩墙的野外地质证据,结合矿物共生组合关系和钾长石同位素年龄数值,可以推测牛圈银(金)矿区早期成矿作用发生在(227.9±4.8)Ma,而主要成矿期为(216.7±6.1)Ma,是印支期多阶段富碱质成矿流体活动的产物。牛圈银(金)矿区成矿作用时间的厘定对于提高该区成矿理论研究水平和寻找隐伏金属矿床均具重要意义。  相似文献   

7.
新疆东天山彩中花岗岩体锆石SHRIMP年龄及地球化学特征   总被引:15,自引:1,他引:15  
对新疆东天山康古尔塔格地区彩霞山一带的彩中岩体黑云母二长花岗岩进行了SHRIMP锆石U-Pb定年、主量和微量元素、Nd-Sr同位素研究。锆石206Pb/238U比值平均加权年龄为316±4(2σ)Ma,表明彩中岩体形成于石炭纪中期,因而修正了前人关于“早二叠世晚期侵入体”的时代划分方案。岩体的主、微量元素研究表明,彩中岩体为铝弱过饱和型钙碱性系列花岗岩,形成于岛弧环境。彩中黑云母二长花岗岩具有高的εNd(t)值(+8.5~+7.4)和低的87Sr/86Sr同位素比值(ISr=0.7034~0.7036),表明其物质来源为亏损的地幔源区。低的Nd模式年龄(TDM=0.38~0.47Ga),暗示其源区物质基本上未受到古老大陆地壳物质的混染。上述特征表明彩中花岗岩与东西准噶尔造山带的花岗岩类有可比性。  相似文献   

8.
江西省安远县园岭寨钼矿是南岭地区新发现的大型独立斑岩型钼矿床,矿体主要产出在园岭寨花岗斑岩与寻乌组变质岩的内外接触带中。通过对园岭寨钼矿系统的岩石学、地球化学和成岩成矿时代研究,结果表明,园岭寨花岗斑岩化学成分具有富K2O(6.52%~8.33%)、P2O5(0.17%~0.21%)、过铝质(A/CNK=1.33~1.59),高Mg#(53~68)、贫CaO(0.37%~2.99%)、Na2O(0.27%~1.01%)和K2O/Na2O>1的特征;微量元素以富含Rb,亏损Ba、Sr等大离子亲石元素(LILE)和富含U、Pb、Nd、Zr、Hf等,亏损Nb、Ta、La、Ce、P、Ti等高场强元素(HFSE)为主要特征,Eu负异常不明显(δEu=0.80~0.90),(La/Yb)N=9.27~13.18,轻重稀土分馏明显。结合成因类型判别图解和矿物学特征,园岭寨斑岩为典型的S型花岗岩,以壳源物质的重熔为主,并受一定程度的幔源物质影响。利用LA-MC-ICP-MS锆石U-Pb年龄,获得了花岗斑岩的成岩年龄为165.49±0.59Ma(MSWD=1.4,n=19);利用辉钼矿Re-Os同位素测年法,获得园岭寨钼矿床辉钼矿的结晶年龄为160±1~162.7±1.1Ma,属赣南燕山期第二次钼成矿作用(150~162Ma)。结合区域年代学资料和已知的矿床(点),指出本区进一步找矿工作应集中在中-晚侏罗世-早白垩世Mo、Pb、Zn等矿床的查找上。  相似文献   

9.
北京密云沙厂环斑花岗岩杂岩体黑钨矿钐—钕同位素研究   总被引:4,自引:0,他引:4  
鉴于缺少可直接用于同位素测年的金属矿物,许多钨矿床的成矿时代大多数是悬而未决的地质难题。本文以我国著名北京密云沙厂环斑花岗质杂岩体内产出的黑钨矿为研究对象,对钨矿床的形成年龄进行了测定,8件黑钨矿Sm-Nd同位素等时线年龄为1430±93Ma(2σ),Nd初始比值为0.510992±3(2σ)和ε_(Nd)(1430Ma)为-10.5±0.84(2σ),这是迄今在我国测定到的最老的钨矿床成矿年龄。通过对全国已有钨矿床同位素年龄数据的对比分析,并且结合它们的地质与地球化学特征,可以认为,我国最古老的钨矿床很可能形成于中元古代,而并非是古生代。另外,密云沙厂地区钨矿床的成矿作用与中元古代富矿碱性岩浆活动有关。  相似文献   

10.
苏北东海地区片麻岩的Nd—Sr同位素定年及其地质意义   总被引:2,自引:1,他引:1  
樊金涛  李金玉 《江苏地质》2000,24(4):193-199
苏北驼峰、牛山片麻岩的原岩是造山后拉张环境下形成的碱性花岗岩。其全岩Rb -Sr等时线法地质年龄为(80 4 8± 0 39)Ma、(797 7± 1 5 )Ma ,此值代表原岩的形成年龄 ,表明苏胶造山带于新元古代中期 (距今 80 0Ma± )已开始向裂解转化。由此推断碰撞造山运动应发生于新元古代早期 (距今 10 0 0Ma~ 90 0Ma)。其时代可与北美格林威尔造山带相当 ,应是Rodinia超大陆汇聚和裂解的组成部分。此外 ,其Nd模式年龄为 186 9Ma~ 1915Ma、1417Ma~ 144 0Ma ,揭示物质来源于前中元古代地壳重熔岩浆与上地幔物质的不同比例混合。  相似文献   

11.
Police, politics, and the right to the city   总被引:1,自引:0,他引:1  
Mustafa Dikeç 《GeoJournal》2002,58(2-3):91-98
Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ18O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.  相似文献   

14.
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.  相似文献   

15.
马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。  相似文献   

16.
The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.  相似文献   

17.
18.
在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明:玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。  相似文献   

19.
The mineral composition of the Talatui gold deposit has been studied with modern methods. Previously unknown minerals (ilmenite, siegenite, glaucodot, wittichenite, matildite, hessite, pilsenite, zircon, tremolite, cummingtonite, hercynite, and goethite) have been identified in the ore. A high Re content has been detected in molybdenite. The spatiotemporal separation of Au and Ag is caused by different mineral species of these elements and their diachronous precipitation during the ore-forming process. Gold crystallized along with early mineral assemblages, beginning from virtually pure gold (the fineness is 996). Silver precipitated largely at the end of the process as hessite (Ag2Te) and matildite (AgBiS2). The temperature of ore deposition varied from 610 to 145°C, the pressure was 3370–110 bar, and the salt concentration ranged from 56.3 to 0.4 wt % NaCl equiv. The heterogeneous state (boiling) of fluid at the early stages has been documented. The chemical and isotopic compositions of the fluid testify to its magmatic nature and the participation of meteoric water at late stages in the ore-forming process. Thermodynamic modeling reproduces the main specific features of ore formation, including separation of Au and Ag. A physicochemical model of the gold mineralization in the Darasun ore district has been proposed. On the basis of several attributes, the Talatui deposit has been referred to the prophyry gold-copper economic type.  相似文献   

20.
岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...  相似文献   

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