西藏邦铺钼(铜)矿床含矿二长花岗斑岩LA-ICP-MS锆石U-Pb定年及地质意义   总被引：8，自引：2，他引：6  

王立强  唐菊兴  陈毓川  冷秋锋  罗茂澄  陈伟  王焕 《矿床地质》2011,30(2):349-360

邦铺斑岩型钼(铜)矿床位于甲玛铜多金属矿床北东约30 km处,与钼(铜)成矿有关的岩体主要为二长花岗斑岩,次为花岗闪长斑岩及闪长(玢)岩.通过对二长花岗斑岩体进行LA-ICP-MS锆石U-Pb年龄测试,获得了含矿母岩的年龄,二长花岗斑岩的26颗锆石206Pb/238U加权平均年龄为(16.23±0.19)Ma(MSWD...  相似文献   

西藏邦铺钼铜矿区花岗斑岩成岩年龄研究   总被引：1，自引：0，他引：1  

温泉  多吉  温春齐  张学全  周雄  霍艳  费光春 《矿物岩石》2011,31(2)

邦铺钼铜矿床是发育于冈底斯成矿带的大型斑岩型钼铜矿床,矿区内岩浆岩发育,(二长)花岗斑岩为成矿母岩。利用斑岩中锆石离子探针U-Pb法和全岩Rb-Sr法测定邦铺含矿斑岩的年龄,以确定含矿斑岩的形成时代。花岗斑岩中锆石SHRIMP U-Pb法测定其年龄为14.2 Ma±0.2 Ma(MSWD=0.79);二长花岗斑岩中锆石SHRIMP U-Pb法测试值为13.9 Ma±0.3 Ma(MSWD=3.05);全岩Rb-Sr等时线年龄为13.88 Ma±0.38 Ma(MSWD=1.7)。因此14.2 Ma~3.9 Ma年龄值可以作为邦铺矿区含矿斑岩体的结晶年龄。  相似文献   

黑龙江鹿鸣钼矿区花岗质杂岩锆石U-Pb年龄、Hf同位素、辉钼矿Re-Os年龄及其地质意义   总被引：5，自引：2，他引：3  

程国华  王瑞良  曾庆栋  郭云鹏  段晓侠  魏金江  张俊生  高秀航 《岩石学报》2015,31(8):2450-2464

鹿鸣超大型钼矿(钼金属量89万吨,平均品位0.084%)产于小兴安岭-张广才岭成矿带北段,矿体呈细脉浸染状赋存于二长花岗斑岩和二长花岗岩体内,围岩蚀变有钾化、绢云母化、硅化、绿泥石化、碳酸盐化等,矿化类型主要为斑岩型矿化。鹿鸣矿区含矿岩体二长花岗斑岩和二长花岗岩的锆石U-Pb定年、Hf同位素及辉钼矿Re-Os同位素定年研究表明:二长花岗岩和二长花岗斑岩锆石的U-Pb年龄分别为186.8±2.1Ma和183.2±1.9Ma,形成于燕山早期,二长花岗斑岩晚于二长花岗岩。6个样品辉钼矿Re-Os等时线年龄为176.7±4.4Ma(MSWD=0.92),Re含量变化于30×10-6~49×10-6。二长花岗岩的锆石εHf(t)值变化于1.1~3.8,Hf单阶段模式年龄为729Ma,两阶段模式年龄为1055Ma;二长花岗斑岩的锆石εHf(t)值变化于0.4~5.9,Hf单阶段模式年龄为741Ma,两阶段模式年龄为1075Ma。研究表明成矿与二长花岗斑岩有关,并且二长花岗岩和二长花岗斑岩岩浆为中新元古代新生的地壳物质熔融的产物,成岩成矿作用与古太平洋板块俯冲作用(或佳木斯与松嫩地块的拼合)有关。  相似文献   

西藏邦铺斑岩矿床黑云二长花岗岩的形成时代及地球化学特征     

《矿物岩石地球化学通报》2017,(5)

邦铺是继驱龙、甲马之后在冈底斯斑岩铜矿带发现的又一大型斑岩型矿床。为探索邦铺矿区岩浆的起源、建立岩浆演化序列提供依据,本文对位于矿区西南侧的黑云二长花岗岩进行了主、微量元素,锆石U-Pb年代学,Sr-Nd-Pb-Hf同位素分析。结果显示,邦铺黑云二长花岗岩的SiO_2平均含量为73.52%,属钙碱性系列、弱过铝质花岗岩;其轻重稀土分异较明显,负Eu异常强烈,富集K、Rb、Th等大离子亲石元素,相对亏损P、Nb、Ta、Ti等高场强元素;锆石U-Pb年龄为(62.2±0.32)Ma,~(176)Hf/~(177)Hf值分布于0.282892~0.283014,εHf(t)均值为7.3。研究表明,邦铺黑云二长花岗岩起源于俯冲的特提斯洋壳板片脱水引起的地幔楔的部分熔融,地幔组分约占80%,岩浆在上升过程中,有较多地壳物质的加入,并经过了强烈的结晶分异作用。  相似文献   

西藏邦铺铅锌矿区石英二长斑岩锆石U-Pb年龄、Hf同位素和稀土元素特征及其地质意义   总被引：1，自引：0，他引：1  

陈伟  王立强  胡正华  罗茂澄  冷秋锋  唐晓倩  王艺云  杨毅  张志 《地球学报》2012,33(4):569-578

邦铺钼(铜)多金属矿床是冈底斯带新近发现的大型斑岩型矿床,矿区内发育大量不同类型、不同期次的侵入岩体。矿区南东方向接触带的铅锌矿床,尽管最早受到关注并进行开采,但研究程度却仍然相对较低。文章采用LA-ICP-MS锆石U-Pb测年和锆石Hf同位素、微量元素,首次对铅锌矿区内出露的含矿石英二长斑岩进行研究,23颗锆石206Pb/238U加权平均年龄为(15.43±0.12)Ma(MSWD=2.7,n=23),系中新世岩浆产物。在完成锆石测年后,同时对部分所测锆石进行了系统的Hf同位素原位分析,测得176Hf/177Hf值为0.282790～0.282913,εHf(t)变化范围为0.6～5.0,Hf同位素测试结果与亏损地幔地球化学储库的Hf同位素特征较为相似,表明石英二长斑岩的源区具亏损特征,但在岩浆演化过程中遭受了下地壳物质的混染。稀土元素结果显示轻稀土亏损,重稀土富集,明显的正Ce异常,Eu负异常,属典型的岩浆成因锆石。与前人对钼(铜)矿区的研究结果一致,故推断铅锌矿与钼(铜)矿为同一斑岩系统的产物。结合与区域上相邻的甲玛、驱龙矿床,该矿床显示出与甲玛、驱龙等超大型斑岩型矿床具有统一的地球动力学背景及深部岩浆活动。  相似文献   

西藏邦铺大型钼铜多金属矿床Rb-Sr等时线年龄及地质意义   总被引：2，自引：0，他引：2  

周雄  温春齐  张学全  曹盛远  吴鹏宇  周玉  费光春 《高校地质学报》2010,16(4):448-456

       西藏邦铺钼铜多金属矿床是西藏冈底斯斑岩铜矿带东段典型的大型斑岩型矿床,以钼、铜为主,共生铅、锌。本文通过二长花岗斑岩全岩 Rb-Sr 法和含钼铜矿石中的黄铁矿 Rb-Sr 等时线法,分别获得等时线年龄为（13.88±0.38）Ma （MSWD=1.7）和（11.0±1.5）Ma（MSWD=3.5）,代表二长花岗斑岩成岩、钼铜晚阶段的成矿年龄,结合锆石 SHRIMP U-Pb年龄（13.9±0.3）Ma 及含钼铜脉石英激光显微探针40Ar-39Ar 年龄（13.9±0.9）Ma,显示邦铺钼铜多金属矿床成岩、成矿年龄具有一致性,成矿时间持续约 3 Ma。锶同位素初始值（0.706538~0.709190）及幔源成分（Pm）含量（4.03%~51.65%）暗示邦铺二长花岗斑岩原始岩浆可能来自地幔,在冈底斯伸展构造背景下就位（14 Ma 前）,幔源岩浆和硅铝质地壳物质发生交换并遭受地壳物质混染,以幔源物质为主,壳源物质为辅。  相似文献   

黔西南晚侏罗世二长花岗斑岩的厘定及其年代学和地球化学研究     

杨恩林  周明忠  张宏伟  曾昭光  陆建宝  周克林 《矿物岩石地球化学通报》2023,(3):508-520

近期在燕山期岩浆活动缺乏的黔西南地区发现了罗悃二长花岗斑岩，为厘定其形成年龄，明确黔西南地区燕山期岩浆岩活动机制，本文对其进行了激光剥蚀电感耦合等离子质谱仪(LA-ICP-MS)锆石U-Pb定年，Hf同位素和主、微量元素分析。结果表明，18颗柱状锆石年龄为(157.8±0.4)Ma(MSWD=1.4),代表二长花岗斑岩的侵位年代为晚侏罗世；锆石的¹⁷⁶Hf/¹⁷⁷Hf值(0.282 390～0.282 478)和ε_Hf(t)(均值为-8.17)表明二长花岗斑岩的岩浆源区主要以富集地幔为主；岩石的SiO₂含量为65.91%,CaO为1.44%,Al₂O₃为15.67%,MgO为0.57%,TFe₂O₃为4.23%,K₂O为4.19%,Na₂O为5.72%,σ为3.76～4.98,A/CNK为0.93～0.96,显示富碱、准铝质的特征，应为I型花岗岩类；岩石的∑REE(32...  相似文献   

西藏邦铺斑岩矽卡岩矿床二长花岗斑岩Sr-Nd-Pb-Hf同位素及闪锌矿黄铁矿Rb-Sr等时线年龄研究   总被引：6，自引：0，他引：6  

赵晓燕  杨竹森  刘英超  裴英茹 《地质学报》2015,89(3):522-533

邦铺钼多金属矿是形成于印亚板块碰撞后碰撞伸展环境中的大型富Mo(~0.09%)、贫Cu(~0.32%),并且伴生Pb-Zn的斑岩-矽卡岩矿床。邦铺矿床位于冈底斯斑岩成矿带东段北侧,其成矿年代(~15.32Ma)与冈底斯斑岩成矿带内其它典型的斑岩矿床具有一致性(12~18Ma)。邦铺矿床除了富Mo(Cu),还含有大量的Pb-Zn矿石,其中Mo(Cu)以斑岩型矿化为特征,而Pb-Zn则主要赋存于矽卡岩之中。本文立足邦铺矿床两大问题:矿床富Mo原因和斑岩-矽卡岩两期矿化的关系,借助含矿岩体二长花岗斑岩Sr-Nd-Pb和锆石Hf同位素及共生闪锌矿和黄铁矿的Rb-Sr等时线年龄研究,为更好地了解矿床成因和冈底斯斑岩成矿带成矿规律提供依据。对矽卡岩矿区共生的黄铁矿闪锌矿进行Rb-Sr定年,87 Rb/87Sr=0.2351~7.903,87Sr/86Sr=0.714011~0.715539,闪锌矿和黄铁矿的Rb-Sr等时线年龄为13.93±0.87Ma,其成矿时间与斑岩成矿时间(辉钼矿Re-Os年龄15.32Ma)近于一致;同时,在空间上,随着距离二长花岗斑岩距离的增大,石榴子石减少,方解石及其它碳酸盐矿物增多,矽卡岩矿物组合由高温向低温转变,闪锌矿颜色由不透明向半透明过渡,暗示了温度连续下降的过程;所以无论时间还是空间上,邦铺斑岩矿化和矽卡岩矿化都属于同一成矿系统。邦铺二长花岗斑岩(87Sr/86Sr)i值介于0.707504~0.710012之间,变化范围较小;εNd(t)值为-3.96~-3.56,TDM2为1020~1050Ma;206 Pb/204 Pb、207 Pb/204 Pb、208Pb/204Pb分别为18.304~18.439、15.744~15.793、38.842~38.904;锆石176 Hf/177 Hf为0.282826~0.283009,平均值为0.282916,εHf(t)值为2.2~8.7,平均值为5.4;全岩Sr-Nd-Pb及锆石Hf同位素特征指示邦铺二长花岗斑岩为壳幔源岩浆混合作用的产物,其壳源组分的含量相对于冈底斯斑岩成矿带典型的含矿斑岩更高。幔源物质来源于上涌的软流圈地幔而壳源物质为加入大量古老地壳成分的新生下地壳;由于Mo、Pb、Zn主要来自于古老的下地壳,含有大量古老地壳物质的新生下地壳源区解释了邦铺Mo(Cu)-Pb-Zn的金属元素组合。  相似文献   

西藏朱诺斑岩铜 钼 金矿区侵入岩锆石U Pb年龄、Hf同位素组成及其成矿意义   总被引：2，自引：0，他引：2  

黄勇  丁俊  李光明  戴婕  闫国强  王刚  刘晓峰 《地质学报》2015,89(1):99-108

朱诺斑岩铜钼金矿位于冈底斯成矿带南缘,是近年来在冈底斯斑岩铜矿带最西端新发现的另一大型斑岩型铜-钼-金矿床,但一直以来对该矿区花岗岩年代学及成因分析缺乏系统的研究。本文选择矿区内主要岩浆岩体开展LA-ICP-MS锆石U-Pb定年,Hf同位素研究。获得黑云母花岗闪长岩锆石U-Pb年龄为14.14±0.32Ma,76 Hf/177 Hf介于0.282484~0.282750,εHf(t)介于-9.87~-0.49,二阶段模式年龄TDMC介于1.13~1.73Ga、似斑状二长花岗岩锆石U-Pb年龄为14.05±0.31Ma,176 Hf/177 Hf介于0.282633~0.282769,εHf(t)介于-4.61~0.21,二阶段模式年龄TDMC介于1.08~1.39Ga之间;角闪闪长玢岩锆石U-Pb年龄为14.10±0.29Ma,除4.1号为继承锆石外,其余测点176 Hf/177 Hf介于0.282607~0.282761,εHf(t)介于-5.53~-0.07,二阶段模式年龄TDMC介于1.10~1.45Ga之间。年代学与Hf同位素结果表明,朱诺斑岩铜矿与斑岩铜矿带中段和东段成岩成矿时代一致,集中在15~13Ma之间,指示了冈底斯在中新世的构造岩浆活动事件。花岗岩Hf同位素组成明显与中-东段斑岩矿床不同,具有富集Hf同位素特征以及古老二阶段模式年龄(1.08~1.73Ga)等特点,反映出朱诺矿区中新世岩浆岩源区与中-东段中新世斑岩矿床明显不同,可能指示古老拉萨地体的印迹。  相似文献   

西藏邦铺大型斑岩钼-铜矿床二长花岗斑岩锆石SHRIMP定年及其地质意义   总被引：3，自引：1，他引：2  

周雄  温春齐  温泉  吴鹏宇  曹盛远  费光春  霍艳  周玉 《矿物岩石地球化学通报》2010,29(4)

利用锆石U-Pb SHRI MP定年技术,测定了西藏冈底斯斑岩铜矿带东段邦铺斑岩钼铜矿床中二长花岗斑岩的年龄,获得该含矿岩体真实侵位年龄为13.9±0.3 Ma(MSWD=3.05),属于喜马拉雅晚期。邦铺二长花岗斑岩的形成时代介于冈底斯成矿带后碰撞期伸展构造环境的斑岩体的形成时代(12~18 Ma),该年龄的厘定进一步丰富了冈底斯带岩浆活动,并为整个冈底斯成矿带岩浆岩演化历史提供年代学数据和新的启示:可以认为其与冈底斯斑岩铜矿带具有相同的动力学背景,同属于大规模的快速爆发成矿作用过程。  相似文献   

云南金平铜厂斑岩铜钼矿区岩体锆石Ce⁴⁺/Ce³⁺比值及其对成矿的指示意义   总被引：4，自引：0，他引：4  

胥磊落  毕献武  陈佑纬  齐有强 《矿物学报》2012,(1):74-82

对金沙江—红河成矿带南段铜厂斑岩铜钼矿区含矿的石英正长斑岩和无矿的细粒正长岩开展了锆石的Ce4+/Ce3+比值、δCe及δEu值的研究,结果显示含矿的4个石英正长斑岩样品的锆石Ce4+/Ce3+比值变化范围为208～336,平均比值为265,δCe值变化范围为17.6～60.6,平均值为33.8,δEu值变化范围为0.592～0.628,平均值为0.611,不含矿的1个细粒正长岩样品的锆石Ce4+/Ce3+比值为61,δCe值为8.50,δEu值为0.424,含矿的石英正长斑岩的锆石Ce4+/Ce3+比值、δCe及δEu值均明显高于不含矿的细粒正长岩,反映了与成矿有关的岩浆具有相对高的氧化状态。对比金沙江—红河成矿带北段的玉龙斑岩铜钼矿带和中段的马厂箐斑岩铜钼矿的含矿与无矿岩体,它们的锆石Ce4+/Ce3+比值与南段铜厂斑岩铜钼矿含矿及无矿岩体具有基本类似的特征,含矿岩体的锆石Ce4+/Ce3+比值通常大于200,而不含矿岩体的锆石Ce4+/Ce3+比值基本上都小于120。这种差异对进一步认识金沙江—红河成矿带斑岩铜钼矿的岩浆氧逸度特征具有重要的理论意义,对斑岩铜钼矿的找矿工作具有一定的指导意义。  相似文献   

海南岛高通岭钼矿床赋矿岩体LA-ICP-MS锆石U-Pb年龄、Hf同位素和Ce⁴⁺/Ce³⁺特征     

朱昱桦  于亮亮  于得水  许德如  付王伟 《矿床地质》2017,36(1):185-199

高通岭钼矿床位于海南岛中部的早白垩世—晚白垩世高通岭岩体中,是一个小型热液脉型钼矿床。作者对赋矿围岩黑云母钾长花岗岩进行了岩相学观察、LA-ICP-MS锆石U-Pb定年、锆石Lu-Hf同位素测试和锆石微量元素分析。结果显示:赋矿围岩矿物组合为钾长石(45%~60%)、石英(20%~30%)、斜长石(10%~20%)及黑云母(10%~15%);矿石矿物以辉钼矿为主,矿石类型主要为石英脉型,次为蚀变黑云母钾长花岗岩型和碎裂岩型;高通岭岩体中的锆石,具有清晰的振荡环带,显示其岩浆成因;锆石U-Pb年代学研究获得206U/238Pb加权平均年龄为(102.5±1.8)Ma,锆石的~(176)Hf/~(177)Hf比值为0.282 349~0.282 663,εHf(t)为-12.8~-1.7,二阶段地壳模式年龄(TCDM)为1976~1271 Ma,峰值为1450~1400 Ma,锆石稀土元素配分模式显示高通岭岩体的陆壳源区属性。地表取样的黑云母钾长花岗岩(GTL-03和GTL-04)具有较低Ce~(4+)/Ce~(3+)比值(160左右),反映了较低氧逸度,钻孔取样的黑云母钾长花岗岩具有较高Ce~(4+)/Ce~(3+)比值(平均值377)。高通岭岩体总体上氧逸度较低,暗示其大规模成矿潜力较低。  相似文献   

Partitioning of Ni²⁺, Co²⁺, Fe²⁺, Mn²⁺ and Mg²⁺ between olivine and silicate melts: compositional dependence of partition coefficient   总被引：1，自引：0，他引：1  

Eiichi Takahashi 《Geochimica et cosmochimica acta》1978,42(12):1829-1844

Partitioning of Ni²⁺, Co²⁺, Fe²⁺, Mn²⁺ and Mg²⁺ between olivine and silicate melts has been determined near the join (Mg_0.5·-Fe_0.5)₂SiO₄-K₂O 4SiO₂ and for seven different basaltic compositions. The experiments were made at 1 atm total pressure, 1500-1100°C, and under moderate to reducing oxygen fugacities. The concentration factor, defined as K^MO = (MO)^ol/(MO)^liq (molar ratio), increases markedly for all the cations studied as the olivine component of the liquid decreases. Much of the increase in K^MO is considered as due to the compositional effect of the coexisting liquid: the temperature effect on K^MO is probably opposite to the compositional effect (K^MO decreases as temperature decreases).The partition coefficient K^MO-MgO = (MO/MgO)^ol/(MO/MgO)^liq for the reaction, M_ol²⁺ + Mg_liq²⁺ = M_liq²⁺ + Mg_ol²⁺. is relatively constant over a wide range of SiO₂ content of the liquid, except in the case of Ni²⁺. The partition coefficients have similar ranges both in synthetic and natural rock systems: K^NiO-MgO = 1.8–3.0, K^CoO-MgO = 0.6–0.8, K^FeO-MgO = 0.27–0.38, and K^MnO-MgO = 0.23–0.32. There is a systematic variation in the partition coefficient K^MO-MgO with the composition of liquid; K^MO-MgO increases with increasing SiO₂ content of melt. The partition coefficients for Co²⁺, Fe²⁺ and Mn²⁺ are useful to test the equilibration of olivine with magma of a wide compositional range.  相似文献   

Polymerization of silicate and aluminate tetrahedra in glasses,melts and aqueous solutions—II. The network modifying effects of Mg²⁺ , K⁺, Na⁺, Li⁺, H⁺, OH⁻, F⁻, Cl⁻, H₂O,CO₂ and H₃O⁺ on silicate polymers     

B.H.W.S. de Jong  Gordon E. Brown 《Geochimica et cosmochimica acta》1980,44(11):1627-1642

The effect of the group IA and VIIA ions, as well as Mg²⁺, and the molecules H₂O, CO₂, H₃O⁺ and OH^? on the energy of the Si-O bond in a H₆Si₂O₇ cluster has been calculated using semiempirical molecular orbital calculations (CNDO/2). Three types of elementary processes, i.e. substitution, addition, and polymerization reactions have been used to interpret data on the dynamic viscosity, surface tension and surface charge, hydrolytic weakening, diffusivity, conductivity, freezing point depression, and degree of polymerization of silicates in melts, glasses, and aqueous solutions. As a test of our calculational procedure, observed X-ray emission spectra of binary alkali silicate glasses were compared with calculated electronic spectra. The well known bondlength variations between the bridging bond [Si-O(br)] and the non-bridging bond [Si-O(nbr)] in alkali silicates are shown to be due to the propagation of oscillating bond-energy patterns through the silica framework. A kinetic interpretation of some results of our calculations is given in terms of the Bell-Evans-Polanyi reaction principle.  相似文献   

An electrochemical study of Ni²⁺, Co²⁺, and Zn²⁺ ions in melts of composition CaMgSi₂O₆     

Krystyna W. Semkow  Ronald A. Rizzo  Larry A. Haskin  David J. Lindstrom 《Geochimica et cosmochimica acta》1982,46(10):1879-1889

Cyclic voltammetry has been done for Ni²⁺, Co²⁺, and Zn²⁺ in melts of diopside composition in the temperature range 1425 to 1575°C. Voltammetric curves for all three ions excellently match theoretical curves for uncomplicated, reversible charge transfer at the Pt electrode. This implies that the neutral metal atoms remain dissolved in the melt. The reference electrode is a form of oxygen electrode. Relative to that reference assigned a reduction potential of 0.00 volt, the values of standard reduction potential for the ions are $\text{E}{}^1\text{(}\text{Ni}{}^{\mathrm{2+}}\text{Ni}{}^0\text{,}\text{diopside}\text{, 1500°C) = ?0.32 ± .01}\text{V}$, $\text{E}{}^1\text{(}\text{Co}{}^{\mathrm{2+}}\text{Co}{}^0\text{,}\text{diopside}\text{, 1500°C) = ?0.45 ± .02}\text{V}$, and $\text{E}{}^1\text{(}\text{Zn}{}^{\mathrm{2+}}\text{Zn}{}^0\text{,}\text{diopside}\text{, 1500°C) = ?0.53 ± .01}\text{V}$. The electrode reactions are rapid, with first order rate constants of the order of 10^?2 cm/sec. Diffusion coefficients were found to be 2.6 × 10^?6 cm²/sec for Ni²⁺, 3.4 × 10^?6 cm²/sec for Co²⁺, and 3.8 × 10^?6 cm²/sec for Zn²⁺ at 1500°C. The value of $\text{E1}$ ($\text{Ni}{}^{\mathrm{2+}}\text{Ni}{}^0$, diopside) is a linear function of temperature over the range studied, with values of ?0.35 V at 1425°C and ?0.29 V at 1575°C. At constant temperature the value of $\text{E}{}^1\text{(}\text{Ni}{}^{\mathrm{2+}}\text{Ni}{}^0\text{, 1525°C}$) was not observed to vary with composition over the range CaO · MgO · 2SiO₂ to CaO·MgO·3SiO₂ or from 1.67 CaO·0.33MgO·2SiO₂ to 0.5 CaO·1.5MgO·2SiO₂. The value for the diffusion coefficient for Ni²⁺ decreased by an order of magnitude at 1525°C over the compositional range CaO · MgO · 1.25SiO₂ to CaO · MgO · 3SiO₂. This is consistent with a mechanism by which Ni²⁺ ions diffuse by moving from one octahedral coordination site to another in the melt, with the same Ni²⁺ species discharging at the cathode regardless of the SiO₂ concentration in the melt.  相似文献   

矿物发光材料CaS∶Mn²⁺的合成及其荧光性质   总被引：1，自引：0，他引：1  

《矿物学报》2001,21(2):209-212

以方解石为原料,使用硫化助熔剂法合成了CaS∶Mn2+磷光体,根据荧光光谱,详细探讨了矿物杂质对其发光性质的影响,指出在矿物材料CaS∶Mn2+体系中,某些杂质离子拓宽了基质的激发带,有利于基质吸收能量及基质→Mn2+发射中心的能量传递,但Fe2+、Co2+、Ni2+等离子降低了Mn2+的发射强度,尤其是Mn2+与它们形成的成对离子中心或离子晶簇,降低了局域对称性,放宽了Mn2+跃迁发射的选择定则,加速了材料发光的衰减过程.  相似文献   

Microscope-photometric methods for non-destructive Fe²⁺ – Fe³⁺ determination in chloritoids (Fe²⁺, Mn²⁺, Mg)₂ (Al,Fe³⁺)₄ Si₂O₁₀(OH)₄     

Ulf Hålenius  Klaus Langer 《Lithos》1980,13(3):291-294

Six natural chloritoid crystals with Fe²⁺ and Fe³⁺ contents ranging from 4.15 to 12.81 and from 0.411 to 0.849g-atoms/l, respectively, as determined by means of microprobe and Mössbauer techniques, served as reference material to develop non-destructive microscope-spectrophotometric methods for quantitative Fe²⁺ – Fe³⁺ determinations in chloritoids from unpolarized spectra of (001) platelets. Fe²⁺ concentrations in g-atom/l can be obtained from [ [Fe³⁺]=C₁xD₁/t where D₁ = log₁₀(I_0/I at 28,000 cm^-1 and t=crystal thickness in cm; C₁ is a conttant that may be influenced somewhat by experimental conditions and is found to be 0.002289 with the experimental set-up used in this study. Fe²⁺ concentrations in g-atom/l can be obtained from [Fe²⁺]=C₁xD₁/D₁-C₃ with D₂=log₁₀(I₀/I) at 16,300 cm^?1 and constants C₄ = 45.36 and C₅ = 3.540. Due to the uncertainties in absorbance measurements, D₁ and D₂ and the thickness measurements, the accuracies are ±0.05 and ±0.15 g-atom/l for [Fe³⁺] and [Fe²⁺], respectively. The determinations may be carried out on chloritoid grains in normal thin sections with an areal resolution of ～10 μm.  相似文献   

腐殖酸与铅锌相互作用的实验地球化学   总被引：6，自引：0，他引：6  

卢家烂  傅家谟  刘金钟 《矿床地质》1995,14(4):362-368

腐殖酸是沉积有机质的成分。实验证明，腐殖酸对铅锌离子具有强烈的富集能力。通过替代反应初步确定了腐殖酸与Ｐｂ，Ｚｎ之间几种结合方式及各种结合方式占数据和比例；证实富非酸和胡敏酸与Ｐｂ＾２＋，Ｚｎ＾２＋之间形成了两大类络合物：一类其稳定常数小于ＥＤＴＡ－Ｐｂ（Ｚｎ）络合物；另一类稳定常数大于ＥＤＴＡ－Ｐｂ（Ｚｎ）络合物。  相似文献   

Thermodynamic model of natural brines accounting for the presence of trace components: II. System Na⁺, K⁺, Mg²⁺ ‖ Cl^?, Br^?-H₂O     

M. V. Charykova  N. A. Charykov 《Geochemistry International》2007,45(10):1040-1049

This paper reports the calculations of parameters for the Pitzer equation and thermodynamic potentials of solid phases crystallizing in water-salt systems modeling chloride brines taking into account the presence of bromide ions in them. Solubility diagrams were calculated for corresponding ternary and quaternary systems containing chlorides and bromides of sodium, potassium, and magnesium at 25°C. The results of calculations are in adequate agreement with the available published experimental data on solubility and can be used to model salt crystallization during the concentration of seawater and brines. Original Russian Text ? M.V. Charykova, N.A. Charykov, 2007, published in Geokhimiya, 2007, No. 10, pp. 1129–1138.  相似文献   

Mg²⁺ removal in the system Mg²⁺—amorphous SiO₂—H₂O by adsorption and Mg-hydroxysilicate precipitation     

Douglas B. Kent  Miriam Kastner 《Geochimica et cosmochimica acta》1985,49(5):1123-1136

Two chemical processes can remove Mg²⁺ from suspensions containing amorphous silica (am-SiO₂) at low temperatures: adsorption and precipitation of a Mg-hydroxysilicate resembling sepiolite. Mg²⁺ removal from am-SiO₂ suspensions was investigated, and the relative role of the two removal processes evaluated, as a function of: pH, ionic strength, Mg²⁺ concentration, and temperature.The extent of Mg²⁺ adsorption onto am-SiO₂ decreases with increasing NaCl concentration due to displacement of Mg²⁺ by Na⁺. At NaCl concentrations of 0.05 M and above, adsorption occurs only at pH values above 8.5, where rapid dissolution of am-SiO₂ gives rise to high concentrations of dissolved silica, resulting in supersaturation with respect to sepiolite. Removal of Mg²⁺, at concentrations of 40 to 650 μM, from am-SiO₂ suspensions in 0.70 M NaCl at 25 °C occurs at pH 9.0 and above. Experiments show that under these conditions adsorption and Mg-hydroxysilicate precipitation remove Mg²⁺ at similar rates. For 0.05 M Mg²⁺, at 0.70 M ionic strength and 25 °C, measurable Mg²⁺ removal occurs down to ca. pH 7.5 but is primarily due to Mg-hydroxysilicate precipitation. For the same solution conditions at 5°C, Mg²⁺ removal occurs above pH 8.0 and is primarily due to adsorption.Assuming that increasing pressure does not greatly enhance adsorption, Mg²⁺ adsorption onto am-SiO₂ is an insignificant process in sea water. The surface charge of pristine am-SiO₂ in sea water is primarily controlled by interactions with Na⁺. The principal reaction between Mg²⁺ and am-SiO₂ in marine sediments is sepiolite precipitation.The age distribution of sepiolite in siliceous pelagic sediments is influenced by temperatures of bottom waters and by geothermal gradients.  相似文献