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1.
南极拉斯曼丘陵莫愁湖和团结湖水中有机物剖析   总被引:2,自引:2,他引:0       下载免费PDF全文
本文给出了南极莫愁湖和团结湖水中有机物信息。在湖水中获得的121个化学组分中确定出93个有机化合物,其中包括正构烷烃、类异戊二烯烷烃、芳烃、多环芳烃、醇、醛、酮、酯、脂肪酸类及酞酸酯类等。其含量在0.027~4.79μg/L之间。湖水中检测出全球性有机物666、DDT和PCBs,浓度在0.012~0.356μg/L。  相似文献   

2.
白洋淀芦苇台地土壤理化因子及其酶活性特征   总被引:1,自引:0,他引:1  
2009年4月22日、6月23日、8月31日和10月31日,在白洋淀鸳鸯岛、北田庄和圈头村芦苇(Phragmites australis)台地3个垂直剖面(0~10cm、10~30cm和30~60cm)上采集了土壤样品,分析了不同季节的土壤理化因子和4种土壤酶活性的时空变化及其相互关系。结果表明,白洋淀芦苇台地土壤含水量随着土壤深度的增加而增加;土壤有机质含量随土壤深度的增加而减少,0~10cm表层土的有机质含量都在70g/kg以上;土壤的全氮和全磷含量随土壤深度的增加而减少,各采样地0~10cm表层土壤的全氮含量为2.04~3.41g/kg,全磷含量为0.71~1.14g/kg。3块采样地0~60cm土壤的蔗糖酶活性、碱性磷酸酶活性、脱氢酶活性和荧光素二乙酸酯(FDA)水解酶活性分别为0.53~28.56mg/g、0.44~2.36mg/g、1.62~12.18mg/g和8.07~172.65μg/g,表层土壤具有较大酶活性。芦苇台地4种土壤酶活性与土壤含水量呈显著负相关(p<0.01),与土壤有机质含量、全氮含量、全磷含量呈显著正相关(p<0.01)。  相似文献   

3.
青海可可西里东北部多秀湖和盐湖水化学特征研究   总被引:1,自引:1,他引:0  
2016年3月系统采集了青海可可西里东北部多秀湖和盐湖的湖水及其入湖冰川融水。研究发现,两个湖泊湖水中离子含量均较高,主要阳离子含量顺序均为Na~+Mg~(2+)K~+Ca~(2+),主要阴离子含量顺序均为Cl~-SO_4~(2-)HCO_3~-CO_3~(2-);而入湖冰川融水的离子含量非常低。根据库尔纳可夫—瓦良什科水化学分类标准,多秀湖湖水属于硫酸盐型—硫酸镁亚型,盐湖湖水属于硫酸盐型—硫酸钠亚型。多秀湖和盐湖湖水Li—Mg—B的相关性均为正相关,说明两个湖泊中这3种元素的物质来源、搬运条件及富集环境具有很强的相似性。由于气候变暖导致大量矿化度低的冰川融水注入盐湖,矿化度较低的卓乃湖和库赛湖决堤湖水泄入盐湖,使得盐湖的面积较1997年扩大了5倍,湖水的矿化度降低了约10倍,而多秀湖近些年湖水矿化度变化较小。多秀湖湖水矿化度以及Li~+、Mg~(2+)和B_2O_3含量均较高,具有较好的资源潜在利用价值。  相似文献   

4.
通过对九寨沟箭竹海沉积物样品中生物硅( BSi)含量的分析,讨论箭竹海沉积物中BSi含量与总有机碳(TOC)及粒度的关系,进而探讨BSi含量反映自然和人类因素对湖泊水体和沉积物的影响.箭竹海沉积物中BSi含量介于5.5~ 15.8 mg/g之间,BSi含量与TOC呈显著正相关关系.BSi含量还较显著地受到粒度影响,较细颗粒沉积物对BSi有较强的吸附作用.箭竹海沉积物中BSi含量变化与气温波动关系不密切,主要反映了森林砍伐和旅游开发等人类活动对湖泊水体和沉积物的影响.  相似文献   

5.
以青藏高原地区的大柴旦盐湖湖表卤水为研究对象,采用不同的固相萃取(Solid phase extraction,SPE)材料(HLB,PPL,ENVI-18,ENVI-Carb,XAD8和XAD4)对大柴旦盐湖湖表卤水中DOM进行了分离和富集,初步建立了从高盐体系盐湖卤水中高效分离富集出具有代表性的溶解性有机质(Dissolved organic matter,DOM)的方法,系统的考察了pH,上样体积,柱流速和洗脱溶剂对DOM回收率的影响。结合傅里叶变换红外光谱分析(Fourier transform infrared spectroscopy,FTIR)、热裂解—气相色谱—串联质谱分析(Pyrolysis-gas chromatography-mass spectrometry,Py-GC/MS)进一步对盐湖卤水分离物进行了谱学表征。研究结果表明,盐湖卤水在酸性条件下(pH=2),柱流速为0.5 mL/min时有助于吸附剂对DOM的吸附,而随着上样体积的增加,DOM的回收率逐渐下降,而甲醇是比较理想的洗脱剂。大柴旦盐湖湖表卤水中的DOM主要以芳香类,碳水化合物以及部分脂肪族化合物为主,而含氮类化合物含量较少。  相似文献   

6.
1Introduction“Anti-adsorptionphysicalycoatedmercuryfilmelectrodesystem”ASVmethodwasproposedbyInstituteofOceanology,ChineseAca...  相似文献   

7.
洪泽湖不同湖区表层沉积物对磷的吸附特征   总被引:1,自引:0,他引:1  
研究了洪泽湖9 个湖区表层沉积物对磷的吸附行为和沉积物对磷的吸附/解吸平衡质量浓度, 并分析了沉积物理化性质与磷吸附特征参数的关系。结果表明, 在低磷浓度条件下(0~1 mg/L), 沉积物对磷的最大吸附量为50.67~85.17 mg/kg, 沉积物在磷酸盐初始质量浓度较低时都存在负吸附(释放)现象。各湖区沉积物的吸附/解吸平衡磷浓度(EPC0) 范围为0.06~0.11mg/L, 均小于其上覆水中磷的含量, 沉积物对其上覆水中的磷表现为吸附作用。沉积物最大磷吸附量(Qmax)、本底吸附态磷量(NAP) 和总最大吸附磷量(TQmax) 与沉积物中活性铁和活性铝的含量显著正相关, 与沉积物中总磷、无机磷、有机磷和有机质的含量相关性不显著。吸附/解吸平衡浓度(EPC0) 与沉积物各理化参数之间没有表现出显著相关性。  相似文献   

8.
查干湖湿地水环境演变特征分析   总被引:1,自引:0,他引:1  
查干湖湿地是吉林西部重要的生态屏障,分析其水环境演变特征,可为保障其水环境安全提供科学依据。利用1982~2011年的水位资料和1985~2011年的水质资料分析其水环境演变特征,采用卡尔森指数法和模糊综合评价法对查干湖湿地进行综合营养状态和水质状况评价。结果显示引松工程通水后湿地水位得以恢复并稳定在129.8~130.3 m;20世纪80年代末湿地水环境大幅改善,水体盐碱化、富营养化、有机污染得以缓解,但2006年以来水质碱化和有机污染加剧,水质由Ⅲ类演变为IV类。现阶段农田退水缓解了主湖区的碱化且暂未加剧其水体富营养化。查干湖水受流域陆源排放、湖泊内源释放及水文情势等多重因素的交互作用,呈以磷素为限制的中营养状态,应控制区域生活污水和畜禽粪便的污染以保护其水环境健康。  相似文献   

9.
王冰  安慧君  吕昌伟 《干旱区地理》2013,36(6):1103-1110
呼伦湖是内蒙古第一大湖,在草原生态环境保护中举足轻重。在气候变化和人类活动的影响下,呼伦湖的水环境状况不容乐观。为了掌握呼伦湖水体的水质状况,在实地采样的基础上,基于地统计学半方差函数理论和GIS克立格空间插值方法,定量分析了呼伦湖水体溶解氧含量的空间变异特征及分布格局。结果表明:溶解氧的半方差拟合最优模型为球面模型,该水质参数具有强烈的空间自相关性;空间分布上,结合地表水环境质量标准,呼伦湖大部分水域的水质为IV类;考虑到鱼类等水生生物的生存需要,呼伦湖整体的溶解氧状况基本适合鱼类的生长,其中比较适合的区域分布在湖中部。  相似文献   

10.
昆明翠湖水质变化特征及影响因素研究   总被引:6,自引:2,他引:4  
翠湖是昆明非常重要的景观水体。通过对翠湖有代表性位点水样及相应底泥样品的采集,翠湖水样及底泥的主要指标进行监测、分析和评价。结果表明:目前翠湖水体(总磷含量0.38mg/L,总氮5.06mg/L,氨氮2.37mg/L)已属富营养化水体;翠湖水体总磷、总氮和氨氮含量随季节呈现明显动态变化,高锰酸盐指数和pH值等含量随季节变化不明显;底泥总磷含量3.02g/kg,速效磷163.29mg/kg,碱解氮493.41mg/kg,水体营养盐和底泥营养盐含量有明显相关性,底泥中营养盐总磷、速效磷和碱解氮含量对水体富营养程度有很大影响。  相似文献   

11.
Field observations showed that the characteristics of chemical composition of waters and the development of plankton algae in the lakes within the delta of the Selenga river are determined by their flowage. The most open Lake Nekipelovskoe communicates with the Selenga outlets throughout a year, and Lake Zavernyaikha only at the period of an open channel. Lake Semenovskoe and Lake Khlystov Zaton are located in the islands and are isolated from the outlets. According to composition of main ions, the lakes under investigation refer to the hydrocarbonate class, the calcium group. The sum of ions in the water of Lake Nekipelovskoe approaches the one in the Selenga (86?221 mg/dm3), and the highest sums of ions were recorded in the wintertime in the lakes isolated from the outlets (446?743 mg/dm3). The lakes of the delta are characterized by a high trophicity. The maximum concentrations of total phosphorus in Lake Nekipelovskoe and Lake Zavernyaikha were 68 and 122 μg mg/dm3, and in Lake Semenovskoe and Lake Khlystov Zaton ?0.8 and ?0.63 μg mg/dm3, respectively. The most intense development of algae is observed in Lake Zavernyaikha, which is due to the high population of Baikal endemics. Lake Zavernyaikha showed a close negative correlation between the concentration of NO 3 ? , mineral phosphorus and phytoplankton biomass; the correlation coefficient was ?0.8 and ?0.63, respectively. The lakes exhibited increased contents readily hydrolysable organic matter, and a decrease in dissolved oxygen concentration in winter; hydrogen sulfide was repeatedly recorded in Lake Khlystov Zaton. The water quality in the lakes during the springtime varies from “quite clean” to “weakly polluted”; at low-water periods, especially in winters, it can drop to the category of “exceedingly dirty”. The water quality of the Selenga can be influenced by the lakes during spring floods when material accumulated during the wintertime is transported to the river outlets and further to Lake Baikal.  相似文献   

12.
Europe Lake occupies a small, closed, basin that would have been an embayment in Lake Michigan during the high water level events in the larger lake. Cores recovered from the lake reveal late Holocene water level fluctuations in the basin that are inferred from changes in taxa and abundance of molluscs, ostracodes, magnetic susceptibility, organic carbon, and oxygen isotopes.Non-glacial, Holocene lacustrine/paludal sedimentation in this portion of the Europe Lake basin started after 6600 RCYBP and was probably initiated by a rise in the water table of the deep bedrock aquifer, during the Nipissing transgression in Lake Michigan. Isotopically light ground water from this source was probably a major contributor during this phase to the negative 18O spikes in Valvata tricarinata and Amnicola limosa.The start of stable lacustrine conditions is marked by maximum diversity of ostracode and mollusc taxa and a shift toward much more positive 18O values. The Europe Lake basin at this time became an embayment of Lake Michigan. This event was probably coeval with the peak of the Nipissing transgression, when the water plane reached an altitude of about 183 m.The isolation of Europe Lake from Lake Michigan started at about 2390 RCYBP and is probably due to a drop in water level in Lake Michigan and/or to isostatic uplift of the Door Peninsula. Since isolation from Lake Michigan, water levels in Europe lake have been controlled primarily by fluctuations in local precipitation, evaporation and ground water discharge.  相似文献   

13.
Salinity fluctuations in lakes of semi-arid regions have long been recognised as indicators of palaeoclimatic change, and have provided a valuable line of evidence in palaeo-climatic reconstruction. In the present study, fossil remains of diatoms and midges were used to reconstruct salinity changes at Mahoney Lake from the early postglacial, through the early, mid and late Holocene. A transition from midges typical of a freshwater community (Protanypus, Sergentia, Heterotrissocladius, Cladopelma, Dicrotendipes) during the early postglacial, to those indicative of saline environments (Cricotopus/Orthocladius, Tanypus) occurred in the early Holocene. The midge-inferred salinity values reflected the shift from freshwater (0.031 g/L) immediately after deglaciation, to saline water (2.4 to 55.2 g/L) in subsequent periods. A less saline period was found to have occurred after 1000 yr BP, suggesting a cooler or wetter period. The diatom record indicates similar trends, with freshwater taxa (e.g.,Cyclotella bodanica var. aff.lemanica) dominating near the bottom of the core. Diatom-inferred salinities indicate that saline conditions (about 30 g/L) prevailed throughout subsequent Holocene time, although relatively fresh conditions are indicated following deposition of the Mazama Ash, and from about 1500 yr BP until the present day. Midge and diatom-inferred salinity reconstructions for Mahoney Lake compare favorably with each other, and with climate trends inferred from earlier palynological evidence. The palaeosalinity record thus contributes new data relevant to past climatic conditions, in a region where little data have previously been collected.  相似文献   

14.
2010年、20111年和2012年7月对北京翠湖湿地水环境进行跟踪调查与监测,评估湿地恢复之后翠湖湿地水环境的改善效果。恢复区水体pH值、总氮(TN)、总磷(TP)、电导率(EC)和溶解氧(DO)等指标在3年间都表现为下降趋势。其中,pH值从2010年的8.36降到2012年的7.44;TN从2010年的1.94 mg/L降到2012年的1.76 mg/L;TP从2010年的0.129 mg/L降到2012年的0.117 mg/L。说明翠湖湿地经过湿地恢复后,总氮(TN)、总磷(TP)去除效果明显,湿地水环境良好改善,水体自净能力得到加强。本研究可为湿地水环境恢复评估及管理提供一定的科学依据。  相似文献   

15.
青藏高原对全球气候变暖响应敏感,研究青藏高原近千年来环境演化过程、规律与驱动机制对预测其未来气候可能发生的变化有重要参照意义.通过位于青藏高原东部的苦海沉积物总有机质相关指标[总有机碳(TOC)、总氮(TN)、总有机碳与总氮比值(TOC/TN)和总有机碳同位素(δ13Corg)]的研究重建了该区域过去840年来的环境演...  相似文献   

16.
青海湖典型湿地土壤重金属分布特征   总被引:4,自引:0,他引:4  
重金属污染是当今土壤污染中影响面最广、危害最大的环境问题之一。对青海湖典型湿地土壤Cu、Zn、Pb、Cr、Fe、Mn 6种重金属元素的含量及分布特征进行了调查分析。结果表明:青海湖湿地土壤Cu、Zn、Pb、Cr、Fe、Mn 6种重金属元素的平均含量分别为16.34μg/g、46.82μg/g、15.65μg/g、58.49μg/g、14.57mg/g和33.08μg/g;青海湖区南北两岸典型湿地土壤重金属含量存在明显的空间差异。南北两岸样带上表层土壤Cu、Cr、Fe的含量变化均呈"W"形,Zn仅在青海湖北岸样带表现出"W"形,Mn元素含量在400m处为最低点,Pb没有表现出明显的变化特征;Cu、Zn、Pb 3种元素含量呈极显著相关,说明青海湖湿地土壤重金属污染有一定的同源性。  相似文献   

17.
Since the construction of the Three Gorges Dam, the Poyang Lake hydrological characteristics obviously changed. During the impoundment period of the Three Gorges Reservoir, the hydrodynamic factors of Poyang Lake varied. Water level dropped, the velocity decreased and water exchange time lengthened, which changed the release of phosphorous from sediments. In order to investigate how the hydrodynamic factors influence the release of phosphorous from sediments, we used a two-way annular flume device to simulate the release characteristics of phosphorous from sediments under variable water levels and velocities. We found that both water level rising and velocity increasing could enhance the disturbance intensity to sediments, which caused the increase of suspended solids (SS) concentration, total phosphorus (TP) concentration in the overlying water, and the ability that phosphorus released to overlying water from sediments enhanced as well: when overlying water velocity maintained 0.3 m/s, SS concentration increased to 4035.85 mg/L at the water level 25 cm which was about 25 times compared to the minimum value and TP concentration in the overlying water also reached the maximum value at the water level 25 cm which was 1.2 times that of the value at 10 cm; when water level maintained 15 cm, SS concentration increased to 4363.35 mg/L at the velocity of 0.5 m/s which was about 28 times compared to the value of 0 m/s, and TP concentration in the overlying water increased from 0.11 mg/L to 0.44 mg/L. When the water level maintained 15 cm, the phosphorous release rate reached the maximum value of 4.86 mg/(md) at 0.4 m/s. The concentration of total dissolved phosphorous (TDP) and soluble reactive phosphate (SRP) both in overlying water and sediment-water interface were negatively correlated with pH. Using the parabolic equation, the optimum water level at a velocity of 0.3 m/s was calculated to be 0.57 cm, and the optimum velocity at water level of 15 cm was found to be 0.2 m/s.  相似文献   

18.
We examine the ecological aspects concerning the status of the surface waters in the delta of the Selenga river for the low-water conditions which have been observed since 1996. The ongoing changes in the most important indicators of the status of the waters in the river delta are assessed on the basis of results of hydrological, hydrochemical and hydrobiological investigations made by these authors in 2013–2015 and with consideration for earlier research efforts. It is established that the low-water conditions resulted in a decrease of the role of the main delta branches, Kharauz and Levoberezhnaya, in streamflow. An increase in the contribution of groundwater in the alimentation of the river led to an increase in concentrations of main ions: for the current low-water period their total content has varied from 119 to 780 mg/L, with a maximum in small delta branches in the wintertime. Changes in concentrations of biogenic elements were recorded: total phosphorus from 10 to 190 μg P/L, mineral phosphorus from 0 to 35 μg P/L, and nitrate nitrogen from 0.01 to 0.81 μg N/L. A minimum of mineral phosphorus compounds and nitrogen was observed at the time of mass development of algae. It is established that the dynamics of organic matter content is determined by changes in hydraulicity, and by the intensity of phytoplankton development. Within the long-term context, a deterioration of water regime and vegetation infill and swamping of shallow delta branches were recorded. The development level of the phytoplankton and changes in its structure point to a progressive eutrophication of the Selenga waters. According to the value of the saprobic index, the quality of the Selenga waters corresponds largely to the category of “moderately polluted” waters (class II and III), and it decreases at low-water periods, especially in shallow delta branches with a high population of cryptophytic algae, to the category of “polluted” waters.  相似文献   

19.
The water quality of Dianchi Lake declines quickly and the eutrophication is getting serious. To identify the internal pollution load of Dianchi Lake it is necessary to evaluate its sediment accumulation. Sedimentation rates of Dianchi Lake are determined by 137Cs dating. However, 137Cs vertical distribution in sediment cores of Dianchi Lake has special characteristics because Dianchi Lake is located on the southeast of the Qinghai-Tibet Plateau, the Kunming quasi-stationary front is over the borders of Yunnan and Guizhou where the specific precipitation is distributed. Besides 1954, 1963 and 1986 137Cs marks can be determined in sediment cores, a 137Cs mark of 1976 representing the major period of 137Cs released from China unclear test can be determined and used for an auxiliary dating mark. Meanwhile Dianchi Lake is divided into seven sections based on the water depth, basin topography, hydrological features and supplies of silt and the lakebed area of each section is calculated. The mean annual sedimentation rates for seven sections are 0.0810, 0.1352, 0.1457, 0.1333, 0.0904, 0.1267 and 0.1023 g/cm2a in 1963–2003, respectively. The gross sediment accumulation of the lake is 26.18×104 t/a in recent 17 years and 39.86×104 t/a in recent 50 years.  相似文献   

20.
借助137Cs估算滇池沉积量   总被引:4,自引:0,他引:4  
The water quality of Dianchi Lake declines quickly and the eutrophication is getting serious. To identify the internal pollution load of Dianchi Lake it is necessary to evaluate its sediment accumulation. Sedimentation rates of Dianchi Lake are determined by 137Cs dating. However, 137Cs vertical distribution in sediment cores of Dianchi Lake has special character-istics because Dianchi Lake is located on the southeast of the Qinghai-Tibet Plateau, the Kunming quasi-stationary front is over the borders of Yunnan and Guizhou where the specific precipitation is distributed. Besides 1954, 1963 and 1986 137Cs marks can be determined in sediment cores, a 137Cs mark of 1976 representing the major period of 137Cs released from China unclear test can be determined and used for an auxiliary dating mark. Meanwhile Di-anchi Lake is divided into seven sections based on the water depth, basin topography, hy-drological features and supplies of silt and the lakebed area of each section is calculated. The mean annual sedimentation rates for seven sections are 0.0810, 0.1352, 0.1457, 0.1333, 0.0904, 0.1267 and 0.1023 g/cm2 a in 1963-2003, respectively. The gross sediment accu-mulation of the lake is 26.18×104 t/a in recent 17 years and 39.86×104 t/a in recent 50 years.  相似文献   

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