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1.
We present results from multiple stable isotope analyses (δ18O of chironomid larval head capsules, chironomid adult thoraxes and other insect remains and δD, δ13C, δ15N of total organic matter—TOM) of a lake sediment core (04-SVID-03) taken from Stora Vidarvatn in northeastern Iceland to reconstruct past environmental, limnological and δ18O of past lake water changes during the Holocene. Core 04-SVID-03 represents a ∼12,000 cal. yrs BP to present record. Large magnitude changes in δ18O occurred during the Holocene at the site. Downcore shifts in δ18O of chironomids did not correlate with measurements of the δ13C and δ15N of chironomid head capsules, implying that the δ18O changes were not primarily driven by changes in chironomid diet during the Holocene. The δD of TOM provided a proxy of relative lake-water δD changes at the site and also showed large magnitude changes during the record. This approach was supported by analyses of a modern training set where δDTOM analyses were conducted using surface sediments from a suite of freshwater lakes over a large latitudinal gradient. The magnitude of changes in both the δ18O and δD and the relatively negative δ18O values throughout much of the core suggest that the proxies represent more paleoenvironmental information than solely temperature. Additional possible influences on lake-water isotopic composition are discussed, including changes in the seasonality of precipitation, in the patterns of air masses supplying precipitation to Iceland and in the dominant mode of the North Atlantic Oscillation.  相似文献   

2.
Long-chain alkenones, a group of sensitive organic molecular indicators of water temperature, have been rather extensively studied in marine environments. However they have never been systematically examined in lacustrine environments, despite reports of their occurrence in lake sediments. Here, we report on a recent study of long-chain alkenones in a sedimentary core from a high altitude (≈5400 m) salt lake, Zabuye Salt Lake (ZSL), Tibet. This is a critical location for global climate studies, especially of the atmospheric circulation of the North Hemisphere. C37−C39 methyl and/or ethyl alkenones, usually dominated by components with tetra- and tri-double bounds, are commonly the major components of the polar fraction of the extracted organic matter from most sections. Down-core (vertical) variation of alkenone indices, the measure of molecular unsaturation, is compared primarily with other environmental signals, including lithology, elemental and mineral compositions, and stable carbon isotopes of hydrocarbon biomarkers of this core. Down-core profiles of alkenone climatic indices (U 37 k and U 38 k ) suggest ZSL had two warm periods, one during ≈20–30 ka (≈Jabula Interglacial Optimum) and another at 8–5 ka (Middle Holocene Optimum), and a severe cold period from ≈18–11 ka (Last Glacial Maximum). The proposed warmer intervals are generally characterized by higher contents of carbonate, organic carbon, alkenones and heavier δ13C values ofn-alkanes.  相似文献   

3.
Walker Lake, a hydrologically closed, saline, alkaline lake located along the western margin of the Great Basin of western United States, has experienced a 77% reduction in volume and commitment drop in lake level as a result of anthropogenic perturbations and climatic fluctuations over the last century. The history of lake-level change in Walker Lake has been recorded instrumentally since 1860. A high-resolution multi-proxy sediment core record from Walker Lake has been generated through analysis of total inorganic carbon (TIC), total organic carbon (TOC), and oxygen and carbon isotope ratios (δ18O and δ13 C) of both downcore bulk TIC and ostracods over the last 200 yr. This allows us to examine how these sediment indices respond to actual changes in this lake’s hydrologic balance at interannual to decadal timescales. In Walker Lake sediments, changes in %TIC, %TOC, and δ13C and δ18O of TIC and ostracods are all associated to varying degrees with changes in the lake’s hydrologic balance, with δ18O of the TIC fraction (δ18OTIC) being the most highly correlated and the most effective hydrologic indicator in this closed-basin lake. The δ18OTIC record from Walker Lake nearly parallels the instrumental lake-level record back to 1860. However, comparison with sporadic lake-water δ18O and dissolved inorganic carbon δ13C (δ13CDIC) results spanning the last several decades suggests that the isotopic values of downcore carbonate sediments may not be readily translated into absolute or even relative values of corresponding lake-water δ18O and δ13CDIC. Changes in the lake’s hydrologic balance usually lead to changes in isotopic composition of lake waters and downcore sediments, but not all the variations in downcore isotopic composition are necessarily caused by hydrologic changes.  相似文献   

4.
We present isotope, cladoceran and diatom results from investigations of Eemian sediments of the palaeolake at Ruszkówek, central Poland. Our analyses of the 15-m-thick sediments indicate that sandy silts occur on the bottom, followed by calcareous gyttja, interbedded with lake marl. The upper part of the sequence contains peat and peaty sands. Values of δ18O change from −9.4‰ to −3.3‰ and δ13C values oscillate between −3.2‰ and +7.0‰. Nine isotope zones (Is) were defined and characterized using stable isotope analysis of carbonates. Fifteen species of subfossil Cladocera were found and six faunal zones were distinguished (Cladocera zones). One hundred and twenty-three diatom taxa, representing 31 genera were identified, enabling us to discern six Diatom Assemblage Zones. The isotope, cladoceran, and diatom data correlate well with pollen data that define seven phases of evolution of the palaeolake at Ruszkówek. The palaeolake began during the final phase of the Wartanian (Late Saalian Glaciation). During the early Eemian, the palaeolake reached its maximum depth. During the Early Vistulian glaciation, the palaeolake declined. Changes in the cladoceran and diatom communities indicate initial oligotrophic conditions in the lake, then an increase to mesotrophy, and finally eutrophic conditions.  相似文献   

5.
Continuous terrestrial records of paleoclimate and paleovegetation that extend to the late Pleistocene are rare for the circum-Caribbean uplands. In this study we analyzed the bulk and compound-specific carbon isotope composition of lake sediments spanning this period from Lago de las Morrenas 1 (LM1), a glacial lake in the highlands of southern Costa Rica, for evidence of climate and vegetation changes that may not have been apparent in previous analyses. The stable carbon isotope ratios of n-alkanes typically derived from terrestrial plants (δ13CC27–C33) indicate an increased abundance of C4 plant taxa during the late Pleistocene and earliest Holocene that may be related to decreased atmospheric carbon dioxide concentrations, increased aridity, or habitat availability. These n-alkane isotope ratios also provide evidence of more arid conditions during the early and late Holocene, and more mesic conditions during the middle Holocene, a pattern prevalent in other paleoclimate records from the region that is thought to be related to millennial-scale dynamics of the intertropical convergence zone (ITCZ). The sensitivity of the LM1 paleorecord to trade wind dynamics provides further support for the role of millennial-scale shifts in ITCZ dynamics in driving neotropical environmental change, and indicates that the effects of ITCZ migration were not limited to the lowlands.  相似文献   

6.
Total organic carbon (TOC), total nitrogen (TN) and total phosphorus (TP) were determined in combination with stable isotope ratios of carbon and nitrogen (δ13COrg, δ15N) in a 63 cm sediment core from Longgan Lake, located in the middle reaches of the Yangtze River, China. These geochemical and isotopic records provide a continuous history of lake productivity and trophic state of Longgan Lake since 1890. Variations of δ13COrg, TOC, TN and TP indicate that primary productivity of Longgan Lake increased continuously during the last century and that the trophic state of the lake shifted from oligotrophic to mestrotrophic conditions accordingly. Anthropogenic sources of organic carbon (OC), nitrogen (N) and phosphorus (P) were distinguished from their natural background in the sediments using mass accumulation rates. Element mass accumulation rates suggested increased human activities in the lake’s catchment since 1950s, were especially the utilization of artificial fertilizers amplified the anthropogenic input of N and P into the lake. In the course of the improved availability of dissolved nutrients also primary productivity of Longgan Lake increased, resulting in an increase of the Suess-effect corrected organic carbon isotope ratios. δ15N of bulk sediments show a marked shift towards lower values around 1950 that has been attributed to the input of nitrogen from chemical fertilizers characterized by relatively depleted isotopic signatures into the lake.  相似文献   

7.
We quantified differences in oxygen isotope fractionation among three biostratigraphically important subfossil ostracod species (Metacypris cordata, Pseudocandona rostrata and Candonopsis kingsleii) from an early Holocene freshwater tufa layer in northern Estonia. Estimated mean δ18O values are −10.05‰ for M. cordata, −9.34‰ for C. kingsleii and −8.75‰ for P. rostrata. All three species exhibit positive offset from the weighted mean annual δ18O of contemporary precipitation (−10.7‰ in δ18OV-PDB) and from the mean δ18O value of authigenic tufa carbonate (−10.64‰) in the ostracod-bearing layer. Assuming that the known oxygen isotope fractionation in P. rostrata (+2.5‰) and M. cordata (+1.5‰) has remained constant over time, the theoretical δ18OV-SMOW of the early Holocene lake water was calculated to have been between −11.52 and −11.92‰, slightly less negative than the local Ordovician groundwater (−11.7 to −12.2‰). δ18O values of the tufa carbonate differ by +0.6 to +1.0‰ from the calculated theoretical isotope composition (δ18OV-PDB) of lake water, indicating that the tufa also did not precipitate in isotopic equilibrium with ambient waters. Results show that the greater the δ18O offset from the calculated, theoretical isotope composition of lake water for an ostracod species, the lower is its preferred mean July temperature. Both our data and earlier published results on δ18O values in Holocene lacustrine carbonates and ostracods from north-eastern Europe, display pronounced decreases in δ18O with an increase in latitude of the study site. This suggests that temperature-dependent, and therefore latitude-dependent isotopic composition of meteoric waters controlled the δ18O values in lacustrine tufa and ostracods throughout the Holocene.  相似文献   

8.
Lake sediments contain archives of past environmental conditions in and around water bodies and stable isotope analyses (δ13C and δ15N) of sediment cores have been used to infer past environmental changes in aquatic ecosystems. In this study, we analyzed organic matter (OM), carbon (C), nitrogen (N), phosphorus (P), and δ13C and δ15N values in sediment cores from three subtropical lakes that span a broad range of trophic state. Our principal objectives were to: (1) evaluate whether nutrient concentrations and stable isotope values in surface deposits reflect modern trophic state conditions in the lakes, and (2) assess whether stratigraphic changes in the measured variables yield information about shifts in trophic status through time, or alternatively, diagenetic changes in sediment OM. Three Florida (USA) lakes of very different trophic status were selected for this study. Results showed that both δ13C and δ15N values in surface sediments of the oligo-mesotrophic lake were relatively low compared to values in surface sediments of the other lakes, and were progressively lower with depth in the sediment core. Sediments of the eutrophic lake had δ13C values that declined upcore, whereas δ15N values increased toward the sediment surface. The eutrophic lake displayed δ13C values intermediate between those in the oligo-mesotrophic and hypereutrophic lakes. Sediments of the hypereutrophic lake had relatively higher δ13C and δ15N values. In general, we found greater δ13C and δ15N values with increasing lake trophic state.  相似文献   

9.
We used elemental carbon, nitrogen, phosphorus and hydrogen ratios (C/N, N/P and H/C) with total organic carbon (TOC) and total phosphorus (TP) as well as stable carbon and nitrogen isotopes (δ13C and δ15N) to investigate the source and depositional conditions of organic matter in sediments from Zeekoevlei, the largest freshwater lake in South Africa. Typical C/N (10–12), H/C ratios (≥1.7) and δ13Corganic values (−22 to −19‰) together with the increase in TOC concentration indicate elevated primary productivity in lower middle (18–22 cm) and top (0–8 cm) sections of the sediment cores. Seepage of nutrients from a nearby waste water treatment plant, rapid urbanization and heavily fertilized farming in the catchments are responsible for the increased productivity. Consistent with this, measured δ15Norganic values (∼11‰) indicate increased raw sewage input towards the top-section of the core. Although cyanobacterial blooms are evident from the low δ15N values (∼3‰) in mid-section of the core, they did not outnumber the phytoplankton population. Low N/P ratio (∼0) and high TP (100–2,200 mg l−1) support cyanobacterial growth under N limited condition, and insignificant input of macrophytes towards the organic matter pool. Dredging in 1983, caused sub-aerial exposure of the suspended and surface sediments, and affected organic matter preservation in the upper mid-section (12–14 cm) of the core.  相似文献   

10.
We conducted multi-proxy geochemical analyses (including measurements of organic carbon, nitrogen and sulphur stable isotope composition, and carbonate carbon and oxygen isotope composition) on a 13.5 m sediment core from Lake Bliden, Denmark, which provide a record of shifting hydrological conditions for the past 6,700 years. The early part of the stratigraphic record (6,700–5,740 cal year BP) was wet, based on δ18Ocarb and lithology, and corresponds to the Holocene Thermal Maximum. Shifts in primarily δ18Ocarb indicate dry conditions prevailed from 5,740 to 2,800 cal year BP, although this was interrupted by very wet conditions from 5,300 to 5,150, 4,300 to 4,050 and 3,700 to 3,450 cal year BP. The timing of the latter two moist intervals is consistent with other Scandinavian paleoclimatic records. Dry conditions at Lake Bliden between 3,450 and 2,800 cal year BP is consistent with other paleolimnological records from southern Sweden but contrasts with records in central Sweden, possibly suggesting a more northerly trajectory of prevailing westerlies carrying moisture from the North Atlantic at this time. Overall, fluctuating moisture conditions at Lake Bliden appear to be strongly linked to changing sea surface temperatures in the Greenland, Iceland and Norwegian seas. After 2,800 cal year BP, sedimentology, magnetic susceptibility, δ13CORG, δ13Ccarb and δ18Ocarb indicate a major reduction on water level, which caused the depositional setting at the coring site to shift from the profundal to littoral zone. The Roman Warm Period (2,200–1,500 cal year BP) appears dry based on enriched δ18Ocarb values. Possible effects of human disturbance in the watershed after 820 cal year BP complicate attempts to interpret the stratigraphic record although tentative interpretation of the δ18Ocarb, magnetic susceptibility, δ13CORG, δ13Ccarb and δ18Ocarb records suggest that the Medieval Warm Period was dry and the Little Ice Age was wet.  相似文献   

11.
Sediment cores from Lakes Punta Laguna, Chichancanab, and Petén Itzá on the Yucatan Peninsula were used to (1) investigate “within-horizon” stable isotope variability (δ18O and δ13C) measured on multiple, single ostracod valves and gastropod shells, (2) determine the optimum number of individuals required to infer low-frequency climate changes, and (3) evaluate the potential for using intra-sample δ18O variability in ostracod and gastropod shells as a proxy measure for high-frequency climate variability. Calculated optimum sample numbers (“n”) for δ18O and δ13C in the ostracod Cytheridella ilosvayi and the gastropod Pyrgophorus coronatus vary appreciably throughout the cores in all three lakes. Variability and optimum “n” values were, in most cases, larger for C. ilosvayi than for P. coronatus for δ18O measurements, whereas there was no significant difference for δ13C measurements. This finding may be explained by differences in the ecology and life history of the two taxa as well as contrasting modes of calcification. Individual δ18O measurements on C. ilosvayi in sediments from Lake Punta Laguna show that samples from core depths that have high mean δ18O values, indicative of low effective moisture, display lower variability, whereas samples with low mean δ18O values, reflecting times of higher effective moisture, display higher variability. Relatively dry periods were thus consistently dry, whereas relatively wet periods had both wet and dry years. This interpretation of data from the cores applies to two important periods of the late Holocene, the Maya Terminal Classic period and the Little Ice Age. δ18O variability during the ancient Maya Terminal Classic Period (ca. 910–990 AD) indicates not only the driest mean conditions in the last 3,000 years, but consistently dry climate. Variability of δ13C measurements in single stratigraphic layers displayed no relationship with climate conditions inferred from δ18O measurements.  相似文献   

12.
The reliability of paleoclimatic inferences from lake-sediment records rests on the understanding of how various sediment indicators respond to environmental changes. Despite the recent proliferation of paleoclimatic records, only a limited number of studies have rigorously evaluated potential indicators by comparing lake-sediment records with instrumental weather data. We analyzed annually laminated sediments of the past 100 years from a lake in north-central Minnesota for a suite of variables commonly used for climatic reconstructions. Results were compared with time series of climatic or climate-derived variables, as well as with indices of climate modes thought to influence the regional climate of the midwestern United States. The oxygen-isotopic composition of calcite (δ18Oc) shows trends similar to those of effective moisture (as measured by precipitation [P] minus actual evapotranspiration [AET], P-AET, and the Palmer Drought Severity Index [PDSI]), with high δ18Oc values generally corresponding to low P-AET and low PDSI. δ18Oc also exhibits striking correspondence with the index of Pacific Decadal Oscillation (PDO) but it lags behind PDO by 3 years. Elevated δ18Oc values during the warm PDO phase probably reflect warm and dry climatic conditions in the midwestern US, especially during winter months. The carbon-isotopic composition of calcite (δ13Cc) shows some similarity with δ18Oc but also displays stratigraphic patterns resembling those of lake-productivity indicators, including biogenic silica, inverse of inorganic carbon, ratio of organic carbon to nitrogen, and to a lesser extent, organic carbon. δ13Cc is correlated with mean annual air temperature (MAAT) and the index of Atlantic Multidecadal Oscillation (AMO), probably because elevated MAAT stimulates the rate of algal carbon uptake, lengthens growing season, and/or enhances CO2 degassing. Varves are typically thicker during periods of lower δ18Oc and higher P-AET (or PDSI) values, because wet climatic conditions probably increase nutrient availability and lake productivity. Gray-scale intensity does not co-vary with any of the above climatic variables or climate-mode indices. These results demonstrate the utility of lake-sediment analyses for reconstructing temperature, drought, and large-scale climatic modes at Steel Lake. However, application to down-core reconstructions may be compromised by a number of factors, including the site specificity and non-stationarity of such relationships.  相似文献   

13.
Stable isotope analysis of ostracod shells is used routinely for palaeoenvironmental studies of ostracod-bearing records. Sample treatment usually involves the disaggregation of sediments and sieving; before the sieving residues were washed with water onto petri dishes and oven-dried. In our study, we compared δ18O and δ13C values of shells that were oven-dried from water and from ethanol alternatively. Large isotopic differences of up to 3‰ were determined for δ18O values, whereas differences in δ13C values were less pronounced with differences of up to 1.6‰. Stable isotope values of shells dried from water were lower for both oxygen and carbon as a result of calcite crystals precipitated on the shell surfaces during the drying process. Therefore, ostracod shells for stable isotope analysis should not be prepared by drying from water. Instead, shells should be dried from ethanol to obtain reliable stable isotope data; likewise freeze-drying is expected to provide trustworthy results.  相似文献   

14.
An 11.6 m long continuous succession of annually laminated sediments from Lake Korttajärvi in central Finland was investigated for the isotopic composition of carbon and hydrogen in organic matter. The sequence covers a time period of 9590 years, and the varve chronology has been thoroughly described in earlier studies. From 7100 to 4400 BC the lake was part of the Ancient Lake Päijänne, but in 4400 BC it became separated and formed the present independent lake system. Two organic fractions were investigated. One fraction obtained by HCl-treatment was analyzed for δ13C and another HCl-HF-digested organic fraction was analyzed for both δ13C and δD. The isotopic data were compared to atomic C/N ratios, carbon contents, diatom-inferred pH values and other environmental parameters. The diatom-inferred pH values and organic carbon contents provide evidence for a long-term change towards more acidic conditions and lower productivity in Lake Korttajärvi. The inferred pH values decrease from 7.0 to 6.1, followed by a slight increase during the last millennia. Variations in pH are accompanied by an increase in the δ13CHCl-HF values of organic matter from ?31.6 to $-29.2\permilleAn 11.6 m long continuous succession of annually laminated sediments from Lake Korttaj?rvi in central Finland was investigated for the isotopic composition of carbon and hydrogen in organic matter. The sequence covers a time period of 9590 years, and the varve chronology has been thoroughly described in earlier studies. From 7100 to 4400 BC the lake was part of the Ancient Lake P?ij?nne, but in 4400 BC it became separated and formed the present independent lake system. Two organic fractions were investigated. One fraction obtained by HCl-treatment was analyzed for δ13C and another HCl-HF-digested organic fraction was analyzed for both δ13C and δD. The isotopic data were compared to atomic C/N ratios, carbon contents, diatom-inferred pH values and other environmental parameters. The diatom-inferred pH values and organic carbon contents provide evidence for a long-term change towards more acidic conditions and lower productivity in Lake Korttaj?rvi. The inferred pH values decrease from 7.0 to 6.1, followed by a slight increase during the last millennia. Variations in pH are accompanied by an increase in the δ13CHCl-HF values of organic matter from −31.6 to , followed by a subtle decrease to . The changes in pH and δ13CHCl-HF are closely related (r = − 0.91, P < 0.01), and apparently reflect changing environmental conditions in the lake and in its catchment area. δD values show a marked shift to higher values during the early Holocene, which may be partly related to a climatic amelioration leading to the Holocene Climatic Optimum in 6000–2500 BC. The Medieval Warm Period in AD 980–1250 is associated with a local maximum in δD, lending support for a significant warming during that time.  相似文献   

15.
Total organic carbon (TOC) content, total nitrogen (TN) content, stable nitrogen isotope (δ15N) and stable organic carbon isotope (δ13Corg) ratios were continuously analysed on a high resolution sediment profile from Lake Sihailongwan (SHL), covering the time span between 16,500 and 9,500 years BP. Strong variations of the investigated proxy parameters are attributed to great climatic fluctuations during the investigated time period. Variations in organic carbon isotope ratios and the ratio of TOC/TN (C/N ratio) are discussed with respect to changing proportions of different organic matter (OM) sources to bulk sedimentary OM. Phases of high TOC content, high TN content, depleted δ13Corg values and high δ15N values are interpreted as times with increased productivity of lacustrine algae in relation to input of terrigenous organic matter. Two distinct phases of enriched nitrogen isotope ratios from 14,200 to 13,700 and 11,550 to 11,050 years BP point towards a reduced phytoplankton discrimination against 15N due to a diminished dissolved inorganic nitrogen pool. The combination of geochemical (TOC, TN, C/N ratio) and isotopic (δ13Corg, δ15N) proxy parameters points to a division of climate development into four stages. A cold and dry stage before 14,200 years BP, a warm optimum stage with high phytoplankton productivity from 14,200 to 12,450 BP, a colder and drier stage from 12,450 to 11,600 BP and a stage of climatic amelioration with high variability in TOC and TN contents after 11,600 BP. These results are discussed in relation to monsoon variability and Northern Hemisphere climate development of the late glacial.  相似文献   

16.
Lacustrine sediments in north-eastern Germany have rarely been used as archives to address the effects of climate change and human impact on both lake ecosystem and landscape evolution for this region. Sacrower See, a hardwater lake located in Brandenburg, provides a unique sediment record covering the past 13,000 years which was used to reconstruct climatic and anthropogenic forcing on lacustrine sedimentation. Time control is provided by 12 AMS 14C dates of terrestrial plant remains, the Laacher See Tephra, and the onset of varve formation in AD 1870 (80 cal. BP). Geochemical (including XRF logging of major elements, CNS analyses as well as δ13Corg and δ15N measurements) and pollen analyses allowed detecting detailed environmental changes in the sediment record. During the Younger Dryas cold phase increased soil erosion and hypolimnetic oxygen depletion enhanced the nutrient supply to the lake water causing eutrophic conditions. The beginning of the Holocene is characterized by large changes in C/N ratios, total sulphur, δ13C of bulk organic matter as well as in K, Si, and Ti, reflecting the response of the lake’s catchment to climatic warming. Reforestation reduced the influx of detrital particles and terrestrial organic matter. The first, rather weak evidence of human impact is documented only in the pollen record at 5,500 cal. BP. However, until 3,200 cal. BP sedimentological and geochemical parameters indicate relatively stable environmental conditions. During periods of intense human impact at around 3,200, 2,800, and 900 cal. BP peaks in Ti and K represent phases of increased soil erosion due to forest clearing during the Bronze Age, Iron Age, and Medieval Times, respectively. In general, greater variation is observed in most variables during these perturbations, indicating less stable environmental conditions. The steady rise of biogenic silica accumulation rates during the Holocene reflects an increasing productivity of Sacrower See until diatoms were outcompeted by other algae during the last centuries. The applied multi-proxy approach fosters the interpretation of the sediment record to reveal a consistent picture of environmental change including environmental factors controlling lake ontogeny and the effects of human impact.  相似文献   

17.
The oxygen isotope ratios of diatoms (δ18Odiatom), and the oxygen and hydrogen isotope ratios of lake water (δW) of lakes in south Alaska provide insight into past changes in atmospheric circulation. Lake water was collected from 31 lakes along an elevation transect and diatoms were isolated from lake sediment from one lake (Mica Lake) in south Alaska. In general, δW values from coastal lakes overlap the global meteoric water line (GMWL). δW values from interior lakes do not lie on the GMWL; they fall on a local evaporation line trajectory suggesting source isotopes are depleted with respect to maritime lakes. Sediment cores were recovered from 58 m depth in Mica Lake (60.96° N, 148.15° W; 100 m asl), an evaporation-insensitive lake in the western Prince William Sound. Thirteen calibrated 14C ages on terrestrial macrofossil samples were used to construct an age-depth model for core MC-2, which spans 9910 cal years. Diatoms from 46, 0.5-cm-thick samples were isolated and analyzed for their oxygen isotope ratios. The analyses employed a newly designed, stepwise fluorination technique, which uses a CO2 laser-ablation system, coupled to a mass spectrometer, and has an external reproducibility of ±0.2‰. δ18Odiatom values from Mica Lake sediment range between 25.2 and 29.8‰. δ18Odiatom values are relatively uniform between 9.6 and 2.6 ka, but exhibit a four-fold increase in variability since 2.6 ka. High-resolution sampling and analyses of the top 100 cm of our lake cores suggest large climate variability during the last 2000 years. The 20th century shows a +4.0‰ increase of δ18Odiatom values. Shifts of δ18Odiatom values are likely not related to changes in diatom taxa or dissolution effects. Late Holocene excursions to lower δ18Odiatom values suggest a reduction of south-to-north storm trajectories delivered by meridional flow, which likely corresponds to prolonged intervals when the Aleutian Low pressure system weakened. Comparisons with isotope records of precipitation (δP) from the region support the storm-track hypothesis, and add to evidence for variability in North Pacific atmospheric circulation during the Holocene.
Zachary SharpEmail:
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18.
Stable isotopes (δ18O and δD) are useful tracers for investigating hydrologic and climatic variability on a variety of temporal and spatial scales. Since the early isotopic studies on mountainous glaciers in the late 1960s, a great deal of information has been generated on the isotopic composition of rainfall, snow, ice, surface waters, and lake carbonate sediments across the Tibetan Plateau. However, measurements of δ18O and δD values of lake water are scarce. Here we present a new dataset of δ18O and δD values of lake waters collected from 27 lakes across the plateau during a reconnaissance survey in summer 2009. δ18O and δD values of lake water range from −19.9 to 6.6‰ and from −153 to −16‰, respectively. The average values of δ18O and δD are −6.4 and −72‰, considerably greater than those of precipitation observed in this region. The derived Tibetan lake water line, δD = 5.2δ18O − 38.9, is significantly different from the global meteoric water line. Most of the lakes, including some freshwater lakes, contain water with negative values of d-excess (d). There is a negative correlation between d and total dissolved solids (TDS). Each of these findings indicates that evaporation-induced isotopic enrichment prevails in Tibetan lakes. Moreover, we develop an isotope modeling scheme to calculate E/P ratios for Tibetan lakes, using a combination of existing isotopic fractionation equations and the Rayleigh distillation model. We use the intersection of the local evaporation line and GMWL as a first approximation of δ18O and δD values of lake water inputs to infer an E/P ratio for each lake. Our modeling calculations reveal that although variable from lake to lake, the water budget across the plateau is positive, with an average E/P of 0.52. This is in good agreement with other observational and model data that show varying degrees of increases in lake size from satellite imagery and significant decreases in lake salinity in many lakes on the plateau over the last several decades. Together with the new isotopic dataset, the proposed modeling framework can be used to examine and quantify past changes in a lake’s hydrologic balance from the isotopic record of downcore carbonate sediments in the region.  相似文献   

19.
We used statistical analyses to determine which subset of 36 environmental variables best explained variations in surface sediment δ13C and δ15N from 50 lakes in western Ireland that span a human-impact gradient. The factors controlling lake sediment δ13C and δ15N depended on whether organics in the lake sediment were mostly derived from the lake catchment (allochthonous) or from productivity within the lake (autochthonous). Lake sediments with a dominantly allochthonous organic source (high C:N ratio sediments) produced δ13C and δ15N measurements similar to values from catchment vegetation. δ13C and δ15N measurements from lake sediments with a dominantly autochthonous organic source (low C:N ratio sediments) were influenced by fractionation in the lake and catchment leading up to assimilation of carbon and nitrogen by lacustrine biota. δ13C values from lake sediment samples in agricultural catchments were more negative than δ13C values from lake sediment samples in non-impacted, bogland catchments. Hypolimnetic oxygen concentrations and methane production had a greater influence on δ13C values than fractionation due to algal productivity. δ15N from lake sediment samples in agricultural catchments were more positive than δ15N in non-impacted bogland catchments. Lower δ15N values from non-impacted lake catchments reflected δ15N values of catchment vegetation, while higher δ15N values in agricultural catchments reflected the high δ15N values of cattle manure and inorganic fertilisers. The influence of changing nitrogen sources and lake/catchment fractionation processes were more important than early diagenesis for lake sediment δ15N values in this dataset. The results from this study suggest a possible influence of bound inorganic nitrogen on the bulk sediment δ15N values. We recommend using a suitable method to control for bound inorganic nitrogen in lake sediments, especially when working with clay-rich sediments. This study confirms the usefulness of δ13C and δ15N from bulk lake sediments, as long as we are mindful of the multiple factors that can influence these values. This study also highlights how stable isotope datasets from lake surface sediments can complement site-specific isotope source/process studies and help identify key processes controlling lake sediment δ13C and δ15N in a study area.  相似文献   

20.
Stable isotopes and trace-element contents of ostracod (Candona neglecta) valves mostly from the Holocene portion of two assembled cores from Petit Lac (Lake Geneva, Switzerland-France) were analysed in order to depict the geochemical record of post-glacial environmental changes of this lake. Additional stable isotope and trace element data from the gastropod Bithynia tentaculata (shells and opercula) from some intervals of these cores, as well as previous data from bulk carbonate from the lower part of the studied intervals were also considered. Mg/Ca and Sr/Ca molar ratios for the Holocene lake water have been estimated from evaluations of the partitioning coefficients for Mg and Sr for C. neglecta and B. tentaculata taking into account the modern-lake water composition. This study shows an overall gentle trend to higher δ18O values in C. neglecta valves from the Boreal interval (mean −8.44‰) to the upper part of the core (mean −8.11‰). This trend is superimposed to higher frequency oscillations of stable isotope values and trace element ratios, especially through the upper Older Atlantic and the Subboreal. The overall isotopic oxygen trend includes several shifts in δ18O of about 1‰. These shifts are interpreted as major regional-global climate changes that have also been observed in other coeval δ18O and pollen records which reflect the Holocene climate variability in other European basins. Especially well-defined peaks in some episodes like Older Atlantic (~8200 yr BP), Younger Atlantic – Subboreal transition (~5600 yr BP) and early Subatlantic (~ 2500 yr BP) correspond to well-recognized events in globally-distributed records. Some of these shifts are correlated with pulses in the lake-level curve of the Lake Geneva. An erratum to this article is available at .  相似文献   

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