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1.
Understanding the variation in a plant's water sources is critical to understanding hydrological processes in water-limited environments. Here, we measured the stable-isotope ratios(δ18 O) of xylem water of Caragana microphylla, precipitation,soil water from different depths, and groundwater to quantitatively analyze the proportion of water sources for the shrub.We found that the water sources of C. microphylla differed with the plant's ages and the seasons. The main water source for young shrubs was upper-soil water, and it showed significant changes with seasonal precipitation inputs. In summer,the proportion contributed by shallow water was significantly increased with increased precipitation inputs. Then, the contribution from shallow-soil water decreased with the decline in precipitation input in spring and autumn. However, the adult shrubs resorted to deep-soil layers and groundwater as the main water sources during the whole growing season and showed much less seasonal variation. We conclude that the main water source of the young shrubs was upper-soil water and was controlled by precipitation inputs. However, once the shrub gradually grew up and the roots reached sufficient depth, the main water sources change from the upper-soil layer recharged by precipitation to deep-soil water and groundwater, which were relatively stable and abundant in the desert ecosystem. These results also suggest that desert shrubs may be able to switch their main water sources to deep and reliable water sources as their age increases, and this adjustment to water availability carries significant importance for their acclimation to the desert habitat.  相似文献   

2.
华北平原降水的长期趋势分析(英文)   总被引：4，自引：1，他引：3  
The North China Plain (NCP) is the most important food grain producing area in China and has suffered from serious water shortages. To capture variation water availability, it is necessary to have an analysis of changing trends in precipitation. This study, based on daily precipitation data from 47 representative stations in NCP records passed the homogeneity test, analyzed the trend and amplitude of variation in monthly, seasonal and annual precipitation, annual maximum continuous no-rain days, annual rain days, rainfall intensity, and rainfall extremes from 1960 to 2007, using the MannKendall (M-K) test and Sen’s slope estimator. It was found that monthly precipitation in winter had a significant increasing trend in most parts, while monthly precipitation in July to September showed a decreasing trend in some parts of NCP. No significant changing trend was found for the annual, dry and wet season precipitation and rainfall extremes in the majority of NCP.A significant decreasing trend was detected for the maximum no-rain duration and annual rain days in the major part of NCP. It was concluded that the changing trend of precipitation in NCP had an apparent seasonal and regional pattern, i.e., precipitation showed an obvious increasing trend in winter, but a decreasing trend in the rainy season (July to September), and the changing trend was more apparent in the northern part than in the southern and middle parts. This implies that with global warming, seasonal variation of precipitation in NCP tends to decline with an increasing of precipitation in winter season, and a decreasing in rainy season, particularly in the sub-humid northern part.  相似文献   

3.
In this study, seasonal variation characteristics of surface soil microbial biomass carbon （MBC） and soil microbial biomass nitrogen （MBN） of an artificial vegetation area located in Shapotou for different time periods were studied using the chloroform fumigation method, and the results were compared with those of near-natural vegetation areas and mobile dunes. Results showed that the MBC and MBN levels in the 0-5 cm soil layer were higher in autumn than in summer and spring. As the prolongation of vegetation restoration raised the MBC and MBN levels in summer and autumn, no clear variation was found in spring. However, the MBC and MBN in 5-20 cm had no obvious seasonal variation. During summer and autumn, the variation trend of MBC and MBN in the vertical direction was shown to be 0-5 〉 5-10 〉 10-20 cm in the vegetation area, while for mobile dunes, the MBC and MBN levels increased as the depth increased. The natural vegetation area was shown to possess the highest MBC and MBN levels, and yet mobile dunes have the lowest MBC and MBN levels. MBC and MBN levels in artificial sand-binding vegetation increased with the prolongation of vegetation restoration, indicating that the succession of sand-binding vegetation will result in the ac- cumulation of soil carbon and nitrogen, as well as the restoration of soil fertility.  相似文献   

4.
By decomposing and reconstructing the runoff information from 1965 to 2007 of the hydrologic stations of Tuotuo River and Zhimenda in the source region of the Yangtze River, and Jimai and Tangnaihai in the source region of the Yellow River with db3 wavelet, runoff of different hydrologic stations tends to be declining in the seasons of spring flood, summer flood and dry ones except for that in Tuotuo River. The declining flood/dry seasons series was summer > spring > dry; while runoff of Tuotuo River was always increasing in different stages from 1965 to 2007 with a higher increase rate in summer flood seasons than that in spring ones. Complex Morlet wavelet was selected to detect runoff periodicity of the four hydrologic stations mentioned above. Over all seasons the periodicity was 11-12 years in the source region of the Yellow River. For the source region of the Yangtze River the periodicity was 4-6 years in the spring flood seasons and 13-14 years in the summer flood seasons. The differences of variations of flow periodicity between the upper catchment areas of the Yellow River and the Yangtze River and between seasons were considered in relation to glacial melt and annual snowfall and rainfall as providers of water for runoff.  相似文献   

5.
Transport of organic carbon via rivers to estuary is a significant geochemical process in the global carbon cycle.This paper presents bulk total organic carbon(TOC) from the Dongjiang catchment to the adjacent Humen outlet,and discusses the applicability of δ13C and ratio of carbon to nitrogen(C/N) as indicators for sources of organic matter in the surface sediments.Survey results showed that organic carbon concentration in summer were higher than in the winter.An elevated trend of TOC occurred along the river to the Humen outlet in both surveys,and the highest mean values of dissolved and particular organic carbon(DOC~279 μmol L–1 and POC~163 μmol L–1) were observed in the urban deltaic region in summer flood flow.Winter samples had a wide range of δ13C and C/N(δ13C –24.6‰ to –30.0‰,C/N 4–13),and summer ones varied slightly(δ13C –24.2‰ to –27.6‰,C/N 6–18).As results suggest that POC in the three zones of upstream-delta-outlet dominantly came from riverbank soil,phytoplankton and agricultural C3 plants in winter,whereas main sources were from the riverbank and mangrove soil in summer.Moreover,anthropogenic sewage inputs had 11% and 7% contribution to POC in the deltaic and outlet.Transport accompanied with seasonal freshwater variation,phytoplankton production and degradation,and removal behavior caused variation of organic carbon concentration.The results also discovered that TOC export bulk in Dongjiang was approximately one quarter of Humen flux in the dry flow,and anthropogenic activity significantly impacted the river export contribution.  相似文献   

6.
三江源地区1961-2010年降水时空变化(英文)   总被引：2，自引：0，他引：2  
Based on a monthly dataset of precipitation time series (1961-2010) from 12 meteorological stations across the Three-River Headwater Region (THRHR) of Qinghai Province, China, the spatio-temporal variation and abrupt change analysis of precipitation were examined by using moving average, linear regression, spline interpolation, the Mann-Kendall test and so on. Major conclusions were as follows. (1) The long-term annual and seasonal precipitation in the study area indicated an increasing trend with some oscillations during 1961-2010; however, the summer precipitation in the Lantsang (Lancang) River Headwater Region (LARHR), and the autumn precipitation in the Yangtze River Headwater Region (YERHR) of the THRHR decreased in the same period. (2) The amount of annual precipitation in the THRHR and its three sub-headwater regions was greater in the 1980s and 2000s. The springs were fairly wet after the 1970s, while the summers were relatively wet in the 1960s, 1980s and 2000s. In addition, the amount of precipitation in the autumn was greater in the 1970s and 1980s, but it was relatively less for the winter precipitation, except in the 1990s. (3) The normal values of spring, summer, winter and annual precipitation in the THRHR and its three sub-headwater regions all increased, but the normal value of summer precipitation in the LARHR had a negative trend and the normal value of winter precipitation declined in general. (4) The spring and winter precipitation increased in most of the THRHR. The summer, autumn and annual precipitation increased mainly in the marginal area of the west and north and decreased in the regions of Yushu, Zaduo, Jiuzhi and Banma. (5) The spring and winter precipitation in the THRHR and its three sub-headwater regions showed an abrupt change, except for the spring precipitation in the YARHR. The abrupt changes of spring precipitation were mainly in the late 1980s and early 1990s, while the abrupt changes of winter precipitation were primary in the mid-to late 1970s. This research would be helpful for further understanding the trends and periodicity of precipitation and for watershed-based water resource management in the THRHR.  相似文献   

7.
The starting dates of the pre-summer rainy season during historical times （1736- 1911） in Fuzhou and Guangzhou of South China, were determined and reconstructed on the basis of historical documents in the Yu-Xue-Fen-Cun archive, together with observed features of precipitation during the pre-summer rainy season. In addition, starting dates of the pre-summer rainy season from 1953 in Fuzhou and from 1952 in Guangzhou were reconstructed for the instrumental period. These data allowed for analyses of inter-annual and inter-decadal changes in the starting dates of the pre-summer rainy season in South China over the past 300 years. Results show that the mean starting date of the pre-summer rainy season in South China was the first pentad of May; in addition, periodicities in the starting dates of 2-3 years, 10 years, and 40 years were detected during the period 1736-1911, and of 2-3 years, 10 years, and 22 years during the instrumental period. From 1736 to 1911, the earliest starting dates at Fuzhou and Guangzhou both occurred at the fourth pentad of April, while the latest starting dates were at the sixth pentad of May in Fuzhou and the first pentad of June in Guangzhou. During the instrumental period, the earliest and latest starting dates were at the fourth pentad of April and the first pentad of June, respectively, in both Fuzhou during 1953-2010 and Guangzhou during 1952-2010. The maximum difference between neighboring decades during 1736-1911 was 2.2 and 1.6 pentads in Fuzhou and Guangzhou, respectively, and during the instrumental period it was 2.5 and 2.4 pentads in Fuzhou and Guangzhou, respectively.  相似文献   

8.
This study firstly analyzed the shrinkage of winter wheat and the changes of crop- ping systems in the Hebei Plain from 1998 to 2010 based on the agricultural statistic data of 11 cities and meteorological data, including daily temperature, precipitation, water vapor, wind speed and minimum relative humidity data from 22 meteorological stations, and then calcu- lated the water deficit and irrigation water resources required by different cropping systems, as well as the irrigation water resources conserved as a result of cropping system changes, using crop coefficient method and every ten-day effective precipitation estimation method. The results are as follows. 1） The sown areas of winter wheat in the 11 cities in the Hebei Plain all shrunk during the study period. The shrinkage rate was 16.07% and the total shrinkage area amounted to 49.62×10^4 ha. The shrinkage was most serious in the Bei- jing-Tianjin-Tangshan metropolitan agglomerate, with a shrinkage rate of 47.23%. 2） The precipitation fill rate of winter wheat was only 20%-30%, while those of spring maize and summer maize both exceeded 50%. The irrigation water resources demanded by the winter wheat-summer maize double cropping system ranged from 400 mm to 530 mm, while those demanded by the spring maize single cropping system ranged only from 160 mm to 210 ram. 3） The water resources conserved as a result of the winter wheat sown area shrinkage during the study period were about 15.96×10^8 m^3/a, accounting for 27.85% of those provided for Beijing, Tianjin and Hebei by the first phase of the Mid-Route of the South-to-North Water Diversion Project.  相似文献   

9.
Global warming has led to significant vegetation changes in recent years. It is necessary to investigate the effects of climatic variations（temperature and precipitation） on vegetation changes for a better understanding of acclimation to climatic change. In this paper, we focused on the integration and application of multi-methods and spatial analysis techniques in GIS to study the spatio-temporal variation of vegetation dynamics and to explore the vegetation change mechanism. The correlations between EVI and climate factors at different time scales were calculated for each pixel including monthly, seasonal and annual scales respectively in Qinghai Lake Basin from the year of 2001 to 2012. The primary objectives of this study are to reveal when, where and why the vegetation change so as to support better understanding of terrestrial response to global change as well as the useful information and techniques for wise regional ecosystem management practices. The main conclusions are as follows：（1） Overall vegetation EVI in the region increased 6% during recent 12 years. The EVI value in growing seasons（i.e. spring and summer） exhibited very significant improving trend, accounted for 12.8% and 9.3% respectively. The spatial pattern of EVI showed obvious spatial heterogeneity which was consistent with hydrothermal condition. In general, the vegetation coverage improved in most parts of the area since nearly 78% pixel of the whole basin showed increasing trend, while degraded slightly in a small part of the area only.（2） The EVI change was positively correlated with average temperature and precipitation. Generally speaking, in Qinghai Lake Basin, precipitation was the dominant driving factor for vegetation growth; however, at different time scale its weight to vegetation has differences.（3） Based on geo-statistical analysis, the autumn precipitation has a strong correlation with the next spring EVI values in the whole region. This findings explore the autumn precipitation is an important indicator  相似文献   

10.
The starting dates of the pre-summer rainy season during historical times(1736– 1911) in Fuzhou and Guangzhou of South China, were determined and reconstructed on the basis of historical documents in the Yu-Xue-Fen-Cun archive, together with observed features of precipitation during the pre-summer rainy season. In addition, starting dates of the pre-summer rainy season from 1953 in Fuzhou and from 1952 in Guangzhou were reconstructed for the instrumental period. These data allowed for analyses of inter-annual and inter-decadal changes in the starting dates of the pre-summer rainy season in South China over the past 300 years. Results show that the mean starting date of the pre-summer rainy season in South China was the first pentad of May; in addition, periodicities in the starting dates of 2–3 years, 10 years, and 40 years were detected during the period 1736–1911, and of 2–3 years, 10 years, and 22 years during the instrumental period. From 1736 to 1911, the earliest starting dates at Fuzhou and Guangzhou both occurred at the fourth pentad of April, while the latest starting dates were at the sixth pentad of May in Fuzhou and the first pentad of June in Guangzhou. During the instrumental period, the earliest and latest starting dates were at the fourth pentad of April and the first pentad of June, respectively, in both Fuzhou during 1953–2010 and Guangzhou during 1952–2010. The maximum difference between neighboring decades during 1736–1911 was 2.2 and 1.6 pentads in Fuzhou and Guangzhou, respectively, and during the instrumental period it was 2.5 and 2.4 pentads in Fuzhou and Guangzhou, respectively.  相似文献   

11.
西江河口段溶解无机碳稳定同位素组成的时空变化   总被引：2，自引：0，他引：2  
从2006 年9 月至2007 年6 月间对西江河口段溶解无机碳稳定同位素组成(δ13CDIC) 及 其相关的水体理化参数进行了一个水文年的季节性采样调查。夏、秋两季δ13CDIC 平均值(-13. 91‰、-13.09‰) 小于春、冬季节(-11.71‰、-12.26‰), 呈现出明显的季节性。δ13CDIC 与温度 呈负相关(p = 0.000; r = -0.646), 而与氧化还原电位正相关(p = 0.000; r = 0.569), 表明河段 表层水体δ13CDIC 受到季节性变化的水体理化性质等河道有机质氧化分解条件的控制; 夏季洪水期δ13CDIC 与航测距离呈正相关, 而春季枯水期的δ13CDIC 与航测距离负相关。δ13CDIC 的这种时空变异证明了研究河段河- 海作用过程影响了水体的理化性状进而控制了河道表层水体DIC 的性质。研究河段δ13CDIC 的上述时空分布规律与流域所处的地理环境关系密切, 汛期的夏季受陆源有机质的强烈分解作用的影响, DIC 的同位素组成向海洋方向变轻; 枯期的春季因海洋作用加强以及咸潮的入侵, 河道DIC 的同位素组成向海洋方向变重。  相似文献   

12.
A 7.6-m lake sediment core from a marl lake, Lough Inchiquin, records variation in landscape evolution from 16,800 cal yrs B.P. to 5,540 cal yrs B.P. We observe significant variations (up to 12‰) in δ 13Corg and δ 13Ccalcite values that are interpreted to reflect secular changes in lake water δ 13CDIC values that result from a regional landscape transition from barren limestone bedrock to a forested ecosystem. Lake water δ 13CDIC values are therefore influenced by two isotopically distinct sources of carbon: terrestrial organic material (−27.1 to −31.2‰VPDB) via oxidized soil organic matter and weathered limestone bedrock (+3.4‰VPDB). Isotope excursions in lacustrine sediment records are forced not only by changes in productivity but also by changes in the terrestrial environment. This has profound implications for the interpretation of paleoclimate records derived from lacustrine sediment and suggests that selection of appropriate lakes can provide records of terrestrial change where other related records are not available.  相似文献   

13.
For researching the spatio-temporal variation of the stable isotopic composition of the riverine dissolved inorganic carbon (DIC), we had carried out a survey throughout the hydrologic year during which the δ13CDIC of the surface water and its physicochemical pa-rameter were examined along the Xijiang River Inner Estuarine waterway from September 2006 to June 2007. There was a striking seasonal variation on the average δ13CDIC, as the average δ13CDIC in summer (?13.91‰) or autumn (?13.09‰) was much less than those in spring (?11.71‰) or winter (?12.26‰). The riverine δ13CDIC was controlled by decomposed condition of the riverine organic matter linking the seasonal variation of the physicochemical parameter in the surface water according to the correlation analysis which indicated notable relations between δ13CDIC and water temperature (p = 0.000; r = ?0.569) or between δ13CDIC and oxide-reduction potential (p = 0.000; r = 0.646). The striking positive correlation between δ13CDIC and the sampling distance happened in the summer rainy season, while striking negative correlation happened in the spring dry season, indicating that river-sea interaction influenced water physicochemical parameters and controlled the riverine DIC property in the survey waterway. In view of the riverine δ13CDIC decreasing for the decomposition of the ter-restrial organic matter in the rainy season in summer and increasing for the briny invaded zone extending in the spring dry season along the waterway from the Makou gauging station to the Modaomen outlet, the δ13CDIC spatio-temporal variation was closely related to the geographical environment of the Xijiang drainage basin.  相似文献   

14.
The apparent isotope enrichment factor εmacrophyte of submerged plants (εmacrophyte–DIC = δ13Cmacrophyte − δ13CDIC) is indicative of dissolved inorganic carbon (DIC) supply in neutral to alkaline waters and is related to variations in aquatic productivity (Papadimitriou et al. in Limnol Oceanogr 50:1084–1095, 2005). This paper aims to evaluate the usage of εmacrophyte inferred from isotopic analyses of submerged plant fossils in addition to analyses of lake carbonate as a palaeolimnological proxy for former HCO3 − concentrations. Stable carbon isotopic analysis of modern Potamogeton pectinatus leaves and its host water DIC from the Tibetan Plateau and Central Yakutia (Russia) yielded values between −23.3 and +0.4‰ and between +14.0 and +6.5‰, respectively. Values of ε Potamogeton–DIC (range −15.4 to +1.1‰) from these lakes are significantly correlated with host water HCO3 − concentration (range 78–2,200 mg/l) (r = −0.86; P < 0.001), thus allowing for the development of a transfer function. Palaeo-ε Potamogeton–ostracods values from Luanhaizi Lake on the NE Tibetan Plateau, as inferred from the stable carbon isotope measurement of fossil Potamogeton pectinatus seeds (range −24 to +2.8‰) and ostracods (range −7.8 to +7.5%) range between −14.8 and 1.6‰. Phases of assumed disequilibrium between δ13CDIC and δ13Costracods known to occur in charophyte swards (as indicated by the deposition of charophyte fossils) were excluded from the analysis of palaeo-ε. The application of the ε Potamogeton–DIC-HCO3 − transfer function yielded a median palaeo-HCO3 − -concentration of 290 mg/l. Variations in the dissolved organic carbon supply compare well with aquatic plant productivity changes and lake level variability as inferred from a multiproxy study of the same record including analyses of plant macrofossils, ostracods, carbonate and organic content.  相似文献   

15.
We quantified differences in oxygen isotope fractionation among three biostratigraphically important subfossil ostracod species (Metacypris cordata, Pseudocandona rostrata and Candonopsis kingsleii) from an early Holocene freshwater tufa layer in northern Estonia. Estimated mean δ18O values are −10.05‰ for M. cordata, −9.34‰ for C. kingsleii and −8.75‰ for P. rostrata. All three species exhibit positive offset from the weighted mean annual δ18O of contemporary precipitation (−10.7‰ in δ18OV-PDB) and from the mean δ18O value of authigenic tufa carbonate (−10.64‰) in the ostracod-bearing layer. Assuming that the known oxygen isotope fractionation in P. rostrata (+2.5‰) and M. cordata (+1.5‰) has remained constant over time, the theoretical δ18OV-SMOW of the early Holocene lake water was calculated to have been between −11.52 and −11.92‰, slightly less negative than the local Ordovician groundwater (−11.7 to −12.2‰). δ18O values of the tufa carbonate differ by +0.6 to +1.0‰ from the calculated theoretical isotope composition (δ18OV-PDB) of lake water, indicating that the tufa also did not precipitate in isotopic equilibrium with ambient waters. Results show that the greater the δ18O offset from the calculated, theoretical isotope composition of lake water for an ostracod species, the lower is its preferred mean July temperature. Both our data and earlier published results on δ18O values in Holocene lacustrine carbonates and ostracods from north-eastern Europe, display pronounced decreases in δ18O with an increase in latitude of the study site. This suggests that temperature-dependent, and therefore latitude-dependent isotopic composition of meteoric waters controlled the δ18O values in lacustrine tufa and ostracods throughout the Holocene.  相似文献   

16.
Stable carbon and nitrogen isotope ratios have been determined on 41 strains ofArtemia sp. from different geographic regions around the world. The δ13C and δ15N values ranged between −13.7 to−25.0 per mil and −0.7 to 21.2 per mil respectively.Artemia δ13C values from coastal environments are consistent with a marine origin for the food sourceArtemia from inland salt lakes have a range of carbon isotope values suggesting C3, C4 and CAM based organic matter could form the base of theArtemia food chain. These data indicate thatArtemia having a wide range of carbon and nitrogen isotope values are available for tropho-dynamic research studies that quantify the effect of respired CO2 on tissue and CaCO3 shell13C/12C ratios. Such stable isotope variation also suggests that stable isotope fingerprinting remains a viable technique for identifying specificArtemia collection sites.  相似文献   

17.
We used elemental carbon, nitrogen, phosphorus and hydrogen ratios (C/N, N/P and H/C) with total organic carbon (TOC) and total phosphorus (TP) as well as stable carbon and nitrogen isotopes (δ13C and δ15N) to investigate the source and depositional conditions of organic matter in sediments from Zeekoevlei, the largest freshwater lake in South Africa. Typical C/N (10–12), H/C ratios (≥1.7) and δ13Corganic values (−22 to −19‰) together with the increase in TOC concentration indicate elevated primary productivity in lower middle (18–22 cm) and top (0–8 cm) sections of the sediment cores. Seepage of nutrients from a nearby waste water treatment plant, rapid urbanization and heavily fertilized farming in the catchments are responsible for the increased productivity. Consistent with this, measured δ15Norganic values (∼11‰) indicate increased raw sewage input towards the top-section of the core. Although cyanobacterial blooms are evident from the low δ15N values (∼3‰) in mid-section of the core, they did not outnumber the phytoplankton population. Low N/P ratio (∼0) and high TP (100–2,200 mg l−1) support cyanobacterial growth under N limited condition, and insignificant input of macrophytes towards the organic matter pool. Dredging in 1983, caused sub-aerial exposure of the suspended and surface sediments, and affected organic matter preservation in the upper mid-section (12–14 cm) of the core.  相似文献   

18.
A sediment core from Lake Koucha (eastern Tibetan Plateau) was investigated using organic biomarkers and their stable carbon isotope signatures. The correlation between TOC content, total amount of aquatic macrophyte-derived n-alkanes (e.g. nC23) and δ13C values of TOC and nC23 indicates that Lake Koucha was macrophyte-dominated before 8 cal ka BP. Shortly after the lake turned from a saline to a freshwater system at 7.2 cal ka BP, a variety of algal and bacterial markers such as hopanoids and isoprenoids emerged, of which phytane, pentamethylicosene (PMI), moretene and diploptene are particularly abundant. Phytane and PMI show different isotopic signals (≈−18 and ≈−28‰, respectively), which indicates that they originated from different sources. Phytane may have been derived from cyanobacteria, while methanogenic archaea may be the source of PMI. The isotopic depletion of diploptene and moretene (≈−60‰) indicates the presence of methanotrophs. After 6.1 cal ka BP, the saturated C20 highly branched isoprenoid (HBI) became the dominant constituent of the aliphatic hydrocarbon fraction. Such dominance has rarely been reported in lacustrine environments, and indicates a strong presence of algae (most likely diatoms) or cyanobacteria. At 4.7 cal ka BP, the appearance of an unsaturated C25 HBI, which is a specific biomarker for diatoms, was noted. Furthermore, the level of nC17-alkane was observed to increase in abundance in the uppermost two samples. These results suggest that the lake was phytoplankton-dominated during the last 6.1 ka. Relatively low biomarker concentrations and δ13C values at 6.0, 3.1 and 1.8 cal ka BP indicate the occurrence of cool periods, which is in agreement with inferences from other locations on the Tibetan Plateau. The δ13C values of nC23 range from −23.5 to −12.6‰, with high values at the peak of macrophyte abundance at ca. 11 cal ka BP and at the phytoplankton maximum between ca 6.1 and 2.8 cal ka BP. Thus, aquatic macrophyte-derived mid-chain n-alkanes have been found to be excellent indicators of carbon-limiting conditions, which lead to the assimilation of isotopically-enriched carbon species. The limitation of carbon sources could be a localized phenomenon occurring in dense plant stands (as in the older section of the core), or it may be induced by high primary productivity (as in the younger section). Since the δ13C value of the inorganic carbon source may vary, the offset between the δ13C values of nC23 and TIC could serve as a more precise proxy for carbon-limiting conditions in lacustrine environments, which could in turn be interpreted with respect to lacustrine paleo-productivity.  相似文献   

19.
Authigenic vivianite and siderite microconcretions were found, respectively, in hemipelagic and deltaic facies of 600-m-long BDP-98 sediment section from Lake Baikal. Textural investigations of these microconcretions show that they are typically <1 mm in size, irregular in shape and composed of aggregated crystallites. Dissimilar orientation of vivianite and siderite crystallites suggests formation at different depths in the sediment; up to tens of centimeters for vivianite and tens of meters for siderite. Chemical analyses of both the vivianite and the siderite indicate cation composition characterized by minor amounts of Mn, Ca and Mn apart from the dominating Fe. Rather limited and distinctive carbon isotopic composition of the siderite, with δ 13CVPDB values between about +13 and +16‰, implies formation of the mineral in the methanogenic zone of diagenesis. Isotopic composition of oxygen in the siderite (δ 18OVPDB values between about −10 and -11‰ ) is consistent with crystallization temperature at about 10–30°C and water δ 18OSMOW values between about −10 and -16‰ . The distribution of the authigenic minerals in the section suggests changes in both sedimentary facies and climate, where vivianite formation was controlled by hemipelagic depositional conditions during the Pliocene and Quaternary, whereas siderite reflects impact of deltaic conditions during the Miocene.  相似文献   

20.
This study presents detailed lithostratigraphy and stable carbon and nitrogen isotopic variations in a 520-cm-long sediment core from a cirque basin in the Labsky důl Valley, Krkonoše Mountains, Czech Republic. Detailed study of the core reveals five major periods of sedimentation during the last 7600 years: silt and sand deposition during ~7.6–5.1 ka cal BP, Sphagnum peat accumulation during ~5.1–4.0 ka cal BP, sandy silt and sand during ~4.0–2.8 ka cal BP, raised peat bog during ~2.8–2.0 ka cal BP (Sphagnum peat), and sedimentation of sandy silt since ~2.0 ka cal BP. The δ13C values of the organic matter in the core vary in the range typical for C3 plants, from −24.35 to −27.68‰, whereas the δ15N values vary from −2.65 to +4.35‰. Core sections having ash contents ≥70% have δ15N > 1‰ and δ13C < −26‰, whereas those having ≤70% ash content have δ15N < 1‰ and δ13C > −26‰. Strong linear correlations are observed between δ13C and δ15N values as well as between C:N ratios and δ15N values in the horizons with ash content >10%, primarily for sand and silt horizons. On the other hand, poor correlations between δ13C and C:N ratio, as well as δ15N and C:N ratio, were observed in Sphagnum peat layers (45–125 and 185–265 cm). We conclude that the primary stable isotope variations are not preserved in the layers where significant correlation between δ15N and C:N ratio is observed. The relatively small δ13C variation in the uppermost Sphagnum peat layer suggests stable temperature during ~2.8–2.0 ka cal BP.  相似文献   

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