首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 93 毫秒
1.
A toposequence of Holocene soils located between 1100–2400 m asl in the Italian Alps served as the basis for the following analyses: the weathering of limestone and dolomite, the calculation of mass balances, understanding the formation of pedogenic Fe and Al, the determination of soil mineral and clay mineral reactions and transformation and the measurement of accumulation and stabilisation mechanisms of soil organic matter. Leaching of carbonates is most intense at the lower elevations, although calcite and dolomite have a higher solubility at low temperatures. The pCO2 in the soil is higher at lower elevations and weathering is driven mainly by carbonic acids. At higher elevations, organic acids appear to determine the mineral transformations and weathering reactions to a greater extent. This suggests that two very different weathering regimes (carbonic and organic acid weathering) exist along the toposequence. The transformation of mica into vermiculite is the main process in both the clay and fine-earth fraction. Weathering of silicate minerals started even before the carbonates had been completely removed from the soils. The transformation mechanisms of silicate minerals in the A and O horizon at higher elevations was at least as intensive as that at the climatically warmer sites. The neoformation of pedogenetic clays at climatically cooler sites was slightly greater than that at the warmer sites. However, the formation rate of secondary Fe and Al phases was more pronounced at lower elevation, which means that this process seemed to be driven dominantly by carbonic acid (weathering of primary minerals). Soil organic matter (SOM) abundance in the mineral soil is nearly 15 kg/m2 at all sites and, surprisingly, no climate-driven effect could be detected. In general, the preservation and stabilisation of SOM was due to poorly crystalline Al and Fe phases and vermiculite, regardless of some variations in the composition of the parent material (varying calcite/dolomite ratio).  相似文献   

2.
This study aimed to reconstruct the history of soil development, ecosystem changes and associated erosional processes in a small mountain lacustrine basin at the decennial to millennial scale. Geochemical proxies of soil evolution were analysed in the Holocene lacustrine sediments and peats from Thyl Lake, Maurienne Valley, French Alps. Podzolization and chemical weathering processes were assessed using secondary Al- and Fe-bearing phases together with major and Rare Earth Elements (REE). The resulting proxy records, spanning ca. 4,400 years between 8.6 and 4.2 cal ka BP, indicate that progressive pedogenesis occurred after deglaciation in a relatively stable subalpine ecosystem. As shown by the associated increase in Al- and Fe-bearing phases and some REE fractions, the establishment of a mixed cembra pine ecosystem from ca. 7.2–6.5 ka BP was associated with enhanced podzolisation processes in the catchment. The progressive soil development was followed by a rapid transformation of the local environment and plant cover (the open waters of the lake were replaced by a confined peat environment) together with changes in forest fire regimes from ca. 6.8 ka BP. Depleted REE patterns, associated with low contents of secondary Al and Fe, suggest a decrease in chemical weathering and podzolization in the catchment at that time, possibly associated with local intensification of weathering and drainage processes in a relatively acidic peat environment. The higher variability of cembra pine and the increased abundance of sedge and other herbaceous plant remains in the lake sediment indicate semi-open vegetation environments from 5.7 cal ka BP onwards. Whereas fire events and plant cover appear to be significantly related, the soil processes seem primarily linked to vegetation composition, and secondarily to changes in fire regime.  相似文献   

3.
Dawn T. Nicholson   《Geomorphology》2008,101(4):655-665
Microweathering of ice-smoothed bedrock surfaces was investigated in the Røldal area of Hardanger Plateau (60°), southern Norway. Postglacial rates of weathering were determined from surface lowering using quartz veins as reference surfaces. Weathering processes are inferred from assessment of weathering rind formation, surface hardness, and the preservation of small-scale glacial erosional features.Surface lowering rates for a range of metamorphic rocks vary from 0.05 to 2.20 mm ka− 1 and are broadly comparable with those obtained from crystalline rocks in other periglacial environments. The mean rate of surface lowering at 0.55 mm ka− 1 is low and demonstrates the relatively small impact of microweathering on postglacial landscape evolution. Variations in bedrock microweathering can be explained by lithological variation. Amphibolite and mica-rich bedrock surfaces experience greater denudation and weakening, least weathering rind formation, and abundant preservation of glacial striae, despite greater surface lowering. Conversely, quartz-rich bedrock surfaces are most resistant to denudation and weakening, but have greater weathering rind formation and fewer preserved striae. Postglacial microweathering is achieved primarily through granular disintegration involving detachment and removal of mineral grains and weakening from increased porosity. Granular decomposition is manifest in the formation of weathering rinds. Analysis of interactions between weathering indices indicates that rind accumulation is limited by microerosion.A conceptual model is proposed that illustrates the temporal interrelationships between in situ and erosional facets of microweathering in two contrasting mineral assemblages. The model proposes that cyclic processes of in situ disintegration, decomposition, and erosion are at work. The relative balance between these processes varies with lithology so that in more resistant quartz-rich rocks the net effect is minimal surface lowering and accumulation of weathering rind. In weaker, amphibolitic and micaceous rocks, the net effect is greater surface lowering and minimal accumulation of weathering rind. The results of the research demonstrate the important influence of rock properties, notably mineral composition, in postglacial microweathering of crystalline bedrock in a periglacial environment.  相似文献   

4.
The chemical weathering intensity and element migration features of the Xiashu loess profile in Zhenjiang are studied in this paper. (1) The Xiashu loess profile underwent moderate chemical weathering. It seems that the precipitation is a more important factor than the temperature in controlling the process of the chemical weathering. (2) The major elements such as Si, K, Na, Ca, Mg, Mn and P were migrated and leached, while the elements Fe and Ti were slightly enriched. The migration features of the major elements reveal that the Xiashu loess finished the primary process of chemical weathering characterized by leaching of Ca and Na, and almost reached the secondary process characterized by leaching of K. Except the elements Sr and Ga, other trace elements such as Th, Ba, Cu, Zn, Co, Ni, Cr and V were enriched. It might be caused by both the biogeochemical process and the adsorption of trace elements by clay mineral and organic materials. (3) The difference of element migration down the Xiashu loess profile reveals that the climate was warm and wet at the early-middle stage of the middle Pleistocene. At the end of the middle Pleistocene, it became dry and cool. At the early stage of the Late Pleistocene, the paleoclimate became warm and wet again. As a whole, the paleoclimate generally became drier and cooler in this region from the beginning of the middle Pleistocene.  相似文献   

5.
A chronosequence of surface and buried soils in moraines and outwash, ranging in age from Middle to Late Holocene, i.e., Little Ice Age, and forming under alpine and subalpine vegetation in the Okstindan Mountains of central‐north Norway (66o N) (Oksskolten) was studied to determine if topographic/stratigraphic setting, weathering characteristics, soil/paleosol properties, SEM/EDS analysis, and extractable Fe and Al could be used to elucidate information on paleoenvironment and age. The geochemical data previously published and geological mapping by the Norwegian Geological Survey indicate a uniform parent material in these profiles. Slight geochemical anomalies of higher U, Th and Br in organic‐rich horizons are related to vegetation and/or higher water content at various times, confirmed by extractable Fe evidence. The data interpretation also shows that extractable Fe, principally Feo, is useful in identifying previous perched water tables, possibly generated by permafrost. The activity ratio of Feo/Fed (oxalate to dithionite) and the ratio Fed/Fet (dithionite to total Fe) appear useful in distinguishing older from younger soils on the basis of the conversion of ferrihydrite to goethite+hematite. Pyrophosphate extracts, proved useful in determining movement of organically bound Al, and showed a pronounced difference between the alpine and subalpine environments. Oxalate‐extractable and dithionite‐extractable Al proved of little value in relative age determination, presumably because sodium dithionite does not extract all crystalline Al.  相似文献   

6.
镇江下蜀土剖面的化学风化强度与元素迁移特征   总被引：27，自引：1，他引：26  
对镇江下蜀土剖面的化学风化强度及元素迁移特征进行了研究, 结合与黄土高原第四纪黄土、古土壤、晚第三纪红粘土以及安徽宣城风成红土等典型风成堆积剖面的对比分析, 得出如下结论: (1) 镇江下蜀土剖面经历了中等强度的化学风化, 明显强于洛川黄土以及古土壤, 显著弱于宣城风成红土, 而与西峰晚第三纪红粘土非常接近。下蜀土的化学风化过程及 其与其他风成堆积剖面风化强度的差异主要受气候条件的控制, 气候条件通过年平均温度和年降水量对化学风化的地球化学环境起重要的影响, 其中降水因素在化学风化过程中可能起着更为重要的制约作用。(2) 镇江下蜀土剖面风化过程中, 绝大部分常量元素的地球化学行为 表现为迁移淋失, 仅Fe 和Ti 轻微富集, 元素的活动性由强至弱依次为: P > Na > Ca > Mg > K > Fe2+ > Si > Mn > Al > Ti > Fe3+; 常量元素的迁移特征揭示下蜀土的化学风化已经完成初级阶段的去Ca、Na 过程, 并初步进入到去K 风化的中级阶段; 微量元素除Sr、Ga 迁移淋 失外, Th、Ba、Cu、Zn、Co、Ni、Cr、V 等均表现出富集特征, 这可能与下蜀土风化成壤过 程中的生物地球化学过程以及粘粒、有机质对微量元素的吸附作用有关。(3) 元素迁移在剖面 中的变化特征揭示, 在0.24 Ma 之前的中更新世早、中期, 该区气候较为暖湿, 兼有干湿交替的特征; 中更新世晚期气候偏干凉, 风化淋溶最弱; 至晚更新世早期则又出现一段明显暖湿的成壤时期, 形成下蜀土剖面中的S1 古土壤层。总之, 中更新世以来本区气候整体上向干凉的方向发展。  相似文献   

7.
作者根据庐山羊角岭红色泥砾的岩性特征,从地形和堆积物的宏观和微观特征进行分析研究,得出庐山有第四纪冰川。  相似文献   

8.
Assessing the thermal evolution of sedimentary basins over time is a major aspect of modern integrated basin analysis. While the behavior of clay minerals and organic matter with increasing burial is well documented in different geological and thermal settings, these methods are often limited by the temperature ranges over which they can be precisely applied and by the available material. Here, we explore the emergent Δ47 clumped isotope geospeedometry (based on the diffusional redistribution of carbon and oxygen isotopes in the carbonate lattice at elevated temperatures) to refine time‐temperature paths of carbonate rocks during their burial evolution. This study provides a reconstruction of the thermal and exhumation history of the Upper Cretaceous thrust belt series in the western subalpine massifs (Bauges and Bornes, French Alps) by a new approach combining for the first time available data from three independent geothermometers. The investigated area presents two zones affected by contrasting thermal histories. The most external zone has undergone a relatively mild thermal history (T < 70°C) and does not record any significant clay mineral diagenetic transformation. By contrast, the internal zone has experienced tectonic burial (prealpine nappes) in response to thrusting, resulting in overheating (T > 160–180°C) that induced widespread clay mineral diagenetic transformations (progressive illitization from R0 to R1 and R3 illite‐smectite mixed‐layers), organic matter maturation (oil window) and Δ47 thermal resetting with apparent equilibrium temperatures above 160°C. The three employed geothermal indicators conjointly reveal that the investigated Upper Cretaceous rocks have suffered a wide range of burial temperatures since their deposition, with a thermal maximum locally up to 160–180°C. High temperatures are associated with the tectonic emplacement of up to 4 km of prealpine nappes in the northern part of the studied area. Finally, a forward thermal modeling using Δ47, vitrinite reflectance and clay mineral data, is attempted to precisely refine the burial and exhumation histories of this area.  相似文献   

9.
Sedimentary cores BDP 96 and 98 and VER 96-2 St. 3 from Academician Ridge in Lake Baikal were investigated to investigate the effect of climatic fluctuations on rock weathering and clay formation in the Baikal drainage basin. Illite, smectite, vermiculite, and kaolinite were identified as the major clay minerals in the sediments by X-ray diffraction analysis. Biotite in gravels in alluvial soils of the Baikal drainage area weathers through illite to vermiculite, smectite, and finally to kaolinite. To investigate the relationship between weathering and climate, we measured the clay content and the concentration of biogenic silica in the sediments. High surface productivity (increased biogenic silica) and high chemical weathering (decreased clay content) occurred simultaneously, showing that crustal weathering and soil formation were enhanced under warm climatic conditions.Clay formation was enhanced in the watershed from the Late Miocene to the Middle Pliocene, and mechanical weathering of rocks increased during glacial intervals after the climate began to cool in Late Pliocene time. This change in the weathering mode in the watershed reduced the nutrient flux and aquatic productivity of Lake Baikal.  相似文献   

10.
镇江下蜀土剖面的化学风化强度与元素迁移特征   总被引：6，自引：1，他引：5  
The chemical weathering intensity and element migration features of the Xiashu loess profile in Zhenjiang are studied in this paper.（1）The Xiashu loess profile underwent moderate chemical weathering.It seems that the precipitation is a more important factor than the temperature in controlling the process of the chemical weathering.（2）The major elements such as Si,K,Na,Ca,Mg,Mn and P were migrated and leached,while the elements Fe and Ti were slightly enriched.The migration features of the major elements reveal that the Xiashu loess finished the primary process of chemical weathering characterized by leaching of Ca and Na,and almost reached the secondary process characterized by leaching of K.Except the elements Sr and Ga,other trace elements such as Th,Ba,Cu,Zn,Co,Ni,Cr and V were enriched.It might be caused by both the biogeochemical process and the adsorption of trace elements by clay mineral and organic materials.（3）The difference of element migration down the Xiashu loess profile reveals that the climate was warm and wet at the early-middle stage of the middle Pleistocene.At the end of the middle Pleistocene,it became dry and cool.At the early stage of the Late Pleistocene,the paleoclimate became warm and wet again.As a whole,the paleoclimate generally became drier and cooler in this region from the beginning of the middle Pleistocene.  相似文献   

11.
Clay mineral assemblages of the Neogene Himalayan foreland basin are studied to decipher their significance with respect to tectonic and climate processes. Fluvial deposits of the Siwalik Group (west‐central Nepal), and sediment of the Ganga River drainage system were analysed for clay mineralogy. The observed clay mineral assemblages are mainly composed of illite (dominant), chlorite, smectite and kaolinite. Illite and chlorite are chiefly of detrital origin, derived from Himalayan sources. Kaolinite and smectite are authigenic, and mainly developed within pore space and as coating of detrital particles. With increasing burial, diagenetic processes affected the original clay mineral signature. Illitisation of smectite and kaolinite occurred below 2500 and 3500 m depth, respectively. Therefore, illite in the lower parts of the Siwalik Group consists of a mixture of inherited illite and illitised smectite and kaolinite, as suggested by illite crystallinity. Detrital grains that make up the framework of the Siwalik Group sandstones mainly consist of quartz, feldspar and lithic fragments, which are principally of sedimentary and metamorphic origin. Lithoclast content increases over time at the expense of quartz and K‐feldspar in response to uplift and erosion of the Lesser Himalaya Series since about 11–10 Ma. Despite mainly felsic source rocks, dominantly physical erosion processes in the Himalayan belt, and high‐energy fluvial depositional systems, smectite is abundant in the <7 Ma Siwalik Group deposits. Analyses of the Siwalik deposits and comparison with the clay mineralogy of the modern drainage system suggest that smectite preferentially formed in floodplains and intermontane valleys during early diagenesis because of downward percolating fluids rich in cations from weathering and soil development. In general, increasing seasonality and aridity linked to variability of the Asian monsoon from about 8 Ma enhanced clay mineral formation and development of authigenic smectite in paleo‐plains on the southern side of the Himalaya.  相似文献   

12.
Major and trace elements, minerals, and grain-size were analysed from the early to mid-Holocene (12 to 4 ky BP) period of a sediment core from the Alpine lake Oberer Landschitzsee (ObLAN, 2076 m a.s.l.), which is located on predominantly crystalline bedrock on the southern slopes of the Austrian Central Alps. Geochemistry and mineralogy were compared with diatom-inferred (Di-) ‘date of autumn mixing’ (Amix), DOC, pH, and selected indicator pollen species from the same sediment core. Principal components analysis (PCA) indicated a positive correlation between processes triggered by temperature and precipitation (e.g., lake mixing, DOC). PCA grouped indicators of physical weathering and enhanced catchment run-off (sand, quartz, feldspar), elements of weathering (e.g., Ti, Rb, Mn) under dryer conditions (clay to silt fractions), and elements that probably were related to changes in redox conditions (Cu, Fe, S, Zn). The duration and height of the snow-pack played an important role in this high-alpine environment, affecting weathering, erosion, pH, and lake stratification. Low Alnus viridis pollen abundance, together with markers for increased elements of erosion, indicated extensive snow-pack. Changes in S coupled with As, and elements indicating increased weathering, reflected climate oscillations. LOI was affected by productivity and erosion. High (late) Di–Amix coupled with increased Di-DOC indicated prolonged summers with increased productivity. Cold and wet (snow-rich) phases and subsequent melting caused low pH and a decoupling of the significant linear correlation between sedimentary Ca and Di-pH. Weathering and leaching during climate deteriorations opposed the long-term trend in a loss of cations and forced in-lake alkalinity generation during the following lake warming. Overall, the multi-proxy study indicated complex climate-driven processes within different time-scales (long-term trends, climate oscillations, seasonality). The climate oscillations within 12–5 ky BP corresponded well with the cool and wet phases known from central Europe suggesting a dominant common Atlantic climate impact. When Mediterranean climate established between 5 and 4 ky BP, its influence on the southern slopes of the Alps increased.  相似文献   

13.
中晚全新世以来玛曲高原的化学风化过程演变   总被引：2，自引：1，他引：1  
在对玛曲高原东南部具有代表性的黄土-古土壤-风成砂沉积剖面进行常量、微量元素及地球化学风化参数分析的基础上,结合14C测年结果,探讨了中晚全新世以来玛曲高原的化学风化过程。结果表明:(1)不同地化学元素在剖面中的化学活性表现出明显的差异性,常量元素Ca、Si、Na以强烈迁移淋失为主,Fe、Mg则表现为明显富集;元素活动性及迁移顺序为Ca >Si >Na >Al >K >Fe >Mg;常量元素的迁移特征表明玛曲高原处于脱Ca、Na的初期化学风化阶段;微量元素除Sr迁移淋失显著外,Cu、Mn、Zn均呈现出强富集特征。(2)根据典型地化学元素记录的冷干-凉润-凉干-温湿的气候变化过程,结合化学风化指标将玛曲高原中晚全新世以来的化学风化过程划分为3.8 ka BP以前的风化较弱期、3.8~3.5 ka BP风化较强期、3.5~1.6 ka BP风化减弱期和1.6 ka BP以来的风化增强期4个阶段。  相似文献   

14.
松嫩平原杜蒙沙地地表物质的地化组成及风化特征   总被引：2，自引：0，他引：2  
谢远云  孟杰  郭令芬  何葵  康春国 《中国沙漠》2013,33(4):1009-1018
本文分析了杜蒙沙地表土样品各粒级组分（全样、>63 μm、63~30μm、30~11 μm和<11 μm）的常量元素组成。结果表明：杜蒙沙地地表物质化学元素组成以Si、Al为主,与上地壳相比,除Si、Mn和Ti外,Fe、Mg、Ca和P严重亏损,Al和Na中度亏损,K轻微亏损;除Si、Al、Na、K外,Fe、Mg、Ca、Ti、P、Mn的变异系数均很高;常量元素在不同粒级中的变化程度按照Al相似文献   

15.
El’gygytgyn Crater Lake, NE Siberia was investigated for sedimentological proxies for regional climate change with a focus on the past 65 ka. Sedimentological parameters assessed relative to magnetic susceptibility include stratigraphy, grain size, clay mineralogy and crystallinity. Earlier work suggests that intervals of high susceptibility in these sediments are coincident with warmer (interglacial-like) conditions and well-mixed oxygenated bottom waters. In contrast, low susceptibility intervals correlate with cold (glacial-like) conditions when perennial ice-cover resulted in anoxia and the dissolution of magnetic carrier minerals. The core stratigraphy contains both well-laminated to non-laminated sequences. Reduced oxygen and lack of water column mixing preserved laminated sequences in the core. A bioturbation index based upon these laminated and non- laminated sequences co-varies with total organic carbon (TOC) and magnetic susceptibility. Clay mineral assemblages include illite, highly inter-stratified illite/smectite, and chlorite. Under warm or hydrolyzing conditions on the landscape around the lake, chlorite weathers easily and illite/smectite abundance increase, which produces an inverse relationship in the relative abundance of these clays. Trends in relative abundance show distinct down-core changes that correlate with shifts in susceptibility. The mean grain-size (6.92 μm) is in the silt-size fraction, with few grains larger than 65 μm. Terrigenous input to the lake comes from over 50 streams that are filtered through storm berms, which limits clastic deposition into the lake system. The sedimentation rate and terrigenous input grain-size is reduced during glacial intervals. Measurements of particle-size distribution indicate that the magnetic susceptibility fluctuations are not related to grain size. Lake El’gygytgyn’s magnetic susceptibility and clay mineralogy preserves regional shifts in climate including many globally recognized␣events like the Younger Dryas and Bolling/Allerod. The sedimentary deposits reflect the climatic transitions starting with MIS4 through the Holocene transition. This work represents the first extensive sedimentological study of limnic sediment proxies of this age from Chukotka (Fig. 1). This is the tenth in a series of eleven papers published in this special issue dedicated to initial studies of El'gygytgyn Crater Lake and its catchment in NE Russia. Julie Brigham-Grette, Martin Melles, Pavel Minyuk were guest editors of this special issue.  相似文献   

16.
Previous studies of chemical weathering rates for soil developed on glacial moraines generally assumed little or no physical erosion of the soil surface. In this study, we investigate the influence of physical erosion on soil profile weathering rate calculations. The calculation of chemical weathering rates is based on the assumption that soil profiles represent the integrated amount of weathering since the time of moraine deposition. The weathering rate of a surface subjected to denudation is the sum of the weathering loss from the existing soil profile added to the weathering loss in the material removed by denudation, divided by the deposition age. In this study, the amount of weathered material removed since moraine deposition is calculated using the denudation rate estimated from cosmogenic nuclide data and the deposition age of the moraine. Weathering rates accounting for denudation since moraine deposition are compared to weathering rates based on the assumption of no physical erosion and on the assumption of steady-state denudation for the Type Pinedale moraine ( 21 ka) and the Bull Lake-age moraine ( 140 ka) in the Fremont Lake Area (Wind River Mountains, Wyoming, USA). The total weathering rates accounting for denudation are 8.15 ± 1.05 g(oxide) m− 2 y− 1 for the Type Pinedale moraine and 4.78 ± 0.89 g(oxide) m− 2 y− 1 for the Bull Lake-age moraine, which are  2 to 4 times higher, respectively, than weathering rates based on the assumption of no physical erosion. The weathering rates based on denudation since moraine deposition are comparable or smaller than weathering rates assuming steady-state denudation. We find the assumption of steady-state denudation is not valid in depositional landscapes with young deposition ages or slow denudation rates. The decrease in weathering rates over time between the Type Pinedale and Bull Lake-age soils that is observed in the case of no physical erosion is decreased when the influence of denudation on the total weathering rates is taken into account. Fresh unweathered material with high reactive mineral surface area is continuously provided to the surface layer by denudation diminishing the effect of decreasing weathering rate over time.  相似文献   

17.
Pollen and plant macrofossils were analysed at Sägistalsee (1935 m asl), a small lake near timber-line in the Swiss Northern Alps. Open forests with Pinus cembra and Abies alba covered the catchment during the early Holocene (9000–6300 cal. BP), suggesting subcontinental climate conditions. After the expansion of Picea abies between 6300 and 6000 cal. BP the subalpine forest became denser and the tree-line reached its maximum elevation at around 2260 m asl. Charcoal fragments in the macrofossil record indicate the beginning of Late-Neolithic human impact at ca. 4400 cal. BP, followed by a extensive deforestation and lowering of the forest-limit in the catchment of Sägistalsee at 3700 cal. BP (Bronze Age). Continuous human activity, combined with a more oceanic climate during the later Holocene, led to the local extinction of Pinus cembra and Abies alba and favoured the mass expansion of Picea and Alnus viridis in the subalpine area of the Northern Alps. The periods before 6300 and after 3700 cal. BP are characterised by high erosion activity in the lake's catchment, whereas during the phase of dense Picea-Pinus cembra-Abies forests (6300–3700 cal. BP) soils were stable and sediment-accumulation rates in the lake were low. Due to decreasing land-use at higher altitudes during the Roman occupation and the Migration period, forests spread beween ca. 2000 and 1500 cal. BP, before human impact increased again in the early Middle Ages. Recent reforestation due to land-use changes in the 20th century is recorded in the top sediments. Pollen-inferred July temperature and annual precipitation suggest a trend to cooler and more oceanic climate starting at about 5500 cal. BP.  相似文献   

18.
The sediment record from a 5.3-m core from Sargent Mountain Pond, Maine USA indicates strong co-evolutionary relationships among climate, vegetation, soil development, runoff chemistry, lake processes, diatom community, and water and sediment chemistry. Early post-glacial time (16,600–12,500 Cal Yr BP) was dominated by deposition of mineral-rich sediment, low in organic matter and secondary hydroxides of Al and Fe; pollen indicate tundra conditions; diatom taxa indicate pH between 7.5 and 8, and total P concentrations of about 25 μg L−1, favoring higher productivity. Chemical weathering was rapid, with high alkalinity, pH, Ca, and P in runoff. As climate ameliorated, about 12,500 Cal Yr BP, forest vegetation became established; soils would have developed vertical zonation, including organic matter accumulation, and incipient podzolic horizons, with accumulating secondary hydroxides of Al and Fe that sequestered P in the soils. Labile minerals (primarily apatite, Ca5(PO4)3(OH,F,Cl)) became depleted in the soil, further reducing the supply of P to the lake. Dissolved organic carbon (DOC) from soil organic matter mobilized Al and Fe to the lake where Al(OH)3 (primarily) and Fe(OH)3 (minor) were precipitated. The sedimenting hydroxides adsorbed P from the water column, further reducing bioavailable P. These long-term trends of moderating climate, and changing terrestrial biology, soils, and aquatic chemistry and phytoplankton were interrupted by the 1,000-year long Younger Dryas cooling, which led to a temporary reversal of these processes, a period that ended with the major onset of Holocene warming. The sequestration of P by soils would have strengthened because of long-term soil acidification and pedogenesis. The lake was transformed from a more productive, high P, high pH, low DOC system into an oligotrophic, relatively low P, acidic, humic lake over a period of 16,600 years, a natural trend that continues. In contrast to many human-affected lakes that become increasingly eutrophic, many lakes become more oligotrophic during their history. The precursors for that are: (1) absence of human land-use in watersheds, (2) bedrock lithology and soil with a paucity of soluble Ca-rich minerals, and (3) vegetation that promotes the accumulation of soil organic matter, podzolization, and increased export of metal-DOC complexes, particularly Al.  相似文献   

19.
This paper aims to compare the geochemical characteristics of loess-paleosol sequences in the upper reaches of the Hanjiang and Weihe river valleyswhich are located in the semi-humid temperate zone and humid subtropical zonerespectively. The Mituosi(MTS) profile in the upper reaches of the Hanjiang River valley and the Yaohecun(YHC) profile in the Weihe River valley were selected for this comparative research. The stratigraphic characteristicscompositionchemical weathering intensityleaching rates of Ca and Namobility of major elementsand transport features of Na and Fe were analyzed with respect to depth and compared between the two profiles. This study reached the following conclusions.(1) The composition of the loess-paleosol sequences in two regions are quite similar to the average composition of the upper continental crust(UCC)indicating that the loess in the two regions came from multiple sources and was mixed well. Thereforethe loess in the two regions is considered aeolian loess.(2) Compared with the loess-paleosol sequence in the Weihe River valleythe loess-paleosol sequence in the upper reaches of the Hanjiang River valley features a darker color; a higher chemical index of alteration(CIA) value; higher leaching rates of Na and Ca; higher migration ratio(relative to K) of AlSiMgand Na; and lower migration ratio of Fe and Ca. This evidence indicates that the loess-paleosol sequence in the humid subtropical environment experienced stronger chemical weathering intensity than the loess-paleosol sequence in the semi-humid temperate zone.(3) Both the YHC profile and MTS profile record a period of climate deterioration at 6000–5000 a BP. The period punctuated the mid-Holocene Climatic Optimum(8500–3100 a BP) in the study area.  相似文献   

20.
Major and trace elements, minerals and grain-size were analysed from a sediment core covering the last 4,000 years of an Austrian Alpine lake (Oberer Landschitzsee, ObLAN, 2,076 m a.s.l.). These analyses were combined with autumn and spring temperature anomalies and ice-cover estimated from a diatom and chrysophyte cyst, thermistor-based regional calibration dataset and selected pollen markers published previously. Diatom-inferred pH (Di-pH) and DOC (Di-DOC) completed the multi-proxy approach, which, together with ordination techniques (PCA and RDA), helped (1) to confirm proposed climatic patterns and hypotheses, and (2) to disentangle the complex interactions between climatic and anthropogenic impacts. Shifts in chemical and physical weathering, erosion, production, lake stratification, redox potentials and air pollution were the major processes that have affected Oberer Landschitzsee in relation to climate, lake/catchment interactions, and human impact. Geochemistry supported the finding that the four waves of high-altitude land use (Early to Middle Bronze, ca. 1,800–1,300 B.C.; Late Bronze to Hallstatt, ca. 1,000–500 B.C.; Celtic to Roman, ca. 300 B.C.–400 A.D.; and Medieval, ca. 1,000–1,600 A.D.) were coupled mainly with warm periods. Increased production, onset of lake stratification, and the deterioration of hypolimnetic oxygen conditions were the major changes governing in-lake processes during climate warming. They resulted in specific element assemblages associated with organic matter accumulation (Br), oxygen depletion (As, Ga, Cu, S), and changes in redox (Fe/Mn). The Se/Di-DOC ratio was introduced to track shifts between in-lake production and allochthonous sources. Nutrient loading from pastures, coupled with climate warming, could explain that in-lake production was highest during Roman and Medieval land use. Lithogenic elements mainly originated from chemical weathering of silicate bedrock and they increased when intense land-use was coupled with climate deterioration and/or increased humidity. These perturbations were highest during a High Medieval climate fluctuation around 1,000 A.D. The association of sand with LOI and C/N and the decoupling of sand from quartz and feldspar separates erosion from physical weathering. Di-DOC, S, and C/N showed hybrid characters in relation to climate and human impact. The mineral proportions indicated gradients in relation to weathering, snow-cover and running waters, as well as vegetation. Air pollution by metallurgic industries, starting during the High Medieval and culminating during the Late Medieval, caused lead accumulation and could have contributed to As and S enrichment. Corresponding features in the distribution of selected elements and pollen tracers, as well as changes in mineral proportions, supported the hypotheses of shifts in seasonal climate and an overall trend towards more continental climate conditions since Medieval times.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号