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1.
The turbidity criterion for the product water of a WTP according to the State Project ‘863＇ on the safeguard technology of drinking water in the southern areas of China is 0.1 NTU. The turbidity removal in the activated carbon filter was analyzed in a pilot-scale test and an innovative technology to improve the turbidity removal in a biologically activated carbon （BAC） filter was put forward in order to meet the criterion. Experimental results showed that the enhanced filtration by adding polymerized aluminium chloride （PAC） into the BAC filter was quite effective in turbidity control. The effluent turbidity was kept at a stable level （mean） of 0.033 NTU with a high removal of about 80% for influent turbidity of 0.110- 0240 NTU with an addition of PAC at 0.05 mg L^-1, meeting the requirement for filtrate turbidity equal to or less than 0.1NTUC totally. In addition, the larger the PAC dosage was, the lower the effluent turbidity was. However, further improvement of turbidity removal was not obvious for PAC dosages beyond 0.10 mg L^- 1, and an optimal PAC dosage in the range of 0.05 - 0.10 mg L^- 1 was proposed.  相似文献   

2.
Study on Algae Removal by Immobilized Biosystem on Sponge   总被引：2，自引：0，他引：2  
In this study, sponges were used to immobilize domesticated sludge microbes in a limited space, forming an immobilized biosystem capable of algae and microcystins removal. The removal effects on algae, microcystins and UV260 of this biosystem and the mechanism of algae removal were studied. The results showed that active sludge from sewage treatment plants was able to remove algae from a eutrophic lake＇s water after 7 d of domestication. The removal efficiency for algae, organic matter and microcystins increased when the domesticated sludge was immobilized on sponges. When the hydraulic retention time （HRT） was 5h, the removal rates of algae, microcystins and UV260 were 90%, 94.17% and 84%, respectively. The immobilized biosystem consisted mostly of bacteria, the Ciliata and Sarcodina protozoans and the Rotifer metazoans. Algal decomposition by zoogloea bacteria and preyingby microcreatures were the two main modes of algal removal, which occurred in two steps： first, absorption by the zoogloea; second, decomposition by the zoogloea bacteria and the predacity of the microcreatures.  相似文献   

3.
In this work,response surface methodology(RSM)was employed to model and optimize electrodialysis process for mercury(Hg(II))removal from seaweed extracts.Box-Behnken design(BBD)was utilized to evaluate the effects and the interaction of influential variables such as operating voltage,influent flow rate,initial concentration of Hg(II)on the removal rate of Hg(II).The developed regression model for removal rate response was validated by analysis of variance,and presented a good agreement of the experimental data with the quadratic equation with high value coefficient of determination value(R2=0.9913,RAdj 2=0.9678).The optimum operating parameters were determined as 7.17V operating voltage,72.54L h−1 influent flow rate and 5.04mgL−1 initial concentration of mercury.Hg(II)removal rate of 76.45%was acquired under the optimum conditions,which showed good agreement with model-predicted(75.81%)result.The results revealed that electrodialysis can be considered as a promising strategy for removal of Hg(II)from seaweed extracts.  相似文献   

4.
Constructed wetlands(CWs) were integrated into an indoor recirculating aquaculture system of obscure puffer(Takifugu obscurus) for effluent treatment. The effect of hydraulic loading rate(HLR) on the efficiency of effluent treatment by CWs was examined for over a month. The CWs were operated under brackish conditions(salinity 7.4–7.6) at 3 different HLRs(0.762, 0.633, and 0.458 m d–1) 3 times, 10 days each. Overall, the CWs exhibited high efficiency in removal of total ammonium nitrogen(by 81.03–92.81%) and nitrite nitrogen(by 99.40%–99.68%). The efficiency of CWs in removal of total ammonium nitrogen, nitrate nitrogen, total Kjeldahl nitrogen, total phosphorous, and total suspended solids(TSS) increased with the decrease of HLR. The CWs operated at the 3 HLRs in a decreasing trend proves to be effective, providing a useful method for effluent treatment in commercial puffer aquaculture systems.  相似文献   

5.
The lowest addition of mercury (0.1 ug Hg 1-1) was used in CEEs for research on mercury flux, speciation and budget. The removal behavior of mercury by phytoplankton in water columns of CEEs can be described by first order kinetic equations for total and particulate mercury in the CEE spiked by mercury. The removal rate of mercury in water columns depends on the size and productivity of phytoplanton in a water column to which mercuric ions were added. A 4.4 day half-life time and a 2.8 day half-life time for total and particulate mercury respectively was obtained in diatom bloom. During microflagellate bloom a 30 day total mercury half-life time was estimated with increase of particulate mercury in the water column. The 0.010 ug Hg cm-2y-1 mercury flux rate that was attained in the control bag agreed with the values from field measurements in Saanich Inlet where the bags Were launched.The proportion of total mercury to dissolved and particulate mercury depended also on the size, productivity, and concen  相似文献   

6.
《山地科学学报》2020,17(6):1345-1359
Acid Mine Drainage(AMD) from coal mining is a serious environmental issue which affects water quality, ecology, and the overall landscape of the basin. A large number of coal mine tailings in the mountainous regions of Guizhou Province, China were unattended and iron-rich AMD was directly discharged to the rivers. This discharge leaves the river ―yellow‖ and heavily polluted. This study tries to find an efficient and economical method for treating iron-rich AMD. We sampled AMD water in two sites: Yangliujie town of Duyun city(hereafter, called Yangliujie), and Xinglong Coal Mine, Duliu town of Guiding county(hereafter, called Xinglong). We performed iron removal laboratory experiment with Cement-Bentonite Agent(CBA, 80% cement and 20% bentonite) in 500 mL AMD water from Yangliujie, scale-up experiment in 15 L AMD water from both Yangliujie and Xinglong, and engineering application in Xinglong respectively. Laboratory experiment results showed the iron removal rate can reach 99.8% and the removal rate depends on the CBA dosage and the treatment time. In the scale-up experiment, we found that Fe concentration could be reduced from 587.0 to 0.2 mg/L when adding 20 g/L CBA to the AMD water and aerating for 3 hours. As sampled water in Xinglong has a very high Fe concentration(Fe 1019.8 mg/L) and the concentration varies with seasons, it is not economical to add the CBA directly to the AMD water. Considering the abundant and cheap limestone resources in Guizhou, we used a twostep treatment method, first we added CaCO_3 to raise the pH, and then we took the supernatant liquor and added CBA to the liquor. It was shown that 15 g/L of CBA was a good dosage for iron removal with Fe concentration being reduced from 1019.8 to 0.3 mg/L when CaCO_3 was used to raise the pH. The best treatment realized over 99.9% iron removal, 99.2% NH_3-N removal, 98.9% CODMn removal, and heavy metals in the treated water were reduced to under the limit stipulated in the ―Environmental Quality Standards of Surface Water in China‖. Thus in the engineering application, we used this two-step treatment method. After the treatment, the pH of the iron-rich AMD(pH 2.86, Fe 2624.6 mg/L) increased to 8.53, the concentration of Fe was reduced to 59.5 mg/L, NH_3-N decreased from 16.15 to less than 0.05 mg/L, COD_(Mn) decreased from 323.33 to 24.57 mg/L, heavy metals except Fe and Mn were reduced to under the limit of surface water. In conclusion, the use of CBA can effectively remove Fe and other heavy metals from the iron-rich AMD and adjust the pH value to the range of a natural water body.  相似文献   

7.
The stable isotope has been extensively applied as an effective tracer especially in precipitation. In glacierized area of arid northwest China, temperature is widely considered to be a major factor affecting isotopes in precipitation, while the influences of precipitation amount, relative humidity and other meteorological parameters are still not clear. Based on analyses on stable isotope values of water samples and NCEP/NCAR(National Centers of Environmental Prediction/National Center for Atmospheric Research, USA) re-analysis data, the moisture source and characteristics of isotopes in the precipitation, meltwater and river water isotopes at Urumqi Glacier No.1 of the upstream Urumqi River Basin, eastern Tianshan Mountains from spring to autumn during four years(from 2008 to 2011) was studied. Results indicated that meltwater are the main source of water for the upper Urumqi River. Seasonal variation of δ~(18) O in precipitation demonstrated that δ18 O was more enriched in summer and depleted in spring and autumn. Temperature was positively correlated with isotopes, while precipitation amount and relative humidity was negatively correlated with isotopes. The water vapor was affected by westerly air mass and regional water vapor cycle. Meanwhile, back trajectory clustering analyses showed that the moisture mainly from Europe and central Asia. The moisture was more likely to be locally sourced with the ratio was 46.8%～52.1%.  相似文献   

8.
Non-point-source pollution has become a major threat to the water quality of the Three Gorges Reservoir(TGR);however,nutrient loadings from terrestrial sources are unclear due to a lack of in situ monitoring.A representative small watershed in the central part of the TGR area was selected to monitor the loss of nitrogen(N) and phosphorous(P) continuously along with the runoff from 2007 through 2009 to understand the exact sources and loadings.Results show that the non-point-source nitrogen and phosphorus comes mainly from the storm runoff from residential areas,citrus orchards and sloping croplands,which contributes up to 76% of the loadings in this watershed.Thus,a crucial measure for controlling non-point-source pollution is to intercept storm runoff from the three sources.Paddy fields provide a sink for non-point-source N and P by intercepting the runoff and sediment along with their different forms of nitrogen and phosphorus.The N and P removal efficiency by paddy fields from residential areas is within the range of 56% to 98%.Paddy fields are an important land-use option for reducing the non-point-source loading of N and P in the TGR area.  相似文献   

9.
Sorption mechanisms of sulfamethazine(SMT) in different pH solutions are complicated. It has not been sufficiently investigated to enhance removal of SMT from alkalescent aqueous solution. In this study, sorption isotherms and kinetics of SMT by corn biochars pyrolyzed at 300℃ and 600℃(300 C, 600 C) under diverse pH conditions were compared. In order to improve the sorption efficiency of SMT from alkalescent aqueous solution, the biochar 300 C was modified by acid or base. Different mathematic models were used to describe sorption driving force and sorption process. Results showed that the biochar 300 C possessed more amorphous organic carbon and polar functional groups, which led to a higher sorption capacity than biochar 600 C. The sorption rate of biochar 300 C was greater than 600 C under diverse pH as the physisorption of 300 C outweighed 600 C. The SMT presented stronger hydrophobicity at pH 5 and higher electrostatic repulsion at p H 1 or 8, which resulted in a higher combining capacity of SMT with both biochars at pH 5 than other pH values. In addition, the acid modified biochar had better removal effect on SMT than alkali at pH solution around 8. The research provides a theoretical basis for the removal of SMT from alkalescent aqueous solution.  相似文献   

10.
This paper deals with the bioconcentration of 14C-simetryne from water by aquatic test organisms : green algae-Monoraphidium minutum, rotifers-Brachionus rubens, daphnids-Daphnia magna, and fish-Brachydanio rerio . The chemical was bioconcentrated rapidly in all test species during the first 48 hours of experiment. The BCF values (bioconcentration factor) from all uptake studies show that simetryne has higher accumulation in algae than in rotifers, daphnids and zebra fish.The logarithm of the n-octanol/water partition coefficient of simetryne measured as 2.06+0.05 was correlated with the BCFs in the organisms as based on the lipid contents.14C-simetryne uptake via the food-chain amounted to only 22% to 42% of the bioconcentration from water. Clearance of 14 C- derived residues from fish was rapid with a half-life of 2.1 days.  相似文献   

11.
High salt and low temperature are the bottlenecks for the remove of oil contaminants by enriched crude-oil degrading microbiota in Liaohe Estuarine Wetland(LEW),China.To improve the performance of crude-oil removal,microbiota was further immobilized by two methods,i.e.,sodium alginate(SA),and polyvinyl alcohol and sodium alginate(PVA+SA).Results showed that the crude oil was effectively removed by the enrichment with an average degrading ratio of 19.42-31.45 mg(L d)?1.The optimal inoculum size for the n-alkanes removal was 10%and 99.89%.Some members of genera Acinetobacter,Actinophytocola,Aquabac-terium,Dysgonomonas,Frigidibacter,Sphingobium,Serpens,and Pseudomonas dominated in crude-oil degrading microflora.Though the removal efficiency was lower than free bacteria when the temperature was 15℃,SA and PVA+SA immobilization im-proved the resistance to salinity.The composite crude-oil degrading microbiota in this study demonstrated a perspective potential for crude oil removal from surface water under high salinity and low temperature conditions.  相似文献   

12.
In Wuxi Wastewater Treatment Plant, the Anaerobic, anoxic and oxic (A2/O) process was employed to remove the nitrogen and phosphorus, which exhibited the positive results of the high removal efficiency for phosphorus with a range of 67.7% to 89.9% and an average value of 78.0. The effluent of phosphorus met the national discharge standard. The removal of TN was effected by both BOD variation of influent and wastewater temperature. TN removal was in the range of 28.5% to 55.8% with an average value of 39.4%. The energy cost was 0.15 kWh(m3d)-1 or 1.35 kWh(kgBOD·d)-1. The annual average sludge production was 46.3 m3d-1, the annual average dosage for the dewatering was 40 kgd-1.  相似文献   

13.
This research deals mainly with the use of the vegetative cells of a marine red alga Porphyra hailanensis (laver) as seeds and their culture into young thalli for further cultivation in the sea. The experimental process was as follows. Enzymatically isolated vegetative cells were attached to rope substrates and cultured in the laboratory for a month until they became about 0.2-0.5 cm long sporelings and were then attached (7-15 sporelings per cm of rope) to nets for removal to the open sea for cultivation. A month after culturing, the thalli reached a maximum length of 50 cm (average of 20-30 cm). The thalli grew faster as the water temperature dropped from 21℃ to 17℃. It was proved that the vegetative cells isolated from a small thallus about 5 cm long could grow up into normal thalli after being kept frozen for a year. The results of this study show that vegetative cells can be used as new seeds to simplify the production of laver sporelings. This technique is a significant advance in the field of P  相似文献   

14.
A rapid method of microwave assisted acid hydrolysis was established to prepare κ-carra-oligosaccharides. The optimal hydrolysis condition was determined by an orthogonal test. The degree of polymerization(DP) of oligosaccharides was detected by high performance thin layer chromatography(HPTLC) and polyacrylamide gel electrophoresis(PAGE). Considering the results of HPTLC and PAGE, the optimum condition of microwave assisted acid hydrolysis was determined. The concentration of κ-carrageenan was 5 mg m L-1; the reaction solution was adjusted to p H 3 with diluted hydrochloric acid; the solution was hydrolyzed under microwave irradiation at 100 for 15℃ min. Oligosaccharides were separated by a Superdex 30 column(2.6 cm × 90 cm) using AKTA Purifier UPC100 and detected with an online refractive index detector. Each fraction was characterized by electrospray ionization mass spectrometry(ESI-MS). The data showed that odd-numbered κ-carra-oligosaccharides with DP ranging from 3 to 21 could be obtained with this method, and the structures of the oligosaccharides were consistent with those obtained by traditional mild acid hydrolysis. The new method was more convenient, efficient and environment-friendly than traditional mild acid hydrolysis. Our results provided a useful reference for the preparation of oligosaccharides from other polysaccharides.  相似文献   

15.
Constructed wetlands （CWs） were integrated into an indoor recirculating aquaculture system of obscure puffer （Takifuguobscurus） for effluent treatment. The effect of hydraulic loading rate （HLR） on the efficiency of effluent treatment by CWs was ex-amined for over a month. The CWs were operated under brackish conditions （salinity 7.4-7.6） at 3 different HLRs （0.762, 0.633, and0.458 m d-1） 3 times, 10 days each. Overall, the CWs exhibited high efficiency in removal of total ammonium nitrogen （by81.03-92.81%） and nitrite nitrogen （by 99.40%-99.68%）. The efficiency of CWs in removal of total ammonium nitrogen, nitratenitrogen, total Kjeldahl nitrogen, total phosphorous, and total suspended solids （TSS） increased with the decrease of HLR. The CWsoperated at the 3 HLRs in a decreasing trend proves to be effective, providing a useful method for effluent treatment in commercialpuffer aquaculture systems.  相似文献   

16.
Earthen structures such as shore protection dikes and river embankments easily suffer from erosion under surface water runoff.This study made experimental efforts to explore the enzyme-induced carbonate precipitation(EICP)method for slope erosion control under surface runoff for earthen structures.The sandy soils were treated by the EICP method for various rounds.Surface characteristics were evaluated by the surface penetration resistance,calcium carbonate content,and surface hard crust thickness of EICP-treated soils.Slope runoff erosion experiments were carried out to evaluate the erosion control performances of the EICP treatment.The surface penetration resistance,calcium carbonate content,and surface hard crust thickness were found to significantly increase with the treatment rounds.In the erosion experiments,it was observed that the level of damages decreased and the water flow volume required to trigger the damage increased with more treatments.The increase in the soil slope angle led to more serious surface damages.The amount and rate that the soil particles were eroded from the slope surfaces declined with more EICP treatments,which was consistent with those of visual observations.The preliminary investigations presented in this study have shown the potential of the EICP method for slope erosion control under surface runoff for earthen structures.  相似文献   

17.
SYNTHESIS AND PROPERTIES OF SULFHYDRYL CHITOSAN   总被引：1，自引：0，他引：1  
A new adsorbent for heavy metal ions, sulfhydryl chitosan (S-chitosan), was produced by treatment of chitosan with sulhydryl acetic acid in the presence of sulfuric acid as a catalyst. Its structure was confrrmed by elemental analysis and FI‘-IR spectra analysis. The adsorption properties of sulthydryl chitosan for Cu(Ⅱ ), Cd(Ⅱ ), Pb(Ⅱ), Cr(Ⅲ) and Ni(Ⅱ) were investigated, and the effect of pH value on adsorption, adsorption kinetics, and selective adsorption was examined. It was shown that S-chitosan has good adsorption for Pb(Ⅱ), Cu(Ⅱ) and Cd(Ⅱ) like chitosan, is also insoluble in acid solution; has good adsorption kinetic properties for heavy metal ions; and can be used in acid solution. The adsorption capacities of S-chitosan can be affected by media acidity. The adsorbed Cu(Ⅱ) Cd(Ⅱ) and Pb(Ⅱ) could be eluted by diluted chlorhydric acid.  相似文献   

18.
Gracilaria asiatica,being highly efficient in nutrient absorption,is cultivated in sea cucumber ponds to remove nutrients such as nitrogen and phosphate.It was cultured in a laboratory simulating field conditions,and its nutrient absorption was measured to evaluate effects of environmental conditions.Ammonia nitrogen(AN),nitrate nitrogen(NN),total inorganic nitrogen(TIN),and soluble reactive phosphorus(SRP) uptake rate and removal efficiency were determined in a 4×2 factorial design experiment in water temperatures(T) at 15℃ and 25℃,algae biomass(AB) at 0.5 g/L and 1.0 g/L,total inorganic nitrogen(TIN) at 30 μmol/L and 60 μmol/L,and soluble reactive phosphorus(SRP) at 3 and 6 μmol/L.AB and ambient TIN or SRP levels significantly affected uptake rate and removal efficiency of AN,NN,TIN,and SRP(P<0.001).G.asiatica in AB of 0.5 g/L showed higher uptake rate and lower removal efficiency relative to that with AB of 1.0 g/L.Nitrogen and phosphorus uptake rate rose with increasing ambient nutrient concentrations;nutrient removal efficiency decreased at higher environmental nutrient concentrations.The algae preferred to absorb AN to NN.Uptake rates of AN,NN,and SRP were significantly affected by temperature(P<0.001);uptake rate was higher for the 25℃ group than for the 15℃ group at the initial experiment stage.Only the removal efficiency of AN and SRP showed a significant difference between the two temperature groups(P<0.01).The four factors had significant interactive effects on absorption of N and P,implying that G.asiatica has great bioremedial potential in sea cucumber culture ponds.  相似文献   

19.
Supercooled water with temperatures below freezing point,was identified from hydrographic data obtained by Chinese and Australian expeditions to Prydz Bay,Antarctica,during the austral summer.The study shows that most supercooled waters occurred at depths of 63-271 m in the region north of the Amery Ice Shelf(AIS) front.The maximum supercooling was 0.16°C below the in-situ freezing point.In temperature and salinity ranges of-2.14--1.96°C and 34.39-34.46,respectively,the water was colder and fresher than peripheral shelf water.The supercooled water had less variability in the vertical profiles compared to shelf water.Based on analysis of their thermohaline features and spatial distribution,as well as the circulation pattern in Prydz Bay,we conclude that these supercooled waters originated from a cavity beneath the AIS and resulted from upwelling just outside of the AIS front.Water emerging from the ice shelf cools to an extremely low temperature(about-2.0°C) by additional cooling from the ice shelf,and becomes buoyant with the addition of melt water from the ice shelf base.When this water flows out of the ice shelf front,its upper boundary is removed,and thus it rises abruptly.Once the temperature of this water reaches below the freezing point,supercooling takes place.In summer,the seasonal pycnocline at-100 m water depth acts as a barrier to upwelling and supercooling.The upwelling of ice shelf outflow water illuminates a unique mid-depth convection of the polar ocean.  相似文献   

20.
The water erosion prediction project(WEPP) model is a popular water erosion prediction tool developed on the basis of the physical processes of water erosion.Although WEPP has been widely used around the world,its application in China is still insufficient.In this study,the performance of WEPP used to estimate the runoff and soil loss on purple soil(Calcaric Regosols in FAO taxonomy) sloping cropland was assessed with the data from runoff plots under simulated rainfall conditions.Based on measured soil properties,runoff and erosion parameters,namely effective hydraulic conductivity,inter-rill erodibility,rill erodibility,and critical shear stress were determined to be 2.68 mm h-1,5.54 × 106 kg s-1 m 4,0.027 s m 1 and 3.5 Pa,respectively,by using the recommended equations in the WEPP user manual.The simulated results were not good due to the low Nash efficiency of 0.41 for runoff and negative Nash efficiency for soil loss.After the four parameters were calibrated,WEPP performed better for soil loss prediction with a Nash efficiency of 0.76.The different results indicated that the equations recommended by WEPP to calculate parameters such as erodiblity and critical shear stress are not suitable for the purple soil areas,Sichuan Province,China.Although the predicted results can be accepted by optimizing the runoff and erosion parameters,more research related to the determination of erodibility and critical sheer stress must be conducted to improve the application of WEPP in the purple soil areas.  相似文献   

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