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Commercial linear alkylbenzene sulfonate (LAS), mixture of alkylchain lengths and phenyl position isomers (C10-C13), is widely used as a major constituent of household and industrial detergents in the People's Republic of China. Degradation process and behaviour of LAS compounds during an 82-hour lake water die-away study, with an added LAS concentration of 1. 5mg .L-1, was quantified and accomplished by HPLO-UV after extractionon the SepPek C18 reversed - phase cartridges. The degradation rate became progressively faster with increasing chain length. The technique described in this study is fast, sensitive and specific, and can be used to determine low levels, of LAS and for establishing water quality criteria and standards relating to LAS and its compounds. 相似文献
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INTRODUCTIONOverthepastseveralycars,considerableinteffethasbocenteIdontheenvir0nmentalbehaviouroftoxicandpersistritcomP0undssuchashalogenatalaromat-ies,inparticularthepolychiorinataldibopdioxins(PCDDe)andpolydil0rinateddi~fUtansrpCDFs).ManyofthesecomPounds,espedllythosewithahighdegere0fchiorinesubstitution,arehighlylipophiliccontawhnantSwithlowWhtersolubility,highre-sistancet0chdricaltransformationsandlowwhcrobiologhaldegradatfonpeatnnann,l988,Bromanetal.,l989,Hites,l990)whichexplain… 相似文献
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Polychlorinated dibenzo-p-dioxins （PCDDs） and dibenzofurans （PCDFs） in surface sediment and bivalve from the Changjiang Estuary, China 总被引：1，自引：0，他引：1
Surface sediments and bivalves were collected from the Changjiang Estuary in December 2003 and November 2004, respectively. Polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) in these samples were measured with high-resolution chromatography (HRGC)/High Resolution Mass Spectrometer (HRMS). The concentrations of total PCDD/Fs and toxic equivalent (TEQ) were 169.83±119.63 and 0.81±0.36 pg/g dry weight (dw) in sediments, and 580.33±240.17 and 7.24±3.65 pg/g dw in bivalves. The homolog compositions of PCDD/Fs were similar among samples, the most abundant congener was octa-chlorinated dibenzo-p-dioxin (OCDD) and then octa-chlorinated dibenzofuran (OCDF) and 1,2,3,4,6,7,8-hepta-chlorinated dibenzo-p-dioxin (HpCDD). The herbicide pentachlorophenol (PCP) and sodium pentachlorophenol (Na-PCP) were proved the main source of PCDD/Fs in this area. 相似文献
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This paper deals with the bioconcentration of 14C-simetryne from water by aquatic test organisms : green algae-Monoraphidium minutum, rotifers-Brachionus rubens, daphnids-Daphnia magna, and fish-Brachydanio rerio . The chemical was bioconcentrated rapidly in all test species during the first 48 hours of experiment. The BCF values (bioconcentration factor) from all uptake studies show that simetryne has higher accumulation in algae than in rotifers, daphnids and zebra fish.The logarithm of the n-octanol/water partition coefficient of simetryne measured as 2.06+0.05 was correlated with the BCFs in the organisms as based on the lipid contents.14C-simetryne uptake via the food-chain amounted to only 22% to 42% of the bioconcentration from water. Clearance of 14 C- derived residues from fish was rapid with a half-life of 2.1 days. 相似文献
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