共查询到18条相似文献，搜索用时 93 毫秒
1.
采自柞水银铅矿地表径流６个沉积物样品,用连续提取法提取了金属元素的５种化学相态（可交换相、碳酸盐相,铁锰氧化物结合相,有机质－硫化物结合相及残渣相）,测定了各相中铜铅锌含量,分析了其分布特征。结果表明,在河流沉积物中,铜主要以残渣相和有机质相存在,铅、锌主要为铁锰水合氧化物相和碳酸盐相。在此基础上,对矿山开采中环境影响进行了讨论。 相似文献
2.
文章论述广西某些地区铝土矿及红土的针铁矿中铝的类质同象置换现象，并运用Ｘ射线衍射分析法测定其中的置换率。这种针铁矿称为铝针铁矿。文中指出，在地表氧化条件下形成的针铁矿中，这种置换现象甚为普遍；置换率的高低反映其形成时的地质环境及物理化学条件；高置换率常常与高成熟度红土化作用特别是红土型铝土矿密切相关。铝一旦进入针铁矿晶格后，将出现稳定性效应，在矿物被溶解或相变成其他矿物之前是不会自行析出的。因此，对其研究不仅可用以判断形成环境，而且，对铝土矿矿物量和有效溶出率的计算以及对工业利用流程合理选择均有重要意义 相似文献
3.
通过在山西省古县中部一带开展地质工作,初步查明了区内地层、构造、岩浆岩分布情况,以及区内锰铁矿矿体赋存层位及空间展布。对锰铁矿的成矿地质条件进行了研究,了解了水文地质情况及开采技术条件,并根据锰铁矿分布规律对成矿远景进行了预测。得出了该区有进一步开展找矿工作的结论。 相似文献
4.
金属元素活动态是我国5种深穿透地球化学技术中应用最广的方法之一。此方法是通过提取地表土壤一定深度介质中元素活动态的微弱隐伏矿信息而找寻隐伏矿,属于通过直接信息找矿,目前该方法的标准化程度不高。为将铜元素活动态应用于地质找矿,该文对铜元素4个活动态的相态(水浸出态、粘土吸附态、有机链合态、铁锰氧化物态)循序提取的条件及ICP-AES测定技术进行了研究,包括采样深度、分析样品粒度、样品存放时间、提取条件、测定干扰等,通过对铜活动态提取液处理方法的改进,提高了分析速度和分析数据的精度。由实验数据计算出各相态方法的检出限和精密度RSD(n=10),水浸出态为0.079mg/L,13.90%～22.49%;粘土吸附态为0.275mg/L,11.99%～23.29%;有机链合态为0.362mg/L,10.70%～57.27%;铁锰氧化物态为0.230mg/L,17.83%～38.61%。该方法操作方便,精密度较好,应用于碑楼隐伏铜矿的野外探测实验,探测结果所圈定的综合异常与实际矿体的水平投影相符,取得了较满意的试验效果,该方法可应用于不同地质景观区。 相似文献
5.
广西横县土壤硒(Se)元素含量分布特征显示,硒含量范围0.03~2.62mg/kg,背景值0.57mg/kg。研究区土壤硒含量空间上呈中东高西低,富硒土壤占74.1%,主要分布于泥盆系、石炭系及二叠系等浅海—滨海相沉积的碳酸盐岩成土母质区;足硒土壤占比24.5%,空间上与白垩系、古近系碎屑岩母质的分布相对应。硒与TFe2O3、Pb、Cr、Ni、Zn、有机碳及p H值等呈显著相关性(p0.01),表明土壤硒含量不仅受成土母岩的影响,还受铁锰氧化物、硫化物成矿元素、有机质及p H值的影响。 相似文献
6.
通过场地灌溉试验，探讨了灌溉活动对非饱和带中砷迁移转化过程的影响机理。结果表明:灌溉过程中非饱和带中砷的迁移转化受多个地球化学过程共同控制，非饱和带ｐＨ 值、Ｅｃ值、ＳＯ２－４ 和 ＨＣＯ－３ 与 Ａｓ的竞争吸附以及氧化还原条件的波动都会影响土壤孔隙水中砷的质量浓度。灌溉活动导致土壤处于相对还原环境，铁氧化物矿物还原溶解，被吸附或与之共沉淀的砷被释放进入水相，灌溉结束后，土壤逐渐恢复相对氧化环境，重新生成铁氧化物矿物，土壤孔隙水中砷以吸附／共沉淀形式被其固定。因此，通过改变非饱和带氧化还原条件导致铁氧化物矿物的沉淀／溶解是灌溉作用下非饱和带水体中砷迁移转化的主要原因。 相似文献
7.
采用批量振荡吸附平衡法设计针铁矿和蒙脱石对菲的吸附解吸试验,对比研究了针铁矿和蒙脱石对菲的吸附解吸行为,并考察了不同K+浓度的溶液对蒙脱石吸附菲的影响,比较分析了线性吸附模型和Freundlich吸附模型描述矿物吸附等温线的准确性,并从吸附热力学角度探讨了矿物的吸附机理。结果表明:针铁矿和蒙脱石对菲的吸附解吸均表现出明显的非线性和解吸滞后现象;相对于线性吸附模型来说,针铁矿和蒙脱石对菲的吸附解吸更符合Freundlich吸附模型;与蒙脱石相比,针铁矿对菲的吸附更为显著,且具有更好的稳定性;溶液中软阳离子K+的存在使蒙脱石对菲的吸附能力得到显著提高;菲在蒙脱石和针铁矿上的吸附过程是一个自发放热,同时伴随着熵值减小的过程;随着温度的升高,蒙脱石和针铁矿对菲的吸附能力均减弱。 相似文献
8.
随着城市建设的发展,南宁市地下水的第一环境发生了较大的变化.地下水质量与60年代相比,许多组分发生了变异。本文通过水质现状与历史水质的对比.及对第一环境因素的分析,探讨了地下水偏酸和铁锰离子较高的原因,并对将来的地下水质变化进行了推测。认为:水质偏酸和铁锰含量较高均属第一环境的本底值问题,将来的地下水质会不断变化,将以有机污染为主。 相似文献
9.
金活动态测量法在红壤区与干旱黄土区找矿中的应用 总被引：1，自引：0，他引：1
文雪琴 《地球科学与环境学报》2007,29(4):369-373
用金属活动态提取法在广西与山西黄土区进行试验研究,发现在山西黄土区,利用金的水提取态含量偏低,异常不明显,而金的粘土结合态、有机物结合态和铁锰氧化物结合态异常清晰地反映在矿体上方;而在雨量充沛的广西红壤区,金的水提取态和铁锰氧化物结合态异常较好,而粘土结合态金异常效果不太理想。研究结果表明在这两个地区应用金属活动态测量法进行找矿研究时,可以对其提取有利的相态来进行靶位确定。 相似文献
10.
介绍了江口式铁矿矿床特征及沉积岩相古地理特点，铁、锰、磷等矿产的沉积成矿序列，认为该类铁矿属条带状铁硅质建造，与前寒武纪苏必利尔湖型铁矿有一定相似性。矿床分布范围广，资源潜力大，建议加强勘查开发。 相似文献
11.
JIANG Xuejun） ）* YAO De） LIN Xuehui） ZHAI Shikui）） College of Geoscience Ocean University of China Qingdao P. R. China ） Qingdao Institute of Marine Geology China Geological Survey P. R. China ） College of Georesources Environmental Engineering Sh ong University of Technology Zibo P. R. China 《中国海洋大学学报(英文版)》2009,8(1):57-64
A series of selective dissolution experiments were conducted on the hydrogenic ferromanganese crusts collected near Line Island to study the geochemistry of Mn, Fe, Cu, Co, Ni and Ti. Despite of the fact that the very close intergrowth between amorphous ferric oxyhydroxides and δ-MnO2 exists in the hydrogenic ferromanganese crusts, there is no isomorphous substitution between iron and manganese. This is because the two elements in oxides have different crystal chemistry and geochemistry, such assertion bein... 相似文献
12.
Simultaneous determination of iron and manganese in water using artificial neural network catalytic spectrophotometric method 总被引：1，自引：0，他引：1
A new analytical method using Back-Propagation (BP) artificial neural network and kinetic spectrophotometry for simultaneous determination of iron and magnesium in tap water, the Yellow River water and seawater is established. By conditional experiments, the optimum analytical conditions and parameters are obtained. Levenberg-Marquart (L-M) algorithm is used for calculation in BP neural network. The topological structure of three-layer BP ANN network architecture is chosen as 15-16-2 (nodes). The initial value of gradient coefficient μ is fixed at 0.001 and the increase factor and reduction factor of μ take the default values of the system. The data are processed by computers with our own programs written in MATLAB 7.0. The relative standard deviation of the calculated results for iron and manganese is 2.30% and 2.67% respectively. The results of standard addition method show that for the tap water, the recoveries of iron and manganese are in the ranges of 98.0%-104.3% and 96.5%-104.5%, and the RSD is in the range of 0.23%-0.98%; for the Yellow River water (Lijin district of Shandong Province), the recoveries of iron and manganese are in the ranges of 96.0%-101.0% and 98.7%-104.2%, and the RSD is in the range of 0.13%-2.52%; for the seawater in Qingdao offshore, the recoveries of iron and manganese are in the ranges of 95.3%-104.8% and 95.3%-104.7%, and the RSD is in the range of 0.14%-2.66%. It is found that 21 common cations and anions do not interfere with the determination of iron and manganese under the optimum experimental conditions. This method exhibits good reproducibility and high accuracy in the determination of iron and manganese and can be used for the simultaneous determination of iron and manganese in tap water and natural water. By using the established ANN- catalytic spectrophotometric method, the iron and manganese concentrations of the surface seawater at 11 sites in Qingdao offshore are determined and the level distribution maps of iron and manganese are drawn. 相似文献
13.
A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c 相似文献
14.
为系统开展鄂东北地区锰矿找矿预测, 以四方山地区典型沉积变质型锰矿床为重点解剖对象, 结合高精度磁法测量异常信息, 查明磁异常与锰矿床(体)的空间对应关系。四方山地区锰矿床主要以层状或似层状赋存于新元古代红安岩群黄麦岭岩组(Pt3h )中, 含锰岩系为一套含火山物质、泥质、粉砂质碎屑沉积岩夹碳酸盐岩, 属于陆源碎屑-碳酸盐岩系。含锰岩系因含少量磁铁矿等铁氧化物而多与1∶5万磁法测量中高强度磁异常套合, 但也有部分位于正负磁异常梯度带上。1∶5万磁法总梯度模量中锰矿化富集地段往往与中-低值区(尤其是线性梯度带)对应。基于矿床地质特征、磁法测量资料的二次开发及野外调查成果, 在四方山地区圈定了四个找矿靶区。其中四方山矿区北侧找矿靶区Ⅰ经TC160揭露一层锰矿体, 厚度2.53 m, Mn平均品位为14.63%;四方山矿区内找矿靶区Ⅱ北段经探槽TC140揭露两层锰矿体, 第一层厚1.63 m, Mn平均品位达24.57%;第二层厚0.98 m, Mn品位为16.73%;南段经探槽TC114揭露一层锰矿体, 厚度1.32 m, Mn平均品位为17.60%。团山沟矿区东南部找矿靶区Ⅳ经地质路线调查也发现了锰矿化体, 显示具有良好的找矿前景。 相似文献
15.
Effects of Fe and Mn on the growth of a red tide dinoflagellateScrippsiella trochoidea (Stein) Loeblch III 总被引：1，自引：0，他引：1
Batch culture experiments were conducted with a red tide dinoflagellateScrippsiella trochoidea (Stein) Loeblch III collected from Jiaozhou Bay, Shangdong, China. Growth rates and oellular Chl—a were measured in media
with iron and manganese ion concentrations controlled at different levels using EdTA-trace metal buffer systems. Cell density
increased 3.2 times to 6.5 times over the range of lowest (0 mol/L) to highest (10−5 mol/L) iron and manganese ion concentrations. The range of cell density response was much lower than the range of total available
iron and manganese, which was >100—fold that of Fe. This nonlinear relationship indicates that the cells adapt to make more
efficient use of iron and manganese under limiting conditions. The cellular Chl—a content maximized after 3 days incubation
and then decreased gradually under either iron or manganese limitation conditions. It indicated that the algae gained higher
photosynthesis ability when transferred to a new environment. Growth responses to iron and manganese limitation can be both
modeled according to the equation of Monod. The half—saturation constant for growth,k, is 4.6×10−8 mol/L for Fe and 5.1×10−8 mol/L for Mn. Our results showed that the iron availability in Jiaozhou Bay does not limit the growth ofS. trochoidea.
Contribution No. 2831 from the Institute of Oceanology, Chinese Academy of Sciences.
Project 9389008 supported by NSFC; Study supported by PDB6. 相似文献
16.
Hyper-spectral data is widely used to determine soil properties. However, few studies have explored the soil spectral characteristics as response to soil erosion. This study analysed the spectral response of different eroded soils in subtropical China, and then identify the spectral characteristics and soil properties that better discriminate softs with different erosion degrees. Two methods were compared： direct identification by inherent spectral characteristics and indirect identification by predictions of critical soft properties. Results showed that the spectral curves for different degrees of erosion were similar in morphology, while overall reflectance and characteristics of specific absorption peaks were different. When the first method is applied, some differences among different eroded groups were found by integration of associated indicators. However, the index of such indicators showed apparent mixing and crossover among different groups, which reduced the accuracy of identification. For the second method, the correlation between critical soil properties, such as soil organic matter （SOM）, iron and aluminium oxides and reflectance spectra, was analysed. The correlation coefficients for the moderate eroded group were primarily between -0.3 to -0.5, which were worse than the other twogroups. However, the maximum value of R2 was obtained as 0.86 and 0.94 for the non-apparent eroded and the severe group. Furthermore, these two groups also showed some differences in the spectral response of iron complex state （Fep）, Aluminium amorphous state （Alo） and the modelling results for soil organic matter （SOM）. The study proved that it is feasible to identify different degrees of soil erosion by hyperspectral data, and that indirect identification by modelling critical soil properties and reflectance spectra is much better than direct identification. These results indicate that hyper-spectral data may represent a promising tool in monitoring and modelling soil erosion. 相似文献
17.
广西大新下雷锰矿是在１９５８年大办钢铁时期由当地村干部赵承祥误为铁矿石而发现的，同年１０月经地质人员颜锦生等到现场检查确认为锰矿石。从１９５８年１１月起至１９９０年底止，历经南宁专署地质局９０３队，广西地质局４２４队、广西第二地质队、广西第四地质队断续地进行找矿勘查工作，探明了锰矿石总储量１３３７８万吨，其中放电性锰矿石５５６万吨，氧化锰矿石１２１０万吨，碳酸锰矿石１１６１２万吨，证实为一特大型锰矿床。因此，广西第二地质队于１９８０年被地质部授予功勋队称号，而广西第四地质队于１９８５年荣获全国地矿系统找矿成果一等奖。现在已建成广西大新锰矿，一座新兴的矿山城镇耸立在桂西南山谷中。 相似文献
18.
扬子地块东南缘是我国南华纪“大塘坡式”沉积型锰矿的重要富集区,南华纪大规模锰矿成矿作用与Rodinia超大陆裂解形成的裂谷盆地、Sturtian冰期-间冰期的气候事件具有密切关系。南华纪裂谷盆地呈北东东向展布,可分为地垒、地堑和次级地垒、地堑,锰矿主要形成于裂谷盆地的地堑区的次级地堑中。Sturtian冰期之后,冰后期经历了小冰期和小间冰期的气候波动,锰矿受这种气候波动影响,推测小冰期的富氧的寒冷海水受温度-密度环流影响进入海底,促使原生氧化锰矿的形成,之后准同生交代形成菱锰矿。冰期(或小冰期)海底的天然气水合物在冰后期(小间冰期)的泄漏促使了菱锰矿的形成。因此华南扬子地块东南缘大规模锰矿成矿作用受原型裂谷盆地和冰期-冰后期气候波动的双重影响。 相似文献