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1.
资江是洞庭湖的第二大支流，其中上游锑(Sb)矿采矿冶炼工业发达，给资江下游及洞庭湖区带来了严重的重金属污染风险。以资江河口区为研究区，采集了132个农田土壤样品及7个资江水样，综合采用多种污染评价方法、空间分析、多元统计分析方法对研究区重金属进行了污染评价及来源分析。结果表明，研究区农田土壤重金属平均质量分数表现为Zn>Cr>Ni>Pb>Cu>As>Sb>Cd，旱田土壤重金属平均质量分数除Pb外均高于水田。Sb、As、Cd为主要污染元素，Sb达到了中等污染和中等生态风险的程度，总体处于轻微-中等生态风险程度。资江水体Sb质量浓度较高，平均为10.51 μg/L。Sb主要来源于中上游的锑矿工业，受高锑质量浓度地表水灌溉、垃圾填埋场以及燃煤等人为活动的控制；Cd主要来源于农药化肥、生活垃圾和城镇废水等人为活动；Cr主要来源于成土母质，而Cu、Zn、As、Ni、Pb受成土母质和人为活动的双重控制。   相似文献   

2.
Surface sediments were collected from Lake Manzala, the Mediterranean coastal wetland located to the east of the Nile Delta, Egypt, to assess the effect of drain effluent on the spatial variations of sedimentary characteristics and heavy metal pollution. Grain-size compositions, textures, and heavy metal distribution patterns in sediments are presented using GIS technique. Results of the analysis of the sediment showed a clear effect of drain effluent, with an increase in fine fractions and homogeneous suspensions in transportation mode. Lake sediments were dominated by sandy mud textures, and mode of transportation was homogeneous suspension and rolling. Spatial distribution of heavy metals(Fe, Mn, Zn, Cu, Ni, Cr, and Pb) was studied in the lake's surficial sediments, along with their relationship to drain effluent and their contamination status in the ecological system. Heavy metal pollution status was assessed by means of accepted sediment quality guidelines and contamination assessment methods(contamination factor, contamination degree, modified contamination degree, geo-accumulation, and enrichment factor). Among the determined heavy metals, Pb had the most ecological risk. Generally, the heavy metals in the surface sediments indicated pollution risk ranging from moderate to considerable, particularly, in those sites facing drains and inlets that had the highest toxic effluent. The results were interpreted by statistical means. A cluster analysis defined areas facing drain discharge and inlets as separated groups. ANOVA indicated that most of the sedimentation and studied metals directed this clustering.  相似文献   

3.
There is an increasing concern for potentially hazardous metals pollution, which can threaten crops production and human health. In this study, the spatial distribution and environmental risks of eight heavy metals in surface soil samples collected from the paddy fields in Yongshuyu irrigation area, Northeast China were investigated. The mean concentrations of Pb, Cr, Cu, Ni, Zn, Cd, Hg and As were 34.6 ± 4.67, 82.8 ± 9.51, 17.3 ± 4.09, 21.2 ± 12.0, 88.6 ± 17.9, 0.18 ± 0.15, 0.22 ± 0.07 and 8.77 ± 2.47 mg/kg, respectively, which were slightly higher than their corresponding background values of Jilin Province, indicating enrichment of these metals in the paddy soils, especially for Ni, Cd and Hg. The spatial distribution of heavy metals was closely correlated with local anthropogenic activities, such as agricultural production, mining and transportation. The hot-spot areas of As and Cd were mainly concentrated in the up-midstream where were associated with agricultural activities. Cr and Cu showed similar spatial distributions with hot-spot areas distributed the whole irrigation area uniformly. Ni was mainly distributed in the downstream where Ni quarries concentrated, while the spatial distribution patterns of Hg was mainly located in the upstream and downstream where the soil was significantly influenced by irrigation and coal mining emission. The spatial distributions of Pb and Zn were mainly concentrated along the highway side. The pollution levels of Yongshuyu irrigation area were estimated through index of geo-accumulation(Igeo), Nemerow integrated pollution index(NIPI) and potential ecological risk index(PERI). The results showed that Cd and Hg were the main pollutants in the study area. Health risk assessment results indicated that children were in higher non-carcinogenic and carcinogenic risks than adults with the carcinogenic metal of As. Ingestion was the main exposure pathway to non-carcinogenic and carcinogenic risk for both adults and children. Principal component analysis(PCA) indicated that Cr and Cu were mainly from parent materials, while Cd and As were mainly affected by agricultural activities. Pb and Zn were controlled by traffic activities, and the accumulations of Ni and Hg were associated with mining activities. This study would be valuable for preventing heavy metals inputs and safety in rice production of the Songhua river basin.  相似文献   

4.
Episodic deposition has been recognized as a major factor affecting the decomposition rate of detrital material in salt marshes. In this paper, three one-off burial treatments, no burial treatment(0 cm, NBT), current burial treatment(10 cm, CBT) and strong burial treatment(20 cm, SBT), were designed in intertidal zone of the Yellow River Estuary to determine the potential influences of episodic deposition on nutrient(C, N) and heavy metal(Pb, Cr, Cu, Zn, Ni, Mn, Cd, V and Co) variations in decomposing litters of Suaeda glauca. Results showed that although various burial treatments showed no statistical difference in decomposition rate of S. glauca, the values generally followed the sequence of CBT(0.002 403/d) SBT(0.002 195/d) NBT(0.002 060/d). The nutrients and heavy metals in decomposing litters of the three burial treatments exhibited different variations except for N, Cu, Cr, Ni and Co. Except for Mn, no significant differences in C, N, Pb, Cr, Cu, Zn, Ni, V and Co concentrations occurred among the three treatments(P 0.05). With increasing burial depth, Cr and Cd levels generally increased while Cu, Ni and Mn concentrations decreased. Although episodic deposition was generally favorable for C and N release from S. glauca, its influence on release was insignificant. In the three burial treatments, Pb, Cr, Zn, Ni, Mn, V and Co stocks in S. glauca generally evidenced the export of metals from litter to environment, and, with increasing burial depth, the export amounts increased greatly. The S. glauca were particular efficient in binding Cd and releasing Pb, Cr, Zn, Ni, Mn, V and Co, and, with increasing burial depth, stocks of Cu in decomposing litters generally shifted from release to accumulation. The experiment indicated that the potential eco-toxic risk of Pb, Cr, Zn, Ni, Mn, V and Co exposure would be serious as the strong burial episodes occurred in S. glauca marsh.  相似文献   

5.
根据2011年7月浙江舟山西蟹峙海洋倾倒区及邻近海域表层沉积物重金属的监测结果,采用单因子指数法和Hakanson生态危害指数法分析表层沉积物重金属的污染特征,并评价其潜在生态风险。结果表明:沉积物重金属元素Cu、Zn、Pb、Cd、Cr、Hg、As含量均符合国家海洋沉积物质量一类标准;重金属元素污染程度由高到低依次为Zn、Cr、Pb、Cu、As、Cd、Hg,其中Cu、Pb、Cd、Hg和As 5种重金属元素为低污染水平,Zn和Cr 2种重金属元素为中等污染程度水平;7种重金属元素单个和综合潜在生态危害程度均为低风险水平,由高到低依次为Cd、Hg、As、Pb、Cu、Cr、Zn。  相似文献   

6.
1IN T R O D U C T IO N With therapiddevelopment of urbanizatio,nurban land was exploitedand utilizetdoform differendtomains be- ing subjectto many potentialpollutionsourcessuch as vehicleemission, industrialactivitieasnd household garbage.Particularl, yur…  相似文献   

7.
人类活动对水环境影响巨大,同时水环境影响着人类的生产生活。采用地质累积指数法及潜在生态危害指数法对武汉市东西湖区主要湖泊表层沉积物重金属情况展开评价发现东西湖主要湖泊表层沉积物平均污染程度处于相对较低水平。地累积指数法评价结果表明,东大湖和金湖中Cd元素处于中度污染水平累积,墨水湖和上金湖中Cd元素为偏中度污染累积水平,其他湖泊沉积物中重金属均处于轻度或无污染水平。潜在生态危害指数法评价结果表明金湖和东大湖沉积物中重金属的潜在风险处于重度生态风险水平,墨水湖、上金湖、下银湖处于中度风险水平,其余湖泊沉积物中重金属的潜在风险均处于低风险水平。主成分分析表明,Hg、Cr、Ni、Cu、Zn、Cd、Pb可能来自于工业和交通源的排放,而As可能与农药的使用有关。后期金湖、东大湖、墨水湖、上金湖和下银湖的内源污染治理过程中需考虑重金属的生态风险问题。   相似文献   

8.
海岸带处于陆地和海洋的接合部,人类开发活动密集,环境影响因素日趋复杂。选取烟台南部海岸带为研究对象,系统采集686个表层土壤样品对As,Cd,Cr,Cu,Hg,Ni,Pb,Zn共8个重金属元素含量进行测量,采用多元统计法及地统计法分析了8个重金属元素的来源及分布特征。最后对烟台南部海岸带地区进行了潜在生态风险评价。研究结果表明烟台南部海岸带地区整体污染程度较轻,所有重金属元素含量平均值均未超过国家二级标准。其中Cr,Ni,Cu元素主要来源于成土母质;As,Pb为混合源;Cd,Zn主要来自于工业三废、农业生产。研究区整体处于中低生态风险水平,Cd,Hg元素高生态风险点数量较多,需优先治理。  相似文献   

9.
烟台近岸海域表层沉积物重金属污染特征   总被引：1，自引：0，他引：1       下载免费PDF全文
采取烟台近岸海域150个海底表层沉积物样品进行Hg,Cu,Pb,Zn,Cd,Cr,As,Ni元素分析。结果显示,烟台市近岸海域重金属主要富集在芝罘湾(Cd,Cu)、龙口(As,Cr,Cu)及海阳东部(Ni,Pb)一带,而莱州、招远及牟平近岸海域重金属含量较低。单因子、内梅罗和潜在生态危害指数评价结果显示,研究区88%海域的沉积物达到一类标准,轻污染区主要分布在芝罘岛北部及龙口市西部,龙口、招远及烟台市近岸沉积物潜在风险中等。  相似文献   

10.
To determine the pollution levels and potential toxic risks of arsenic(As) and heavy metals(Cr, Ni, Cu, Zn, Pb and Cd) in water and suspended particulate matter(SPM) in tail reaches(including freshwater reach and low-salinity reach) of the Yellow River as the Flow-Sediment Regulation Project(FSRP) has been carried out for approximately 15 yr, the surface water and SPM were sampled at pre-flood(April) and post-flood seasons(October). Results showed that similar changes of As and metal levels in water and SPM were observed along the tail reaches at pre-flood or post-flood season. Compared to pre-flood season, the levels of As, Cu, Cr and Ni in freshwater reach and the concentrations of Cr and Ni in low-salinity reach rose greatly at post-flood season. The levels of As and metals in SPM of freshwater reach or low-salinity reach at pre-flood season were significantly higher than those at post-flood season(P < 0.01).The pollutions of As and metals in surface water of tail reaches at pre-flood or post-flood season were not serious. The SPM in freshwater reach at pre-flood season were polluted by Cd, As, Cr, Cu and Ni while those in low-salinity reach were polluted by Cd and Cr. The SPM in freshwater reach at post-flood season were polluted by Cd and Pb while those in low-salinity reach were polluted by Cd and Cr.Cd was identified as heavy metal of primary concern at both pre-flood and post-flood seasons. Combined with the existed data reported in present research, this study found that the toxic risk of As and metals in SPM of tail reaches at pre-flood season was higher than that at post-flood season, implying that the implementation of FSRP during flooding season, to a great extent, reduced the toxic risk of these elements. With the long-term implementation of FSRP, the pollution levels of As and metals(particularly for Cd) in SPM of tail reaches might be elevated and the potential toxic risk primarily produced by Cr, Ni and As might be increased if effective measures were not taken in future.  相似文献   

11.
According to ＂Environmental quality standard for soil＂ and using As, Cd, Cr, Cu, Hg, Ni, Pb, Zn elements as evaluation index, the author evaluated soil environmental quality in Xihe area of Shenyang. The results show that the soil in Xihe area is polluted rifely by heavy metal elements. The polluted areas are mainly distributed near the upstreams of Xihe River, Shenxin River and Shenliao irrigation canal. There exist large distinctions among the heavy metal elements to the pollution degree. Cd pollution area is the biggest and the most serious in pollution degree.  相似文献   

12.
Twenty-nine samples of surface sediments from tidal flats in the Northern Shandong Province were collected for grain size, heavy metal(Hg, Cu, Pb, Zn, Cd, and Cr), and oil pollution analyses. The geoaccumulation index(Igeo) and factor analysis were introduced to evaluate sediment quality and source of contaminants. The mean concentrations of Hg, Cu, Pb, Zn, Cd, Cr, and oil in the surface sediments in the study area are 0.033, 17.756, 19.121, 55.700, 0.291, 59.563, and 14.213 μg g-1, respectively. The heavy metal contamination in the old delta lobe is slightly higher than that in the abandoned delta lobe; however, the opposite was observed for oil pollution. The Igeo results revealed that the overall quality of the surface sediments in the study area is in good condition. The heavy metal pollution levels show a descending order: Cd Hg Cr Cu Zn Pb, Cd being the main pollutant. The contamination level for in the study area is relatively lower than those for China's other tidal flats. Heavy metals are mainly derived from natural sources of rock weathering and erosion, partly influenced by industrial and agricultural discharge. However, oil pollution is mainly from runoff input, motorized fishing boat sewage, and oil exploitation.  相似文献   

13.
According to "Environmental quality standard for soil" and using As, Cd, Cr, Cu, Hg, Ni, Pb, Zn elements as evaluation index, the author evaluated soil environmental quality in Xihe area of Shenyang. The results show that the soil in Xihe area is polluted rifely by heavy metal elements. The polluted areas are mainly distributed near the upstreams of Xihe River, Shenxin River and Shenliao irrigation canal. There exist large distinctions among the heavy metal elements to the pollution degree. Cd pollution area is the biggest and the most serious in pollution degree.  相似文献   

14.
The concentrations of Zn, Cd, Pb, Cu ions are shown to be similar in natural waters of Tianshan Mountains and Qinghai-Tibet plateau and to be similar in those of the sea water. The average and variability of concentraions of trace metal ions in fresh water are Zn 5.7±1.5, Cd 0.092±0.038, Pb 0.048±0.011, and Cu 1.1±0.20 ppb. The average concentrations in the East China Sea are Zn 7.3 (5.5 in 1976), Cd 0.12, Pb 0.036, and Cu 0.94 ppb. It proves that the homogeneous distribution of trace metal ions (free ion and unstable complexes) in natural waters is present in the nature as a rule. Contribution No. 985 from the Institute of Oceanology, Academia Sinica.  相似文献   

15.
The Nanfei River(Anhui Province,China) is a severely polluted urban river that flows into Chaohu Lake.In the present study,sediments were collected from the river and analyzed for their heavy metal contents.Multivariate statistics and the fuzzy comprehensive assessment method were used to determine the sources of pollution,the current pollution status,and spatial and temporal variations in heavy metal pollution in sediments.The concentrations of arsenic(As),cadmium(Cd),chromium(Cr),copper(Cu),mercury(Hg),nickel(Ni),lead(Pb),and zinc(Zn) in sediments ranged from 5.67–113,0.08–40.2,41.6–524,15.5–460,0.03–4.84,13.5–180,18.8–250,and 47.9–1 996 mg/kg,and the average concentrations of each metal were 1.7,38.7,1.8,5.5,18.8,1.3,2.5,and 11.1 times greater than the background values,respectively.Multivariate statistical analysis demonstrated that Hg,Cu,Cr,Cd,and Ni may have originated from industrial activities,whereas As and Pb came from agricultural activities.The fuzzy comprehensive assessment method,based on the fuzzy mathematics theory,was used to obtain a detailed assessment of the sediment quality in the Nanfei River watershed.The results indicated that the pollution was moderate in the downstream tributaries of the Nianbu and Dianbu Rivers,but was severe in the main channel of the Nanfei River and in the upstream tributaries of the Sili and Banqiao Rivers.Therefore,sediments in the Nanfei River watershed are heavily polluted and urgent measures should be taken to remedy the status.  相似文献   

16.
Core sediments from the Muthupettai mangroves on the southeast coast of India were analyzed for soil texture,total nitrogen,organic carbon,phosphorus and heavy metals(Fe,Mn,Cr,Cu,Ni,Pb,Zn and Cd).The distinct seasonal variation in the distribution of metals in the sediments was observed.The minimum concentration was recorded in river mouth and the maximum was in lagoon.High metal concentration in sediment was observed during monsoon and low concentration in summer.The total nu-trient in lagoon and river mouth was recorded in the range of 4.528 to 8.526 mg g-1 for organic carbon,2.213 to 10.5 mg g-1 for nitro-gen and 0.824 to 7.22 mg g-1.  相似文献   

17.
A total of 30 surface sediments samples from the estuary wetland of the Tangxi River, Chaohu Lake Basin were obtained and tested. Enrichment factor (EF) and geoaccumulation index (I_(geo)) as well as multivariate statistical analysis methods including Factor Analysis (FA) and Hierarchical Cluster Analysis (HCA) were applied for the assessment of heavy metal pollution in surface sediments. The results of EF values show that the pollution of copper (Cu) and cadmium (Cd) occurs in the estuarine sediments, and that zinc (Zn), lead (Pb) and chrome (Cr) may originate from crustal materials or natural weathering process. The mean EF values of the five heavy metals are in the decreasing order: Cu>Cd>Zn>Pb>Cr. Based on the I_(geo) of target heavy metals, the surface sediments collected from the study area can be approximately categorized as unpolluted with Zn, Pb and Cr, and moderately polluted with Cu and Cd. The degree of heavy metal pollution decreases in the order of Cu>Cd>Zn>Pb>Cr. Three groups of pollution factors are presented from FA: Zn-TOC, Cu-Cd and Cr-Pb, which respectively accounte for 27.22%, 25.20% and 21.05% of variance. By means of HCA, a total number of seven groups are distinguished from 30 sampling sites. Results indicate that Cu and Cd are the prior controlled pollutants in the estuarine sediments of the Tangxi River.  相似文献   

18.
Metal pollution has become an major issue governing the wetland ecosystem health.The southern coastal wetland of the Qiangtang Estuary are facing unusual perturbation due to rapid development along the embayment in recent decades.This study evaluated the bioavailability of metals(Cu,Pb,Cd,Cr and Zn)in the sediment of the southern coastal wetland of the Qiangtang Es-tuary using diffusive gradients in thin films(DGT)techniques and compared with several methods based on total metal content.The results showed that the contents of Cr,Pb,Cd and Cu in sediment,as detected using DGT,were considerably correlated with the exchangeable fraction and the content in Phragmites australis roots,while a weak correlation was observed for Zn.Therefore,DGT analysis could be used to evaluate the bioavailability and potential risk of Cr,Cd,Pb and Cu for P.australis.Quantitative indices,such as DGT concentration,bioaccumulation in P.australis,geoaccumulation index(Igeo)and potential ecological risk index(RI),revealed that Cd was a major potential ecological risk factor along the southern coast wetland of the Qiantang Estuary,especially in the upstream region,which is potentially more vulnerable to the anthropogenic pollution.  相似文献   

19.
The bioavailability of five divalent cationic heavy metals(Pb,Cd,Cu,Zn and Ni) in 10 superficial sediment samples from Baihua Lake was assessed based on the molar ratio of simultaneously extracted metals(SEMs) to acid volatile sulfide(AVS).Atomic absorption spectrometry(AAS) and X-ray powder diffraction(XRD) were used to determine the heavy metal concentrations and examine the mineralogy of the crystalline phases,respectively.The AVS loadings in sediments from Baihua Lake ranged from 64.30 to 350.08 μmol/g(dry weight).The corresponding SEM levels for the sampling sites varied from 1.770 to 14.660 μmol/g.The molar ratio of SEMs to AVS ranged from 0.014 to 0.084 with a mean value of 0.034.The XRD analysis also confirmed the presence of some metal sulfides in sediments from Baihua Lake.The SEMs/AVS ratios for all sampling sites were significantly lower than 1.0,indicating that AVS in the sediments was sufficient to bind the five heavy metals;thus,these heavy metals are currently not significantly bioavailable to benthic organisms.Comparing the SEMs results to published guideline values for metal toxicity to benthic organisms in sediments,however,suggests that Zn and Ni pose a risk at some sampling locations in Baihua Lake.  相似文献   

20.
In the current study, we determined concentrations and transfer rates of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, P, Rb, Sr and Zn to Brown Birch Scaber Stalks (Leccinum scabrum) mushrooms emerged in the area of Sudety Mountains (Sudetes) in Poland. Fruiting bodies and topsoil samples beneath L. scabrum were collected form the K odzka Dale. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES) for final measurement. Mushrooms contained Ag, Cr, Hg, Co, Ni and Sr at < 1.0 μg/g dry weight; Ba and Pb at ~1.0 μg/g dw; Cd at < 5 μg/g dw; Cu and Mn at > 10 μg/g dw; Al and Ca at ~100 μg/g dw; Fe, Na, Rb and Zn at 100 to 500 μg/g dw, Mg at ~1,000 μg/g dw; P at ~5,000 μg/g dw and K at ~30,000 μg/g dw. Ca, Mn and Ni were nearly equally distributed between stipes and caps; stipes compared to caps were enriched in Ba, Na and Sr, while caps were enriched in Ag, Al, Cd, Co, Cr, Cu, Fe, K, P, Pb, Rb and Zn. The values of bioconcentration factor (BCF) varied highly depending on chemical element and were >1 for Ag, Cd, Cu, K, Mg, Na, P, Rb and Zn, while <1 for Al, Ba, Ca, Co, Cr, Fe, Mn, Ni, Pb and Sr. Topsoil showed elevated content of lead and mean concentration was 99 ± 32 μg/g dw, while cadmium was at 0.41 ± 0.15 and those two highly toxic to human elements occurred in edible caps of L. scabrum at 4.5 ± 2.2 and 2.9 ± 2.0 μg/g dw, respectively.  相似文献   

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