首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 140 毫秒
1.
We performed chemical, mineralogical, and isotopic studies of the first interplanetary dust particles (IDPs) collected in the stratosphere without the use of silicone oil. The collection substrate, polyurethane foam, effectively traps impacting particles, but the lack of an embedding medium results in significant particle fragmentation. Two dust particles found on the collector exhibit the typical compositional and mineralogical properties of chondritic porous interplanetary dust particles (CP‐IDPs). Hydrogen and nitrogen isotopic imaging revealed isotopic anomalies of typical magnitude and spatial variability observed in previous CP‐IDP studies. Oxygen isotopic imaging shows that individual mineral grains and glass with embedded metal and sulfide (GEMS) grains are dominated by solar system materials. No systematic differences are observed in element abundance patterns of GEMS grains from the dry collection versus silicone oil‐collected IDPs. This initial study establishes the validity of a new IDP collection substrate that avoids the use of silicone oil as a collection medium, removing the need for this problematic contaminant and the organic solvents necessary to remove it. Additional silicone oil‐free collections of this type are needed to determine more accurate bulk element abundances of IDPs and to examine the indigenous soluble organic components of IDPs.  相似文献   

2.
Abstract– Oxygen three‐isotope ratios of three anhydrous chondritic interplanetary dust particles (IDPs) were analyzed using an ion microprobe with a 2 μm small beam. The three anhydrous IDPs show Δ17O values ranging from ?5‰ to +1‰, which overlap with those of ferromagnesian silicate particles from comet Wild 2 and anhydrous porous IDPs. For the first time, internal oxygen isotope heterogeneity was resolved in two IDPs at the level of a few per mil in Δ17O values. Anhydrous IDPs are loose aggregates of fine‐grained silicates (≤3 μm in this study), with only a few coarse‐grained silicates (2–20 μm in this study). On the other hand, Wild 2 particles analyzed so far show relatively coarse‐grained (≥ few μm) igneous textures. If anhydrous IDPs represent fine‐grained particles from comets, the similar Δ17O values between anhydrous IDPs and Wild 2 particles may imply that oxygen isotope ratios in cometary crystalline silicates are similar, independent of crystal sizes and their textures. The range of Δ17O values of the three anhydrous IDPs overlaps also with that of chondrules in carbonaceous chondrites, suggesting a genetic link between cometary dust particles (Wild 2 particles and most anhydrous IDPs) and carbonaceous chondrite chondrules.  相似文献   

3.
Abstract— Terminal particles and mineral fragments from comet 81P/Wild 2 were studied in 16 aerogel tracks by transmission and secondary electron microscopy. In eight tracks clinopyroxenes with correlated Na2O and Cr2O3 contents as high as 6.0 wt% and 13.0 wt%, respectively, were found. Kosmochloric (Ko) clinopyroxenes were also observed in 4 chondritic interplanetary dust particles (IDPs). The Ko‐clinopyroxenes were often associated with FeO‐rich olivine ± Cr‐rich spinel ± aluminosilicate glass or albitic feldspar, assemblages referred to as Kool grains (Ko = kosmochloric Ca‐rich pyroxene, ol = olivine). Fine‐grained (submicron) Kool fragments have textures suggestive of crystallization from melts while coarse‐grained (>1 μm) Kool fragments are often glass‐free and may have formed by thermal metamorphism in the nebula. Average major and minor element distributions between clinopyroxenes and coexisting FeO‐rich olivines are consistent with these phases forming at or near equilibrium. In glass‐bearing fine‐grained Kool fragments, high concentrations of Na in the clinopyroxenes are inconsistent with existing experimentally determined partition coefficients at equilibrium. We speculate that the availability of Cr in the melt increased the clinopyroxene Na partition coefficient via a coupled substitution thereby enhancing this phase with the kosmochlor component. The high temperature minerals, fine‐grain sizes, bulk compositions and common occurrence in the SD tracks and IDPs support the idea that Kool grains could have been precursors to type II chondrules in ordinary chondrites. These grains, however, have not been observed in these meteorites suggesting that they were destroyed during chondrule formation and recycling or were not present in the nebula at the time and location where meteoritic chondrules formed.  相似文献   

4.
Abstract Reflectance spectra were collected from chondritic interplanetary dust particles (IDPs), a polar micrometeorite, Allende (CV3) meteorite matrix, and mineral standards using a microscope spectrophotometer. Data were acquired over the 380–1100 nm wavelength range in darkfield mode using a halogen light source, particle aperturing diaphrams, and photomultiplier tube (PMT) detectors. Spectra collected from titanium oxide (Ti4O7), magnetite (Fe3O4), and Allende matrix establish that it is possible to measure indigenous reflectivities of micrometer-sized (>5 μm in diameter) particles over the visible (VIS) wavelength range 450–800 nm. Below 450 nm, small particle effects cause a fall-off in signal into the ultraviolet (UV). Near-infrared (IR) spectra collected from olivine and pyroxene standards suggest that the ～1 μm absorption features of Fe-bearing silicates in IDPs can be detected using microscope spectrophotometry. Chondritic IDPs are dark objects (<15% reflectivity) over the VIS 450–800 nm range. Large (>1 μm in diameter) embedded and adhering single mineral grains make IDPs significantly brighter, while surficial magnetite formed by frictional heating during atmospheric entry makes them darker. Most chondritic smooth (CS) IDPs, dominated by hydrated layer silicates, exhibit generally flat spectra with slight fall-off towards 800 nm, which is similar to type CI and CM meteorites and main-belt C-type asteroids. Most chondritic porous (CP) IDPs, dominated by anhydrous silicates (pyroxene and olivine), exhibit generally flat spectra with a slight rise towards 800 nm, which is similar to outer P and D asteroids. The most C-rich CP IDPs rise steeply towards 800 nm with a redness comparable to that of the outer asteroid object Pholus (Binzel, 1992). Chondritic porous IDPs are the first identified class of meteoritic materials exhibiting spectral reflectivities (between 450 and 800 nm) similar to those of P and D asteroids. Although large mineral grains, secondary magnetite, and small particle effects complicate interpretation of IDP reflectance spectra, microscope spectrophotometry appears to offer a rapid, nondestructive technique for probing the mineralogy of IDPs, comparing them with meteorites, investigating their parent body origins, and identifying IDPs that may have been strongly heated during atmospheric entry.  相似文献   

5.
Abstract– Interplanetary dust particles (IDPs) are the most primitive extraterrestrial material available for laboratory studies and may, being likely of cometary origin, sample or represent the unaltered starting material of the solar system. Here we compare IDPs from a “targeted” collection, acquired when the Earth passed through the dust stream of comet 26P/Grigg‐Skjellerup (GSC), with IDPs from nontargeted collections (i.e., of nonspecific origin). We examine both sets to further our understanding of abundances and character of their isotopically anomalous phases to constrain the nature of their parent bodies. We identified ten presolar silicates, two oxides, one SiC, and three isotopically anomalous C‐rich grains. One of seven non‐GSC IDPs contains a wealth of unaltered nebula material, including two presolar silicates, one oxide, and one SiC, as well as numerous δD and δ15N hotspots, demonstrating its very pristine character and suggesting a cometary origin. One of these presolar silicates is the most 17O‐rich discovered in an IDP and has been identified as a possible GEMS (glass with embedded metal and sulfides). Organic matter in an anhydrous GSC IDP is extremely disordered and, based on Raman spectral analyses, appears to be the most primitive IDP analyzed in this study, albeit only one presolar silicate was identified. No defining difference was seen between the GSC and non‐GSC IDPs studied here. However, the GSC collectors are expected to contain IDPs of nonspecific origin. One measure alone, such as presolar grain abundances, isotopic anomalies, or Raman spectroscopy cannot distinguish targeted cometary from unspecified IDPs, and therefore combined studies are required. Whilst targeted IDP populations as a whole may not show distinguishable parameters from unspecified populations (due to statistics, heterogeneity, sampling bias, mixing from other cometary sources), particular IDPs in a targeted collection may well indicate special properties and a fresh origin from a known source.  相似文献   

6.
Abstract– An IDP nicknamed Andric, from a stratospheric dust collector targeted to collect dust from comet 55P/Tempel‐Tuttle, contains five distinct presolar silicate and/or oxide grains in 14 ultramicrotome slices analyzed, for an estimated abundance of approximately 700 ppm in this IDP. Three of the grains are 17O‐enriched and probably formed in low‐mass red giant or asymptotic giant branch (AGB) stars; the other two grains exhibit 18O enrichments and may have a supernova origin. Carbon and N isotopic analyses show that Andric also exhibits significant variations in its N isotopic composition, with numerous discrete 15N‐rich hotspots and more diffuse regions that are also isotopically anomalous. Three 15N‐rich hotspots also have statistically significant 13C enrichments. Auger elemental analysis shows that these isotopically anomalous areas consist largely of carbonaceous matter and that the anomalies may be hosted by a variety of components. In addition, there is evidence for dilution of the isotopically heavy components with an isotopically normal endmember; this may have occurred either as a result of extraterrestrial alteration or during atmospheric entry. Isotopically primitive IDPs such as Andric share many characteristics with primitive meteorites such as the CR chondrites, which also contain isotopically anomalous carbonaceous matter and abundant presolar silicate and oxide grains. Although comets are one likely source for the origin of primitive IDPs, the presence of similar characteristics in meteorites thought to come from the asteroid belt suggests that other origins are also possible. Indeed the distinction between cometary and asteroidal sources is somewhat blurred by recent observations of icy comet‐like planetesimals in the outer asteroid belt.  相似文献   

7.
We built a collector to filter interplanetary dust particles (IDPs) larger than 5 μm from the clean air at the Amundsen Scott South Pole station. Our sampling strategy used long duration, continuous dry filtering of near‐surface air in place of short duration, high‐speed impact collection on flags flown in the stratosphere. We filtered ~107 m3 of clean Antarctic air through 20 cm diameter, 3 µm filters coupled to a suction blower of modest power consumption (5–6 kW). Our collector ran continuously for 2 years and yielded 41 filters for analyses. Based on stratospheric concentrations, we predicted that each month’s collection would provide 300–900 IDPs for analysis. We identified 19 extraterrestrial (ET) particles on the 66 cm2 of filter examined, which represented ~0.5% of the exposed filter surfaces. The 11 ET particles larger than 5 µm yield about a fifth of the expected flux based on >5 µm stratospheric ET particle flux. Of the 19 ET particles identified, four were chondritic porous IDPs, seven were FeNiS beads, two were FeNi grains, and six were chondritic material with FeNiS components. Most were <10 µm in diameter and none were cluster particles. Additionally, a carbon‐rich candidate particle was found to have a small 15N isotopic enrichment, supporting an ET origin. Many other candidate grains, including chondritic glasses and C‐rich particles with Mg and Si and FeS grains, require further analysis to determine if they are ET. The vast majority of exposed filter surfaces remain to be examined.  相似文献   

8.
We present results of FIB–TEM studies of 12 Stardust analog Al foil craters which were created by firing refractory Si and Ti carbide and nitride grains into Al foils at 6.05 km s?1 with a light‐gas gun to simulate capture of cometary grains by the Stardust mission. These foils were prepared primarily to understand the low presolar grain abundances (both SiC and silicates) measured by SIMS in Stardust Al foil samples. Our results demonstrate the intact survival of submicron SiC, TiC, TiN, and less‐refractory Si3N4 grains. In small (<2 μm) craters that are formed by single grain impacts, the entire impacting crystalline grain is often preserved intact with minimal modification. While they also survive in crystalline form, grains at the bottom of larger craters (>5 μm) are typically fragmented and are somewhat flattened in the direction of impact due to partial melting and/or plastic deformation. The low presolar grain abundance estimates derived from SIMS measurements of large craters (mostly >50 μm) likely result from greater modification of these impactors (i.e., melting and isotopic dilution), due to higher peak temperatures/pressures in these crater impacts. The better survivability of grains in smaller craters suggests that more accurate presolar grain estimates may be achievable through measurement of such craters. It also suggests small craters can provide a complementary method of study of the Wild 2 fine fraction, especially for refractory CAI‐like minerals.  相似文献   

9.
The chondritic‐porous subset of interplanetary dust particles (CP‐IDPs) are thought to have a cometary origin. Since the CP‐IDPs are anhydrous and unaltered by aqueous processes that are common to chondritic organic matter (OM), they represent the most pristine material of the solar system. However, the study of IDP OM might be hindered by their further alteration by flash heating during atmospheric entry, and we have limited understanding on how short‐term heating influences their organic content. In order to investigate this problem, five CP‐IDPs were studied for their OM contents, distributions, and isotopic compositions at the submicro‐ to nanoscale levels. The OM contained in the IDPs in this study spans the spectrum from primitive OM to that which has been significantly processed by heat. Similarities in the Raman D bands of the meteoritic and IDP OMs indicate that the overall gain in the sizes of crystalline domains in response to heating is similar. However, the Raman ΓG values of the OM in all of the five IDPs clearly deviate from those of chondritic OM that had been processed during a prolonged episode of parent body heating. Such disparity suggests that the nonaromatic contents of the OM are different. Short duration heating further increases the H/C ratio and reduces the δ13C and δD values of the IDP OM. Our findings suggest that IDP OM contains a significant proportion of disordered C with low H content, such as sp2 olefinic C=C, sp3 C–C, and/or carbonyl contents as bridging material.  相似文献   

10.
Abstract– To constrain the effects of capture modification processes, the size distribution of nanoscale refractory Fe‐Ni‐S inclusions (“droplets”) was measured in five allocations extracted from throughout the depth of Stardust Track 35. The Fe/S ratio has been previously shown to increase significantly with penetration depth in this track, suggesting increasing capture‐related modification along the track. Astronomical image analysis tools were employed to measure the sizes of more than 8000 droplets from TEM images, and completeness simulations were used to correct the distribution for detection bias as a function of radius. The size distribution characteristics are found to be similar within independent regions of individual allocations, demonstrating uniformity within grains. The size distribution of the Fe‐Ni‐S droplets in each allocation is dominated by a mode near 11 nm, but is coarse‐skewed and leptokurtic with a mean of ～17 nm and a standard deviation of ～9 nm. The size distribution characteristics do not vary systematically with penetration depth, despite the strong trend in bulk Fe/S ratio. This suggests that the capture modification process is not primarily responsible for producing the morphology of these nanoscale droplets. The Stardust Track 35 droplet size distribution indicates slightly smaller sizes, but otherwise resembles those in carbonaceous chondrite Acfer 094, and chondritic porous interplanetary dust particles that escaped nebular annealing of sulfides. The size distribution of metal‐sulfide beads in Stardust’s quenched melted‐grain emulsions appears to be inherited from the size distribution of unmelted sulfide mineral grains in comet‐dust particles of chondritic character.  相似文献   

11.
Relationships between organic molecules and inorganic minerals are investigated in a single 34 μm diameter grain of the CR2 chondrite Northwest Africa 852 (NWA) 852 with submicron spatial resolution using synchrotron‐based imaging micro‐FTIR spectroscopy. Correlations based on absorption strength for the various constituents are determined using statistical correlation analysis. The silicate band is found to be correlated with the hydration band, and the latter is highly correlated with stretching modes of aliphatic hydrocarbons. Spatial distribution maps show that water+organic combination, silicate, OH, and C‐H distributions overlap, suggesting a possible catalytic role of phyllosilicates in the formation of organics. In contrast, the carbonate band is anticorrelated with water+organic combination, however uncorrelated with any other spectral feature. The average ratio of asymmetric CH2 and CH3 band strengths (CH2/CH3 = 2.53) for NWA 852 is similar to the average ratio of interplanetary dust particles (~2.40) and Wild 2 cometary dust particles (2.50), but it significantly exceeds that of interstellar medium objects (~1.00) and several aqueously altered carbonaceous chondrites (~1.40). This suggests organics of similar length/branching, and perhaps similar formation regions, for NWA 852, Wild 2 dust particles, and interplanetary dust particles. The heterogeneous spatial distribution of ratio values indicates the presence of a mixture of aliphatic organic material with different length/branching, and thus a wide range of parent body processes, which occurred before the considered grain was formed.  相似文献   

12.
Comets and the chondritic porous interplanetary dust particles (CP IDPs) that they shed in their comae are reservoirs of primitive solar nebula materials. The high porosity and fragility of cometary grains and CP IDPs, and anomalously high deuterium contents of highly fragile, pyroxene-rich Cluster IDPs imply these aggregate particles contain significant abundances of grains from the interstellar medium (ISM). IR spectra of comets (3–40 μm) reveal the presence of a warm (near-IR) featureless emission modeled by amorphous carbon grains. Broad andnarrow resonances near 10 and 20 microns are modeled by warm chondritic (50% Feand 50% Mg) amorphous silicates and cooler Mg-rich crystalline silicate minerals, respectively. Cometary amorphous silicates resonances are well matched by IRspectra of CP IDPs dominated by GEMS (0.1 μm silicate spherules) that are thought to be the interstellar Fe-bearing amorphous silicates produced in AGB stars. Acid-etched ultramicrotomed CP IDP samples, however, show that both the carbon phase (amorphous and aliphatic) and the Mg-rich amorphous silicate phase in GEMS are not optically absorbing. Rather, it is Fe and FeS nanoparticles embedded in the GEMS that makes the CP IDPs dark. Therefore, CP IDPs suggest significant processing has occurred in the ISM. ISM processing probably includes in He+ ion bombardment in supernovae shocks. Laboratory experiments show He+ ion bombardment amorphizes crystalline silicates, increases porosity, and reduces Fe into nanoparticles. Cometary crystalline silicate resonances are well matched by IR spectra of laboratory submicron Mg-rich olivine crystals and pyroxene crystals. Discovery of a Mg-pure olivine crystal in a Cluster IDP with isotopically anomalous oxygen indicates that a small fraction of crystalline silicates may have survived their journey from AGB stars through the ISM to the early solar nebula. The ISM does not have enough crystalline silicates (<5%), however, to account for the deduced abundance of crystalline silicates in comet dust. An insufficient source of ISMMg-rich crystals leads to the inference that most Mg-rich crystals in comets are primitive grains processed in the early solar nebula prior to their incorporation into comets. Mg-rich crystals may condense in the hot (～1450 K), inner zones of the early solar nebula and then travel large radial distances out to the comet-forming zone. On the other hand, Mg-rich silicate crystals may be ISM amorphous silicates annealed at ～1000 K and radially distributed out to the comet-forming zone or annealed in nebular shocks at ～5-10 AU. Determining the relative abundance of amorphous and crystalline silicatesin comets probes the relative contributions of ISM grains and primitive grains to small, icy bodies in the solar system. The life cycle of dust from its stardust origins through the ISM to its incorporation into comets is discussed.  相似文献   

13.
We report on the investigation of presolar grain inventories of hydrated lithic clasts in three metal-rich carbonaceous chondrites from the CR clan, Acfer 182 (CH3), Isheyevo (CH3/CBb3), and Lewis Cliff (LEW) 85332 (C3-un), as well as the carbon- and nitrogen-isotopic compositions of the fine-grained clast material. Eleven presolar silicate grains as well as nine presolar silicon carbide (SiC) grains were identified in the clasts. Presolar silicate abundances range from 4 to 22 parts per million (ppm), significantly lower than in pristine meteorites and interplanetary dust particles (IDP), and comparable to recent findings for CM2s and CR2 interchondrule matrix. SiC concentrations lie between 9 and 23 ppm, and are comparable to the values for CI, CM, and CR chondrites. The results of our investigation suggest similar alteration pathways for the clast material, the interchondrule matrix of the CR2 chondrites, and the fine-grained fraction of CM2 chondrites. Fine-grained matter of all three meteorites contains moderate to high 15N-enrichments (~50‰ ≤ δ15N ≤ ~1600‰) compared to the terrestrial value, indicating the presence of primitive organic material. We observed no correlation between 15N-enrichments and presolar dust concentrations in the clasts. This is in contrast to the findings from a suite of primitive IDPs, which display in several cases enhanced bulk 15N/14N ratios and high presolar grain abundances of several hundred or even thousand ppm. The bulk 15N/14N ratios of the clasts are comparable to the range for primitive IDPs, suggesting a nitrogen carrier less susceptible to destruction by aqueous alteration than silicate stardust.  相似文献   

14.
Abstract— We report mass‐spectrometric measurements of light noble gases pyrolytically extracted from 28 interplanetary dust particles (IDPs) and discuss these new data in the context of earlier analyses of 44 IDPs at the University of Minnesota. The noble gas database for IDPs is still very sparse, especially given their wide mineralogic and chemical variability, but two intriguing differences from isotopic distributions observed in lunar and meteoritic regolith grains are already apparent. First are puzzling overabundances of 3He, manifested as often strikingly elevated 3He/4He ratios—up to >40x the solar‐wind value—‐and found primarily but not exclusively in shards of some of the larger IDPs (“cluster particles”) that fragmented on impact with the collectors carried by high‐altitude aircraft. It is difficult to attribute these high ratios to 3He production by cosmic‐ray‐induced spallation during estimated space residence times of IDPs, or by direct implantation of solar‐flare He. Minimum exposure ages inferred from the 3He excesses range from ～50 Ma to an impossible >10 Ga, compared to Poynting‐Robertson drag lifetimes for low‐density 20–30 μm particles on the order of ～0.1 Ma for an asteroidal source and ～10 Ma for origin in the Kuiper belt. The second difference is a dominant contribution of solar‐energetic‐particle (SEP) gases, to the virtual exclusion of solar‐wind (SW) components, in several particles scattered throughout the various datasets but most clearly and consistently observed in recent measurements of a group of individual and cluster IDPs from three different collectors. Values of the SEP/SW fluence ratio in interplanetary space from a simple model utilizing these data are ～1% of the relative SEP/SW abundances observed in lunar regolith grains, but still factors of approximately 10–100 above estimates for this ratio in low‐energy solar particle emission.  相似文献   

15.
Abstract— Submicron platey Sn-rich grains are present in chondritic porous interplanetary dust particle (IDP) W7029*A and it is the second occurrence of a tin mineral in a stratospheric micrometeorite. Selected Area Electron Diffraction data for the Snrich grains match with Sn2O3 and Sn3O4. The oxide(s) may have formed in the solar nebula when tin metal catalytically supported reduction of CO or during flash heating on atmospheric entry of the IDP. The presence of tin is consistent with enrichments for other volatile trace elements in chondritic IDPs and may signal an emerging trend towards non-chondritic volatile element abundances in chondritic IDPs. The observation confirms small-scale mineralogical heterogeneity in fine-grained chondritic porous interplanetary dust.  相似文献   

16.
Abstract– The deceleration tracks in the Stardust aerogel display a wide range of morphologies, which reveal a large diversity of incoming particles from comet 81P/Wild 2. If the large and dense mineral grains survived the extreme conditions of hypervelocity capture, this was not the case for the fine‐grained material that is found strongly damaged within the aerogel. Due to their low mechanical strength, these assemblages were disaggregated, dispersed, and flash melted in the aerogel in walls of bulbous deceleration tracks. Their petrologic and mineralogical properties are found significantly modified by the flash heating of the capture. Originating from a quenched melt mixture of comet material and aerogel, the representative microstructure consists of silica‐rich glassy clumps containing Fe‐Ni‐S inclusions, vesicles and “dust‐rich” patches, the latter being remnants of individual silicate components of the impacting aggregate. The average composition of these melted particle fragments is close to the chondritic CI composition. They might originate from ultrafine‐grained primitive components comparable to those found in chondritic porous IDPs. Capture effects in aerogel and associated sample biases are discussed in terms of size, chemical and mineralogical properties of the grains. These properties are essential for the grain survival in the extremely hot environment of hypervelocity impact capture in aerogel, and thus for inferring the correct properties of Wild 2 material.  相似文献   

17.
Abstract— Grain-by-grain analytical electron microscope analyses of two micrometeorites, or interplanetary dust particles (IDPs), of the chondritic porous subtype, show the presence of rare barite (BaSO4) and magnesium carbonate, probably magnesite. Salt minerals in chondritic porous (CP) IDPs give evidence for in situ aqueous alteration in their parent bodies. The uniquely high barium content of CP IDP W7029*C1 is consistent with barite precipitation from a mildly acidic (pH > ～5) aqueous fluid at temperatures below 417 K and low oxygen fugacity. The presence of magnesite in olivine-rich, anhydrous CP IDP W7010*A2 is evidence that carbonate minerals occur in both the chondritic porous and chondritic smooth subtypes of chondritic IDPs. Citing Schramm et al. (1989) for putative asteroidal-type aqueous alteration in IDPs and probable sources of chondritic IDPs, salt minerals in CP IDPs could support low-temperature aqueous activity in nuclei of active short-period comets.  相似文献   

18.
We investigated the inventory of presolar silicate, oxide, and silicon carbide (SiC) grains of fine‐grained chondrule rims in six Mighei‐type (CM) carbonaceous chondrites (Banten, Jbilet Winselwan, Maribo, Murchison, Murray and Yamato 791198), and the CM‐related carbonaceous chondrite Sutter's Mill. Sixteen O‐anomalous grains (nine silicates, six oxides) were detected, corresponding to a combined matrix‐normalized abundance of ~18 ppm, together with 21 presolar SiC grains (~42 ppm). Twelve of the O‐rich grains are enriched in 17O, and could originate from low‐mass asymptotic giant branch stars. One grain is enriched in 17O and significantly depleted in 18O, indicative of additional cool bottom processing or hot bottom burning in its stellar parent, and three grains are of likely core‐collapse supernova origin showing enhanced 18O/16O ratios relative to the solar system ratio. We find a presolar silicate/oxide ratio of 1.5, significantly lower than the ratios typically observed for chondritic meteorites. This may indicate a higher degree of aqueous alteration in the studied meteorites, or hint at a heterogeneous distribution of presolar silicates and oxides in the solar nebula. Nevertheless, the low O‐anomalous grain abundance is consistent with aqueous alteration occurring in the protosolar nebula and/or on the respective parent bodies. Six O‐rich presolar grains were studied by Auger Electron Spectroscopy, revealing two Fe‐rich silicates, one forsterite‐like Mg‐rich silicate, two Al‐oxides with spinel‐like compositions, and one Fe‐(Mg‐)oxide. Scanning electron and transmission electron microscopic investigation of a relatively large silicate grain (490 nm × 735 nm) revealed that it was crystalline åkermanite (Ca2Mg[Si2O7]) or a an åkermanite‐diopside (MgCaSi2O6) intergrowth.  相似文献   

19.
Comet 81P/Wild 2 dust, the first comet sample of known provenance, was widely expected to resemble anhydrous chondritic porous (CP) interplanetary dust particles (IDPs). GEMS, distinctly characteristic of CP IDPs, have yet to be unambiguously identified in the Stardust mission samples despite claims of likely candidates. One such candidate is Stardust impact track 57 “Febo” in aerogel, which contains fine‐grained objects texturally and compositionally similar to GEMS. Their position adjacent the terminal particle suggests that they may be indigenous, fine‐grained, cometary material, like that in CP IDPs, shielded by the terminal particle from damage during deceleration from hypervelocity. Dark‐field imaging and multidetector energy‐dispersive X‐ray mapping were used to compare GEMS‐like‐objects in the Febo terminal particle with GEMS in an anhydrous, chondritic IDP. GEMS in the IDP are within 3× CI (solar) abundances for major and minor elements. In the Febo GEMS‐like objects, Mg and Ca are systematically and strongly depleted relative to CI; S and Fe are somewhat enriched; and Au, a known aerogel contaminant, is present, consistent with ablation, melting, abrasion, and mixing of the SiOx aerogel with crystalline Fe‐sulfide and minor enstatite, high‐Ni sulfide, and augite identified by elemental mapping in the terminal particle. Thus, GEMS‐like objects in “caches” of fine‐grained debris abutting terminal particles are most likely deceleration debris packed in place during particle transit through the aerogel.  相似文献   

20.
The bulbous Stardust track #80 (C2092,3,80,0,0) is a huge cavity. Allocations C2092,2,80,46,1 nearest the entry hole and C2092,2,80,47,6 about 0.8 mm beneath the entry hole provide evidence of highly chaotic conditions during capture. They are dominated by nonvesicular low‐Mg silica glass instead of highly vesicular glass found deeper into this track which is consistent with the escape of magnesiosilica vapors generated from the smallest comet grains. The survival of delicate (Mg,Al,Ca)‐bearing silica glass structures is unique to the entry hole. Both allocations show a dearth of surviving comet dust except for a small enstatite, a low‐Ca hypersthene grain, and a Ti‐oxide fragment. Finding scattered TiO2 fragments in the silica glass could support, but not prove, TiO2 grain fragmentation during hypervelocity capture. The here reported dearth in mineral species is in marked contrast to the wealth of surviving silicate and oxide minerals deeper into the bulb. Both allocations show Fe‐Ni‐S nanograins dispersed throughout the low‐Mg silica glass matrix. It is noted that neither comet Halley nor Wild 2 had a CI bulk composition for the smallest grains. Using the analogs of interplanetary dust particles (IDPs) and cluster IDPs it is argued that a CI chondritic composition requires the mixing of nonchondritic components in the appropriate proportions. So far, the fine‐grained Wild 2 dust is biased toward nonchondritic ferromagnesiosilica materials and lacking contributions of nonchondritic components with Mg‐Fe‐Ni‐S[Si‐O] compositions. To be specific, “Where are the GEMS”? The GEMS look‐alike found in this study suggests that evidence of GEMS in comet Wild 2 may still be found in the Stardust glass.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号