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1.
Abstract— Seven large (10 g) impact melt rock samples from boreholes from the Boltysh impact crater (Ukraine) and six samples from the East Clearwater crater (Canada) were analyzed for Os, Ir, Ru, Rh, Pd, Re and Au by the nickel sulfide technique in combination with neutron activation. Earlier analyses of Clearwater East impact melt rocks have shown that they are strongly enriched in Ir, Os, Pd and Re. In this work, I confirm earlier findings and demonstrate similarly high enrichments of Rh and Ru. The average Os/Ir, Ru/Ir, Pd/Ir, Rh/Ir and Ru/Rh ratios of the melt rock samples from Clearwater East are CI-chondritic and yield an average Ir content of 25.2 ± 6.5 ng/g relative to an average upper crust concentration of 0.03 ± 0.02 ng/g Ir. The amount of meteoritic component corresponds to 4 to 7% of a nominal CI component for Clearwater East. The impact melt rock samples from a bore hole from Boltysh are low in Ir with an average of 0.2 ± 0.1 ng/g. The CI-normalized abundances increase from the refractory to the more volatile siderophile elements (Os < Ir < Ru < Rh ～ Pd ～ Au ～ Ni ～ Co). Because of the low Ir anomaly and uncertainties in making corrections (correlations are weak) for indigenous siderophile elements, no clear projectile assignment can be made.  相似文献   

2.
A factor analysis has been performed on nickel and trace element data for iron meteorites. The technique shows that the present distribution of these elements is the result of three processes. These can be identified from the elements involved:
  • 1 Ga, Ge, Sb and Zn (condensation and accretion).
  • 2 Ni, Pd, Co and Cu (oxidation and sulphuration).
  • 3 Ir, Au, As, Re, Pt, Os, Ru and Cr (an igneous event).
The distribution of Mo, however, is not readily explicable in terms of these processes. Within the groups IAB and IIAB only one process is required for all elements, but in groups IIIAB and IVA the situation for Ga, Ge and Sb is more complex.  相似文献   

3.
Abstract— Siderophile elements have been used to constrain projectile compositions in terrestrial and lunar impact melt rocks. To obtain a better knowledge of compositional differences between potential chondritic projectile types, meteorite analyses of the elements Ru, Rh, Pd, Os, Ir, Pt, Cr, Co, Ni, and Au were gathered into a database. The presented compilation comprises 806 analyses of 278 chondrites including new ICP‐MS analyses of Allende and two ordinary chondrites. Each data set was evaluated by comparing element ratios of meteorites from the same chondrite group. Characteristic element abundances and ratios were determined for each group. Features observed in the element abundance patterns can be linked directly to the presence of certain components, such as the abundance of refractory elements Os, Ir, and Ru correlating with the occurrence of refractory inclusions in CV, CO, CK, and CM chondrites. The refined characteristic element ratios appear to be representative not only for meteorites, but also for related asteroidal bodies. Chondrite element ratios were compared to previously published values from impact melt rocks of the Popigai and Morokweng impact structures confirming that an identification of the specific type of projectile (L and LL chondrite, respectively) is possible. The assessment for Morokweng is supported by the recent discovery of an LL chondrite fragment in the impact melt rocks. Ultimately, the database provides valuable information for understanding processes in the solar nebula as they are recorded in chondrites. A new type of complementarity between element patterns of CK and EH chondrites is suggested to be the result of condensation, redox, and transportation processes in the solar nebula.  相似文献   

4.
Abstract The Manitouwabing meteorite whose trace constituents have not been previously quantified was analysed for Au, As, Ga, Ge, Ir, Ni, Os, Pd, Pt, Rh and Ru. Our data confirm that it belongs to subgroup IIIA of the IIIAB group and on the basis of the much higher concentrations of As, Ir, Os, Pt, Rh and Ru, it is not paired with Madoc as had previously been proposed.  相似文献   

5.
We have studied the feldspathic lunar meteorite Dhofar 1428 chemically and petrologically to better understand the evolution of the lunar surface. Dhofar 1428 is a feldspathic regolith breccia derived from the lunar highland. Bulk chemical and mineral compositions of Dhofar 1428 are similar to those of other feldspathic lunar meteorites. We found a few clasts of evolved lithologies, such as K‐rich plagioclases and quartz monzogabbro. Dhofar 1428 contains approximately 1 wt% of chondritic materials like CM chondrite on the basis of abundances of platinum group elements (Ru, Rh, Pd, Os, Ir, and Pt).  相似文献   

6.
Abstract– Despite the fact that Si is considered a potentially important metalloid in planetary systems, little is known about the effect of Si in metallic melts on trace element partitioning behavior. Previous studies have established the effects of S, C, and P, nonmetals, through solid metal/liquid metal experiments in the corresponding Fe binary systems, but the Fe‐Si system is not appropriate for similar experiments because of the high solubility of Si in solid metal. In this work, we present the results from 0.1 MPa experiments with two coexisting immiscible metallic liquids in the Fe‐S‐Si system. By leveraging the extensive available knowledge about the effect of S on trace element partitioning behavior, we explore the effect of Si. Results for 22 trace elements are presented. Strong Si avoidance behavior is demonstrated by As, Au, Ga, Ge, Sb, Sn, and Zn. Iridium, Os, Pt, Re, Ru, and W exhibit weak Si avoidance tendencies. Silicon appears to have no significant effect on the partitioning behaviors of Ag, Co, Cu, Cr, Ni, Pd, and V, all of which had similar partition coefficients over a wide range of Si liquid concentrations from Si‐free to 13 wt%. The only elements in our experiments to show evidence of a potentially weak attraction to Si were Mo and Rh. Applications of the newly determined effects of Si to problems in planetary science indicate that (1) The elements Ni, Co, Mo, and W, which are commonly used in planetary differentiation models, are minimally affected by the presence of Si in the metal, especially in comparison to other effects such as from oxygen fugacity. 2) Reduced enstatite‐rich meteorites may record a chemical signature due to Si in the metallic melts during partial melting, and if so, elements identified by this study as having strong Si avoidance may offer unique insight into unraveling the history of these meteorites.  相似文献   

7.
Ejecta at North Ray crater (Apollo 16) sampled a unique section of the lunar highlands not accessible at most other landing sites and provide important constraints on the composition of late accreted materials. New data on multiple aliquots of four fragmental matrix breccias and a fragment‐laden melt breccia from this site display a variety of highly siderophile element patterns which may represent the signatures of volatile element‐depleted carbonaceous chondrite‐like material, primitive achondrite, differentiated metal, and an impactor component that cannot be related to known meteoritic material. The latter component is prevalent in these rocks besides characterized by depletions in Re and Os compared to Ir, Ru and Pt, chondritic Re/Os, and a gradual depletion of Pd and Au. The observed characteristics are more consistent with fractionations by nebular processes, like incomplete condensation or evaporation, than with lunar crustal processes, like partial melting or volatilization. The impactor signature preserved in these breccias may stem from primitive meteorites with a refractory element composition moderately different from known chondrites. The presence of distinct impactor components within the North Ray crater breccias together with observed correlations of characteristic element ratios (e.g., Re/Os, Ru/Pt, Pd/Ir) in different impact lithologies of four Apollo landing sites constrains physical mixing processes ranging from the scale of gram‐sized samples to the area covered by the Apollo missions.  相似文献   

8.
We have studied magnetic fractions of five acapulcoites, three lodranites, and two winonaites to investigate chemical compositions of their precursor materials and metallic partial melting processes occurring on their parent bodies. One winonaite metal is similar in composition to low Au, low Ni IAB iron subgroup, indicating genetic relationship between them. Magnetic fractions of chondrule‐bearing acapulcoite and winonaite have intermediate chemical compositions of metals between H chondrites and EL chondrites. This fact indicates that the precursor materials of acapulcoite–lodranites and winonaites were similar to H and/or EL chondrites in chemical compositions. Magnetic fractions in acapulcoite–lodranites have a large variety of chemical compositions. Most of them show enrichments of W, Re, Ir, Pt, Mo, and Rh, and one of them shows clear depletion in Re and Ir relative to those of chondrule‐bearing acapulcoite. Chemical compositional variations among acapulcoite–lodranite metals cannot be explained by a single Fe‐Ni‐S partial melting event, but a two‐step partial melting model can explain it.  相似文献   

9.
Abstract– Aubrites exhibit a wide range of highly siderophile element (HSE—Re, Os, Ir, Ru, Rh, Pt, Pd, Au) concentrations and 187Os/188Os compositions. Their HSE concentrations are one to three orders of magnitude less than chondrites, with the exception of the Shallowater and Mt. Egerton samples. While most aubrites show chondritic HSE abundance ratios, significant enrichments of Pd and Re relative to Os, Ir, and Ru are observed in 12 of 16 samples. Present‐day 187Os/188Os ratios range from subchondritic values of 0.1174 to superchondritic values of up to 0.2263. Half of the samples have 187Os/188Os ratios of 0.127 to 0.130, which is in the range of enstatite chondrites. Along with the brecciated nature of aubrites, the HSE and Re‐Os isotope systematics support a history of extensive postaccretion processing, including core formation, late addition of chondritic material and/or core material and potential breakup and reassembly. Highly siderophile element signatures for some aubrites are consistent with a mixing of HSE‐rich chondritic fragments with a HSE‐free aubrite matrix. The enrichments in incompatible HSE such as Pd and Re observed in some aubrites, reminiscent of terrestrial basalts, suggest an extensive magmatic and impact history, which is supported by both the 187Re‐187Os isotope system and silicate‐hosted isotope systems (Rb‐Sr, K‐Ar) yielding young formation ages of 1.3–3.9 Ga for a subset of samples. Compared with other differentiated achondrites derived from small planetary bodies, aubrites show a wide range in HSE concentrations and 187Os/188Os, most similar to angrites. While similarities exist between the diverse groups of achondrites formed early in solar system history, the aubrite parent body(ies) clearly underwent a distinct evolution, different from angrites, brachinites, ureilites, howardites, eucrites, and diogenites.  相似文献   

10.
Abstract— Compositions of four metal nodules from two ordinary chondrites, WIS91627 (H3.7) and Juin (H5), were determined by instrumental and radiochemical neutron activation analyses. Compared with bulk metal fractions, the metal nodules are characterized by strong and variable depletion of the refractory siderophile elements Re, Os, Ir, Ru, Pt and Rh but normal W and Mo, some fractionation of Co from Ni, and low Cu concentrations. These characteristics are difficult to explain by shock-induced vaporization followed by fractional condensation, a mechanism suggested by Widom et al. (1986). We propose formation of metal nodules during metamorphism in the parent body. Refractory siderophile elements, such as Ir, Os, Rh, etc., are partly locked up in noble metal nuggets and cannot participate in kamacite formation. The occurrence of metal nodules in both equilibrated and unequilibrated ordinary chondrites suggests that diffusion along grain boundaries was important in the development of kamacite and taenite in ordinary chondrites.  相似文献   

11.
Abstract— Experimental solid metal‐liquid metal partition coefficients have been used to model the crystallization of magmatic iron meteorites and understand the evolution of asteroid cores. However, the majority of the partitioning experiments have been conducted with trace elements doped at levels that are orders of magnitude higher than measured in iron meteorites. Concern about Henry's Law and the unnatural doping levels have been cited as one reason that two recent iron meteorite studies have dismissed the experimental partition coefficients in their modeling. Using laser ablation ICP‐MS analysis, this study reports experimentally determined solid metal‐liquid metal trace element partition coefficients from runs doped down to the levels occurring in iron meteorites. The analyses for 12 trace elements (As, Co, Cr, Cu, Ga, Ge, Ir, Os, Pd, Pt, Re, and W) show no deviations from Henry's Law, and these results support decades of experimental work in which the partition coefficients were assumed to be independent of trace element concentration. Further, since our experiments are doped with natural levels of trace elements, the partitioning results are directly applicable to iron meteorites and should be used when modeling their crystallization. In contrast, our new Ag data are inconsistent with previous studies, suggesting the high Ag‐content in previous studies may have influenced the measured Ag partitioning behavior.  相似文献   

12.
Abstract– Perryite [(Fe,Ni)x(Si,P)y], schreibersite [(Fe,Ni)3P], and kamacite (αFeNi) are constituent minerals of the metal‐sulfide nodules in the Sahara 97072 (EH3) enstatite chondrite meteorite. We have measured concentrations of Ni, Cu, Ga, Au, Ir, Ru, and Pd in these minerals with laser ablation, inductively coupled plasma mass spectrometry (ICP‐MS). We also measured their Fe, Ni, P, Si, and Co concentrations with electron microprobe. In kamacite, ratios of Ru/Ir, Pd/Ir, and Pd/Ru cluster around their respective CI values and all elements analyzed plot near the intersection of the equilibrium condensation trajectory versus Ni and the respective CI ratios. In schreibersite, the Pd/Ru ratio is near the CI value and perryite contains significant Cu, Ga, and Pd. We propose that schreibersite and perryite formed separately near the condensation temperatures of P and Si in a reduced gas and were incorporated into Fe‐Ni alloy. Upon further cooling, sulfidation of Fe in kamacite resulted in the formation of additional perryite at the sulfide interface. Still later, transient heating re‐melted this perryite near the Fe‐FeS eutectic temperature during partial melting of the metal‐sulfide nodules. The metal‐sulfide nodules are pre‐accretionary objects that retain CI ratios of most siderophile elements, although they have experienced transient heating events.  相似文献   

13.
This study uses experimentally determined plagioclase‐melt D values to estimate the trace element concentrations of Sr, Hf, Ga, W, Mo, Ru, Pd, Au, Ni, and Co in a crystallizing lunar magma ocean at the point of plagioclase flotation. Similarly, experimentally determined metal‐silicate partition experiments combined with a composition model for the Moon are used to constrain the concentrations of W, Mo, Ru, Pd, Au, Ni, and Co in the lunar magma ocean at the time of core formation. The metal‐silicate derived lunar mantle estimates are generally consistent with previous estimates for the concentration of these elements in the lunar mantle. Plagioclase‐melt derived concentrations for Sr, Ga, Ru, Pd, Au, Ni, and Co are also consistent with prior estimates. Estimates for Hf, W, and Mo, however, are higher. These elements may be concentrated in the residual liquid during fractional crystallization due to their incompatibility. Alternatively, the apparent enrichment could reflect the inappropriate use of bulk anorthosite data, rather than data for plagioclase separates.  相似文献   

14.
Abstract— Instrumental neutron activation analysis (INAA) was used to determine Ni, Co, Cu, Ga, As, Au, W, Re and Ir in taenite lamellae isolated by acid dissolution from eight iron meteorites from groups IA, IIIAB and IVA. Taenite is enriched in Ni, Cu, Ga, As, Au, W, Re and Ir relative to kamacite, whereas taenite is depleted in Co. Taenite/kamacite partition ratios in slowly cooled IAB meteorites are farther from unity than those in rapidly cooled IVA meteorites. Taenite/kamacite partition ratios for Cu, Ir, Au and Co may be sensitive cooling rate indicators.  相似文献   

15.
Abstract— The platinum group elements (PGE; Ru, Rh, Pd, Os, Ir, Pt), Re and Au comprise the highly siderophile elements (HSE). We reexamine selected isotopic and abundance data sets for HSE in upper mantle peridotites to resolve a longstanding dichotomy. Re‐Os and Pt‐Os isotope systematics, and approximately chondritic proportions of PGE in these rocks, suggest the presence in undepleted mantle of a chondrite‐like component, which is parsimoniously explained by late influx of large planetisimals after formation of the Earth's core and the Moon. But some suites of xenolithic and orogenic spinel lherzolites, and abyssal peridotites, have a CI‐normalized PGE pattern with enhanced Pd that is sometimes termed “non‐chondritic”. We find that this observation is consistent with other evidence of a late influx of material more closely resembling enstatite, rather than ordinary or carbonaceous, chondrites. Regional variations in HSE patterns may be a consequence of a late influx of very large objects of variable composition. Studies of many ancient (>3.8 Ga) lunar breccias show regional variations in Au/Ir and suggest that “graininess” existed during the early bombardment of the Earth and Moon. Reliable Pd values are available only for Apollo 17 breccias 73215 and 73255, however. Differences in HSE patterns between the aphanitic and anorthositic lithologies in these breccias show fractionation between a refractory group (Re, Os and Ir) and a normal (Pd, Ni, and Au) group and may reflect the compositions of the impacting bodies. Similar fractionation is apparent between the EH and EL chondrites, whose PGE patterns resemble those of the aphanitic and anorthositic lithologies, respectively. The striking resemblance of HSE and chalcogen (S, Se) patterns in the Apollo aphanites and high‐Pd terrestrial peridotites suggest that the “non‐chondritic” abundance ratios in the latter may be reflected in the composition of planetisimals striking the Moon in the first 700 Ma of Earth–Moon history. Most notably, high Pd may be part of a general enhancement of HSE more volatile than Fe suggesting that the Au abundance in at least parts of the upper mantle may be 1.5 to 2x higher than previously estimated. The early lunar influx may be estimated from observed basin‐sized craters. Comparison of relative influx to Earth and Moon suggests that the enrichment of HSE is limited to the upper mantle above 670 km. To infer enrichment of the whole mantle would require several large lunar impacts not yet identified.  相似文献   

16.
Olivine‐dominated (70–80 modal %) achondrite meteorite Lewis Cliff (LEW) 88763 originated from metamorphism and limited partial melting of a FeO‐rich parent body. The meteorite experienced some alteration on Earth, evident from subchondritic Re/Os, and redistribution of rhenium within the sample. LEW 88763 is texturally similar to winonaites, has a Δ17O value of ?1.19 ± 0.10‰, and low bulk‐rock Mg/(Mg+Fe) (0.39), similar to the FeO‐rich cumulate achondrite Northwest Africa (NWA) 6693. The similar bulk‐rock major‐, minor‐, and trace‐element abundances of LEW 88763, relative to some carbonaceous chondrites, including ratios of Pd/Os, Pt/Os, Ir/Os, and 187Os/188Os (0.1262), implies a FeO‐ and volatile‐rich precursor composition. Lack of fractionation of the rare earth elements, but a factor of approximately two lower highly siderophile element abundances in LEW 88763, compared with chondrites, implies limited loss of Fe‐Ni‐S melts during metamorphism and anatexis. These results support the generation of high Fe/Mg, sulfide, and/or metal‐rich partial melts from FeO‐rich parent bodies during partial melting. In detail, however, LEW 88763 cannot be a parent composition to any other meteorite sample, due to highly limited silicate melt loss (0 to <<5%). As such, LEW 88763 represents the least‐modified FeO‐rich achondrite source composition recognized to date and is distinct from all other meteorites. LEW 88763 should be reclassified as an anomalous achondrite that experienced limited Fe,Ni‐FeS melt loss. Lewis Cliff 88763, combined with a growing collection of FeO‐rich meteorites, such as brachinites, brachinite‐like achondrites, the Graves Nunataks (GRA) 06128/9 meteorites, NWA 6693, and Tafassasset, has important implications for understanding the initiation of planetary differentiation. Specifically, regardless of precursor compositions, partial melting and differentiation processes appear to be similar on asteroidal bodies spanning a range of initial oxidation states and volatile contents.  相似文献   

17.
Abstract— Seismic reflection data and an at least 350 m thick, PGE‐rich carbonate breccia lens intersected by the Fohn‐1 exploration well in the Timor Sea off northern Australia, are interpreted in terms of a buried 4.8 km‐diameter impact crater of late Eocene to pre‐Miocene age. The crater displays the classic elements of impact structures, including a central uplift, ring syncline, and upraised rims. The presence in the breccia of redeposited Campanian and Maastrichtian microfossils suggests rebound of strata from levels deeper than 1250 m below the pre‐Miocene unconformity. Morphometric modelling suggests an original crater at least 1400 m deep, which is consistent with the excavation of Cretaceous strata. Stratigraphic and palaeontological evidence suggests that the impact occurred between 36 and 24.6 Ma. The breccia contains a pseudotachylite component enriched in the inert Pt group elements (PGE) (Ir, Ru) by factors of 5–12 above the values of common sediments. The more mobile PGE (Os, Pt, Pd) show a wide scatter and terrestrial‐type values. Opposite geochemical/stratigraphic trends pertain to different PGE species—the relatively inert Ir‐Ru group shows an overall concentration at the base of the section, whereas the more mobile Os shows peaks at median levels of the section—suggesting upward diagenetic leaching. The near‐chondritic PGE patterns at the base of the breccia pile are accompanied by near‐chondritic Ni/Cr, Co/Cr, Ni/Ir, Ni/Pt, and Cu/Pd ratios. Departure from these values related to alteration at higher levels in the breccia pile is accompanied with high S levels (～1%).  相似文献   

18.
Abstract– We examined 378 micrometeorites collected from deep‐sea sediments of the Indian Ocean of which 175, 180, and 23 are I‐type, S‐type, and G‐type, respectively. Of the 175 I‐type spherules, 13 contained platinum group element nuggets (PGNs). The nuggets occur in two distinct sizes and have distinctly different elemental compositions: micrometer (μm)‐sized nuggets that are >3 μm contain dominantly Ir, Os, and Ru (iridium‐platinum group element or IPGE) and sub‐μm (or nanometer)‐sized (<1 μm) nuggets, which contain dominantly Pt, Rh, and Pd (palladium—PGE or PPGE). The μm‐sized nuggets are found only one per spherule in the cross section observed and are usually found at the edge of the spherule. By contrast, there are hundreds of nanometer‐sized nuggets distributed dominantly in the magnetite phases of the spherules, and rarely in the wüstite phases. Both the nugget types are found as separate entities in the same spherule and apparently, nugget formation is a common phenomenon among I‐type micrometeorites. However, the μm‐sized nuggets are seen in fewer specimens (～2.5% of the observed I‐type spherules). In all, we analyzed four nuggets of μm size and 213 nanometer‐sized nuggets from 13 I‐type spherules for platinum group elements. Chemically, the μm‐sized PGNs contain chondritic ratios of Os/Ir, but are depleted in the more volatile PGE (Pt, Rh, and Pd) relative to chondritic ratios. On the other hand, the nanometer‐sized nuggets contain dominantly Pt and Rh. Importantly, the refractory PGEs are conspicuous by their absence in these nanometer nuggets. Palladium, the most volatile PGE is highly depleted (<1.1%) with respect to chondritic ratios in the μm‐sized PGNs, and is observed in only 17 of 213 nanometer nuggets with concentrations that are just above the detection limit (≥0.2%). Distinct fractionation of the PGE into IPGE (Ir, Os, Ru) and PPGE seems to take place during the short span of atmospheric entry. These observations suggest several implications: (1) The observation of fractionated PGE in an Fe‐Ni system gives rise to the possibility that Earth’s core could contain fractionated PGE. (2) The present data support the processes suggested for the fractionated PGE patterns observed in the ejecta of ancient meteorite impacts. (3) Meteoric metals released in the troposphere could contain fractionated PGNs in large numbers.  相似文献   

19.
Abstract— Thallium has been quantified in 50 iron meteorites and 6 chondrites using a combination of solvent extraction and graphite furnace atomic absorption spectrometry. The accuracy of the data was checked by analysis of two iron meteorites by laser-excited ICP mass spectrometry. The Tl abundance values for irons appear to be the first recorded and show that the Tl content allows for taxonomic separation of several groups on Tl vs. Ni abundance plots. The Tl content of irons is inversely correlated with abundances of platinum group metals such as Ir, Pt, and Rh and, in this respect, behaves like Pd and As that favour sulphur-rich phases in meteorites. Analysis of carbonaceous chondrites showed a 30-fold enrichment of Tl compared with ordinary chondrites.  相似文献   

20.
Abstract— The measured Cu and Cr contents in magmatic iron meteorites appear to contradict the behavior predicted by experimental fractional crystallization studies currently available. To investigate the origin of Cu and Cr concentrations observed in these meteorites, a thorough set of solid metal/liquid metal experiments were conducted in the Fe‐Ni‐S system. In addition to Cu and Cr, partitioning values were also determined for As, Au, Bi, Co, Mo, Ni, Pb, Rh, Ru, Sb, Sn, V, and Zn from the experiments. Experimental results for Cu and Cr showed similar chalcophile partitioning behavior, whereas these elements have differently sloped trends within magmatic iron meteorite groups. Thus, fractional crystallization alone cannot control both the Cu and Cr concentrations in these iron meteorite groups. A simple fractional crystallization model based on our experimental Cu partitioning results was able to match the Cu versus Au trend observed in the S‐poor IVB iron meteorite group but not the decreasing Cu versus Au trends in the IIAB and IIIAB groups or the unique S‐shaped Cu versus Au trend in the IVA group. However, the crystallization model calculations were found to be very sensitive to the specific choice for the mathematical expression of D(Cu), suggesting that any future refinement of the parameterization of D(Cu) should include a reassessment of the Cu fractional crystallization trends. The Cr versus Au trends in magmatic iron meteorite groups are steeper than those of Cu and not explained by fractional crystallization. Other influences, such as the removal of chromite from the crystallizing system or sampling biases during iron meteorite compositional analyses, are likely responsible for the Cr trends in magmatic iron meteorite groups.  相似文献   

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