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1.
Abstract— Seven large (10 g) impact melt rock samples from boreholes from the Boltysh impact crater (Ukraine) and six samples from the East Clearwater crater (Canada) were analyzed for Os, Ir, Ru, Rh, Pd, Re and Au by the nickel sulfide technique in combination with neutron activation. Earlier analyses of Clearwater East impact melt rocks have shown that they are strongly enriched in Ir, Os, Pd and Re. In this work, I confirm earlier findings and demonstrate similarly high enrichments of Rh and Ru. The average Os/Ir, Ru/Ir, Pd/Ir, Rh/Ir and Ru/Rh ratios of the melt rock samples from Clearwater East are CI-chondritic and yield an average Ir content of 25.2 ± 6.5 ng/g relative to an average upper crust concentration of 0.03 ± 0.02 ng/g Ir. The amount of meteoritic component corresponds to 4 to 7% of a nominal CI component for Clearwater East. The impact melt rock samples from a bore hole from Boltysh are low in Ir with an average of 0.2 ± 0.1 ng/g. The CI-normalized abundances increase from the refractory to the more volatile siderophile elements (Os < Ir < Ru < Rh ~ Pd ~ Au ~ Ni ~ Co). Because of the low Ir anomaly and uncertainties in making corrections (correlations are weak) for indigenous siderophile elements, no clear projectile assignment can be made.  相似文献   
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The Walter‐Outalpa shear zone in the southern Curnamona Province of NE South Australia is an example of a shear zone that has undergone intensely focused fluid flow and alteration at mid‐crustal depths. Results from this study have demonstrated that the intense deformation and ductile shear zone reactivation, at amphibolite facies conditions of 534 ± 20 °C and 500 ± 82 MPa, that overprint the Proterozoic Willyama Supergroup occurred during the Delamerian Orogeny (c. 500 Ma) (EPMA monazite ages of 501 ± 16 and 491 ± 19 Ma). This is in contrast to the general belief that the majority of basement deformation and alteration in the southern Curnamona Province occurred during the waning stages of the Olarian Orogeny (c. 1610–1580 Ma). These shear zones contain hydrous mineral assemblages that cut wall rocks that have experienced amphibolite facies metamorphism during the Olarian Orogeny. The shear zone rock volumes have much lower δ18O values (as low as 1‰) than their unsheared counterparts (7–9‰), and calculated fluid δ18O values (5–8‰) consistent with a surface‐derived fluid source. Hydrous minerals show a decrease in δD(H2O) from ?14 to ?22‰, for minerals outside the shear zones, to ?28 to ?40‰, for minerals within the shear zones consistent with a contribution from a meteoric source. It is unclear how near‐surface fluids initially under hydrostatic pressure penetrate into the middle crust where fluid pressures approach lithostatic, and where fluid flow is expected to be dominantly upward because of pressure gradients. We propose a mechanism whereby faulting during basin formation associated with the Adelaidean Rift Complex (c. 700 Ma) created broad hydrous zones containing mineral assemblages in equilibrium with surface waters. These panels of fault rock were subsequently buried to depths where the onset of metamorphism begins to dehydrate the fault rock volumes evolving a low δ18O fluid that is channelled through shear zones related to Delamerian Orogenic activity.  相似文献   
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A 2.9 m long sedimentary record was studied from a small lake, here referred to as Duck Lake, located at 76°25'N, 18°45'W on Store Koldewey, an elongated island off the coast of Northeast Greenland. The sediments were investigated for their geophysical and biogeochemical characteristics, and for their fossil chironomid assemblages. Organic matter began to accumulate in the lake at 9.1 cal. kyr BP, which provides a minimum age for the deglaciation of the basin. Although the early to mid-Holocene is known as a thermal maximum in East Greenland, organic matter accumulation in the lake remained low during the early Holocene, likely due to late plant immigration and lack of nutrient availability. Organic matter accumulation increased during the middle and late Holocene, when temperatures in East Greenland gradually decreased. Enhanced soil formation probably led to higher nutrient availability and increased production in the lake. Chironomids are abundant throughout the record after 9.1 cal. kyr BP and seem to react sensitively to changes in temperature and nutrient availability. It is concluded that relative temperature reconstructions based on biogeochemical data have to be regarded critically, particularly in the period shortly after deglaciation when nutrient availability was low. Chironomids may be a suitable tool for climatic reconstructions even in those high arctic environments. However, a better understanding of the ecology of chironomids under these extreme conditions is needed.  相似文献   
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INVERSE THEORY APPLIED TO MULTI-SOURCE CROSS-HOLE TOMOGRAPHY.   总被引:4,自引:0,他引:4  
Frequency-domain methods are well suited to the imaging of wide-aperture cross-hole data. However, although the combination of the frequency domain with the wavenumber domain has facilitated the development of rapid algorithms, such as diffraction tomography, this has also required linearization with respect to homogeneous reference media. This restriction, and association restrictions on source-receiver geometries, are overcome by applying inverse techniques that operate in the frequency-space domain. In order to incorporate the rigorous modelling technique of finite differences into the inverse procedure a nonlinear approach is used. To reduce computational costs the method of finite differences is applied directly to the frequency-domain wave equation. The use of high speed, high capacity vector computers allow the resultant finite-difference equations to be factored in-place. In this way wavefields can be computed for additional source positions at minimal extra cost, allowing inversions to be generated using data from a very large number of source positions. Synthetic studies show that where weak scatter approximations are valid, diffraction tomography performs slightly better than a single iteration of non-linear inversion. However, if the background velocities increase systematically with depth, diffraction tomography is ineffective whereas non-linear inversion yields useful images from one frequency component of the data after a single iteration. Further synthetic studies indicate the efficacy of the method in the time-lapse monitoring of injection fluids in tertiary hydrocarbon recovery projects.  相似文献   
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Lake Xingcuo is a small, closed, hardwater lake situated in the eastern Tibetan Plateau. Stable isotope data (δ18O and δ13C) from the freshwater snail Gyraulus sibirica (Dunker) in a 34-cm-long, radioactive isotope-dated sediment core represent the past 200 years of Lake Xingcuo environmental history. Carbon and oxygen isotope ratios in the shells of the snail yield information on the isotopic composition of the water in which the shell was formed, which in turn relates to climatic conditions prevailing during the snail's life-span. Living and fossil shells from Lake Xingcuo were collected. δ18O values in the living shells from Lake Xingcuo are in equilibrium with ambient waters, while δ13C values may trace snail dietary carbon. On comparing δ18O and δ13C in the shell of Gyraulus sibirica with monitored data for the period 1954-1995, we found that the δ18O composition in the shell is an efficient proxy revealing air temperature during the warmer months from April to September. There is a positive correlation between the δ18O in the shells of Gyraulus sibirica and the running average temperature of the warmer months. Climatic variability in the eastern Tibetan Plateau for the past two centuries has been inferred from the δ18O record from the freshwater snails in the sediments of Lake Xingcuo. As such, the last 200 years' palaeoclimatic record for this region can be separated into three periods representing oscillations between warm and cool conditions consistent with the Guliya ice record in the Tibetan Plateau.  相似文献   
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