Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

典型深街谷内树木空间配置对行人呼吸高度处气流的影响     

林定  申小云  朱勇兵  陈崇成 《地球信息科学学报》2018,20(9):1235-1243

为揭示树木的不同空间配植方案对行人呼吸高度气流的影响,本文将树木视为均匀多孔介质,通过附加源项法从空气动力学角度用CFD模拟了H/W=2的典型深街谷几何内4种树木配植情景,实验表明,不同空间配置下树木对街谷内行人呼吸高度处局地气流的影响强弱在空间分布模式上差异悬殊：① 均匀种植的树木对街谷内行人呼吸高度的气流起到阻碍作用,不均匀种植则有效提升街谷的整体流速。4种空间配植方案下树木对气流的影响程度不同,阻碍作用从大到小的顺序为均匀间距8 m（Spa8m）>均匀间距6 m（Spa6m）>均匀间距20 m（Spa20m）>不均匀配植（Non-uniform）;对应的平均气流增强指标顺序为$\bar{D}_{spa8}$（-19.31%）<$\bar{D}_{spa6}$（-16.14%）<$\bar{D}_{spa20}$（-10.73%）<$\bar{D}_{non-uniform}$（1.25%）。② 对比不均匀和均匀的种植方案,不均匀植树的街谷内部行人呼吸高度的气流流速比其对照案例（均匀植树Spa8m方案）整体增强了106.49%。街谷中部不种树,在街谷两端配置树木并预留足够的自由空间的不均匀植树方案,能够让角涡渗入街谷中部,促使街谷内部的垂直漩涡和两端的水平角涡运动,增强湍流和垂直交换,有效减少了街道两端“风口效应”和街道中部“风影效应”的区域,改善了整个街谷行人呼吸平面的风环境。④ 合理空间配置的树木能够改善街谷内部的行人风环境。街谷内行人呼吸高度处的气流对局地条件很敏感,树木的局部配置（空间簇集、密度）将引起强烈的空间变化。在既有城市建筑布局条件下,如何通过谨慎的景观设计,利用树木等城市绿化措施有效地改善城市的行人风环境,缓解污染扩散、疾病传播等问题,本文的方法可提供一定的参考。  相似文献   

面向稀疏散布数据集的时空Kriging优化     

杨明远  刘海砚  季晓林  郭文月  陈思雯 《地球信息科学学报》2018,20(4):505-514

时空Kriging法通过将变异函数向时空域进行扩展得到时空变异函数,有效地利用时空邻近的采样点综合进行插值,由于时空稀疏散布数据集具有单一时刻下样本点数量少以及时空分布不规律的特点,难以满足使用时空Kriging插值法的基本条件,导致插值精度不高,据此本文提出了优化方法：通过多时段叠置拟合空间变异函数的方法,综合利用时空邻域内的采样点以解决单一时刻下空间邻域内数量不足情况;控制时间变异对空间变异函数拟合的误差影响;采用积合式模型构建时空变异函数进行插值。最后使用Argo海温数据进行插值实验,在相同条件下与时空Kriging法以及时空权重法的交叉验证结果对比得出,该方法在保证拟合所需采样点数量要求的同时,有效削减了一般时空Kriging法中时间变异对空间变异函数拟合结果的干扰,插值结果的绝对误差均值从0.5降低至0.2以内,稳定性进一步增强,改善了时空Kriging法在稀疏散布数据条件下精度上的不足。  相似文献   

涉密矢量数字地图中敏感要素几何信息量的测度方法     

李安波  陈楹  姚蒙蒙  吴赛松 《地球信息科学学报》2018,20(1):7-16

涉密矢量数字地图中敏感要素几何信息的定量测度,是实现定量化密级评定的基础和前提。如何进行敏感要素几何信息量的计算,目前尚缺乏相关研究。在现有地图信息论研究成果的基础上,论文主要开展了3方面的研究工作：首先,从地理对象的敏感性入手,探讨了地图要素敏感性的定义与要素集合的敏感性表征指标;然后,基于任意发生元的Voronoi构建方法,实现了对点要素集、线要素集、部分覆盖面要素集及综合要素集的信息单元自动化剖分;最后,基于长度系数、面积系数和角度系数,提出了线、面要素图形复杂度的计算方法,并在此基础上形成了涉密矢量数字地图中敏感几何信息量的测度方法。实验表明,该方法的计算结果遵循了信息量的非负性、连续性、可加性等特点,较为合理地反映了相关因素（地图比例尺、要素空间分布、要素图形复杂度、要素敏感系数等）对计算结果的影响。相关成果将支持矢量数字地图的定量化密级评定,并有助于完善地理信息安全监管的理论和方法体系。  相似文献   

日照市土壤地球化学元素分布规律及成因探讨          下载免费PDF全文

庞绪贵  宋娟娟  代杰瑞  喻超  张华平  陈磊  任天龙  王红晋 《山东国土资源》2018,34(4)

在日照市开展多目标区域地球化学调查，获取了表层土壤和深层土壤地球化学数据，通过对获得的地球化学参数进行统计分析，确定了日照市土壤地球化学基准值和背景值，认为日照市除部分元素或指标外，大部分元素或指标土壤地球化学基准值和背景值与全省土壤地球化学基准值和背景值接近。研究发现，日照市As，Cd，Cr，Cu，Hg，Ni，Pb，Zn等8种重金属元素背景值含量低于国家土壤环境质量标准的土壤一级标准限值，日照市土壤质量基本保持自然背景水平；而受工业化生产和城市化建设等后期人为活动影响，日照市表层土壤中Cd，C，Hg，N，P，S，Se，Corg等元素或指标出现明显富集，应引起重视。  相似文献   

日照市露天开采矿山地质环境问题及恢复治理措施          下载免费PDF全文

汪继学  尹俊凯  陈鹏  张承斌 《山东国土资源》2018,34(12)

通过1∶5万矿山地质环境调查和遥感解译手段,对日照市矿山进行了全面的调查,查明各类矿山546处,主要集中在莒县和五莲县境内。除莒县刘官庄煤矿外,其余全部为露天开采矿山,主要选用直接开挖的方式,不仅破坏了地表环境,而且矿山生产活动产生的固体废弃物占用了大面积的土地。该文根据矿山地理位置及开采方式的不同,将相同类型的多个矿山划分为同一治理区,针对不同治理区的特点,采取科学有效的治理方法,建立健全矿山地质环境监督管理机制,切实解决矿山地质环境问题,改善生态环境。  相似文献   

A CASE STUDY ON CONCENTRATION AND DECENTRALIZATION：BEHAVIOR AND DYNAMIC MECHANISM OF SPATIAL EVOLUTION IN METROPOLITAN AREA，NANJING，CHINA   总被引：1，自引：1，他引：0  

ZHUXi－gang  ZHANGJing－xiang 《中国地理科学(英文版)》2002,12(3):212-217

In rapid socio-economic development,the process of concentration and dispersal of various elements tends to be more dramatic,tremendously influencing the shaping and transformation of the space in metropolitan area.Survey of spatial concentration and decentralization has thus become a basic method in examining metropolitan spatial evolution.In this research,three elements were selected as the essential indicators of the process:demographic density distribu-tion,employment density distribution and business office location.Performance of these elements in Nanjing City was exam-ined historically.As Nanjing City could be regarded as a representative of metropolitan areas in China,its situation large-ly suggestes the general characteristics in similar areas of China.Hence based on the investigation of Nanjing City,four general implications were highlighted.First ,metropolitan areas in China are in a violent process and shift of spatial concentra-tion and decentralization.Second,from now to at least the near future,concentration will continue to be the central fea-ture.Third,the landscape of metropolitan areas basically exhibits a dual structure character.The gap in environmental and ecological qualities among different districts will continue for a long time.Fourth,Central Business District (CBD) is playing an important role in helping to convert the traditionally single-centered city structure into a polycentric one.  相似文献   

Discovery of 13 New Variable Stars in the Field of the Open Cluster NGC 2168 （M35）     

Juei-Hwa Hu  Wing-Huen Ip 《中国天文和天体物理学报》2005,5(4):356-362

A wide-field time-series CCD photometric survey of variable stars in the field of the open cluster NGC 2168 was carried out using the BATC Schmidt telescope. In total 13 new variable stars are discovered with three W UMa systems, one EA type and two EB type eclipsing binaries (one of them could be a W UMa system), and seven pulsating stars including three candidates of δScuti stars.  相似文献   

银盘恒星运动学和化学丰度与银河系结构     

侯金良  陈力  常瑞香  孙振娜 《天文研究与技术》2004,1(1):16-27

大样本的银盘恒星的运动学数据和元素丰度特征是研究银河系结构及演化，尤其是银盘形成和演化的2个重要探针。本文首先介绍了银河系的总体结构特征，然后较详细的综述了以上2个探针的重要性。对我国LAMOST项目在研究银河系结构方面，尤其是银盘的形成和演化方面的能力作了合理的分析。  相似文献   

关于改进的Encke方法中参考轨道的选择和校正     

刘林  胡松杰 《天文学报》1996,37(3):285-293

对于改进的Ｅｎｃｋｅ方法，选择适当的参考轨道是一个关键．然而，对于人造地球卫星长弧轨道计算，目前所给出的几种参考轨道均需要逐段校正，这将给定轨问题带来附加的复杂性．本文将仔细探讨如何选择参考轨道和减少校正次数．  相似文献