电感耦合等离子体质谱法同时测定地下水中硼溴碘   总被引：6，自引：4，他引：2  

黄光明  窦银萍  张静梅  张培新  高孝礼 《岩矿测试》2008,27(1):25-28

建立了电感耦合等离子体质谱法同时测定地下水中B、Br、I的方法。选定φ=2%(体积分数)的稀NH3.H2O介质消除碘的记忆效应。采用干扰较少的10B和79Br同位素。B、Br、I在0~10 000 ng/mL呈良好的线性关系。方法的检出限为10B 0.176 ng/mL,79Br 0.876ng/mL,127I 0.132 ng/mL;精密度(RSD,n=12)为10B 2.86%,79Br 3.36%,127I 2.69%;10B的阶梯加标回收率为94.6%~101.5%,79Br为98.3%~104.9%,127I为96.5%~102.0%。  相似文献   

长江河口硼的测定及分布规律研究     

韩庆平  吴玲  奚建风  陈邦林 《海洋科学》1997,21(2):35-38

采用ＨＰＴＡ方法对长江口水中硼进行分析，并与姜黄素法进行比较，方法的标准偏差为０．００５，变动系数小于５％，对长江口水样分析结果与姜黄素法相比较，其相对误差为－０．４％。  相似文献   

Composition-Induced Variations in SIMS Instrumental Mass Fractionation during Boron Isotope Ratio Measurements of Silicate Glasses     

Martin Rosner  Michael Wiedenbeck  Thomas Ludwig 《Geostandards and Geoanalytical Research》2008,32(1):27-38

An analytical artefact is reported here related to differences in instrumental mass fractionation between NIST SRM glasses and natural geological glasses during SIMS boron isotope determinations. The data presented demonstrated an average 3.4‰ difference between the NIST glasses and natural basaltic to rhyolitic glasses mainly in terms of their sputtering-induced fractionation of boron isotopes. As no matrix effect was found among basaltic to rhyolitic glasses, instrumental mass fractionation of most natural glass samples can be corrected by using appropriate glass reference materials. In order to confirm the existence of the compositionally induced variations in boron SIMS instrumental mass bias, the observed offset in SIMS instrumental mass bias has been independently reproduced in two laboratories and the phenomenon has been found to be stable over a period of more than one year. This study highlights the need for a close match between the chemical composition of the reference material and the samples being investigated.  相似文献   

Boron isotopic geochemistry of karst groundwater in Guiyang City, China     

Wei ZHANG Congqiang LIU Zhiqi ZHAO 《中国地球化学学报》2006,25(B08):172-172

Boron has two stable isotopes （^10B and ^11B） with relative abundances of about 20% and 80%, respectively. Boron isotopic ratios in natural materials show a huge range of variations, from -70‰ to ＋60‰, when expressed with the classical δ^11B notation. Most of these isotopic variations occur at the surface of the Earth. Hence, boron isotopic composition can be used as a sensitive tracer in geochemical study, for instance, to identify the different sources of contamination and factors controlling the salinity of groundwater. During the last decade, boron isotopes have been used to discriminate between the influences of seawater intrusion and anthropogenic discharge. But few of those researches can precisely identify the different sources of contamination. We measured the boron concentrations and boron isotopic ratios of groundwater samples collected in Guiyang City, as well as the major ions. The results indicate that the major ion composition of the groundwater in the investigated area is mainly controlled by the interactions between water and the dominant rock i.e. carbonates. All the water compositions are characterized by high concentrations of Ca^2＋, Mg^2＋, HCO3^-, SO4^2-, and NO3^-, which are the dominant contaminants. Both dissolved boron concentrations and isotopic ratios show large variations among the ground waters, from 2 μg/L to 90 μg/L and from -6‰ to ＋26‰, respectively. The boron concentrations and isotopic ratios indicate that the river across the studied city has been seriously contaminated by urban discharge. Boron concentrations of fiver water samples varied from 20 μg/L to 140 μg/L, with an average δ^11B value of ＋2.0‰. Using boron isotopic compositions and different geochemical indices allowed us to clearly identify and distinguish the two major sources of contamination, agricultural activity and urban wastewater. Both of the two sources are characterized by high boron concentrations but their boron isotopic compositions significantly differ.  相似文献   

锶,硼和氟联合作用的亚急性毒理实验及环境意义   总被引：1，自引：0，他引：1  

章敏  张景荣 《高校地质学报》1997,3(4):405-410

本文以自由饮水给药方式进行了锶、硼和氟联合作用的亚急性实验，以探讨锶、硼对氟的拮抗作用。实验结果，给予小鼠200×l0^-6 F 六个月后，可使其骨氟含量显著升高(P<0.01)，肾碱性磷酸酶活力(ALP)显著增高(P<0.01)，4、5个月后血清碱性磷酸酶(ALP)活力亦显著增高(P<0.O1)，同时给予80×l0^-1 B3+、100×l0^-6Sr2+ 时，可以显著降低骨氟含量，抑制血清、肾碱性磷酸酶的活力，表明锶与硼对氟存在拮抗作用。  相似文献   

四川成都盆地某深层富钾卤水的地球化学特征及成因   总被引：7，自引：0，他引：7  

黄思静  曾允孚 《沉积学报》1997,15(3):67-71

本文报道了四川成都盆地某深层富钾层卤水的化学组成，氧、氢、硫和硼同位素组成以及２５℃等温蒸发析盐过程中，从卤水中获得的固相物质组成。在此基础上讨论了卤水的成因，认为该卤水是蒸发浓缩的海相卤水、非海相卤水以及埋藏成岩过程中封存卤水对地层中海相蒸发盐溶滤作用形成的混合水。  相似文献   

发射光谱载体蒸馏法测定地质样品中微量硼铍锡银   总被引：2，自引：2，他引：2  

李滦宁  赵淑杰  王烨 《岩矿测试》2004,23(1):30-32

选择了适合的缓冲剂,利用载体蒸馏法将被测元素与基体元素分离,使Be转变为易挥发的氟化物与B、Sn、Ag同时蒸发;降低了谱线背景及元素检出限;加入内标元素Au、Bi,提高了方法的准确度和精密度;采用普通 3mm×3mm×0.7mm杯型电极,装样量少,操作简单。方法检出限(wB/10-6)分别可达B1.5、Be0.3、Sn0.8、Ag0.02;准确度(Δlog C)基本在-0.05～0.05,精密度(RSD,n=8)为2.9%～17%。  相似文献   

湘南地区芙蓉锡矿床中硼矿化的发现及意义     

李小赛  李厚民  李立兴  沈宏飞 《矿床地质》2021,40(6):1351-1356

硼矿是中国重要的紧缺矿产,长期依赖进口,找寻新的硼矿资源迫在眉睫.笔者在湘南地区芙蓉锡矿床新发现了矽卡岩型硼矿化,硼矿物包括硼镁铁矿、遂安石和氟硼镁石,1件典型样品的X射线粉晶衍射分析结果表明硼矿物总含量达到47.4％,换算成w(B)(以B2O3计)约为9.5％,高于5％的硼矿最低工业品位.该发现预示着湘南地区,乃至华南与高分异花岗岩有关的钨锡多金属矿集区有良好的硼成矿潜力,在今后的找矿过程中,需加强与钨锡多金属共伴生的硼矿化评价工作.  相似文献   

东山峰背斜寒武系地层中硼锂元素的指相意义     

黄晶莹 《湖南地质》1994,13(2):71-74

东山峰背斜寒武系地层分布区内，Ｂ，Ｌｉ元素的水系沉积物测量平均值分别为１７７．７８×１０－６、２２０．０×１０－６，衬值分别为２．３２、５．０７，Ｒｂ／ｋ比值为０．００６２。这些地球化学特征具典型的指相意义，反映出本区在早寒武世晚期至中、晚寒武世期间为一高盐度、强蒸发的泻湖相沉积环境，可与现代盐湖相环境类比。  相似文献   

硅硼镁铝矿－柱晶石－电气石组合在南极的发现          下载免费PDF全文

任留东  刘小汉 《极地研究》1994,6(1):4-10

硅硼镁铝矿、柱晶石和电气石组合产于东南极拉斯曼丘陵，三种矿物相互接触并表现出特定的顺序：电气石（Ｔｒｎ１）→硅硼镁铝矿→电气石（Ｔｒｎ２）→柱晶石→电气石（Ｔｒｎ３），表明其产出是受Ｂ２Ｏ３、Ｈ２Ｏ活度的时间演化而不是空间变化所控制。这一组合的出现对于变质作用环境及过程中组分性质是一个很好的限定  相似文献