Petrochronology of oxidized granulites from southern Peru     

Chris Yakymchuk  Adrian Rehm  Zhuoheng Liao  John M. Cottle 《Journal of Metamorphic Geology》2019,37(6):839-862

Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks.  相似文献   

冰碛扇型砂金矿床特征及其成矿初探     

杨文智 《河南国土资源》1997,(2)

成生于冰碛扇内，经一定的生物、物理、化学成矿作用，以砂金形态分布而富集成矿的金矿称为冰碛扇型砂金矿床。它具有沿造山带一定标高范围成群、成带分布，沉积物为近源且半胶结，砂金呈面状分布，并以粒金、块金为主，具胶状、浑圆状、包块状构造形态，分布极不均匀等特征。冰碛扇型砂金矿床的成矿作用与河成砂金矿床有本质的区别。它的成矿作用模式是：造山带下地壳富含的活化金通过新构造运动活化的断裂运移地表，经地下流体和地表流体的迁移聚集到冰碛扇这一封闭稳定的生物、物理、化学障环境中，主要经高效聚金微生物有机胶体成矿作用沉淀、再生加大形成砂金，逐步富集成矿床。而红色磨拉石建造中风化离解的Ｆｅ，Ｍｎ物质对沉淀环境ｐＨ值起着一定的调节作用。冰碛扇型砂金矿床在我国西部造山带内广泛分布，具有一定的工业价值，是砂金矿床中一重要类型，应予以重视  相似文献   

Anthropogenic trace metals in an ice core at Vestfonna,Svalbard, Norway     

Sumito Matoba  Hideaki Motoyama  Hideki Narita  Okitsugu Watanabe 《极地研究(英文版)》2003,14(1)

1　IntroductionAnicecoreobtainedfrom polarglaciersoricesheetsisoneofthemostimportantarchivestoreconstructpaleoclimaticandpaleoatmosphericcondition .Informationonpale o environmentcanbeextractedfromicecoresaschemicaland/orphysicalsignals.Amongthechemicalsignals,heavymetalsarenotedassignalsofterrestrialenvironmentalchangeandanthropogenicpollution (e.g .Murozumietal.1 969;NgandPatterson 1 981 ;Hongetal.1 994) .SinceconcentrationsofmostofthemetalsinpolarsnowincentralGreen landareatorbelowthepptl…  相似文献   

青海省沙柳河南区有色金属矿成矿物质来源及矿床成矿模式探讨     

马永铨  姜洪成 《青海国土经略》1994,(1)

本文简述了沙柳河南区有色金属矿床的基本特征。通过对成矿热液及成矿物质的来源与性质的研究,认为该矿床的成因类型为火山沉积—接触交代改造叠加型,进而探讨了该矿床的成矿模式。  相似文献   

Ab initio infra-red spectra of iron-polycyclic aromatic hydrocarbon compounds: a model case     

《Planetary and Space Science》2002,50(9):871-876

C₁₀H₆-Fe⁺ complexes were observed by Fourier transform mass spectrometry by Marty et al. (Chem. Phys. Lett. 256 (1996) 669). In this article, we present the infra-red (IR) spectra of the two isomers calculated by ab initio methods of quantum chemistry. In the past, the same approach has predicted successfully unexpected features of the IR spectra of polycyclic aromatic hydrocarbon (PAH) cations which were confirmed by measurements in matrices (J. Phys. Chem. 98 (1994) 9187). The C₁₀H₆-Fe⁺ systems are models for larger PAHs-Fe⁺ complexes, which are believed to play a key rôle in space chemistry.  相似文献   

Accumulation of Zn,Cu and Cd by crabs and barnacles     

P.S. Rainbow 《Estuarine, Coastal and Shelf Science》1985,21(5):669-686

The crab Carcinus maenas (L.) and the barnacle Elminius modestus Darwin were exposed to a range of dissolved concentrations of Zn, Cu and Cd for 21 days in artificial seawater. Accumulation of Zn and Cu by crabs has been interpreted in terms of the presence of a regulation mechanism to maintain constant body concentrations (83·2 ± 19·4 μg Zn g^?1 dry wt.; 39·8 ± 9·8 μg Cu g^?1 dry wt.) under varying external dissolved metal levels, until a threshold dissolved metal concentration (c. 400 μg Zn l^?1; c. 170 μg Cu l^?1) beyond which net accumulation of metal begins. Cadium appears to be accumulated by C. maenas at all exposures with no evidence for regulation of body cadmium concentrations. Exposure of E. modestus to Zn, Cu or Cd caused net accumulation of the respective metal in the bodies of the barnacles, with no evidence for regulation of body metal concentrations.  相似文献   

广西芒场锡多金属矿田稳定同位素组成对矿床成因探讨     

邹锡青  王思源 《南方国土资源》1993,(2)

笔者曾对广西芒场锡多金属矿田的稳定同位素进行研究。本文根据硫、铅、氢、氧、碳等稳定同位素组成和锶的初始值提供的信息.探讨了矿床成因。并结合矿田矿床地质特征、控矿条件及有关统计参数,参考前人对矿床认识的基础上,修正提出了该矿田混合热液成矿模式,可供类似矿床研究和找矿的参考。  相似文献   

A numerical investigation of the destruction of peroxy radical by Cu ion catalysed reactions on atmospheric particles     

Howard B. Ross  Kevin J. Noone 《Journal of Atmospheric Chemistry》1991,12(2):121-136

To determine if Cu mediated reactions on atmospheric particles are important to HO₂ chemistry in the ambient atmosphere, Cu molalities were calculated from measured Cu aerosol particle concentrations, mass and number size distribution data from a site in central Sweden. A comparison of characteristic times indicates that at low relative humidities the reaction is limited by the mass transport of gas phase HO₂ to the particle surface and not by the chemical kinetics of the aqueous reaction. Comparison of half-lives for particle reactions and the gas phase destruction of HO₂ to form H₂O₂ indicate that heterogeneous reactions on aerosol particles may have important consequences on the chemistry of HO₂ and H₂O₂ in the troposphere.  相似文献   

Detailed <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of geologic events associated with the Mantos Blancos copper deposit,northern Chile     

Verónica Oliveros  Gilbert Féraud  Luis Aguirre  Luis Ramírez  Michel Fornari  Carlos Palacios  Miguel Parada 《Mineralium Deposita》2008,43(3):281-293

The ⁴⁰Ar/³⁹Ar geochronological method was applied to date magmatic and hydrothermal alteration events in the Mantos Blancos mining district in the Coastal Cordillera of northern Chile, allowing the distinction of two separate mineralization events. The Late Jurassic Mantos Blancos orebody, hosted in Jurassic volcanic rocks, is a magmatic-hydrothermal breccia-style Cu deposit. Two superimposed mineralization events have been recently proposed. The first event is accompanied by a phyllic hydrothermal alteration affecting a rhyolitic dome. The second mineralization event is related to the intrusion of bimodal stocks and sills inside the deposit. Because of the superposition of several magmatic and hydrothermal events, the obtained ⁴⁰Ar/³⁹Ar age data are complex; however, with a careful interpretation of the age spectra, it is possible to detect complex histories of successive emplacement, alteration, mineralization, and thermal resetting. The extrusion of Jurassic basic to intermediate volcanic rocks of the La Negra Formation is dated at 156.3 ± 1.4 Ma (2σ) using plagioclase from an andesitic lava flow. The first mineralization event and associated phyllic alteration affecting the rhyolitic dome occurred around 155–156 Ma. A younger bimodal intrusive event, supposed to be equivalent to the bimodal stock and sill system inside the deposit, is probably responsible for the second mineralization event dated at ca. 142 Ma. Other low-temperature alteration events have been dated on sericitized plagioclase at ca. 145–146, 125, and 101 Ma. This is the first time that two distinct mineralization events have been documented from radiometric data for a copper deposit in the metallogenic belt of the Coastal Cordillera of northern Chile. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

西藏驱龙超大型斑岩铜矿床:地质、蚀变与成矿   总被引：54，自引：17，他引：37  

杨志明  侯增谦  宋玉财  李振清  夏代详  潘凤雏 《矿床地质》2008,27(3):279-318

驱龙超大型矿床是一个产于后碰撞伸展环境下、与大洋俯冲无关的新型斑岩铜矿。文章通过对驱龙铜矿床地质、蚀变与矿化的详细研究,建立了驱龙中新世岩浆演化序列,初步查明了岩浆浅成侵位的构造控制要素,厘定了主要的围岩蚀变类型及空间展布规律,查明了引起各期蚀变事件的地质记录及矿化的空间分布规律,并探讨了成矿物质沉淀的机制,初步建立了该矿床的成矿模型。研究表明,驱龙铜矿中新世斑岩是闪长质深部岩浆房不断演化的产物,花岗闪长岩中新发现的、结晶时间为22.2Ma左右的闪长质包体可近似代表深部岩浆房组分,依次产出的花岗闪长岩、呈岩株或岩枝产出的P斑岩、X斑岩及最晚期的闪长玢岩(15.7±0.2)Ma,均为深部岩浆房连续演化的产物,岩浆持续6Ma左右。岩浆演化过程中角闪石、斜长石不断的结晶分异,导致了岩石常量元素、稀土元素及微量元素组成的规律性变化,斑岩埃达克质的特征也因岩浆演化过程中角闪石等矿物的不断结晶分异而引起。X斑岩中锆石的Hf同位素特征表明,岩石可能形成于新生下地壳的部分熔融。大面积产出的花岗闪长岩为驱龙铜矿最主要的含矿围岩,容纳了驱龙矿床70%以上的矿体,主要由斜长石、钾长石和石英组成,具花岗结构-似斑状结构,近EW向产出,其浅成就位可能受背斜控制,其后的各期斑岩均沿该侵位中心上侵,而冈底斯地壳中新世的快速抬升与剥蚀是导致含矿斑岩浅成侵位的根本原因;矿区内的SN向裂隙带既不控岩,也不控矿。浅成侵位的斑岩及深部岩浆房均发生了流体出溶。发生了大量流体出溶的深部岩浆房,是矿区早期蚀变流体的主要来源,显微晶洞构造及单向固结结构(UST)是流体出溶的地质记录。蚀变主要有3种类型,分别为早期的钾硅酸盐化、青磐岩化以及晚期的长石分解。钾硅酸盐化可分为2个阶段,即蚀变矿物以次生钾长石为主的早期钾硅酸盐化和以次生黑云母为主的晚期钾硅酸盐化。青磐岩化因产出的岩石类型不同,蚀变矿物组合具有明显差异性:产于叶巴组地层中的青磐岩化相对较强,蚀变矿物以绿帘石为主;产于花岗闪长岩中的青磐岩化相对较弱,蚀变矿物以绿泥石为主。晚期长石分解蚀变以破坏长石类矿物为特征,蚀变矿物主要为绢云母-绿泥石-粘土等。石英和硬石膏贯穿于上述各种蚀变中。空间上,钾硅酸盐化位于斑岩体及其周围地区,青磐岩化位于钾硅酸岩化外侧。后期形成的长石分解蚀变强烈叠加了早期钾硅酸盐化,介于钾硅酸盐化带与青磐岩化带之间。与早期钾长石化有关的脉体主要为不规则石英-钾长石脉,与晚期黑云母化有关的脉体主要为不规则至板状的石英-硬石膏脉、黑云母脉,与青磐岩化有关的脉体主要为板状的绿帘石-石英脉,与晚期长石分解蚀变有关的脉体主要为板状黄铜矿-黄铁矿脉及黄铁矿脉;在早期钾硅酸盐蚀变与晚期长石分解蚀变转换阶段,发育一组板状的石英-硫化物脉。早期不规则的脉体形成于斑岩结晶早期、矿区裂隙小规模发育阶段;晚期的板状脉体形成于斑岩弱固结或固结之后、矿区大规模连通裂隙发育阶段。驱龙矿区的铜矿化分布较为均一,主体产于花岗闪长岩中,其中,铜矿化主体形成于黑云母化蚀变阶段,转变阶段及长石分解阶段也有大量铜的形成;钼主要形成于转换阶段,长石分解蚀变阶段也有产出。黑云母化阶段,铜的沉淀与角闪石黑云母化、斜长石钾长石化过程中Ca2 的大量释放有关;转换阶段,铜钼矿化可能与压力和(或)温度骤降有关;晚期铜矿化与长石矿化蚀变阶段,斜长石绿泥石化、黑云母绿帘石化过程中Ca2 及Fe2 的释放有关。  相似文献