Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N   总被引：1，自引：0，他引：1  

荣坤波  曾志刚  殷学博  陈帅  王晓媛  齐海燕  马瑶 《海洋学报(英文版)》2018,37(9):67-81

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.  相似文献   

Simulating methane emission from a Chinese rice field as influenced by fertilizer and water level     

Z. Yu  X. Shangguan  D. Pollard  E. J. Barron 《水文研究》2003,17(17):3485-3501

Natural and agricultural wetlands are considered to be the major sources of global atmospheric methane (CH₄). A one‐dimensional model was developed to simulate methane emission and used to examine the influence of various physical processes on the rate of methane emission. Three processes involved in the methane emission are implemented in the model: production, reoxidation and transport. Three transport pathways were considered: diffusion across water–air or soil–air interfaces, ebullition and diffusion through plants. These pathways are influenced by soil properties, plant growth, water‐table conditions, temperature and external inputs (e.g. fertilizer). The model was used to examine the seasonal variation of the methane emission at a rice field in Hunan, China, which was observed during a field experiment for consecutive (early and late) rice seasons in 1992. The observed seasonal variations of methane emission, and role of plants in transporting methane to the atmosphere, are captured by the model simulation. Further model applications were conducted to simulate effects of fertilizer and water‐level condition on the methane emission. The results indicate that unfermented organic fertilizer produces a higher methane emission rate than mineral fertilizer. The simulations with treatments of a deep‐water covering and constant moisture reduced the methane emission. The rice field study provides a framework for further development of the model towards simulations based on spatially distributed variables (e.g. water table, soil temperature and vegetation) at a regional scale. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Is Precipitation the Dominant Controlling Factor of High Inorganic Nitrogen Content in the Changjiang River and Its Mouth？   总被引：1，自引：1，他引：0  

沈志良 《中国海洋湖沼学报》2003,21(4):368-376

The main reasons for the high content of inorganic N and its increase by several times in the Changjiang River and its mouth during the last 40 years were analysed in this work. The inorganic N in precipitation in the Changjiang River catchment mainly comes from gaseous loss of fertilizer N, N resulting from the increases of population and livestock, and from high temperature combustions of fossil fuels. N from precipitation is the first N source in the Changjiang River water and the only direct cause of high content of inorganic N in the Changjiang River and its mouth. The lost N in gaseous form and from agriculture non-point sources fertilizer comprised about 60% of annual consumption of fertilizer N in the Changjiang River catchment and were key factors controlling the high content of inorganic N in the Changjiang River mouth. The fate of the N in precipitation and other N sources in the Changjiang River catchment are also discussed in this paper.  相似文献   

An Ecosystem Model Coupled with Nitrogen-Silicon-Carbon Cycles Applied to Station A7 in the Northwestern Pacific   总被引：1，自引：0，他引：1  

Yasuhiro Yamanaka  Naoki Yoshie  Masahiko Fujii  Maki N. Aita  Michio J. Kishi 《Journal of Oceanography》2004,60(2):227-241

A model based on that of Kishi et al. (2001) has been extended to 15 compartments including silicon and carbon cycles. This model was applied to Station A7 off Hokkaido, Japan, in the Northwestern Pacific. The model successfully simulated the observations of: 1. a spring bloom of diatoms; 2. large seasonal variations of nitrate and silicate concentrations in the surface water; and 3. large inter-annual variations in chlorophyll-a. It also reproduced the observed features of the seasonal variations of carbon dioxide partial pressure (pCO₂)—a peak in pCO₂ in winter resulting from deep winter convection, a rapid decrease in pCO₂ as a result of the spring bloom, and an almost constant pCO₂ from summer through fall (when the effect of increasing temperature cancels the effect of biological production). A comparison of cases with and without silicate limitation shows that including silicate limitation in the model results in: 1. decreased production by diatoms during summer; and 2. a transition in the dominant phytoplankton species, from diatoms to other species that do not take up silicate. Both of these phenomena are observed at Station A7, and our results support the hypothesis that they are caused by silicate limitation of diatom growth. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

硅酸盐细菌解钾作用机理的综合效应   总被引：44，自引：5，他引：44  

连宾  傅平秋  莫德明  刘丛强 《矿物学报》2002,22(2):179-183

硅酸盐细菌能释放土壤含钾硅酸盐矿物中的磷、钾、硅等元素，直接供给植物生长利用，同时亦具有固氮能力。这为挖掘土壤潜在肥力、发展可持续农业提供了一条新的思路。本文分析了硅酸盐细菌对钾长石、伊利石的解钾作用过程，细菌-矿物复合体的形成，细菌对矿物的溶蚀作用，矿物晶体结构与细菌的解钾作用关系，复合体微环境的变化对细菌解钾作用的影响以及细菌对K^ 的主动吸收等，从微生物矿物学的角度讨论了硅酸盐细菌对含钾硅酸盐矿物解钾作用的机理问题，提出了硅酸盐细菌解钾作用综合效应的看法，并就农业生产上的利用问题指出，应根据当地的土壤环境，选择适宜的生产菌种和吸附剂，并配合使用其它化学肥料和有机肥料。  相似文献   

中国化肥利用率的区域分异   总被引：77，自引：2，他引：77  

陈同斌  曾希柏  胡清秀 《地理学报》2002,57(5):531-538

据全国各县近10年的化肥施用量和粮食产量数据，并从不同年份单位播种面积粮食产量和肥料施用量的变化，求出相应不施肥产量和通过施肥可能达到的最高产量，并以上述结果为基础计算出该地区化肥利用率，研究结果表明：当前我国化肥施用的地区差异明显，施用量较集中范围是180－270kg/hm^2和90－180kg/hm^2，部分地区的化肥施用已经过量；单位化肥的粮食产出率主要集中在10－30kg/kg，化肥利用率大多集中在15％－35％，且与化肥施用量有关，按地区统计，高施肥量区化肥施用明显过量，平均达339kg/hm^2，是全国平均用量（262kg/hm^2)的1．29倍，中施肥量区单位面积化肥平均施用量为252kg/hm^2，略低于全国平均水平，低施肥量区则仅为178kg/hm^2，是全国平均的67．8％，我国单位化肥的生产效率及化肥利用率均以低施肥量区最高，分别为17．5kg/kg和39．8％，中施肥量区为13．7和36。  相似文献   

滇池农村固体废物和化肥流失治理试验研究   总被引：5，自引：1，他引：5  

戴丽  郭慧光  汤承彬  罗丽 《云南地理环境研究》2002,14(2):70-79

怎样合理处置农村固体废物和减少农田化肥流失一直是农村面源污染控制的难题之一。该研究将农村固体废物的处理与减少化肥施用措施有机结合，利用微生物复合发酵剂和农村固体废物生产活性肥料，开展了一系列农业种植试验和数据监测，在此基础上，提出了一套实用性强、效果好的控制农业固体废物和化肥流失污染的对策措施。  相似文献   

长效钾肥产业化与农业可持续发展     

钱发军  赵凤兰  邓挺  刘夏茹  豆来平 《地域研究与开发》2003,22(2):67-69

我国钾肥需求量逐年增加，80％需要进口，但同时又有大量的低品位非水溶性钾矿资源没有利用，利用非水溶性钾矿生产长效钾肥既能缓解钾肥短缺的矛盾，又可以解决普通钾肥对环境的污染和破坏。长效钾肥原料分布广，生产和施用技术简单，成本低，易于推广普及形成产业化，其对农业可持续发展将会产生重要的促进作用。  相似文献   

由膨润土提铝残渣直接合成五配位体有机硅化合物     

于少明  周爱萍  陆亚玲  李忠 《矿物学报》2003,23(4):355-358

研究了以膨润土提铝残渣为原料，采用低温加热法直接合成有机硅化合物新方法。由实验确定了最佳的合成条件。用红外光谱法和X射线衍射法分析了合成产物的结构。结果表明，当以碱金属氢氧化物为介质时，合成的产物为五配位体有机硅化合物；在最佳合成条件下，钠盐和锂盐的收率分别为63．0％和44．9％。  相似文献   

NHC硅化法及其应用   总被引：1，自引：0，他引：1  

尚继红 《岩土工程技术》2004,18(3):151-153

NHC硅化加固方法 ,已在数十项工程中推广应用 ,均取得满意效果 ,介绍了这一方法的作用原理及其特性 ,并列举了在几项工程中的应用实例。  相似文献