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1.
In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ18O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ18O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ18O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ18O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ18O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.  相似文献   
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Understanding changes in evapotranspiration during forest regrowth is essential to predict changes of stream runoff and recovery after forest cutting. Canopy interception (Ic) is an important component of evapotranspiration, however Ic changes and the impact on stream runoff during regrowth after cutting remains unclear due to limited observations. The objective of this study was to examine the effects of Ic changes on long-term stream runoff in a regrowth Japanese cedar and Japanese cypress forest following clear-cutting. This study was conducted in two 1-ha paired headwater catchments at Fukuroyamasawa Experimental Watershed in Japan. The catchments were 100% covered by Japanese coniferous plantation forest, one of which was 100% clear-cut in 1999 when the forest was 70 years old. In the treated catchment, annual runoff increased by 301 mm/year (14% of precipitation) the year following clear-cutting, and remained 185 mm/year (7.9% of precipitation) higher in the young regrowth forest for 12–14 years compared to the estimated runoff assuming no clear-cutting. The Ic change was −358 mm/year (17% of precipitation) after cutting and was −168 mm/year (6.7% of precipitation) in the 12–14 years old regrowth forest compared to the observed Ic during the pre-cutting period. Stream runoff increased in all seasons, and the Ic change was the main fraction of evapotranspiration change in all seasons throughout the observation period. These results suggest that the change in Ic accounted for most of the runoff response following forest cutting and the subsequent runoff recovery in this coniferous forest.  相似文献   
3.
Soil salinization, caused by salt migration and accumulation underneath the soil surface, will corrode structures. To analyze the moisture-salt migration and salt precipitation in soil under evaporation conditions, a mathematical model consisting of a series of theoretical equations is briefly presented. The filling effect of precipitated salts on tortuosity factor and evaporation rate are taken into account in relevant equations. Besides, a transition equation to link the solute transport equation before and after salt precipitation is proposed. Meanwhile, a new relative humidity equation deduced from Pitzer ions model is used to modify the vapor transport flux equation. The results show that the calculated values are in good agreement with the published experimental data, especially for the simulation of volume water content and evaporation rate of Toyoura sand, which confirm the reliability and applicability of the proposed model.  相似文献   
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Microbial degradation technologies have been developed to restore ground water quality in aquifers polluted by organic contaminants effectively in recent years. However, in course of the degradation, the formation of biofilms in ground water remediation technology can be detrimental to the effectiveness of a ground water remediation project. Several alternatives are available to a remedial design engineer, such as Permeable Reactive Barriers (PRBs) and in -situ bioremediation, Hydrogen Releasing Compounds (HRCs) barrier, Oxygen Releasing Compounds (ORCs) barrier etc. which are efficient and cost- effective technologies. Excessive biomass formation renders a barrier ineffective in degrading the contaminants, Efforts are made to develop kinetics models which accurately determine bio - fouling and bio - filn formation and to control excessive biomass formation.  相似文献   
5.
《Astroparticle Physics》2002,16(4):183-386
Frequency distributions of local muon densities in high-energy extensive air showers (EAS) are presented as signature of the primary cosmic ray energy spectrum in the knee region. Together with the gross shower variables like shower core position, angle of incidence, and the shower sizes, the KASCADE experiment is able to measure local muon densities for two different muon energy thresholds. The spectra have been reconstructed for various core distances, as well as for particular subsamples, classified on the basis of the shower size ratio Nμ/Ne. The measured density spectra of the total sample exhibit clear kinks reflecting the knee of the primary energy spectrum. While relatively sharp changes of the slopes are observed in the spectrum of EAS with small values of the shower size ratio, no such feature is detected at EAS of large Nμ/Ne ratio in the energy range of 1–10 PeV. Comparing the spectra for various thresholds and core distances with detailed Monte Carlo simulations the validity of EAS simulations is discussed.  相似文献   
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The kinetics of the reactions of C2H radical with ethane (k1), propane (k2), and n-butane (k3) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C2H decay profiles in the presence of both the alkane reactant and O2 are monitored by the CH(A2Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k1(T) = (0.51 ± 0.06) × 10−10 exp[(−76 ± 30)K/T] cm3 molecule−1 s−1 (T = 96-800 K), k2(T) = (0.98 ± 0.32) × 10−10exp[(−71 ± 60)K/T] cm3 molecule−1 s−1 (T = 96-361 K), and k3(T) = (1.23 ± 0.26) × 10−10 cm3 molecule−1 s−1 (T = 96-297 K). At T = 296 K, k1 is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   
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