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对美国近年来有关溴及其产品的生产研发情况进行了评述。包括原料资源,生产厂家,装置能力,近期统计资料,消耗构成,Albemarle’s真空提溴技术,国际合作项目,溴系阻燃剂,溴系杀生剂,完井液和重点含溴农药等,并展望了发展前景。 相似文献
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离子色谱法测定岩石,土壤,水系沉积物等样品中的氯,溴,碘 总被引:1,自引:0,他引:1
本文采用碳酸钠一氧化锌烧结法分解样品,利用DIONEX2020i离子色谱仪,电导、电化学检测器,建立了一测定岩石等样品中氯、溴、碘的分析流程。实验表明,本方法选择性好,灵敏度高,检出限分别为:氯1.03×10~(-6)、溴0.012×10~(-6)、碘0.014×10~(-6)。 相似文献
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以乙腈为溶剂,在H2O2存在下,以双酚A、溴为原料制备了四溴双酚A,讨论了加料方式、搅拌速率、n(Br2)/nBPA、反应温度、氧化剂的滴加速度等工艺条件对制取四溴双酚A产率的影响。在选定的实验条件下制取四溴双酚A的产率可达95.2%。 相似文献
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报导合成了四种新的单取代苯甲酸多溴代芳酯:4-溴苯甲酸-2',4',6'-三溴苯酯,双(4-溴苯甲酸)-2',3',5',6'-四溴-1',4'-苯二酯,双(4-羟基苯甲酸)-2',3'5',6'-四溴-1',4'-苯二酯和双(2-羟基苯甲酸)-2',3',5',6'-四溴-1',4'-苯二酯。 相似文献
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利用土壤环境中溴元素资源 76 7个数据和癌症死亡调查资料 7870 80例 ,研究了癌症死亡率与人群生存区土壤环境中溴元素的关系。结果表明 ,食道癌、肝癌、宫颈癌、鼻咽癌死亡率与溴元素有相关性 ,等级相关系数分别为- 0 4 333(P <0 0 1) ,0 4 837(P <0 0 0 5 ) ,- 0 4 0 4 7(P <0 0 2 5 ) ,0 5 2 0 7(P <0 0 0 2 5 )。 相似文献
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Alexandre Raphael Cabral Harilaos Tsikos Yasuyuki Muramatsu Tomoko Sekiya 《Chemie der Erde / Geochemistry》2011,71(3):297-301
A reconnaissance bulk geochemical study was carried out on ten samples from the Palaeoproterozoic Hotazel iron formation, South Africa, with emphasis on iodine and bromine abundances. Very low-absolute contents recorded for both halogens, i.e. 0.08–0.26 μg/g for I and 0.35–1.23 μg/g for Br, indicate that they should largely have been lost during burial diagenesis. Bulk I/Br ratios (0.08–0.50), however, show marginal variation across the selected sample set and broadly resemble those that typify recent marine sediments containing organic matter. The possibility emerges that both elements are organic matter-sourced and may thus provide a potential proxy for the role of biological processes during deposition and diagenesis of Precambrian iron formations. 相似文献
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Sediment geochemistry in coastal maritime Antarctica (Admiralty Bay, King George Island): Evidence from rare earths and other elements 总被引:1,自引:0,他引:1
Isaac R. Santos Dborah I.T. Fvaro Carlos E.G.R. Schaefer Emmanoel V. Silva-Filho 《Marine Chemistry》2007,107(4):464-474
We report the concentrations of 22 elements in short coastal sediment cores of Admiralty Bay (King George Island, Antarctica) determined by Neutron Activation Analysis. We focus the discussion on rare earth elements (REE) because their fractionation patterns in sediments relative to local sources may offer insights about weathering, transportation, deposition, and diagenetic processes. We found strong correlations between REE and Th, indicating detrital origin. Despite strong Eh gradients, the Th-normalized redox-sensitive elements (e.g., Eu, Ce, Fe, As, and others) showed little variability within the sedimentary environment. The exceptions were U (depleted in the upper few centimeters) and Br (enriched in the upper few centimeters). While U appears to be removed from seawater via uptake across the boundary of reducing sediments, the mechanisms driving Br accumulation are unclear, but perhaps related to increasing diatom production driven by regional warming. A comparison with published concentrations from rocks representing the regional eroding units showed that the characteristics of source rock could be recognized in the REE fractionation patterns in our sediments. These results imply no significant alteration during weathering and sediment transport in the coastal region of Admiralty Bay and the prevalence of strong periglacial erosion in ice-free areas of maritime Antarctica in spite of the relatively mild regional environmental setting (e.g., high moisture and high temperatures). 相似文献