Stability and chemical equilibrium of amphibole in calc-alkaline magmas: an overview, new thermobarometric formulations and application to subduction-related volcanoes   总被引：33，自引：9，他引：24  

Filippo Ridolfi  Alberto Renzulli  Matteo Puerini 《Contributions to Mineralogy and Petrology》2010,160(1):45-66

This work focuses on a rigorous analysis of the physical–chemical, compositional and textural relationships of amphibole stability and the development of new thermobarometric formulations for amphibole-bearing calc-alkaline products of subduction-related systems. Literature experimental results (550–1,120°C, <1,200 MPa, −1 ≤ ΔNNO ≤ +5), H₂O–CO₂ solubility models, a multitude of amphibole-bearing calc-alkaline products (whole-rocks and glasses, representing 38 volcanoes worldwide), crustal and high-P (1–3 GPa) mantle amphibole compositions have been used. Calcic amphiboles of basalt-rhyolite volcanic products display tschermakitic pargasite (37%), magnesiohastingsite (32%) and magnesiohornblende (31%) compositions with aluminium number (i.e. Al# = ^[6]Al/Al_T) ≤ 0.21. A few volcanic amphiboles (~1%) show high Al# (>0.21) and are inferred to represent xenocrysts of crustal or mantle materials. Most experimental results on calc-alkaline suites have been found to be unsuitable for using in thermobarometric calibrations due to the high Al# (>0.21) of amphiboles and high Al₂O₃/SiO₂ ratios of the coexisting melts. The pre-eruptive crystallization of consistent amphiboles is confined to relatively narrow physical–chemical ranges, next to their dehydration curves. The widespread occurrence of amphiboles with dehydration (breakdown) rims made of anhydrous phases and/or glass, related to sub-volcanic processes such as magma mixing and/or slow ascent during extrusion, confirms that crystal destabilization occurs with relatively low T–P shifts. At the stability curves, the variance of the system decreases so that amphibole composition and physical–chemical conditions are strictly linked to each other. This allowed us to retrieve some empirical thermobarometric formulations which work independently with different compositional components (i.e. Si^*, Al_T, Mg^*, ^[6]Al^*) of a single phase (amphibole), and are therefore easily applicable to all types of calc-alkaline volcanic products (including hybrid andesites). The Si^*-sensitive thermometer and the fO₂–Mg^* equation account for accuracies of ±22°C (σ_est) and 0.4 log units (maximum error), respectively. The uncertainties of the Al_T-sensitive barometer increase with pressure and decrease with temperature. Near the P–T stability curve, the error is <11% whereas for crystal-rich (porphyritic index i.e. PI > 35%) and lower-T magmas, the uncertainty increases up to 24%, consistent with depth uncertainties of 0.4 km, at 90 MPa (~3.4 km), and 7.9 km, at 800 MPa (~30 km), respectively. For magnesiohornblendes, the ^[6]Al^*-sensitive hygrometer has an accuracy of 0.4 wt% (σ_est) whereas for magnesiohastingsite and tschermakitic pargasite species, H₂O_melt uncertainties can be as high as 15% relative. The thermobarometric results obtained with the application of these equations to calc-alkaline amphibole-bearing products were finally, and successfully, crosschecked on several subduction-related volcanoes, through complementary methodologies such as pre-eruptive seismicity (volcano-tectonic earthquake locations and frequency), seismic tomography, Fe–Ti oxides, amphibole–plagioclase, plagioclase–liquid equilibria thermobarometry and melt inclusion studies. A user-friendly spreadsheet (i.e. AMP-TB.xls) to calculate the physical–chemical conditions of amphibole crystallization is also provided.  相似文献   

Temperature induced decoupling of enzymatic hydrolysis and carbon remineralization in long-term incubations of Arctic and temperate sediments     

Alberto Robador  Volker Brüchert  Carol Arnosti 《Geochimica et cosmochimica acta》2010,74(8):2316-2326

Extracellular enzymatic hydrolysis of high-molecular weight organic matter is the initial step in sedimentary organic carbon degradation and is often regarded as the rate-limiting step. Temperature effects on enzyme activities may therefore exert an indirect control on carbon mineralization. We explored the temperature sensitivity of enzymatic hydrolysis and its connection to subsequent steps in anoxic organic carbon degradation in long-term incubations of sediments from the Arctic and the North Sea. These sediments were incubated under anaerobic conditions for 24 months at temperatures of 0, 10, and 20 °C. The short-term temperature response of the active microbial community was tested in temperature gradient block incubations. The temperature optimum of extracellular enzymatic hydrolysis, as measured with a polysaccharide (chondroitin sulfate), differed between Arctic and temperate habitats by about 8-13 °C in fresh sediments and in sediments incubated for 24 months. In both Arctic and temperate sediments, the temperature response of chondroitin sulfate hydrolysis was initially similar to that of sulfate reduction. After 24 months, however, hydrolysis outpaced sulfate reduction rates, as demonstrated by increased concentrations of dissolved organic carbon (DOC) and total dissolved carbohydrates. This effect was stronger at higher incubation temperatures, particularly in the Arctic sediments. In all experiments, concentrations of volatile fatty acids (VFA) were low, indicating tight coupling between VFA production and consumption. Together, these data indicate that long-term incubation at elevated temperatures led to increased decoupling of hydrolytic DOC production relative to fermentation. Temperature increases in marine sedimentary environments may thus significantly affect the downstream carbon mineralization and lead to the increased formation of refractory DOC.  相似文献   

The economics of boldness: equity,action, and hope     

José Alberto Garibaldi 《Climate Policy》2014,14(1):82-101

Equity is usually interpreted in terms of the concept of justice, such that an equitable share of the atmospheric space is understood in terms of past emissions. This emphasizes the collective nature of sharing the burden of mitigation and the duty to act for those who have emitted the most. An alternative is considered: the aggregate costs and benefits to all Parties that could result from both increasing the level of collective ambition and implementing a climate regime that supports bold actions across all Parties. The regional impacts and carbon flow costs across differentiated scenarios are assessed and it is argued that the majority of developing-country Parties would be better off if a high ambition outcome to which all contributed, but some more than others. Moreover, those with middle or low emissions would have proportionally more to gain (or lose) relative to the level of ambition compared to those that have had higher emissions. The climate regime should be built on the principle of common but differentiated responsibility and respective capabilities (CBDR&RC), in which all act early even if some do much more; one that accounts for justice but does not forget hope.

Policy relevance

Differing interpretations of equity and the principles of the United Nations Framework Convention on Climate Change (UNFCCC) are discussed, with a focus on how these can enhance or hinder collective action. Whilst the climate change negotiations are usually taken as games in which one party gains and another loses, and interactions are dogged by continuous conflict, it is explored instead how negotiation responses can be framed in terms of cooperation. This would emphasize the gains that could be achieved by common but differentiated collective action, which could result in a collective avoidance of impacts. The possibilities that this shift of perspective could bring are explored by comparing costs under global cooperation (or lack of it). It is found that cooperation reduces the total costs for these regions. Thus, thinking in terms of cooperation focuses the options for negotiation on the means and interpretations of the UNFCCC principles that spur action and avoid climate impacts through collective action.  相似文献   

Description of soils based on geomechanical criteria for improved landslide classification     

Gianfrancesco Rocchi  Giovanni Vaciago  Alberto Callerio  Maurizio Fontana  Riccardo Previtali 《Landslides》2014,11(5):813-825

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Using distributed temperature sensing (DTS) technology in acid gas injection design     

Liaqat Ali  Russell E. Bentley  Alberto A. Gutierrez  Yosmar Gonzalez 《Acta Geotechnica》2014,9(1):135-144

The use of slickline distributed temperature sensing (SL-DTS) technology is becoming widespread due to its ease of operation and ability to acquire real-time multiple temperature traces inside the wellbore. Injection of treated acid gas (TAG)—a mixture of CO₂ and H₂S—into geologic formations has become an attractive technical and economic option for oil and gas producers and processors who are faced with regulations concerning excess sulfur and greenhouse gas emissions. Acid gas injection (AGI) into geologic formations is more economical and more flexible in dealing with varying TAG compositions than sulfur recovery units (SRUs) using the Claus process. SRUs do not achieve air quality standards and have high operation and maintenance costs. In addition, there is low demand for sulfur and sulfur disposal costs are high. The results of the analysis of SL-DTS data acquired in conjunction with step rate and pressure falloff (PFO) tests are presented in this paper. These tests were conducted to evaluate the injection potential of geologic formations. The injection zone consisted of a carbonate formation characterized by Karst features, vugs, and natural fractures. The SL-DTS data during the initial injection flow rate for the step rate test (SRT) indicated that high permeability zones accepted fluid at lower injection rates. An increasing number of discrete zones began to accept fluid as the injection rate was increased. The results of the SRT provided the fracture pressure of the formation. This information was used to design an AGI program that would avoid fracturing the formation while allowing for the required volume of TAG to be injected. The results of the PFO test provided information on the reservoir pressure and permeability and also indicated the presence of one or more hydraulic fractures. This case study of SL-DTS measurements made during a SRT and a PFO test for the design of an AGI well provides valuable insights into the potential of DTS technology and its use in AGI and carbon capture/sequestration (CCS) operations. Its findings could be applied to analyze injection potential of geological formations not only for AGI projects but also for CCS, and CO₂ enhanced oil recovery opportunities.  相似文献   

Technical, financial and location criteria for the design of land application system treatment     

Juana María Sanz  Ángel de Miguel  Irene de Bustamante  Alberto de Tomás  José Luis Goy 《Environmental Earth Sciences》2014,71(1):13-21

Conventional water treatments when downsized to cover the demands of small and scattered populations are costly and ineffective. In fact, many small towns cannot afford the high average treatment costs nor provide the skill and complex management requirements. Even when these facilities are available, waste water might not be properly treated. Land application system treatments (LAST) have been shown to be preferable on the basis of their technical effectiveness and financial viability. The recently approved Spanish regulations (RDL 1620/2007, pp 50369–50661) represent an opportunity for the implementation of well-designed LASTs. This paper presents an assessment methodology for the design of LASTs by combining technical, financial and location criteria. The method is applied to the design of LASTs to cover the water disposal demand of twelve municipalities located within the protected natural landscape, and surrounding areas of ‘El Rebollar’, Salamanca, Spain.  相似文献   

FTIR spectroscopy of Ti-chondrodite,Ti-clinohumite,and olivine in deeply subducted serpentinites and implications for the deep water cycle   总被引：1，自引：0，他引：1  

Tingting Shen  Jőrg Hermann  Lifei Zhang  José Alberto Padrón-Navarta  Jing Chen 《Contributions to Mineralogy and Petrology》2014,167(4):1-15

Separated olivine grains from a deeply subducted serpentinized wehrlite (Changawuzi in the western Tianshan ultrahigh-pressure belt, China) were analysed with unpolarized transmission FTIR and the Ti contents were determined using LA-ICP-MS. The major bands in the olivine spectra display striking similarities to Ti-clinohumite and are interpreted as OH in lamellae. The quantification of the water content in lamellae requires calibration of the IR-absorption for such bands. We have obtained a new absorption coefficient for Ti-clinohumite of 0.125+/?0.017 ppm cm² based on polarized FTIR measurements on three orthogonal sections through a large single crystal of Ti-clinohumite from Val Malenco, which has a known water content of 1.53 wt%. The resulting water content in olivine using this calibration factor ranges from 440 to 2,600 ppm and correlates positively with the Ti content that ranges from 130 to 1,400 ppm. For the quantification of the water content in Ti-chondrodite and Ti-clinohumite that are associated with olivine, we developed a new method using attenuated total reflectance FTIR spectroscopy. Ti-chondrodite and Ti-clinohumite display similar IR bands at ~3,562, 3,525 and ~3,583–3,586 cm^?1. As in olivine, the water content and Ti content correlate in both Ti-clinohumite and Ti-chondrodite, indicating an intergrowth of these minerals, which has been confirmed by TEM analyses. Our results confirm previous suggestions that there is a strong correlation between the Ti content of ultramafic rocks and their capacity to transport water to the deeper mantle in subduction zones beyond conditions where hydrous phases are stable.  相似文献   

Age and origin of the lowlands of Mars     

Alberto G Fairén  James M Dohm 《Icarus》2004,168(2):277-284

One of the many significant findings of the Mars Global Surveyor mission is the presence of hundreds of quasi-circular depressions (QCDs) observed from high-resolution MOLA topography data. Their presence has recently been interpreted to reflect a northern lowlands that archive some of the earliest recorded rocks on Mars, mostly below a veneer of Hesperian and Amazonian materials. Here we analyze these data, coupled with a recent synthesis of geologic, geophysical, geomorphic, topographic, and magnetic information. Such analysis allows us to suggest a potential plate tectonic phase during the recorded Early into Middle Noachian martian history that transitioned into a monoplate world with episodic magmatic-driven activity persisting to present. This working hypothesis is based on: (1) the observation that the basement of the northern plains is younger than the basement of the southern highlands, but older than the material exposures of the cratered highlands, suggesting different formational ages for each one of the three geologic-time units; (2) the observation that parts of the very ancient highland's crust are highly magnetized, thus suggesting that most if not all of the formation of the lowlands basement postdates the shut off of the martian dynamo, some 4 Gyr ago, and so allowing hundreds of millions of years for the shaping of the buried lowlands. Consequently, the role of endogenic processes in the earliest geological evolution of Mars (Early perhaps into Middle Noachian) requires reconsideration, since MOLA topographic and MGS magnetic data afford a temporal window sufficient for very early, non-primordial shaping of the northern lowlands' basement.  相似文献   

The marine Jurassic of Argentina： a biostratigraphic framework     

Alberto C. Riccardi 《《幕》》2008,31(3):326-335

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Putative Meteoritic Craters in Río Cuarto (Central Argentina) Interpreted as Eolian Structures     

Cione  Alberto L.  Tonni  Eduardo P.  San Cristóbal  Jorge  Hernández  Pedro J.  Benítez  Adrián  Bordignon  Fernando  Perí  Jorge A. 《Earth, Moon, and Planets》2002,91(1):9-24

Ten oblong aligned depressions in the Río Cuarto area (provincia de Córdoba, Argentina) were supposed to be the result of very-low-angle Holocene meteoroid impacts. However, we consider that authors that studied the structures did not demonstrated their extraterrestrial origin. We suggest that an eolian origin for the structures of Río Cuarto is more likely. Actually, these landforms integrate large systems of similar deflation/accumulation geoforms aligned according to predominant winds during different periods.  相似文献