Fluoride Biomonitoring around a Large Aluminium Smelter Using Foliage from Different Tree Species     

Judith Hebelen Rodriguez  Eduardo Daniel Wannaz  María Luisa Pignata  Andreas Fangmeier  Jürgen Franzaring 《洁净——土壤、空气、水》2012,40(12):1315-1319

In order to study the pollution gradient in the vicinity of a large aluminium production facility in Patagonia (Argentina), a passive biomonitoring was performed employing foliage from three tree species. Primary scope was to identify pollution gradients and to select suitable tree species which can be used as biomonitor plants in the study area. Therefore, leaves of Eucalyptus rostrata, Populus hybridus and different needle ages of Pinus radiata were collected at different distances from the industry and the fluoride concentration was analysed in washed and unwashed samples in order to determine the amount of external fluoride. Washing reduced the F‐concentrations by 24, 39 and 51% on average in E. rostrata, P. hybridus and P. radiata, respectively, indicating that species‐specific characteristics determine the accumulation and wash‐off of dust‐associated fluorine. F‐concentrations varied from 6 to 3652 ppm F in unwashed samples indicating a steep pollution gradient in the study area. The influence of F‐emissions was discernible in all samples up to a distance of 3500 m from the smelter. E. rostrata accumulated more fluorine than the other species at equal distance from the emission source. The present study confirms that aluminium smelting results in high F deposition in the study area. Establishing a biomonitor network around large emitters is suitable and feasible to evaluate the efficiency of air control measures.  相似文献   

Arctic freshwater ostracods from modern periglacial environments in the Lena River Delta (Siberian Arctic,Russia): geochemical applications for palaeoenvironmental reconstructions     

Sebastian?WetterichEmail author  Lutz?Schirrmeister  Hanno?Meyer  Finn?Andreas?Viehberg  Andreas?Mackensen 《Journal of Paleolimnology》2008,39(4):427-449

The aim of this study is to describe ostracods from freshwater habitats in the Siberian Arctic in order to estimate the present-day relationships between the environmental setting and the geochemical properties of ostracod calcite. A special focus is on the element ratios (Mg/Ca, Sr/Ca), and the stable isotope composition (δ¹⁸O, δ¹³C), in both ambient waters and ostracod calcite. The most common species are Fabaeformiscandona pedata and F. harmsworthi with the highest frequency in all studied waters. Average partition coefficients D(Sr) of F. pedata are 0.33 ± 0.06 (1σ) in females, and 0.32 ± 0.06 (1σ) in males. A near 1:1 relationship of δ¹⁸O was found, with a mean shift of Δ_mean = 2.2‰ ± 0.5 (1σ) to heavier values in ostracod calcite of F. pedata as compared to ambient waters. The shift is not dependent on δ¹⁸O_water, and is caused by metabolic (vital) and temperature effects. Temperature-dependence is reflected in the variations of this shift. For ostracod calcite of F. pedata a vital effect as compared to inorganic calcite in equilibrium was quantified with 1.4‰. Results of this study are valuable for the palaeoenvironmental interpretation of geochemical data of fossil ostracods from permafrost deposits.  相似文献   

Assessment of nutrient sources and paleoproductivity during the past century in Longgan Lake,middle reaches of the Yangtze River,China   总被引：3，自引：0，他引：3  

Yanhong Wu  Andreas Lücke  Sumin Wang 《Journal of Paleolimnology》2008,39(4):451-462

Total organic carbon (TOC), total nitrogen (TN) and total phosphorus (TP) were determined in combination with stable isotope ratios of carbon and nitrogen (δ¹³C_Org, δ¹⁵N) in a 63 cm sediment core from Longgan Lake, located in the middle reaches of the Yangtze River, China. These geochemical and isotopic records provide a continuous history of lake productivity and trophic state of Longgan Lake since 1890. Variations of δ¹³C_Org, TOC, TN and TP indicate that primary productivity of Longgan Lake increased continuously during the last century and that the trophic state of the lake shifted from oligotrophic to mestrotrophic conditions accordingly. Anthropogenic sources of organic carbon (OC), nitrogen (N) and phosphorus (P) were distinguished from their natural background in the sediments using mass accumulation rates. Element mass accumulation rates suggested increased human activities in the lake’s catchment since 1950s, were especially the utilization of artificial fertilizers amplified the anthropogenic input of N and P into the lake. In the course of the improved availability of dissolved nutrients also primary productivity of Longgan Lake increased, resulting in an increase of the Suess-effect corrected organic carbon isotope ratios. δ¹⁵N of bulk sediments show a marked shift towards lower values around 1950 that has been attributed to the input of nitrogen from chemical fertilizers characterized by relatively depleted isotopic signatures into the lake.  相似文献   

Sedimentological and ichnological implications of rapid Holocene flooding of a gently sloping mud‐dominated incised valley – an example from the Red River (Gulf of Tonkin)          下载免费PDF全文

Andreas Wetzel  Agata Szczygielski  Daniel Unverricht  Karl Stattegger 《Sedimentology》2017,64(5):1173-1202

The Gulf of Tonkin coastline migrated at an average rate of ca 60 m year^?1 landward during Holocene sea‐level rise (20 to 8 ka). Due to a combination of rapid coastline migration and undersupply of sand, neither coastal barriers nor tidal sand bars developed at the mouth of the Red River incised valley. Only a 30 to 80 cm thick sandy interval formed at the base of full‐marine deposits. Thus, the river mouth represented a mud‐dominated open funnel‐shaped estuary during transgression. At the base of the valley fill, a thin fluvial lag deposit marks a period of lowered sea‐level when the river did not reach geomorphic equilibrium and was thus prone to erosion. The onset of base‐level rise is documented by non‐bioturbated to sparsely bioturbated mud that occasionally contains pyrite indicating short‐term seawater incursions. Siderite in overlying deposits points to low‐salinity estuarine conditions. The open funnel‐shaped river mouth favoured upstream incursion of seawater that varied inversely to the seasonal strongly fluctuating discharge: several centimetres to a few tens of centimetres thick intervals showing marine or freshwater dominance alternate, as indicated by bioturbational and physical sedimentary structures, and by the presence of Fe sulphides or siderite, respectively. Recurrent short‐term seawater incursions stressed the burrowing fauna. The degree of bioturbation increases upward corresponding to increasing marine influence. The uppermost estuarine sediments are completely bioturbated. The estuarine deposits aggraded on average rapidly, up to several metres kyr^?1. Siphonichnidal burrows produced by bivalves, however, document recurrent episodes of enhanced deposition (>0·5 m) and pronounced erosion (<1 m) that are otherwise not recorded. The slope of the incised valley affected the sedimentary facies. In steep valley segments, the marine transgressive surface (equivalent to the onset of full‐marine conditions) is accentuated by the Glossifungites ichnofacies, whereas in gently sloped valley segments the marine transgressive surface is gradational and bioturbated. Marine deposits are completely bioturbated.  相似文献   

Environmental Radioxenon Levels in Europe: a Comprehensive Overview     

Paul R. J. Saey  Clemens Schlosser  Pascal Achim  Matthias Auer  Anders Axelsson  Andreas Becker  Xavier Blanchard  Guy Brachet  Luis Cella  Lars-Erik De Geer  Martin B. Kalinowski  Gilbert Le Petit  Jenny Peterson  Vladimir Popov  Yury Popov  Anders Ringbom  Hartmut Sartorius  Thomas Taffary  Matthias Zähringer 《Pure and Applied Geophysics》2010,167(4-5):499-515

Activity concentration data from ambient radioxenon measurements in ground level air, which were carried out in Europe in the framework of the International Noble Gas Experiment (INGE) in support of the development and build-up of a radioxenon monitoring network for the Comprehensive Nuclear-Test-Ban Treaty verification regime are presented and discussed. Six measurement stations provided data from 5 years of measurements performed between 2003 and 2008: Longyearbyen (Spitsbergen, Norway), Stockholm (Sweden), Dubna (Russian Federation), Schauinsland Mountain (Germany), Bruyères-le-Châtel and Marseille (both France). The noble gas systems used within the INGE are designed to continuously measure low concentrations of the four radioxenon isotopes which are most relevant for detection of nuclear explosions: ^131mXe, ^133mXe, ¹³³Xe and ¹³⁵Xe with a time resolution less than or equal to 24 h and a minimum detectable concentration of ¹³³Xe less than 1 mBq/m³. This European cluster of six stations is particularly interesting because it is highly influenced by a high density of nuclear power reactors and some radiopharmaceutical production facilities. The activity concentrations at the European INGE stations are studied to characterise the influence of civilian releases, to be able to distinguish them from possible nuclear explosions. It was found that the mean activity concentration of the most frequently detected isotope, ¹³³Xe, was 5–20 mBq/m³ within Central Europe where most nuclear installations are situated (Bruyères-le-Châtel and Schauinsland), 1.4–2.4 mBq/m³ just outside that region (Stockholm, Dubna and Marseille) and 0.2 mBq/m³ in the remote polar station of Spitsbergen. No seasonal trends could be observed from the data. Two interesting events have been examined and their source regions have been identified using atmospheric backtracking methods that deploy Lagrangian particle dispersion modelling and inversion techniques. The results are consistent with known releases of a radiopharmaceutical facility.  相似文献   

Rock slope instability assessment using spatially distributed structural orientation data in Darjeeling Himalaya (India)   总被引：1，自引：0，他引：1  

Saibal Ghosh  Andreas Günther  Emmanuel John M. Carranza  Cees J. van Westen  Victor G. Jetten 《地球表面变化过程与地形》2010,35(15):1773-1792

We discuss a geographic information system (GIS)‐based methodology for rock slope instability assessment based on geometrical relationships between topographic slopes and structural discontinuities in rocks. The methodology involves (a) regionalization of point observations of orientations (azimuth and dip) of structural discontinuities in rocks in order to generate a digital structural model (DStM), (b) testing the kinematical possibility of specific modes of rock slope failures by integrating DStMs and digital elevation model (DEM)‐derived slope and aspect data and (c) computation of stability scenarios with respect to identified rock slope failure modes. We tested the methodology in an area of 90 km² in Darjeeling Himalaya (India) and in a small portion (9 km²) within this area with higher density of field structural orientation data. The results of the study show better classification of rock slope instability in the smaller area with respect to known occurrences of deep‐seated rockslides than with respect to shallow translational rockslides, implying that structural control is more important for deep‐seated rockslides than for shallow translational rockslides. Results of scenario‐based analysis show that, in rock slopes classified to be unstable, stress‐induced rock slope instability tends to increase with increasing level of water saturation. The study demonstrates the usefulness of spatially distributed data of orientations of structural discontinuities in rocks for medium‐ to small‐scale classification of rock slope instability in mountainous terrains. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Diachronous isotopic and sedimentary responses to topographic change as indicators of mid‐Eocene hydrologic reorganization in the western United States     

Malinda L. Kent‐Corson  Andreas Mulch  Stephan A. Graham  Alan R. Carroll  Bradley D. Ritts  C. Page Chamberlain 《Basin Research》2010,22(6):829-845

Early Cenozoic terrestrial deposits in the western United States represent well‐preserved archives of climatic and tectonic processes that together shaped the Earth's surface during the demise of a large continental plateau. This study examines a Cenozoic terrestrial sedimentary sequence in the central part of the Cordilleran orogen (Montana) using sedimentologic and geochemical techniques. At ～49 Ma, we observe rapid major shifts in oxygen, carbon and strontium isotope records that are too large to directly reflect changes in meteoric water composition due to simple orographic rainout. The transition to low‐δ¹⁸O values in pedogenic carbonate in concert with changes in the composition of clastic material at ～49 Ma points to the input of evolved meteoric water to the hydrological cycle due to a change in the source of waters reaching Cordilleran intermontane regions in southwestern Montana. This drainage reorganization coincides with the initiation of magmatism and extension to the west in what is now Montana and Idaho. The sedimentological record shows evidence that depositional gradients increased in the study area ～46 Ma, ～3 Myr after the drainage reorganization occurred. This interval is most likely the time it took for extensional deformation to propagate to the study area itself. Evidence of freshening events in Laramide Basins to the southeast suggests that this drainage reorganization diverted waters to progressively fill these basins and highlights the impact of post‐plateau extension‐related landscape reorganization on river networks and lake dynamics. This study also emphasizes the importance of using multiple tools in deciphering topographic history through the study of terrestrial basin deposits, in that interpretation based on any single method employed would have compromised our ability to successfully identify the regional evolution of topography and drainage networks.  相似文献   

Seismic damage analysis including inelastic shear–flexure interaction     

Panagiotis E. Mergos  Andreas J. Kappos 《Bulletin of Earthquake Engineering》2010,8(1):27-46

The paper focusses on seismic damage analysis of reinforced concrete (R/C) members, accounting for shear–flexure interaction in the inelastic range. A finite element of the beam-column type recently proposed by the writers for the seismic analysis of R/C structures is first briefly described. The analytical model consists of two distributed flexibility sub-elements which interact throughout the analysis to simulate inelastic flexural and shear response. The finite element accounts for shear strength degradation with inelastic curvature demand, as well as coupling between inelastic flexural and shear deformations after flexural yielding. Based on this model, a seismic damage index is proposed taking into account both inelastic flexural and shear deformations, as well as their interaction. The finite element and the seismic damage index are used to analyse the response of R/C columns tested under cyclic loading and failing either in shear or in flexure. It is shown that the analytical model and damage index can predict and describe well the hysteretic response of R/C columns with different types of failure.  相似文献   

A deformation-based seismic design method for 3D R/C irregular buildings using inelastic dynamic analysis     

Andreas J. Kappos  Sotiria Stefanidou 《Bulletin of Earthquake Engineering》2010,8(4):875-895

A new deformation-based design method concerning 3D reinforced concrete (R/C) buildings is presented, which involves the use of advanced analysis tools, i.e. response-history analysis for appropriately scaled input motions, for multiple levels of earthquake action. The critical issues concerning the inelastic response-history analysis used for the design, namely the definition of the appropriate input, the set up of the analytical model that should account for post-yield behaviour of plastic hinge zones, and the direction of loading, are discussed. The proposed method is based on a partially inelastic model, while the design of structural members is carried out for different performance levels related to their inelastic behaviour. The aforementioned method builds on previous proposals by the first author and his co-workers, nevertheless a new procedure for the design of members that are expected to develop inelastic behaviour for the serviceability earthquake is proposed; its aim is the reduction of member design forces and the a-priori definition of their inelastic performance, by exploiting the deformation limits for the specific performance level, which are related to the damage level of the structural members. The proposed method was applied to irregular multistorey R/C 3D frame buildings with setbacks, and their performance for several levels of earthquake action was assessed using a fully inelastic model and additional ground motions not used at the design phase. The same buildings were designed according to the provisions of Eurocode 8. Comparison of the two methods of seismic design, revealed the advantages of the proposed design method, in particular the more economic detailing of transverse reinforcement in the members that develop very little inelastic behaviour even for very strong earthquakes.  相似文献   

What Can be Expected from the GRACE-FO Laser Ranging Interferometer for Earth Science Applications?     

Frank Flechtner  Karl-Hans Neumayer  Christoph Dahle  Henryk Dobslaw  Elisa Fagiolini  Jean-Claude Raimondo  Andreas Güntner 《Surveys in Geophysics》2016,37(2):453-470

The primary objective of the gravity recovery and climate experiment follow-on (GRACE-FO) satellite mission, due for launch in August 2017, is to continue the GRACE time series of global monthly gravity field models. For this, evolved versions of the GRACE microwave instrument, GPS receiver, and accelerometer will be used. A secondary objective is to demonstrate the effectiveness of a laser ranging interferometer (LRI) in improving the satellite-to-satellite tracking measurement performance. In order to investigate the expected enhancement for Earth science applications, we have performed a full-scale simulation over the nominal mission lifetime of 5 years using a realistic orbit scenario and error assumptions both for instrument and background model errors. Unfiltered differences between the synthetic input and the finally recovered time-variable monthly gravity models show notable improvements with the LRI, on a global scale, of the order of 23 %. The gain is realized for wavelengths smaller than 240 km in case of Gaussian filtering but decreases to just a few percent when anisotropic filtering is applied. This is also confirmed for some typical regional Earth science applications which show randomly distributed patterns of small improvements but also degradations when using DDK4-filtered LRI-based models. Analysis of applied error models indicates that accelerometer noise followed by ocean tide and non-tidal mass variation errors are the main contributors to the overall GRACE-FO gravity model error. Improvements in these fields are therefore necessary, besides optimized constellations, to make use of the increased LRI accuracy and to significantly improve gravity field models from next-generation gravity missions.  相似文献