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Thermal waters of northern (18°–27°S) and southern (37°–45°S) Chile occur in two very different climatic, geologic and hydrologic environments: arid closed basins with abundant evaporites in the north; humid climate and well drained valleys in the south. The origin and behavior of the main components of the two groups of waters are examined and compared to each other. The modeling of the alteration of volcanic rocks leads to water compositions very different from those observed both in the north and south. In addition to hydrothermal alteration and deep emanations, the Cl/Br ratio reveals a major contribution of saline waters to the two groups: infiltrating brines from salt lakes in the north; seawater in the south.In the north, concentrations of Cl, Br, Na, K, Ca, SO4, Li, B, Si result from the mixing of alteration waters with recycled brines. Hydrothermal alteration is obscured by this massive saline input, except for Mg. δ34S values are consistent with an origin of sulfate from salar brines, which are themselves derived from deep Tertiary gypsum. In the south, two processes account for the composition of thermal waters: mixing of alteration waters with seawater and deep magmatic contribution. The mixing process controls the concentration of Cl, Br, Na, Alk, Si, K, Ca, Mg. Magmatic inputs are detectable for SO4, Li and B. δ34S suggests that sulfate stems from the mixing of alteration waters with either marine SO4 in coastal waters or with deep SO2 in inland waters. In both the north and south, the Mg concentration is drastically lowered (<1 μmol/L) by the probable formation of a chlorite-type mineral. In the south, very small amounts of seawater (<1% in volume) are sufficient to imprint a clear signature on thermal waters. Not only coastal springs are affected by seawater mixing, but also remote inland springs, as far as 150 km from the sea. Subduction of marine sediments in the accretive margin could be the source of the marine imprint in thermal waters of southern Chile. Seawater may be expelled from the subducted lithosphere and incorporated into the mantle source.  相似文献   
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We propose a conceptual model that examines the ‘variable source area’ (VSA) and ‘nitrate flushing’ hypothesis in the vertical direction, and use this approach to explain nitrate concentration–discharge relationships in a semi-arid watershed. We use an eco-hydrology simulation model (RHESSys) to show that small changes in the vertical distribution of nitrate mass and their interaction with soil hydraulic conductivity can result in abrupt changes in the nitrate concentration–discharge relationship. We show that the estimated concentration–discharge relationship is sensitive to the parameters governing soil vertical nitrate distribution and soil hydraulic conductivity, at both patch scale and watershed scale, where lateral redistribution of water and nitrate is also accounted for. Given heterogeneity in nitrogen inputs, uptake processes, soil drainage and storage processes, substantial variation in parameters that describe rate of changes in vertical distribution of soil nitrate and hydraulic properties is likely both within and between watersheds. Thus, we argue that vertical ‘variable source area’ processes may be as important as lateral VSA in determining concentration discharge relationships.  相似文献   
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Natural Hazards - Principal characteristics of summer mesoscale convective systems in the Yucatan Peninsula, Mexico, were studied using three years of radar imagery. MCSs occurred almost daily in...  相似文献   
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Abstract— We demonstrate that a massive asymptotic giant branch (AGB) star is a good candidate as the main source of short‐lived radionuclides in the early solar system. Recent identification of massive (4–8 M⊙) AGB stars in the galaxy, which are both lithium‐ and rubidium‐rich, demonstrates that these stars experience proton captures at the base of the convective envelope (hot bottom burning), together with high‐neutron density nucleosynthesis with 22Ne as a neutron source in the He shell and efficient dredge‐up of the processed material. A model of a 6.5 M⊙ star of solar metallicity can simultaneously match the abundances of 26Al, 41Ca, 60Fe, and 107Pd inferred to have been present in the solar nebula by using a dilution factor of 1 part of AGB material per 300 parts of original solar nebula material, and taking into account a time interval between injection of the short‐lived nuclides and consolidation of the first meteorites equal to 0.53 Myr. Such a polluting source does not overproduce 53Mn, as supernova models do, and only marginally affects isotopic ratios of stable elements. It is usually argued that it is unlikely that the short‐lived radionuclides in the early solar system came from an AGB star because these stars are rarely found in star forming regions, however, we think that further interdisciplinary studies are needed to address the fundamental problem of the birth of our solar system.  相似文献   
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Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is a microanalytical tool especially suitable for providing fast and precise U-Pb geochronological results on zircon grains. A new 193 nm excimer laser adapted to a micromachining workstation, equipped with a newly designed two-volume ablation cell and coupled with a quadrupole ICP-MS, is presented here. The system was tuned routinely to achieve sensitivities in the range of 3000 cps/μg g−1 for 238U (< 2% RSD), with a 34 μm spot size, at 5 Hz and ∼ 8 J cm−2, while ablating the NIST SRM 612 glass reference material. The system was capable of providing fast (< 1.5 minutes each analysis) and precise (generally < 1.5% 1s errors) 206Pb/238U zircon ages. The ages of widely used reference material zircons (Plesovice, 337 Ma; Temora, 416 Ma; R33, 418 Ma; Sri Lanka, 564 Ma; 91500, 1065 Ma) could be precisely matched, with an accuracy on isotopic ratios that ranged from ∼ 2 to ∼ 6%, depending on the homogeneity of the natural reference materials.  相似文献   
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A simplified method of 3-D dynamic analysis, named 3-D quasi-dynamic analysis, is presented. This method has been primarily used to evaluate stress states at identified times of peak dynamic responses of structures with flexible diaphragms. The quasi-dynamic analysis consists of extracting the accelerations predicted by the time-step integration analyses of two 2-D discrete MDOF dynamic models of a given structure (each discrete model corresponding to one of the principal orthogonal directions of the structure) at given times of interest. These accelerations are imposed on a 3-D representation of the structure (for example, a finite element mesh) as equivalent static forces. Accelerations at the diaphragms are assumed to act over the same tributary areas of the diaphragms considered in the 2-D discrete dynamic models. The study of the firehouse of Gilroy (an unreinforced masonry structure with flexible diaphragms) during the Loma Prieta Earthquake is presented to illustrate the 3-D quasi-dynamic seismic analysis. This method was compared to the more traditional 3-D modal time-step integration and 3-D response spectra analyses. The quasi-dynamic analysis had a general good agreement with the more formal, complex and computationally extensive modal time-step integration analysis. The 3-D response spectra analysis was very conservative and had a poor correlation with both the quasi-dynamic and the modal time-step integration analyses. The case study of the firehouse of Gilroy suggested that if 3-D effects have to be considered in the evaluation of a given structure, the quasi-dynamic analysis constitutes a reliable and computationally cheaper alternative to the more traditional methods of 3-D dynamic analysis.  相似文献   
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Zusammenfassung Die im vorläufigen Bericht beschriebene Anlage für die Analyse von atmosphärischem CO2-Gehalt wurde vervollständigt. Es können nunmehr kontinuierliche Analysen sowie Einzelanalysen mit Gaspipetten ausgeführt werden. Die Arbeitsweise wird beschrieben und einige Resultate werden mitgeteilt. Es kann mit einer Messgenauigkeit von ±0.3 ppm gerechnet werden.
Summary The second and the third part of the installation of the equipment for measuring the CO2 content in the atmospheric air has been accomplished. It is now possible to make continuous local air analysis, and of samples collected in pipettes. The procedure is described and a few results reported. The measurement accuracy lies to within ±0.3 ppm.

Riassunto Sono state completate la seconda e la terza parte dell'apparecchiatura per la misura del CO2 atmosferico. Esse permettono l'analisi continua dell'aria locale e l'analisi di campioni raccolti in pipette; di queste si riporta un esempio. La precisione della misura è di ±0.3 ppm.


Meteorologisches Institut der Universität Stockholm. Contribution No. 164.  相似文献   
30.
We measured organochlorine residues in three species of sea turtles from the Baja California peninsula, Mexico. Seventeen of 21 organochlorine pesticides analyzed were detected, with heptachlor epoxide and gamma-hexachlorocyclohexane the most prevalent (14 (40%) and 11 (31%) of the 35 tissue samples, respectively). PCBs were detected in all but one of the 9 turtles studied, with congener 18 the most commonly detected (8 (23%) of the samples). The dioxin-like congeners 118 and 180 were detected in 4 (11%) and 3 (9%) of the samples, respectively. Percent contribution of congeners was negatively correlated to their octanol-water partition coefficients, with kidney and muscle containing more lower-chlorinated congeners than liver or adipose samples. Levels of organochlorines detected in the present study were low, potentially attributable to the feeding habits of the predominant species collected in this study (herbivorous) and/or the samples obtained in an unindustrialized region.  相似文献   
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