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Beginning June of 1993 suites of 13 water samples have been collected at Oyster Landing, North Inlet (SC), every 20 days covering two consecutive tidal cycles at 2.07 h intervals. In order to ascertain whether this large (and still growing) water chemistry data set can be used to determine tidal fluxes of nutrients and sediments, we coupled measured concentrations to estimates of instantaneous tidal discharge based on a basin water storage curve and hindcast tides. The mean advective fluxes of all constituents, including salt, showed statistically significant exports. This result, however, is largely due to an ebb bias in the sampling protocol, which resulted in 52% of the samples being collected on ebb tide versus a theoretical percentage of 48%. When this bias was corrected by reducing the mean discharge (−610 l s−1) to a value (−125 l s−1) that produced a balance between the mean advective and dispersive salt fluxes, the advective fluxes of the other constituents were reduced to values that are not significantly different from zero. In addition to a statistically significant dispersive influx of salt, significant dispersive exports were found for DON, NH4, DOP, PO4 and DOC. All particulate constituents (PN, PP, ISS and OSS) yielded dispersive fluxes that were not significantly different from zero. Annual material budgets for the Oyster Landing basin based on the dispersive fluxes of all constituents (except salt) are generally similar in magnitude and direction to those measured by [Dame, R.F., Spurrier, J.D., Williams, T.M., Kjerfve, B., Zingmark, R.G., Wolaver, T.G., Chrzanowski, T.H., McKeller, H.N., Vernberg, F.J., 1991. Annual material processing by a salt marsh-estuarine basin in South Carolina, USA. Marine Ecology Progress Series 72, 153–166.] in the nearby and ecologically similar Bly Creek basin, indicating that the dispersive fluxes determined in this study are realistic. We offer suggestions for improving the reliability and usefulness of future Oyster Landing water quality data.  相似文献   
3.
Chromophoric dissolved organic matter (CDOM) was measured in the spring and summer in the northern Gulf of Mexico with the ECOShuttle, a towed, instrumented, undulating vehicle. A submersible pump mounted on the vehicle supplied continuously flowing, uncontaminated seawater to online instruments in the shipboard laboratory and allowed discrete samples to be taken for further analysis. CDOM in the northern Gulf of Mexico was dominated by freshwater inputs from the Mississippi River through the Birdfoot region and to the west by discharge from the Atchafalaya River. CDOM was more extensively dispersed in the high-flow period in the spring but in both time periods was limited by stratification to the upper 12 m or so. Thin, subsurface CDOM maxima were observed below the plume during the highly stratified summer period but were absent in the spring. However, there was evidence of significant in situ biological production of CDOM in both seasons.The Mississippi River freshwater end member was similar in spring and summer, while the Atchafalaya end member was significantly higher in the spring. In both time periods, the Atchafalaya was significantly higher in CDOM and dissolved organic carbon (DOC) than the Mississippi presumably due to local production and exchange within the coastal wetlands along the lower Atchafalaya which are absent along the lower Mississippi. Nearshore waters may also have higher CDOM due to outwelling from coastal wetlands. High-resolution measurements allow the differentiation of various water masses and are indicative of rapidly varying (days to weeks) source waters. Highly dynamic but conservative mixing between various freshwater and marine end members apparently dominates CDOM distributions in the area with significant in situ biological inputs (bacterial degradation of phytoplankton detritus), evidence of flocculation, and minor photobleaching effects also observed. It is clear that high-resolution measurements and adaptive sampling strategies allow a more detailed examination of the processes that control CDOM distributions in river-dominated systems.  相似文献   
4.
A linear decrease in dissolved organic carbon and nitrogen with increasing salinity offshore from the Georgia coast suggests that organic nitrogen compounds contributed to coastal waters by rivers are stable during the period (2–3 months) of their transfer over the continental shelf. While the C/N ratio decreased with distance from shore, total dissolved organic nitrogen (DON), total amino nitrogen, and primary amino nitrogen showed similar relative decreases, suggesting that nitrogen is associated with refractory organic compounds. Measured amino nitrogen accounted for about 20% of the total DON, leaving about 80% of the organic nitrogen undefined.  相似文献   
5.
Remote sensing and surface POC concentration in the South Atlantic   总被引:1,自引:0,他引:1  
Several SeaWiFS products have been compared with shipboard data to assess the possibility of using remote sensing to estimate particulate organic carbon (POC) concentration in surface waters. Transmissometer data were collected during six South Atlantic Ventilation Experiment (SAVE) hydrographic expeditions conducted between November 1987 and March 1989 from R/V Knorr, and Melville. A total of 361 beam attenuation profiles were made with a SeaTech transmissometer interfaced with a CTD/rosette. In order to calculate the POC concentration from transmissometer profiles, a regression between beam attenuation and POC for open Atlantic Ocean waters derived from our research in the North Atlantic (North Atlantic Bloom Experiment, NABE) and enhanced by data from the Bermuda Atlantic Time Series Station (BATS) was applied. The profiles were processed and examined as vertical sections of the surface 250 m. The data were collected in two successive years, during the same season, which allowed us to compile a combined data set over the austral summer for examination. Beam attenuation/POC concentrations were integrated down to one attenuation depth with the intent of making comparisons with satellite optical data. No satellite optical data were available for 1987–1989, so the only option was to compare our integrated data with SeaWiFS-derived variables from later years averaged over the same season as SAVE data. Analysis of four SeaWiFS products acquired from 1997 to 2002 demonstrated very low variations from year to year for seasonally averaged data, suggesting that making comparisons of the beam attenuation/POC fields with averaged satellite optical products from later years is a valid (though not optimal) approach for this area. The highest correlation between beam attenuation/POC concentration and remotely derived products was found with normalized water-leaving radiance at 555 nm. Other SeaWiFS-derived variables—chlorophyll concentration, diffuse attenuation coefficient at 490 nm and integral chlorophyll (integrated over one attenuation depth)—were also compared but showed a slightly less satisfactory correlation.  相似文献   
6.
Small quantities of groundwater interact with hydrothermal surface water to drive in-stream geochemical processes in a silica-armored hot-spring outflow channel in Yellowstone National Park, USA. The objective of this study was to characterize the hydrology and geochemistry of this unique system in order to (1) learn more about the Yellowstone Plateau’s subsurface water mixing between meteoric and hydrothermal waters and (2) learn more about the chemical and physical processes that lead to accumulation of streambed cements, i.e., streambed armor. A combination of hydrological, geochemical, mineralogical, microscopic, and petrographic techniques were used to identify groundwater and surface-water exchange. Interaction could be identified in winter because of differences in surface water and groundwater composition but interaction at other times of the year cannot be ruled out. Dissolved constituents originating from groundwater (e.g., Fe(II) and Mg) were traced downstream until oxidation and/or subsequent precipitation with silica removed them, particularly where high affinity substrates like cyanobacterial surfaces were present. Because the stream lies in a relatively flat drainage basin and is fed mainly by a seasonally relatively stable hot spring, this system allowed study of the chemical processes along a stream without the obscuring effects of sedimentation.  相似文献   
7.
Natural resources of all kinds have been overexploited by user groups who cannot or will not develop rules to constrain their own exploitive efforts. One notable exception is the Maine lobster industry, where an effective set of conservation laws has been developed due, in great part, to the strong support of the industry. In the early decades of the 20th century, however, the lobster industry was marked by widespread violations of the existing conservation laws and opposition to developing more. This article explores the way that the pirate ethic gave way to the conservation ethic in the 1930s. Our explorations in evolutionary game theory suggest that this change was produced by three factors: costs and benefits of defection from the conservation ethic; numbers of people accepting the conservation ethic quality rule; and events that shocked the system from one state to another. We argue that the shock to the system in the late 1920s and 1930s was caused by massive stock failure which changed the attitudes of many fishermen about the need for conservation. People began to report violations of the law, which made law enforcement more effective and quickly led to a cascade of fishermen abandoning the pirate ethic. In the late 1930s, increasing catches, in combination with a number of other social, technical, and economic factors continued the upward spiral.  相似文献   
8.
Benthic macroinvertebrate biomass and ammonium excretion rates were measured at four stations in the Gulf of Mexico near the Mississippi River mouth. Calculated areal excretion rates were then compared to sediment-water nitrogen fluxes measured in benthic bottom lander chambers at similar stations to estimate the potential importance of macroinvertebrate excretion to sediment nitrogen mineralization. Excretion rates for individual crustaceans (amphipods and decapods) was 2–21 nmoles NH4 + (mg dry weight)?1 h?1. The mean excretion rates for the polychaetes, Paraprionaspio pinnata [6–12 nmoles NH4 + (mg dry weight)?1h?1] and Magelona sp. [27–53 nmoles NH4 + (mg dry weight)?1h?1], were comparable or higher than previous measurements for similar size benthic or pelagic invertebrates incubated at the same temperature (22±1°C). Although the relatively high rates of excretion by these selective feeders may have been partially caused by experimental handling effects (e.g., removal from sediment substrates), they probably reflected the availability of nitrogen-rich food supplies in the Mississippi River plume. When the measured weight-specific rates were extrapolated to total areal biomass, areal macroinvertebrate excretion estimates ranged from 7 μmole NH4 + m?2h?1 at a 40-m deep station near the river mouth to 18 μmole NH4 + m?2h?1 at a shallower (28-m deep) station further from the river mouth. The net flux of ammonium and nitrate from the sediments to the water measured in bottom lander chambers in the same region were 15–53 μmole NH4 + m?2h?1 and ?25–21 μmole NO3 ? m?2h?1. These results suggest that excretion of NH4 + by macroinvertebrates could be a potentially important component of benthic nitrogen regeneration in the Mississippi River plume-Gulf shelf region.  相似文献   
9.
Snow avalanche hazards in mountainous areas of developing countries have received scant attention in the scientific literature. The purpose of this paper is to describe this hazard and mitigative measures in Kaghan Valley, Pakistan Himalaya, and to review alternatives for future reduction of this hazard. Snow avalanches have long posed a hazard and risk to indigenous populations of the Himalaya and Trans-Himalaya mountains. Land use intensification due to population growth, new transportation routes, military activity and tourism is raising levels of risk. The history of land use in the study area is such that investigations of avalanche hazard must rely on different theoretical bases and data than in most industrialised countries. Despite the intensive use of valley-bottom land which is affected by avalanches, a number of simple measures are currently employed by the indigenous population to mitigate the hazard. Out-migration during the winter months is the most important one. During the intensive use period of summer avalanche-transported snow provides numerous resources for the population. In Kaghan the avalanche hazard is increasing primarily as a result of poorly located new buildings and other construction projects. The large scale of avalanche activity there rules out any significant improvement or protection of the currently difficult winter access. Instead, future mitigation of the hazard should focus on protecting the small number of winter inhabitants and minimising property damage.  相似文献   
10.
Stable carbon and oxygen isotope measurements have been obtained from ten calcareous soil profiles developed on noncalcareous parent materials in Nevada and New Mexico. Despite the number of variables that can affect the isotopic composition of soil carbonate, most of these profiles show remarkably little variation in δ 13C and δ 18O with depth. This tendency towards uniformity is attributed to the fact that pedogenic carbonate forms by the incremental accumulation of a large number of small aliquots of CaCO3. As the number of aliquots of CaCO3 increases, the composition of their sum, which is the calcareous horizon itself, tends to converge to the long-term average of the individual aliquots. A mathematical model is presented to show how the time required for convergence is affected by the amplitude and period of aliquot variation and the extent of dissolution and reprecipitation of previously deposited carbonate. Calculations further indicate that in some cases the variation in δ 18O of soil carbonates may be moderated by the opposing effects of temperature change on the H2OCaCO3 fractionation factor and on the extent of evapotranspiration.The data of this study indicate that soil carbonates from sites within a homogeneous climatic region show relatively little site-to-site variation in δ 18O as compared to geographical variation in δ 13C. This suggests that the δ 18O of soil carbonates is primarily controlled by broad climatic factors (rainfall composition and temperature) whereas site factors (e.g., soil CO2) have a strong effect on δ 13C. In Nevada and New Mexico the δ 18O of Pleistocene calcareous profiles is 2.0–4.0‰ lighter than that of nearby Holocene soil carbonate, suggesting that old well-developed profiles may have formed dominantly under cooler pluvial conditions.  相似文献   
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