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101.
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103.
A batch sorption technique for the determination of particle–water interactions of hydrophobic organic micropollutants under simulated estuarine conditions is described. Results are presented for the behaviour of 2,2′,5,5′-tetrachlorobiphenyl (2,2′,5,5′-TCB) in river and sea waters, both in the presence and absence of estuarine suspended particles. Adsorption onto particles in sea water was enhanced compared with adsorption in river water owing to salting out of the compound, and possibly of the particulate organic matter, in the presence of high concentrations of dissolved ions. The particle–water distribution coefficient, KD, decreased from about 120×103 to 10×103 ml g−1, and from about 150×103 to 20×103 ml g−1, in river water and sea water, respectively, over a particle concentration range of 10–1000 mg l−1. Incomplete recovery of compound from the reactor walls is partly responsible for a particle concentration effect, while artefacts relating to inadequate sediment and water phase separation were ruled out following further experiments. The particle concentration effect, which is replicated in many field studies of hydrophobic organic micropollutants, including 2,2′,5,5′-TCB, is incorporated into a simple partitioning model and is discussed in the context of the likely estuarine behaviour of such compounds.  相似文献   
104.
Carl Keller 《Ground water》2017,55(2):244-254
This study describes a new technique for measuring the head profile in a geologic formation. The technique provides rapid, low cost information on the depth of water‐producing zones and aquitards in heterogeneous aquifers, yielding estimates of hydraulic heads in each zone while identifying any potential for cross contamination between zones. The measurements can be performed in a typical borehole in just a few hours. The procedure uses both the continuous transmissivity profile obtained by the installation (eversion) of a flexible borehole liner into an open borehole and the subsequent removal (inversion) of the same liner from the borehole. The method is possible because of the continuous transmissivity profile (T profile described by Keller et al. 2014) obtained by measuring the rate of liner eversion under a constant driving head. The hydraulic heads of producing zones are measured using the reverse head profile (RHP) method (patent no. 9,008,971) based on a stepwise inversion of the borehole liner. As each interval of the borehole is uncovered by inversion of the liner, the head beneath the liner is allowed to equilibrate to a steady‐state value. The individual hydraulic heads contributing to each measurement are calculated using the measured transmissivity for each zone. Application of the RHP method to a sedimentary bedrock borehole in New Jersey verified that it reproduced the head distribution obtained the same day in the same borehole instrumented with a multilevel sampling system.  相似文献   
105.
Image-based methods have compelling, demonstrated potential for characterizing flow fields in rivers, but algorithms like particle image velocimetry (PIV) must be further tested and improved to enable more effective use of these techniques. This paper presents a framework designed for this exact purpose: Simulating Hydraulics and Images for Velocimetry Evaluation and Refinement (SHIVER). The approach involves coupling a hydrodynamic model with a synthetic particle generator to advect particles between frames, as dictated by local velocity vectors and thus construct a plausible image sequence specific to the reach of interest. The resulting time series can then be used as input to a velocimetry algorithm to compare image-derived estimates with known (modelled) velocities to perform an exhaustive, spatially distributed accuracy assessment. As an example application of SHIVER, we examined the effects of interrogation area (IA) size, frame rate, flow velocity, and image sequence duration on the performance of a standard PIV algorithm. This analysis indicated that image-derived velocities were generally in close agreement with those from the flow model (root mean square error <10% and mean bias <3%), except when small IAs were coupled with low frame rates. Velocity estimates were most accurate for the lowest modelled discharge ( at baseflow) and became less reliable as the mean flow velocity increased ( for an intermediate discharge and at bankfull). Accuracy was essentially independent of image sequence duration, implying that long occupations might not be necessary. Errors were concentrated along channel margins, where PIV-based velocities tended to be greater than those from the flow model. Small IAs led to underpredictions of velocity, while larger IAs led to overpredictions. SHIVER is highly modular and could be updated to make use of different hydrodynamic models or image simulators. The framework could also facilitate more thorough sensitivity analyses and comparison of various velocimetry algorithms.  相似文献   
106.
While seismic reflection amplitudes are generally determined by real acoustical impedance contrasts, there has been recent interest in reflections due to contrasts in seismic‐Q. Herein we compare theoretical and modelled seismic reflection amplitudes for two different cases of material contrasts. In case A, we examine reflections from material interfaces that have a large contrast in real‐valued impedance () with virtually no contrast in seismic‐Q. In case B, we examine reflections from material interfaces that have virtually no contrast in but that have very large seismic‐Q contrasts. The complex‐valued reflection coefficient formula predicts non‐zero seismic reflection amplitudes for both cases. We choose physical materials that typify the physics of both case A and case B. Physical modelling experiments show significantly large reflections for both cases – with the reflections in the two cases being phase shifted with respect to each other, as predicted theoretically. While these modelling experiments show the existence of reflections that are predicted by theory, there are still intriguing questions regarding the size of the Q‐contrast reflections, the existence of large Q‐contrast reflections in reservoir rocks and the possible application of Q‐reflection analysis to viscosity estimation in heavy oilfields.  相似文献   
107.
New Method for Continuous Transmissivity Profiling in Fractured Rock   总被引:2,自引:0,他引:2  
A new method is presented to search for hydraulically transmissive features in open boreholes in bedrock. A flexible borehole liner made of a watertight, nylon fabric is filled with water to create a constant driving head to evert (reverse of invert) the liner down the hole so that the liner pushes the borehole water out into transmissive fractures or other permeable features. The descent rate is governed by the bulk transmissivity of the remaining permeable features below the liner. Initially, the liner descent rate or velocity is a measure of transmissivity (T) of the entire hole. As the everting liner passes and seals each permeable feature, changes in the liner velocity indicate the position of each feature and an estimate of T using the Thiem equation for steady radial flow. This method has been performed in boreholes with diameters ranging from 96 to 330 mm. Profiling commonly takes a few hours in holes 200‐ to 300‐m long. After arrival of the liner at the bottom of the hole, the liner acts as a seal preventing borehole cross connection between transmissive features at different depths. Liner removal allows the hole to be used for other purposes. The T values determined using this method in a dolostone aquifer were found to be similar to the values from injection tests using conventional straddle packers. This method is not a replacement for straddle‐packer hydraulic testing of specific zones where greater accuracy is desired; however, it is effective and efficient for scanning entire holes for transmissive features.  相似文献   
108.
An ice microphysics parameterization scheme has been modified to better describe and understand ice fog formation. The modeling effort is based on observations in the Sub-Arctic Region of Interior Alaska, where ice fog occurs frequently during the cold season due to abundant water vapor sources and strong inversions existing near the surface at extremely low air temperatures. The microphysical characteristics of ice fog are different from those of other ice clouds, implying that the microphysical processes of ice should be changed in order to generate ice fog particles. Ice fog microphysical characteristics were derived with the NCAR Video Ice Particle Sampler during strong ice fog cases in the vicinity of Fairbanks, Alaska, in January and February 2012. To improve the prediction of ice fog in the Weather Research and Forecasting model, observational data were used to change particle size distribution properties and gravitational settling rates, as well as to implement a homogeneous freezing process. The newly implemented homogeneous freezing process compliments the existing heterogeneous freezing scheme and generates a higher number concentration of ice crystals than the original Thompson scheme. The size distribution of ice crystals is changed into a Gamma distribution with the shape factor of 2.0, using the observed size distribution. Furthermore, gravitational settling rates are reduced for the ice crystals since the crystals in ice fog do not precipitate in a similar manner when compared to the ice crystals of cirrus clouds. The slow terminal velocity plays a role in increasing the time scale for the ice crystals to settle to the surface. Sensitivity tests contribute to understanding the effects of water vapor emissions as an anthropogenic source on the formation of ice fog.  相似文献   
109.
Predicting spatial and temporal variations in bank erosion due to extreme floods presents a long‐standing challenge in geomorphology. We develop two methodologies for rapid, regional‐scale assessments of stream reaches susceptible to channel widening. The first proposes that channel widening occurs when unit stream power exceeds a critical threshold (300 W/m2). The second is motivated by the observation that widening often occurs at channel bends. We introduce a new metric, the bend stress parameter, which is proportional to the centripetal force exerted on a concave bank. We propose that high centripetal forces generate locally high bank shear forces and enhance channel bank erosion. We test both metrics using the geomorphic signature of Tropical Storm Irene (2011) on the White and the Saxtons Rivers, Vermont. Specifically, we test if reaches where significant channel widening occurred during Irene required one or both metrics to exceed threshold values. We observe two distinct styles of channel widening. Where unit stream power and bend stress parameter are high, widening is usually due to bank retreat. Elsewhere widening is usually due to the stripping of the upstream end of mid‐channel islands. Excluding widening associated with the stripping of the heads of mid‐channel islands, almost all the widening (> 98%) occurred along reaches identified as susceptible to widening. The combined metrics identify up to one‐quarter of the reaches lacking susceptibility to channel widening. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
110.
This study developed and evaluated a hybrid approach to remote measurement of river morphology that combines LiDAR topography with spectrally based bathymetry. Comparison of filtered LiDAR point clouds with surveyed cross‐sections indicated that subtle features on low‐relief floodplains were accurately resolved by LiDAR but that submerged areas could not be detected due to strong absorption of near‐infrared laser pulses by water. The reduced number of returns made the active channel evident in a LiDAR point density map. A second dataset suggested that pulse intensity also could be used to discriminate land from water via a threshold‐based masking procedure. Fusion of LiDAR and optical data required accurate co‐registration of images to the LiDAR, and we developed an object‐oriented procedure for achieving this alignment. Information on flow depths was derived by correlating pixel values with field measurements of depth. Highly turbid conditions dictated a positive relation between green band radiance and flow depth and contributed to under‐prediction of pool depths. Water surface elevations extracted from the LiDAR along the water's edge were used to produce a continuous water surface that preserved along‐channel variations in slope. Subtracting local flow depths from this surface yielded estimates of the bed elevation that were then combined with LiDAR topography for exposed areas to create a composite representation of the riverine terrain. The accuracy of this terrain model was assessed via comparison with detailed field surveys. A map of elevation residuals showed that the greatest errors were associated with underestimation of pool depths and failure to capture cross‐stream differences in water surface elevation. Nevertheless, fusion of LiDAR and passive optical image data provided an efficient means of characterizing river morphology that would not have been possible if either dataset had been used in isolation. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
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