全文获取类型
收费全文 | 830篇 |
免费 | 47篇 |
国内免费 | 9篇 |
专业分类
测绘学 | 23篇 |
大气科学 | 69篇 |
地球物理 | 207篇 |
地质学 | 303篇 |
海洋学 | 98篇 |
天文学 | 103篇 |
综合类 | 2篇 |
自然地理 | 81篇 |
出版年
2022年 | 3篇 |
2021年 | 7篇 |
2020年 | 21篇 |
2019年 | 23篇 |
2018年 | 21篇 |
2017年 | 29篇 |
2016年 | 36篇 |
2015年 | 38篇 |
2014年 | 39篇 |
2013年 | 36篇 |
2012年 | 40篇 |
2011年 | 52篇 |
2010年 | 62篇 |
2009年 | 61篇 |
2008年 | 37篇 |
2007年 | 45篇 |
2006年 | 38篇 |
2005年 | 40篇 |
2004年 | 38篇 |
2003年 | 25篇 |
2002年 | 21篇 |
2001年 | 12篇 |
2000年 | 19篇 |
1999年 | 10篇 |
1998年 | 20篇 |
1997年 | 9篇 |
1996年 | 8篇 |
1995年 | 4篇 |
1994年 | 6篇 |
1993年 | 9篇 |
1992年 | 7篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 7篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1985年 | 7篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1969年 | 2篇 |
1965年 | 2篇 |
1963年 | 2篇 |
1962年 | 2篇 |
排序方式: 共有886条查询结果,搜索用时 31 毫秒
61.
André Burnol Francis Garrido Philippe Baranger Catherine Joulian Marie-Christine Dictor Françoise Bodénan Guillaume Morin Laurent Charlet 《Geochemical transactions》2007,8(1):12
High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the
release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis.
Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted.
Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The
biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and
genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing
bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase
amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant
after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant,
or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial
solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst
X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction
revealed vivianite Fe(II)3(PO4)2.8H2O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results.
The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high
Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically
more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more
weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully
applied to recent experimental results on the release of arsenic from Bengal delta sediments. 相似文献
62.
The use of logic trees in probabilistic seismic hazard analyses often involves a large number of branches that reflect the uncertainty in the selection of different models and in the selection of the parameter values of each model. The sensitivity analysis, as proposed by Rabinowitz and Steinberg [Rabinowitz, N., Steinberg, D.M., 1991. Seismic hazard sensitivity analysis: a multi-parameter approach. Bull. Seismol. Soc. Am. 81, 796–817], is an efficient tool that allows the construction of logic trees focusing attention on the parameters that have greater impact on the hazard.In this paper the sensitivity analysis is performed in order to identify the parameters that have the largest influence on the Western Liguria (North Western Italy) seismic hazard. The analysis is conducted for six strategic sites following the multi-parameter approach developed by Rabinowitz and Steinberg [Rabinowitz, N., Steinberg, D.M., 1991. Seismic hazard sensitivity analysis: a multi-parameter approach. Bull. Seismol. Soc. Am. 81, 796–817] and accounts for both mean hazard values and hazard values corresponding to different percentiles (e.g., 16%-ile and 84%-ile). The results are assessed in terms of the expected PGA with a 10% probability of exceedance in 50 years for rock conditions and account for both the contribution from specific source zones using the Cornell approach [Cornell, C.A., 1968. Engineering seismic risk analysis. Bull. Seismol. Soc. Am. 58, 1583–1606] and the spatially smoothed seismicity [Frankel, A., 1995. Mapping seismic hazard in the Central and Eastern United States. Seismol. Res. Lett. 66, 8–21]. The influence of different procedures for calculating seismic hazard, seismic catalogues (epicentral parameters), source zone models, frequency–magnitude parameters, maximum earthquake magnitude values and attenuation relationships is considered. As a result, the sensitivity analysis allows us to identify the parameters with higher influence on the hazard. Only these parameters should be subjected to careful discussion or further research in order to reduce the uncertainty in the hazard while those with little or no effect can be excluded from subsequent logic-tree-based seismic hazard analyses. 相似文献
63.
Lisa K. Whalley Kate L. Furneaux Tom Gravestock Helen M. Atkinson Catherine S. E. Bale Trevor Ingham William J. Bloss Dwayne E. Heard 《Journal of Atmospheric Chemistry》2007,58(1):19-39
A Laser Induced Fluorescence (LIF) instrument has been developed to detect iodine monoxide (IO) radicals in the atmosphere.
An all solid-state Nd:YAG pumped Ti:Sapphire laser operating at approximately 445 nm was used to excite the (2,0) band of
the IO A2Π3/2 ← X2Π3/2 electronic transition, with off-resonance fluorescence in the (2,5) band detected at 521 nm. The sensitivity of the instrument
was determined by calibration. IO (between 10 and 150 pptV) was generated following the 184.9 nm photolysis of N2O/CF3I/N2 mixtures with O3 actinometry used to determine the photolysis flux. The detection limit was determined to be 0.3 pptV for a 300 s integration
period, with an uncertainty of 23% (1σ). The instrument was deployed in August/September 2006 during the RHaMBLe (Reactive Halogens in the Marine Boundary Layer)
campaign in Roscoff, France. Located on a small jetty, a few metres from the water’s edge at high tide, the instrument measured
significant levels of IO on 11 days, with a maximum of 27.6 ± 3.2 pptV observed on one day (averaged over 10 s) representing
the highest IO mixing ratio recorded in the marine boundary layer to date. IO displayed a clear diurnal profile with a maximum
at low tide during the daytime. These results represent the first point measurements of IO in the atmosphere by LIF. 相似文献
64.
Catherine H. Yansa 《Journal of Paleolimnology》1998,19(4):429-441
The Andrews site represents one of countless prairie potholes found in areas of hummocky moraine on the northern Great Plains. Sediments from a depth of 5.8 to 3.1 m at this 'kettle-fill' site in the Missouri Coteau upland of southern Saskatchewan, Canada, provides a record of vegetation, climate, and hydrologic changes within a small, ca 30 m diameter, closed-drainage basin from ca 10.2 to 5.8 ka. Plant macrofossil analyses of 67 samples, 6 14C ages, and stratigraphy were used to identify 5 zones, representing the paleohydrological changes that followed deglaciation in southern Saskatchewan.Results of this study indicate that with the melting of residual stagnant ice a pond (>2 m deep) with abundant aquatic, emergent, and shoreline plants developed in the basin at ca 10.2 ka and persisted until at least ca 8.8 ka. During this time there was a shift in upland vegetation from a white spruce forest (Zone II) to a deciduous parkland at ca 10 ka (Zone III). As climate warmed, brackish and alkaline conditions developed coincident with shallowing of the pond at the end of Zone III. The perennial water phase ended at ca 8.8 ka and was followed by a low-water stand lasting ca 1100 years. Prairie fires and slopewash from unstable slopes were dominant sedimentological processes until ca 7.7 ka (Zone IV). Water levels began to rise and between ca 7.7 and 5.8 ka a semi-permanent pond was established in a grassland setting (Zone V). After ca 5.8 ka this prairie pothole wetland became ephemeral, to the point that plant macrofossils could not be preserved, a situation continuing today. Interactions between climate change, variability in local groundwater supply, and sedimentological processes likely account for the paleohydrologic events reconstructed at the Andrews site. 相似文献
65.
66.
Catherine Rhein 《GeoJournal》1998,46(1):51-62
Which places are left to minorities in the housing and labour markets in metropolitan Paris? Over the last two decades, job structures have evolved dramatically, eroding the formerly prominent Paris working-class, shaking the social and political roots of its identity. These indicators would lead one to diagnose a growing fragmentation of metropolitan society. In the political debate, the burning issue of the crisis of suburbs has replaced outdated debate of the class struggle. This paper aims first to re-examine the interactions between social status and national origins, then analyses the housing conditions of different social strata, and finally demonstrates the pre-eminence of social status over national origins in the pattern of residential segregation. 相似文献
67.
68.
Eclogites formed by the Lufilian (post-Katanga) metamorphism of gabbros intruded into rocks of the Katanga System (Upper Proterozoic) occur in the Central Province of Zambia. Typical constituents of these rocks are omphacite, almandine garnet with significant contents of the pyrope and grossular components, kyanite and rutile. Eclogites from some localities display well preserved, relict ophitic texture inherited from the original gabbro. Hornblende-scapolite metagabbro and coronite metagabbro often accompany the eclogites, and metalherzolite and serpentinite occur at a few localities. The Zambian eclogites are broadly associated with a variety of relatively high-pressure, kyanite-bearing mineral assemblages some of which are possibly in the eclogite facies. It is suggested that, in addition to temperature and load pressure, fluid pressure, fluid composition (H2O, CO2, Cl, SO3) and permeability of the gabbro due to deformation were important factors for the transformation of gabbro to eclogite in the environment of the Lufilian Arc. 相似文献
69.
Tunicates may serve as marine pollution indicators for monitoring the release of industrial and/or radioactive wastes into the marine environment. Their ability to accumulate certain trace elements from the seawater can be employed in order to define a suitable organism as indicator for some specific pollutants. In this work the concentration of the elements cobalt, zinc, chromium, caesium, silver, iron, rubidium, selenium, scandium and antimony has been determined by instrumental neutron activation analysis and γ-ray spectroscopy, in two tunicates, Microcosmus sulcatus (Pyuridae) and Ciona intestinalis (Cionidae).According to the concentration factors found for these species Ciona intestinalis can be used as indicator for iron, while Microcosmus sulcatus as indicator for the elements selenium, chromium, zinc and cobalt. 相似文献
70.
Prey diversity of Homo sapiens in north Iberia exhibited shifts associated with climate warming after the Last Glacial Maximum, as deduced from animal remains obtained from Upper Palaeolithic caves in Asturias (northern Spain). Significant association of prey diversity and river proximity was found during adverse climate conditions, indicating opportunistic predation. A high increase of prey diversity was found when small animals (including fish) were taken into account in archaeological records, highlighting the importance of this type of prey in Palaeolithic diets. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献