Impact of coal tar pavement on polycyclic hydrocarbon distribution in lacustrine sediments from non-traditional sources   总被引：1，自引：1，他引：0  

S. Froehner  D. B. de Souza  K. S. Machado  F. Falc?o  C. S. Fernandes  T. Bleninger  D. M. Neto 《International Journal of Environmental Science and Technology》2012,9(2):327-332

The evaluation of potential environmental impacts from polycyclic aromatic hydrocarbon is a subject that requires investigation, especially related to emission sources from highway roads with high traffic. In this paper, the distribution of polycyclic aromatic hydrocarbons was investigated in the surface sediments from a subtropical lake, located in the south of Brazil and away from urban areas. The results showed that all sediments presented such compounds in significant concentration, ranging from 9.50 to 29.88???g/g. The highest total concentration was found in those sites close to the highway (bridges) and the deepest area of the lake. Moreover, a high concentration of polycyclic aromatic hydrocarbons of high molecular weight, such as benzo(a)anthracene and dibenzo(a,h)anthracene was found. It was laso found that high concentrations might be related to asphalt and coal tar pavement used in the highway construction close to the lake. In addition, the potential capacity of sediment toxicity was compared with values of the interim sediment quality guidelines values. The results indicate that most of the sediment presents concentrations of hydrocarbons above these limits. Only fluoranthene and chrysene were found in concentrations below the guideline values. The concentrations of most of the polycyclic hydrocarbons are higher than the quality guidelines. However, the main concern is associated with the presence of benzo(a)anthracene whose concentration is 416 times higher than the limit establisehed by guidelines. The same observation can be done to traces of benzo(a)pyrene and dibenz(a,h)anthracene, with concentration values of 13 and 1,993 times higher.  相似文献   

Treatment of an ECF bleaching effluent with white-rot fungi in an air-lift bioreactor     

Érica S. Souza  João V. B. Souza  Flávio T. Silva  Teresa C. B. Paiva 《Environmental Earth Sciences》2014,72(4):1289-1294

Pulp and paper mills utilise huge amount of natural resources, inorganic and organic materials along with large volume of water in different stages of paper manufacturing, resulting in a significant volume of effluents. The aim of this work was to investigate the treatment of a bleaching effluent [effluent chlorine free (ECF)] from the cellulose industry with white-rot fungi in an air-lift bioreactor. This effluent was submitted to the biological treatment with three white-rot fungi, and, every 24 h for 120 h, analytical tests were performed to analyse the quality parameters of treatment (COD, phenols, colour, pH). Before and after treatment, the effluent was analysed as its molecular mass distribution and absorptivity in the UV/VIS. Lentinus edodes, Trametes versicolor and Trametes villosa promoted similarly significant reductions in the following characteristics: (a) effluent colour (40–44 %), (b) total phenol (30–51 %) and (c) COD (37–43 %). The UV/visible spectrometry reading of the effluent after the fungi treatment showed a reduction in the absorbance of all wavelengths between 260 and 500 nm. The size exclusion HPLC profile of the effluent was modified, and the treatment promoted changes in the intensity of the peaks associated with compounds of high and low molecular weight. Phenoloxidases were produced during the treatment. T. versicolor produced the highest levels of laccase, and L. edodes was the only fungus that produced peroxidases.  相似文献   

Ground-based measurements of local cloud cover     

Abel Antônio Silva  Mariza Pereira de Souza Echer 《Meteorology and Atmospheric Physics》2013,120(3-4):201-212

Clouds are believed to reflect temporal climate changes through variations in their amounts, characteristics, and occurrence. In addition, they reflect both weather and climate in a region. In this work, a methodology to determine the local cloud cover (LCC) is proposed using sky images obtained from a ground-based instrument. Three years of sky images from an urban, tropical site were obtained and analyzed through that methodology. Monthly average LCC varied from 3 to 96 %, while seasonal average values were 68 % for summer, 54 % for spring, 46 % for fall, and 23 % for winter. LCC results show a clear seasonal dependence and a fair agreement (r ² = 0.72) with satellite data, which typically underestimate the cloud cover in relation to LCC. Our analysis also suggests the possibility of a measurable link between LCC and natural events like the El Niño Southern Oscillation.  相似文献   

Effects of upwelling,tides and biological processes on the inorganic carbon system of a coastal lagoon in Baja California     

M. Ribas-Ribas  J.M. Hernández-Ayón  V.F. Camacho-Ibar  A. Cabello-Pasini  A. Mejia-Trejo  R. Durazo  S. Galindo-Bect  A.J. Souza  J.M. Forja  A. Siqueiros-Valencia 《Estuarine, Coastal and Shelf Science》2011

The role of coastal lagoons and estuaries as sources or sinks of inorganic carbon in upwelling areas has not been fully understood. During the months of May–July, 2005, we studied the dissolved inorganic carbon system in a coastal lagoon of northwestern Mexico during the strongest period of upwelling events. Along the bay, different scenarios were observed for the distributions of pH, dissolved inorganic carbon (DIC) and apparent oxygen utilization (AOU) as a result of different combinations of upwelling intensity and tidal amplitude. DIC concentrations in the outer part of the bay were controlled by mixing processes. At the inner part of the bay DIC was as low as 1800 μmol kg⁻¹, most likely due to high water residence times and seagrass CO₂ uptake. It is estimated that 85% of San Quintín Bay, at the oceanic end, acted as a source of CO₂ to the atmosphere due to the inflow of CO₂-rich upwelled waters from the neighboring ocean with high positive fluxes higher than 30 mmol C m⁻² d⁻¹. In contrast, there was a net uptake of CO₂ and HCO₃⁻ by the seagrass bed Zostera marina in the inner part of the bay, so the pCO₂ in this zone was below the equilibrium value and slightly negative CO₂ fluxes of −6 mmol C m⁻² d⁻¹. Our positive NEP and ΔDIC values indicate that Bahía San Quintín was a net autotrophic system during the upwelling season during 2005.  相似文献   

Ionization and dissociation of cometary gaseous organic molecules by solar wind particles – I. Formic acid     

S. Pilling  A. C. F. Santos  W. Wolff  M. M. Sant'Anna  A. L. F. Barros  G. G. B. de Souza  N. V. de Castro Faria  H. M. Boechat-Roberty 《Monthly notices of the Royal Astronomical Society》2006,372(3):1379-1388

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The redshift of twelve southern ring galaxies     

M. Faúndez-Abans  R. E. de Souza 《Astrophysics and Space Science》1993,204(2):175-179

In this work the redshift of twelve southern Ring Galaxies observed at the Laboratório Nacional de Astrofísica, Brasil is obtained. The classical distances to these objects are also presented.Based on observations made at the CNPq/Laboratório Nacional de Astrofísica, Brasil.  相似文献   

Electromagnetic radiation from a source at the center of a static charged dust sphere     

L. F. Bloomfield Torres  J. A. Souza 《Astrophysics and Space Science》1993,204(1):1-8

Using Maxwell equations in a background metric discovered by Bonnor, which describes the gravitational field generated by an optimally charged dust ball, we calculate the external radiation field from an electric dipole source at the center the ball. Possible applications to stellar mode 1 s are discussed in the conclusions.  相似文献   

Genesis of the mafic impact melt rock in the northwest sector of the Vredefort Dome,South Africa     

Wolf Uwe Reimold  Natalia Hauser  Alisson Lopes Oliveira  Ana Rita Pereira Maciel  Steven Goderis  Lidia Pittarello  Wencke Wegner  Mario Fischer-Goedde  Christian Koeberl  Vinciane Debaille  Carolinna Silva Maia de Souza 《Meteoritics & planetary science》2023,58(7):907-944

Genesis and emplacement of Vredefort Granophyre, the impact melt rock exposed on the Vredefort Dome, the erosional remnant of the central uplift of the Vredefort impact structure, South Africa, have long been debated. This debate was recently reinvigorated by the discovery that besides the previously known felsic variety of >66 wt% SiO₂, a second, somewhat more mafic phase of <66 wt% SiO₂ occurs along a Granophyre dike on farms Kopjeskraal and Eldorado in the northwest sector of the dome. Two hypotheses have been put forward to explain the genesis and emplacement of this second phase: (1) successive injections of impact melt into extensional fractures opened in the course of central uplift formation/crater modification, with melts of distinct compositions derived from a differentiating impact melt body in the crater, and (2) generation of the more mafic phase as a product of admixture/assimilation of a mafic country rock component, either the so-called epidiorite of possible Ventersdorp Supergroup affiliation or the Dominion Group meta-lava (DGL), to Felsic Granophyre. In the latter model, contamination with mafic country rock would have occurred during downward intrusion and stoping into and below the crater floor. The so-called Mafic Granophyre has previously only ever been sampled on a single site (Farm Kopjeskraal). In this study, samples of Granophyre occurring along the southerly extension of this dike on farm Rensburgdrif, and from a second dike on the Rietkuil property further southwest were investigated by field work, and petrographic, geochemical, and isotopic analysis. The mafic phase indeed occurs in the interior of the dike at Rensburgdrif, and also on Rietkuil. New geochemical and Sr-Nd isotope data support the hypothesis that the Mafic Granophyre composition represents a mixture between Felsic Granophyre and a mafic country rock. A 20% admixture of epidiorite or DGL to Felsic Granophyre provides an excellent match for the chemical composition of the Mafic Granophyre. The Sr-Nd isotope data indicate that this admixture likely involved the epidiorite component rather than DGL. Together with earlier Sr-Nd-Os-Se isotopic data, and other geochemical data, these results further support formation of the Mafic Granophyre by local assimilation/admixture of epidiorite to Felsic Granophyre.  相似文献   

Prediction of sunspot number amplitude and solar cycle length for cycles 24 and 25     

N.R. Rigozo  M.P. Souza Echer  H. Evangelista  D.J.R. Nordemann  E. Echer 《Journal of Atmospheric and Solar》2011,73(11-12):1294-1299

The prediction of solar activity strength for solar cycles 24 and 25 is made on the basis of extrapolation of sunspot number spectral components. Monthly sunspot number data during the 1850–2007 interval (solar cycles 9–23) are decomposed into several levels and searched for periodicities by iterative regression in each level. For solar cycle 24, the peak is predicted in November 2013 with a sunspot number of 113.3. The cycle is expected to be weak, with a length of 133 mo (months) or 11.1 yr. The sunspot number maximum in cycle 25 is predicted to occur in April 2023 with a sunspot number 132.1 and a solar cycle length of 118 mo or 9.8 yr. Thus, solar cycle 24 is predicted to have an intensity 23% lower than cycle 23, and cycle 25 will be 5% lower than cycle 23.  相似文献   

Timing of the HT/LP transpression in the Neoproterozoic Seridó Belt (Borborema Province,Brazil): Constraints from UPb (SHRIMP) geochronology and implications for the connections between NE Brazil and West Africa     

Carlos J. Archanjo  Luiz G.F. Viegas  Maria Helena B.M. Hollanda  Laecio C. Souza  Dunyi Liu 《Gondwana Research》2013,23(2):701-714

The Seridó schist belt is a classical domain of the Borborema Province (NE Brazil) recording crustal melting at HT/LP conditions in a tectonic setting dominated by dextral transpressive deformation. A comparable tectonometamorphic setting has been described in the Pan-African Igarra and Ilesha schist belts of south Nigeria (Africa). The HT‐transpression of the Seridó has previously been imprecisely dated by using a range of isotopic methods on a suite of syntectonic granites. We provide new UPb zircon ages of the Acari granite and Santa Luzia migmatite that constrain the HT/LP metamorphism of the Seridó at c. 575 Ma. Anisotropy of magnetic susceptibility of the Santa Luzia migmatite shows that the magnetic fabric records the NE-trending dextral kinematics similar to those previously described in the Acari pluton. On the other hand, the UPb ages of the Totoró pluton provide evidence for an older, mostly mafic to intermediate magmatism intruding the pelitic schist that precedes the HT/LP metamorphism by approximately 15 m.y. In contrast with the Acari pluton and Santa Luzia migmatite, the magnetic fabrics of Totoró show a concentric steep-dipping structure apparently related to magma ascent. Thermobarometric studies in the Seridó, Igarra and Ilesha schist belts indicate that a large domain in the northern Borborema and south of the Nigeria shields was deformed at a high temperature and at relatively shallow depths. Although the tectonic setting for such a post-collision HT event remains an open issue, it allows us nevertheless to refine the across-Atlantic geological correlation between the continents.  相似文献