Deconvolving the δO seawater component from subseasonal coral δO and Sr/Ca at Rarotonga in the southwestern subtropical Pacific for the period 1726 to 1997     

Lei Ren  Braddock K. Linsley  Daniel P. Schrag 《Geochimica et cosmochimica acta》2003,67(9):1609-1621

To reconstruct oceanographic variations in the subtropical South Pacific, 271-year long subseasonal time series of Sr/Ca and δ¹⁸O were generated from a coral growing at Rarotonga (21.5°S, 159.5°W). In this case, coral Sr/Ca appears to be an excellent proxy for sea surface temperature (SST) and coral δ¹⁸O is a function of both SST and seawater δ¹⁸O composition (δ¹⁸O_sw). Here, we focus on extracting the δ¹⁸O_sw signal from these proxy records. A method is presented assuming that coral Sr/Ca is solely a function of SST and that coral δ¹⁸O is a function of both SST and δ¹⁸O_sw. This method separates the effects of δ¹⁸O_sw from SST by breaking the instantaneous changes of coral δ¹⁸O into separate contributions by instantaneous SST and δ¹⁸O_sw changes, respectively. The results show that on average δ¹⁸O_sw at Rarotonga explains ∼39% of the variance in δ¹⁸O and that variations in SST explains the remaining ∼61% of δ¹⁸O variance. Reconstructed δ¹⁸O_sw shows systematic increases in summer months (December-February) consistent with the regional pattern of variations in precipitation and evaporation. The δ¹⁸O_sw also shows a positive linear correlation with satellite-derived estimated salinity for the period 1980 to 1997 (r = 0.72). This linear correlation between reconstructed δ¹⁸O_sw and salinity makes it possible to use the reconstructed δ¹⁸O_sw to estimate the past interannual and decadal salinity changes in this region. Comparisons of coral δ¹⁸O and δ¹⁸O_sw at Rarotonga with the Pacific decadal oscillation index suggest that the decadal and interdecadal salinity and SST variability at Rarotonga appears to be related to basin-scale decadal variability in the Pacific.  相似文献   

A late quaternary record of eolian silt deposition in a maar lake, St. Michael Island, western Alaska     

Daniel R Muhs  Thomas A AgerJosh Been  J.Platt BradburyWalter E Dean 《Quaternary Research》2003,60(1):110-122

Recent stratigraphic studies in central Alaska have yielded the unexpected finding that there is little evidence for full-glacial (late Wisconsin) loess deposition. Because the loess record of western Alaska is poorly exposed and not well known, we analyzed a core from Zagoskin Lake, a maar lake on St. Michael Island, to determine if a full-glacial eolian record could be found in that region. Particle size and geochemical data indicate that the mineral fraction of the lake sediments is not derived from the local basalt and is probably eolian. Silt deposition took place from at least the latter part of the mid-Wisconsin interstadial period through the Holocene, based on radiocarbon dating. Based on the locations of likely loess sources, eolian silt in western Alaska was probably deflated by northeasterly winds from glaciofluvial sediments. If last-glacial winds that deposited loess were indeed from the northeast, this reconstruction is in conflict with a model-derived reconstruction of paleowinds in Alaska. Mass accumulation rates in Zagoskin Lake were higher during the Pleistocene than during the Holocene. In addition, more eolian sediment is recorded in the lake sediments than as loess on the adjacent landscape. The thinner loess record on land may be due to the sparse, herb tundra vegetation that dominated the landscape in full-glacial time. Herb tundra would have been an inefficient loess trap compared to forest or even shrub tundra due to its low roughness height. The lack of abundant, full-glacial, eolian silt deposition in the loess stratigraphic record of central Alaska may be due, therefore, to a mimimal ability of the landscape to trap loess, rather than a lack of available eolian sediment.  相似文献   

Tracing the flow of organic matter from primary producers to filter feeders in Ria Formosa lagoon, Southern Portugal     

Raquel Machás  Rui Santos  Bruce Peterson 《Estuaries and Coasts》2003,26(4):846-856

The flow of organic matter along the main navigation channel of Ria Formosa, Portugal, was assessed using determinations of suspended particulate matter (SPM), particulate organic matter (POM), and chlorophyll a (chla) concentrations in conjunction with stable isotope values of primary producers, particulate matter, and two filter feeders. SPM in the lagoon is dominated by inorganic particles comprising 80% of total weight with organic matter averaging about 20%. The algal component of the POM averaged about 5% with the remainder comprised of detritus. The δ¹³C values of primary producers ranged from ?9.1‰ in the intertidal seagrassZostera noltii to ?30.7‰ in the red seaweedBostrychia scorpioides revealing underlying differences in the mechanisms of carbon uptake. The δ¹³C value ofB. scorpioides, which develops entangled on the salt marsh speciesSpartina maritima, suggests that its main source of inorganic carbon is atmospheric CO₂. The δ¹³C values of the high marsh macrophyteSarcocornia perennis significantly increased with distance from the ocean while δ¹³C values ofZ. noltii decreased, probably because higher decomposition of organic matter at inner stations lowers the δ¹³CO₂ value in the water. The δ¹⁵N values of Ulvales, seagrasses, and marsh plants significantly increased from outer stations to inner stations. This increase may be due either to recycling of nitrogen (N) within the marsh (with loss of light N₂ or NH₄) or to inputs of isotopically heavy N from sewage. The δ¹⁵N values of particulate matter showed an opposite trend, which indicates higher microbial degradation of organic matter at the inner lagoon. The data demonstrate that the seston in the lagoon is a mixture of detritus from lagoon primary producers with a minor contribution of microalgae. The filter feeders are most likely assimilating a mixture of phytoplankton and microphytobenthos. Digestion of lagoon seston is selective. The δ¹⁵N values of both muscle and digestive gland of filter feeders showed the opposite gradient of particulate matter indicating that the depleted δ¹⁵N of SPM at inner stations was not assimilated or even ingested. Stable isotopes values did not differ between the filter-feeders—the musselMytilus galloprovincialis collected on buoys and the clamTapes decussatus collected in the sediment—suggesting a considerable mixture of benthic-pelagic organic matter throughout the water column. Assessment of the changes in isotopic decomposition of detritus as it decays is required to refine our understanding of organic matter transfers in detrital food webs.  相似文献   

Comparative studies of the kinetic parameters of various algaenans and kerogens via open-system pyrolyses     

Daniel Dessort  Jacques Connan  Sylvie Derenne  Claude Largeau 《Organic Geochemistry》1997,26(11-12)

Kinetic parameters were determined for the first time, via open-system pyrolyses, on algaenans (highly resistant biomacromolecules that are selectively preserved during kerogen formation) isolated from extant microalgae. Parallel studies were also carried out on 10 kerogens exhibiting, with one exception, a low level of maturity. These kerogens included samples chiefly derived from the selective preservation of the above algaenans and samples mainly, or almost exclusively, derived from the “natural vulcanization” pathway. Important differences in activation energy (E_a) distributions were observed between the four algaenans investigated and correlated with their chemical structures. The kerogens predominantly derived from algaenan-selective preservation (Pula alginite, NE 70 and BJ 248 Torbanites, Rundle Oil Shale) also exhibited pronounced differences in E_a distributions. These distributions provided: (i) information on the diversity of the source materials; and (ii) reflected the occurrence of important differences in chemical structures and thermal behaviour between three of the tested kerogens, even though they are all classified as low maturity type I. The Kimmeridge Clay samples and the Lorca Oil Shale showed broad E_a distributions shifted to low energies when compared with the above algaenans and kerogens. Such shifts reflect an important (or even almost exclusive for some of these kerogens) contribution of materials originating from sulphur incorporation into various lipids during early diagenesis. Finally, the kinetic data derived for the nine low maturity fossil samples were extrapolated to a very low, geological heating rate of 3°C Ma⁻¹ and the generation rate curves and cumulative yield curves thus obtained were compared.  相似文献   

Partial melting of metagreywackes, Part II. Compositions of minerals and melts   总被引：16，自引：0，他引：16  

Jean-Marc Montel  Daniel Vielzeuf 《Contributions to Mineralogy and Petrology》1997,128(2-3):176-196

A series of experiments on the fluid-absent melting of a quartz-rich aluminous metagreywacke has been carried out. In this paper, we report the chemical composition of the phases present in the experimental charges as determined by electron microprobe. This analytical work includes biotite, plagioclase, orthopyroxene, garnet, cordierite, hercynite, staurolite, gedrite, oxide, and glass, over the range 100–1000 MPa, 780–1025 °C. Biotites are Na- and Mg-rich, with Ti contents increasing with temperature. The compositions of plagioclase range from An₁₇ to An₃₅, with a significant orthoclase component, and are always different from the starting minerals. At high temperature, plagioclase crystals correspond to ternary feldspars with Or contents in the range 11–20 mol%. Garnets are almandine pyrope grossular spessartine solid solutions, with a regular and significant increase of the grossular content with pressure. All glasses are silicic (SiO₂ = 67.6–74.4 wt%), peraluminous, and leucocratic (FeO + MgO = 0.9–2.9 wt%), with a bulk composition close to that of peraluminous leucogranites, even for degrees of melting as high as 60 vol.%. With increasing pressure, SiO₂ contents decrease while K₂O increases. At any pressure, the melt compositions are more potassic than the water-saturated granitic minima. The H₂O contents estimated by mass balance are in the range 2.5–5.6 wt%. These values are higher than those predicted by thermodynamic models. Modal compositions were estimated by mass balance calculations and by image processing of the SEM photographs. The positions of the 20 to 70% isotects (curves of equal proportion of melt) have been located in the pressure-temperature space between 100 MPa and 1000 MPa. With increasing pressure, the isotects shift toward lower temperature between 100 and 200 MPa, then bend back toward higher temperature. The melting interval increases with pressure; the difference in temperature between the 20% and the 70% isotects is 40 °C at 100 MPa, and 150 °C at 800 MPa. The position of the isotects is interpreted in terms of both the solubility of water in the melt and the nature of the reactions involved in the melting process. A comparison with other partial melting experiments suggests that pelites are the most fertile source rocks above 800 MPa. The difference in fertility between pelites and greywackes decreases with decreasing pressure. A review of the glass compositions obtained in experimental studies demonstrates that partial melting of fertile rock types in the crust (greywackes, pelites, or orthogneisses) produces only peraluminous leucogranites. More mafic granitic compositions such as the various types of calk-alkaline rocks, or mafic S-type rocks, have never been obtained during partial melting experiments. Thus, only peraluminous leucogranites may correspond to liquids directly formed by partial melting of metasediments. Other types of granites involve other components or processes, such as restite unmixing from the source region, and/or interaction with mafic mantle-derived materials. Received: 11 July 1995 / Accepted: 27 February 1997  相似文献   

Harmonic Analysis of Sedimentary Cyclic Sequences in Kansas, Midcontinent, USA     

Daniel F. Merriam  Joseph E. Robinson 《Mathematical Geology》1997,29(8):953-962

Several stratigraphic sequences in the Upper Carboniferous (Pennsylvanian) in Kansas (Midcontinent, USA) were analyzed quantitatively for periodic repetitions. The sequences were coded by lithologic type into strings of datasets. The strings then were analyzed by an adaptation of a one-dimensional Fourier transform analysis and examined for evidence of periodicity. The method was tested using different states in coding to determine the robustness of the method and data. The most persistent response is in multiples of 8–10 ft (2.5–3.0 m) and probably is dependent on the depositional thickness of the original lithologic units. Other cyclicities occurred in multiples of the basic frequency of 8–10 with persistent ones at 22 and 30 feet (6.5–9.0 m) and large ones at 80 and 160 feet (25–50 m). These levels of thickness relate well to the basic cyclothem and megacyclothem as measured on outcrop. We propose that this approach is a suitable one for analyzing cyclic events in the stratigraphic record.  相似文献   

Greenhouse Gas Emissions from Hydroelectric Reservoirs in Tropical Regions   总被引：2，自引：1，他引：2  

Luiz Pinguelli Rosa  Marco Aurelio dos Santos  Bohdan Matvienko  Ednaldo Oliveira dos Santos  Elizabeth Sikar 《Climatic change》2004,66(1-2):9-21

This paper discusses emissions by power-dams in the tropics. Greenhouse gas emissions from tropical power-dams are produced underwater through biomass decomposition by bacteria. The gases produced in these dams are mainly nitrogen, carbon dioxide and methane. A methodology was established for measuring greenhouse gases emitted by various power-dams in Brazil. Experimental measurements of gas emissions by dams were made to determine accurately their emissions of methane (CH₄) and carbon dioxide (CO₂) gases through bubbles formed on the lake bottom by decomposing organic matter, as well as rising up the lake gradient by molecular diffusion.The main source of gas in power-dams reservoirs is the bacterial decomposition (aerobic and anaerobic) of autochthonous and allochthonous organic matter that basically produces CO₂ and CH₄. The types and modes of gas production and release in the tropics are reviewed.  相似文献   

The organisation of fish assemblages in the regulated Lima basin, Northern Portugal     

Jos Maria Santos  Francisco Godinho  Maria Teresa Ferreira  Rui Cortes 《Limnologica》2004,34(3):224-235

In order to understand the structure of fish assemblages in the modified Lima basin (Northern Portugal), two distinct datasets concerning the presence and abundance of fish species were subjected to multivariate analysis. On the River Lima two types of flow modification are present within kilometres of one another: (a) a reduced and constant flow due to hypolimnetic release; and (b) an intense and irregular flow. A comparison of their influence on fish assemblages revealed a gradient of assemblage types from tributaries to main river sites. The latter were characterised by a strong dominance of cyprinids, particularly Iberian barbel (Barbus bocagei). The former harboured two kinds of fish assemblages: those closer to the river mouth were dominated by the cyprinids Iberian chub (Squalius carolitertii) and Iberian nase (Chondrostoma polylepis), which were also frequently present in the main river; while in those further upstream the predominant species was the brown trout (Salmo trutta). Although explanatory variables such as distance from source, altitude, substrate coarseness and width were the primary correlates of fish assemblage composition, dam construction and flow regulation also had a significant effect upon assemblage structure, particularly by: i) reducing the importance of migratory species; ii) constraining the presence of trout in the regulated segments; and iii) simplifying the community, especially in the case of the constant and reduced flow regime.  相似文献   

A vibrational spectroscopic study of the oxidation of pyrite by molecular oxygen     

Michael J Borda  Daniel R Strongin 《Geochimica et cosmochimica acta》2004,68(8):1807-1813

In situ flow-through attenuated total reflectance (ATR) Fourier transform infrared (FTIR) spectroscopy has been used to investigate the formation, and step-wise oxidation, of sulfoxyanions at the pyrite surface during oxidation by molecular oxygen. The surface was studied under two different pH regimes (pH 2.5 and pH 5.6) and under two light conditions (dark and ultraviolet light). It was experimentally observed that multiple sulfoxyanions were present at the pyrite surface during oxidation by molecular oxygen, spectroscopically illustrating the concept of sulfur step-wise oxidation. The results from photochemical experiments were complex and suggest a dependence on both pH and surface speciation.  相似文献   

Are isolated stable rigid clasts in shear zones equivalent to voids?     

Daniel W. Schmid  Yuri Yu. Podladchikov 《Tectonophysics》2004,384(1-4):233-242

Particles in shear enclose important information about a rock's past and can potentially be used to decipher the kinematic history and mechanical behavior of a certain outcrop or region. Isolated rigid clasts in shear zones often exhibit systematic inclinations with respect to the shear-plane at small angles, tending towards the instantaneous stretching direction of the shear zone. This shape preferred orientation cannot be easily explained by any of the analytical theories used in geology. It was recently recognized that a weak mantle surrounding the clast or a slipping clast–matrix interface might be responsible for the development of the observed inclinations. Physical considerations lead us to conjecture that such mantled, rigid clasts can be effectively treated as voids that are not allowed to change their shape. The resulting equivalent void conjecture agrees well with numerical and field data and has the following important geological implications. (i) Clasts in shear zones can have stable positions in simple shear without the requirement of an additional pure shear component. (ii) The stable orientation can be approached either syn- or antithetically; hence, the clast can rotate against the applied shear sense. (iii) The strain needed to develop a strong shape preferred orientation is small (γ≈1) and therefore evaluations based on other theories may overestimate strain by orders of magnitude. (iv) The reconstruction of far-field shear flow conditions and kinematic vorticity analysis must be modified to incorporate these new findings.  相似文献