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Abstract— The Ordovician Lockne impact structure is located in central Sweden. The target lithology consisted of limestone and black unconsolidated shale overlaying a Precambrian crystalline basement. The Precambrian basement is uranium‐rich, and the black shale is both uranium‐ and organic‐rich. This circumstance makes Lockne a good candidate for testing the occurrence of U‐Th‐rich bitumen nodules in an impact structure setting. U‐Th‐rich bitumen nodules are formed through irradiation; hence the increase in the complexity of organic matter by a radioactive (uranium‐ and thorium‐rich) mineral phase. U‐Th‐rich bitumen nodules were detected in crystalline impact breccia and resurge deposits from the impact structure, but samples of non‐impact‐affected rocks from outside the impact structure do not contain any U‐Th‐rich bitumen nodules. This implies that in the Lockne impact structure, the nodules are associated with impact‐related processes. U‐Th‐rich bitumen nodules occur throughout the geological record and are not restricted to an impact structure setting, but our studies at Lockne show that this process of irradiation can readily occur in impact structures where fracturing of rocks and a post‐impact hydrothermal system enhances fluid circulation. The irradiation of organic matter by radioactive minerals has previously been proposed as a process for concentration of carbon on the early Earth. Impact structures are suggested as sites for prebiotic chemistry and primitive evolution, and irradiation by radioactive minerals could be an important mechanism for carbon concentration at impact sites.  相似文献   
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Quantitative techniques that link sediments to their sources are needed to understand a range of tectonic, climate, and anthropogenic driven Earth surface processes. Many provenance techniques exist for sand-sized material but fewer are available for fine-grained sediment archives. In this respect, bulk 40Ar/39Ar ages from silt-sized sediment show potential, but many questions remain about the significance of a bulk sediment 40Ar/39Ar age. We interrogate bulk sediment 40Ar/39Ar ages by step heating mixtures of well-constrained 40Ar/39Ar mineral standards crushed to silt-sized. Silt-sized end member components Alder Creek Sanidine, Taylor Creek Sanidine and Heidelberg Biotite all yield plateau ages within uncertainty of their coarse-grained counterparts. High-resolution step heating (as many as 43 steps) of the mineral mixtures shows that biotite degasses first at lower temperatures compared to the two sanidines that degas generally in concert. Concordant age steps develop at both low and high temperatures and the transition from the isotope signal being dominated by one mineral phase to another is clearly observed. We show that age spectra for the mineral standard mixtures can be modeled and predicted for all mixtures by assuming a (simplistic) Gaussian distributed release of Ar, and by using the degassing maxima, variance, K concentration, and 40Ar/39Ar age of each monitor mineral. Thus, bulk sediment 40Ar/39Ar ages can be robust indicators of the average cooling/crystallization age of all contributing K-bearing minerals to a depositional center. Furthermore, we discuss the potential to deconvolve individual mineral age populations by model inversion. The application of this bulk sediment provenance technique should not be considered a replacement for single grain analyses. It should be applied to environments that do not provide sand-sized sediment archives (e.g., distal terrigenous sedimentary archives) when information about source changes through time are more important than precise sediment source identification.  相似文献   
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Soil particles may be lost through dissolution, degradation or erosion. Regardless of the process of loss, there follows a change in soil structure both in terms of phase composition and grading. In this paper, the influence of size and amount of particle loss on phase composition at two stresses is investigated. The tests are performed on sand–salt mixtures, loaded in a modified permeation oedometer and subsequently dissolved. Changes in overall volume and void ratio are presented. Two significant observations about the volumetric consequences of particle loss can be made. First, overall volume changes are directly related to the amount of dissolved particles and to a lesser extent, the size of particle lost. Second, particle loss leads to an increase in void ratio; the magnitude of the increase is related to the amount of dissolved particles but appears not to be sensitive to either the size of particle lost or the pre-dissolution void ratio. Based on the observed response and a dissolution-induced void change parameter, the influence of different mechanisms of volume change is discussed. Tests were performed at two different vertical stresses with no discernible influence on void ratio change.  相似文献   
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We compared water chemistry and environmental data with midge assemblage data, using multivariate analysis to assess the environmental gradients that limit midge (Chironomidae, Chaoboridae and Ceratopogonidae) distributions in the Hudson Bay Lowlands, northeastern Manitoba, Canada. Midge remains, comprising 62 taxa, were obtained from surficial sediments of 63 ponds. Ponds were sampled to maximize the salinity gradient. Specific conductance ranged from 46 to 29,000 μS cm?1. Proximity to the coast was a principal determinant of pond salinity, with ponds closer to Hudson Bay shoreline more saline that those farther away. Multivariate analysis indicated that midge distributions have a significant relationship ( $ {\text{r}}_{\text{boot}}^{2} = 0.68 $ ) with salinity in the data set. This work will allow paleolimnological inferences of midge community responses to changing sea level (i.e. salinity) via isostatic rebound within the Hudson Bay Lowlands, and will provide essential limnological information to scientists and managers in a region where understanding of aquatic ecosystems is limited. One undescribed midge taxon was dominant in ponds with the highest salinities and may be a key indicator for inferring highly saline environments.  相似文献   
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