A benchmark study on problems related to CO2 storage in geologic formations   总被引：1，自引：0，他引：1  

Holger Class  Anozie Ebigbo  Rainer Helmig  Helge K. Dahle  Jan M. Nordbotten  Michael A. Celia  Pascal Audigane  Melanie Darcis  Jonathan Ennis-King  Yaqing Fan  Bernd Flemisch  Sarah E. Gasda  Min Jin  Stefanie Krug  Diane Labregere  Ali Naderi Beni  Rajesh J. Pawar  Adil Sbai  Sunil G. Thomas  Laurent Trenty  Lingli Wei 《Computational Geosciences》2009,13(4):409-434

  相似文献   

Effect of varied atmospheric stability on sea surface drag in shallow seas and its impact on wind-wave growth     

R. Rajesh Kumar  B. Prasad Kumar  A. N. V. Satyanarayana  D. Bala Subrahamanyam  A. D. Rao  S. K. Dube 《Natural Hazards》2009,49(2):213-224

This work reports an efficient bulk formulation of sea surface drag that incorporates effect of dynamic stability under varied atmospheric forcing. The proposed formulation exhibits a polynomial dependence of wind speed on air–sea temperature difference based on statistical analysis. Quality checked meteorological and oceanographic data from four shallow water buoys located off Korean seas having measurements at an interval of every 1 h were used for this study. The analyses of in situ records for this region suggest stability ranging from highly stable to very unstable conditions. Importance of this proposed formulation is better reflected during unstable condition where other popular bulk formulations fail. In addition, importance and impact of such a study on wind-wave growth using the state-of-art wave model was also investigated. Finally, we advocate a new drag formulation, which accounts for varied atmospheric stability and suggest that this should be considered as an essential pre-requisite for ocean modeling studies.  相似文献   

Precambrian mafic magmatism in the Bastar craton,central India     

Rajesh K. Srivastava  Gulab C. Gautam 《Journal of the Geological Society of India》2009,73(1):52-72

The Bastar craton has experienced many episodes of mafic magmatism during the Precambrian. This is evidenced from a variety of Precambrian mafic rocks exposed in all parts of the Bastar craton in the form of volcanics and dykes. They include (i) three distinct mafic dyke swarms and a variety of mafic volcanic rocks of Precambrian age in the southern Bastar region; two sets of mafic dyke swarms are sub-alkaline tholeiitic in nature, whereas the third dyke swarm is high-Si, low-Ti and high-Mg in nature and documented as boninite-norite mafic rocks, (ii) mafic dykes of varying composition exposed in Bhanupratappur-Keskal area having dominantly high-Mg and high-Fe quartz tholeiitic compositions and rarely olivine and nepheline normative nature, (iii) four suites of Paleoproterozoic mafic dykes are recognized in and around the Chattisgarh basin comprising metadolerite, metagabbro, and metapyroxenite, Neoarchaean amphibolite dykes, Neoproterozoic younger fine-grained dolerite dykes, and Early Precambrian boninite dykes, and (iv) Dongargarh mafic volcanics, which are classified into three groups, viz. early Pitepani mafic volcanic rocks, later Sitagota and Mangikhuta mafic volcanics, and Pitepani siliceous high-magnesium basalts (SHMB). Available petrological and geochemical data on these distinct mafic rocks of the Bastar craton are summarized in this paper. Recently high precision U-Pb dates of 1891.1±0.9 Ma and 1883.0±1.4 Ma for two SE-trending mafic dykes from the BD2 (subalkaline) dyke swarm, from the southern Bastar craton have been reported. But more precise radiometric age determinations for a number of litho-units are required to establish discrete mafic magmatic episodes experienced by the craton. It is also important to note that very close geochemical similarity exist between boninite-norite suite exposed in the Bastar craton and many parts of the world. Spatial and temporal correlation suggests that such magmatism occurred globally during the Neoarchaean-Paleoproterozoic boundary. Many Archaean terrains were united as a supercontinent as Expanded Ur and Arctica at that time, and its rifting gave rise to numerous mafic dyke swarms, including boninitenorite, world-wide.  相似文献   

Precambrian mafic magmatism in the Indian shield: Retrospect and prospect     

Rajesh K. Srivastava  Talat Ahmad 《Journal of the Geological Society of India》2009,73(1):7-11

  相似文献   

Petrology and geochemistry of diamondiferous Mesoproterozoic kimberlites from Wajrakarur kimberlite field,Eastern Dharwar craton,southern India: genesis and constraints on mantle source regions   总被引：1，自引：0，他引：1  

N. V. Chalapathi Rao  Rajesh K. Srivastava 《Contributions to Mineralogy and Petrology》2009,157(2):245-265

The petrology and geochemistry of some new occurrences of Mesoproterozoic diamondiferous hypabyssal-facies kimberlites from the Chigicherla, Wajrakarur-Lattavaram and Kalyandurg clusters of the Wajrakarur kimberlite field (WKF), Eastern Dharwar craton (EDC), southern India, are reported. The kimberlites contain two generations of olivine, and multiple groundmass phases including phlogopite, spinel, calcite, dolomite, apatite, perovskite, apatite and rare titanite, and xenocrysts of eclogitic garnet and picro-ilmenite. Since many of the silicate minerals in these kimberlites have been subjected to carbonisation and alteration, the compositions of the groundmass oxide minerals play a crucial role in their characterisation and in understanding melt compositions. While there is no evidence for significant crustal contamination in these kimberlites, some limited effects of ilmenite entrainment are evident in samples from the Kalyandurg cluster. Geochemical studies reveal that the WKF kimberlites are less differentiated and more primitive than those from the Narayanpet kimberlite field (NKF), Eastern Dharwar craton. Highly fractionated (La/Yb = 108–145) chondrite-normalised distribution patterns with La abundances of 500–1,000 × chondrite and low heavy rare earth elements (HREE) abundances of 5–10 × chondrite are characteristic of these rocks. Metasomatism by percolating melts from the convecting mantle, rather than by subduction-related processes, is inferred to have occurred in their source regions based on incompatible element signatures. While the majority of the Eastern Dharwar craton kimberlites are similar to the Group I kimberlites of southern Africa in terms of petrology, geochemistry and Sr–Nd isotope systematics, others show the geochemical traits of Group II kimberlites or an overlap between Group I and II kimberlites. Rare earth element (REE)-based semi-quantitative forward modelling of batch melting of southern African Group I and II kimberlite source compositions involving a metasomatised garnet lherzolite and very low degrees of partial melting demonstrate that (1) WKF and NKF kimberlites display a relatively far greater range in the degree of melting than those from the on-craton occurrences from southern Africa and are similar to that of world-wide melilitites, (2) different degrees of partial melting of a common source cannot account for the genesis of all the EDC kimberlites, (3) multiple and highly heterogeneous kimberlite sources involve in the sub-continental lithospheric mantle (SCLM) in the Eastern Dharwar craton and (4) WKF and NKF kimberlites generation is a resultant of complex interplay between the heterogeneous sources and their different degrees of partial melting. These observations are consistent with the recent results obtained from inversion modelling of REE concentrations from EDC kimberlites in that both the forward as wells as inverse melting models necessitate a dominantly lithospheric, and not asthenospheric, mantle source regions. The invading metasomatic (enriching) melts percolating from the convecting (asthenosphere) mantle impart an OIB-like isotopic signature to the final melt products.  相似文献   

Identification and mapping of chromium (VI) plume in groundwater for remediation: A case study at Kanpur,Uttar Pradesh   总被引：1，自引：0，他引：1  

R. K. Singh  B. Sengupta  Rameshwar Bali  B. P. Shukla  V. V. S. Gurunadharao  Rajesh Srivatstava 《Journal of the Geological Society of India》2009,74(1):49-57

With only twenty five percent population living in urban areas, India has cities amongst the biggest in the world. Urban growth in most of Indian cities is concomitant with rise in water demand for community, as well as, for industrial purposes. The complex situation resulting from indiscriminate disposal of waste and its severe impact on groundwater quality is set for continuous worsening mainly for want of sustained effort aimed at site-specific remediation. The study, a prerequisite for actual remediation in an industrial city of Kanpur, India, envisages detailed investigation about pollutant transport, evaluation of concept of Bio-remediation and a range of other options and finally full scale implementation of the best suited. Drilling of piezometers and resistivity survey indicates that the area is constituted of alluvial sands, gravels and their various admixtures. Chemical analysis of water samples collected from piezometers and hand pumps shows the presence of hexavalent chromium rich horizons at various depths. The alarming concentration of this carcinogenic heavy metal of the order of 16.3 mg/l against the permissible concentration (of 0.05 mg/l) for drinking water and high concentration within sediments of the area poses a major threat to the entire ecosystem. The projection of migration contaminant plume of hexavalent chromium as depicted in the paper is indicative of a concentrated extent of core zone existing in shallow alluvial aquifer, which may be targeted for interception by remedial measures. The present work, elaborating on the source, potential and monitoring the migration of the pollutant plume is the first field scale study of its kind in the country. The findings of these studies are of strong relevance in addressing the ground water pollution due to indiscriminate disposal practices of hazardous waste in areas located within the alluvial zones.  相似文献   

Granularity and textural analysis as a proxy for extreme wave events in southeast coast of India   总被引：1，自引：0，他引：1  

C. S. Vijaya Lakshmi  P. Srinivasan  S. G. N. Murthy  Deshraj Trivedi  Rajesh R. Nair 《Journal of Earth System Science》2010,119(3):297-305

Extreme wave events of 1000 and 1500 years (radiocarbon ages) have been recently reported in Mahabalipuram region, southeast coast of India. Subsequently, we carried out extensive sedimenttological analysis in regions covering a total lateral coverage of 12 km with a new archeological site as the central portion of the study area. Twelve trenches in shore normal profiles exhibit landward thinning sequences as well as upward fining sequences confirming with the global signatures of extreme wave events. The sediment size ranges from fine-to-medium and moderately well sorted-to-well sorted, and exhibit positive skewness with platykurtic-to-leptokurtic nature. We now propose the abrupt winnowing or back and forth motion including unidirectional transport of these deposited sediments, which results in positive skewness. Textural analyses derived from scanning electron microscope studies (SEM) demonstrate the alteration produced, in the ilmenite mineral with vivid presence of pits and crescents with deformation observed on the surface due to extreme wave activities. This is further confirmed with the predominance of high-density mineral such as magnetite (5.2) and other heavy minerals in these deposits inferred the high-intensity of the reworking process of the beach shelf sediments.  相似文献   

Biogenic uraninite precipitation and its reoxidation by iron(III) (hydr)oxides: A reaction modeling approach     

Nicolas F. Spycher  Montarat Issarangkun  S. Sevinç ?engör  Tim R. Ginn  Rajesh K. Sani 《Geochimica et cosmochimica acta》2011,75(16):4426-4440

One option for immobilizing uranium present in subsurface contaminated groundwater is in situ bioremediation, whereby dissimilatory metal-reducing bacteria and/or sulfate-reducing bacteria are stimulated to catalyze the reduction of soluble U(VI) and precipitate it as uraninite (UO₂). This is typically accomplished by amending groundwater with an organic electron donor. It has been shown, however, that once the electron donor is entirely consumed, Fe(III) (hydr)oxides can reoxidize biogenically produced UO₂, thus potentially impeding cleanup efforts. On the basis of published experiments showing that such reoxidation takes place even under highly reducing conditions (e.g., sulfate-reducing conditions), thermodynamic and kinetic constraints affecting this reoxidation are examined using multicomponent biogeochemical simulations, with particular focus on the role of sulfide and Fe(II) in solution. The solubility of UO₂ and Fe(III) (hydr)oxides are presented, and the effect of nanoscale particle size on stability is discussed. Thermodynamically, sulfide is preferentially oxidized by Fe(III) (hydr)oxides, compared to biogenic UO₂, and for this reason the relative rates of sulfide and UO₂ oxidation play a key role on whether or not UO₂ reoxidizes. The amount of Fe(II) in solution is another important factor, with the precipitation of Fe(II) minerals lowering the Fe⁺² activity in solution and increasing the potential for both sulfide and UO₂ reoxidation. The greater (and unintuitive) UO₂ reoxidation by hematite compared to ferrihydrite previously reported in some experiments can be explained by the exhaustion of this mineral from reaction with sulfide. Simulations also confirm previous studies suggesting that carbonate produced by the degradation of organic electron donors used for bioreduction may significantly increase the potential for UO₂ reoxidation through formation of uranyl carbonate aqueous complexes.  相似文献   

Phosphorus fractionation in sediments of the Pichavaram mangrove ecosystem,south-eastern coast of India     

Rajesh Kumar Ranjan  AL. Ramanathan  Rita Chauhan  Gurmeet Singh 《Environmental Earth Sciences》2011,62(8):1779-1787

Present study examined phosphorus dynamics through delineation of source as well as availability of phosphorus and its fractionation within the intertidal sediments of Pichavaram mangrove ecosystem. Twelve sediment samples and two cores were collected from the mangrove forest along with estuarine area (Vellar-Coleroon) during January 2005. Sediments were analyzed for total phosphorus and its fractionation using operationally defined chemical sequential extraction scheme (SEDEX). Dissolved phosphorus (in water) and total phosphorus (in sediments) concentrations were high in the Vellar region of Pichavaram mangrove area due to pollution load from nearby villages and agricultural fields. However, the spatial variation in dissolved phosphorus were insignificant (at significance level = 0.05). The results for the phosphorus fractionation (post-tsunami) were compared with earlier studies (pre-tsunami). It was observed that all phosphorus fractions (except adsorbed-phosphorus) showed a highly significant (at significance level = 0.05) increase in concentration after the tsunami event. There was significant decrease in the adsorbed phosphorus concentration as a result of tsunami. The changes were more pronounced for organic phosphorus which increased by almost twofold following the event. These variations were attributed to change in salinity, increase in dissolved oxygen as well as the retreat of tsunami water carrying the waste load. The vertical distribution of phosphorus through core sediments showed that mixing after tsunami had altered the different phosphorus fraction and its availability. Overall, the study indicated that the fluvial weathering along with litter degradation and anthropogenic sources controlled the biogeochemistry of phosphorus in this mangrove ecosystem. Observed changes in the concentrations are a result of altered physico-chemical characteristics caused by tsunami.  相似文献   

Effect of sludge pretreatment on the performance of anaerobic/ anoxic/ oxic membrane bioreactor treating domestic wastewater     

J. Rajesh Banu M.Sc.  M.Phil.  Ph.D.  D. K. Uan Ph.D.  S. Kaliappan BE  M. Tech.  Ph.D.  I. T. Yeom Ph.D. 《International Journal of Environmental Science and Technology》2011,8(2):281-290

In the present study, two bench-scale anaerobic/ anoxic/ oxic submerged membrane bioreactors were used to study the effect of thermochemical sludge disintegration system on the excess sludge production. Among the two membrane bioreactors, one was named experimental membrane bioreactor and another one was named as control membrane bioreactor, where a part of the mixed liquor was treated with thermo chemical and was returned back to membrane bioreactor. Thermo chemical digestion of sludge was carried out at fixed pH (11) and temperature (75 °C) for 24 % chemical oxygen demand solution. The other one was named control membrane bioreactor and was used as control. The reactors were operated at three different mixed liquor suspended solids range starting from 7500 mg/L to 15000 mg/L. Both of membrane bioreactors were operated at a flux of 17 LMH over a period of 240 days. The designed flux was increased stepwise over a period of one week. During the 240 days of reactor operation, both of membrane bioreactors maintained relatively constant transmembrane pressure. The sludge digestion had no impact on chemical oxygen demand removal efficiency of the reactor. The results based on the study indicated that the proposed process configuration has potential to reduce the excess sludge production as well as it didn’t deteriorate the treated water quality.  相似文献