Pedo-geochemical baseline content levels and soil quality reference values of trace elements in soils from the Mediterranean (Castilla La Mancha, Spain)   总被引：3，自引：0，他引：3  

Raimundo Jiménez Ballesta  Paz Conde Bueno  Juan A. Martin Rubi  Rosario Garcia Giménez 《Central European Journal of Geosciences》2010,2(4):441-454

To evaluate trace element soil contamination, geochemical baseline contents and reference values need to be established. Pedo-geochemical baseline levels of trace elements in 72 soil samples of 24 soil profiles from the Mediterranean, Castilla La Mancha, are assessed and soil quality reference values are calculated. Reference value contents (in mg kg^?1) were: Sc 50.8; V 123.2; Cr 113.4; Co 20.8; Ni 42.6; Cu 27.0; Zn 86.5; Ga 26.7; Ge 1.3; As 16.7; Se 1.4; Br 20.1; Rb 234.7; Sr 1868.4; Y 38.3; Zr 413.1; Nb 18.7; Mo 2.0; Ag 7.8; Cd 4.4; Sn 8.7; Sb 5.7; I 25.4; Cs 14.2; Ba 1049.3; La 348.4; Ce 97.9; Nd 40.1; Sm 10.7; Yb 4.2; Hf 10.0; Ta 4.0; W 5.5; Tl 2.3; Pb 44.2; Bi 2.2; Th 21.6; U 10.3. The contents obtained for some elements are below or close to the detection limit: Co, Ge, Se, Mo, Ag, Cd, Sb, Yb, Hf, Ta, W, Tl and Bi. The element content ranges (the maximum value minus the minimum value) are: Sc 55.0, V 196.0, Cr 346.0, Co 64.4, Ni 188.7, Cu 49.5, Zn 102.3, Ga 28.7, Ge 1.5, As 26.4, Se 0.9, Br 33.0 Rb 432.7, Sr 3372.6, Y 39.8, Zr 523.2, Nb 59.7, Mo 3.9, Ag 10.1, Cd 1.8, Sn 75.2, Sb 9.9, I 68.0, Cs 17.6, Ba 1394.9, La 51.3, Ce 93.5, Nd 52.5, Sm 11.2, Yb 4.2, Hf 11.3, Ta 6.3, W 5.2, Tl 2.1, Pb 96.4, Bi 3.0, Th 24.4, U 16.4 (in mg kg^?1). The spatial distribution of the elements was affected mainly by the nature of the bedrock and by pedological processes. The upper limit of expected background variation for each trace element in the soil is documented, as is its range as a criterion for evaluating which sites may require decontamination.  相似文献   

Galactic X-ray binary jets     

Elena Gallo 《Astrophysics and Space Science》2007,311(1-3):161-165

With their relatively fast variability time-scales, Galactic X-ray binaries provide an excellent laboratory to explore the physics of accretion and related phenomena, most notably outflows, over different regimes. After comparing the phenomenology of jets in black hole systems to that of neutron stars, here I discuss the role of the jet at very low Eddington ratios, and present preliminary results obtained by fitting the broadband spectral energy distribution of a quiescent black hole binary with a ‘maximally jet-dominated’ model. Chandra Fellow  相似文献   

Changing hillslope and fluvial Holocene sediment dynamics in a Belgian loess catchment     

Bastiaan Notebaert  Gert Verstraeten  Dimitri Vandenberghe  Elena Marinova  Jean Poesen  Gerard Govers 《第四纪科学杂志》2011,26(1):44-58

Floodplain deposition is an essential part of the Holocene sediment dynamics of many catchments and a thorough dating control of these floodplain deposits is therefore essential to understand the driving forces of these sediment dynamics. In this paper we date floodplain and colluvial deposition in the Belgian Dijle catchment using accelerator mass spectrometric radiocarbon and optical stimulated luminescence dating. Relative mass accumulation curves for the Holocene were constructed for three colluvial sites and 12 alluvial sites. A database was constructed of all available radiocarbon ages of the catchment and this database was analysed using relative sediment mass accumulation rates and cumulative probability functions of ages and site‐specific sedimentation curves. Cumulative probability functions of ages were split into different depositional environments representing stable phases and phases of accelerated clastic deposition. The results indicate that there is an important variation between the different dated sites. After an initial stable early and middle Holocene phase with mainly peat growth in the floodplains, clastic sedimentation rates increased from 4000 BC on. This first phase was more pronounced and started somewhat earlier for colluvial deposits then for alluvial deposits. The main part of the Holocene deposits, both in colluvial and alluvial valleys, was deposited during the last 1 ka. The sedimentation pattern of the individual dated sites and the catchment‐wide pattern indicate that land use changes are responsible for the main variations in the Holocene sediment dynamics of this catchment, while the field data do not provide indications for a climatological influence on the sediment dynamics. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Kinematics of gas and stars in the circumnuclear star-forming ring of NGC 3351     

Guillermo F. Hägele †  Ángeles I. Díaz ‡  Mónica V. Cardaci †  Elena Terlevich §  Roberto Terlevich § 《Monthly notices of the Royal Astronomical Society》2007,378(1):163-178

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Palaeomagnetism of the Ferrar dolerite in the northern Prince Albert Mountains (Victoria Land, Antarctica)     

Roberto Lanza  Elena Zanella 《Geophysical Journal International》1993,114(3):501-511

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Complex geographical analysis of the Greater Sochi region on the Black Sea coast     

Elena A. Rybak  Oleg O. Rybak  Yuri V. Zasedatelev 《GeoJournal》1994,34(4):507-513

Results of the complex analysis of the unique natural territory of Greater Sochi from the point of view of physical geography are considered. The region of Greater Sochi is located on the S slopes of the Main Caucasus chain on the eastern coast of the Black Sea. Morphometrical analysis of the relief and analysis air surface temperature and precipitation allowed to distinguish four specific subregions within the whole territory. It is demonstrated that the period of stable snow cover in the two subregions which occupy more than half of the region's area is sufficient for successful development of winter tourism. Peculiar combination of the mild climate of the coast with stable snow cover in the mountains till the beginning of summer provide strong attractivity of the region for all-the-year-round tourists inflow to the most modern recreational centre of Russia. The work provides the methodology for similar studies.  相似文献   

Earthquake Swarms In the Kamchatka-Commander Region     

Vyacheslav M. Zobin  Elena I. Ivanova 《Geophysical Journal International》1994,117(1):33-47

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Chromite composition and platinum-group mineral assemblage in the Uktus Uralian-Alaskan-type complex (Central Urals,Russia)     

Giorgio?GarutiEmail author  Evgeny?V.?Pushkarev  Federica?Zaccarini  Roberto?Cabella  Elena?Anikina 《Mineralium Deposita》2003,38(3):312-326

Chromitite segregations in dunites of the Uktus Uralian-Alaskan-type complex (Central Urals, Russia) display large variation of the chromite composition: Cr/(Cr+Al)=0.46-0.77, Fe²⁺/(Fe²⁺+Mg)=0.28-0.66, and Fe³⁺/(Fe³⁺+Fe²⁺)=0.23-0.59. Three types of PGM assemblages have been recognized, varying in accordance with chromite composition: type I, dominated by Ru-Os-Ir (sulfides), is associated with magnesiochromite having Fe³⁺/(Fe³⁺+Fe²⁺)<0.30, in the southern dunite body. Type II, containing abundant Pt-Ir (alloys, minor sulfides), is found in magnesiochromite with Fe³⁺/(Fe³⁺+Fe²⁺)=0.40-0.44; type III, consisting of Ir-Rh-Pt-Pd (alloys, sulfarsenides, antimonides) in Fe-rich chromite having Fe²⁺/(Fe²⁺+Mg)=0.66 and Fe³⁺/(Fe³⁺+Fe²⁺)=0.59. Positive anomalies of Ir and Pt, and a negative peak of Ru characterize the PGE patterns of chromitites with type II and III PGM assemblages, whereas a positive Pt anomaly is observed in their dunite host. Intensive fractionation of Pt-Fe alloys in the Uktus chromitites reflects the anomalous behavior of Pt which is decoupled from Rh and Pd. Among other factors, the high iron activity and oxygen fugacity in the parent melt appear to exert a major control on precipitation of Pt-Fe alloys, below sulfur saturation. The strong Pt anomaly in chromitites from Uktus may indicate that Uralian-Alaskan-type magmas were derived from a Pt-rich mantle source.  相似文献   

Cytochrome P4501A expression,chemical contaminants and histopathology in roach,goby and sturgeon and chemical contaminants in sediments from the Caspian Sea,Lake Balkhash and the Ily River Delta,Kazakhstan   总被引：1，自引：0，他引：1  

Moore MJ  Mitrofanov IV  Valentini SS  Volkov VV  Kurbskiy AV  Zhimbey EN  Eglinton LB  Stegeman JJ 《Marine pollution bulletin》2003,46(1):107-119

Roach, goby and sturgeon were examined for cytochrome P4501A (CYP1A) expression and histopathology, in relation to contaminant burdens in fish and sediment. Gradients of induction of CYP1A were observed. Roach from the Ural and Ily River Deltas and roach and goby from the two stations nearest the Caspian Sea oil fields displayed higher levels of CYP1A expression in several organs than was observed in fish from further offshore. Great sturgeon and Russian sturgeon showed higher levels of CYP1A expression than was seen in starred sturgeon and gobies in the Ural delta. No fish showed evidence of contaminant-related histopathologies in the organs examined, despite the elevated CYP1A levels. Low levels of polychlorinated biphenyls and elevated levels of inshore and riverine petroleum hydrocarbons from these habitats suggest that this ongoing hydrocarbon exposure, and that from natural sources and long-term oil exploration on the Northeastern Caspian shore, contributed to the CYP1A induction observed.  相似文献   

The use of a non-lethal tool for evaluating toxicological hazard of organochlorine contaminants in Mediterranean cetaceans: new data 10 years after the first paper published in MPB     

Fossi MC  Marsili L  Neri G  Natoli A  Politi E  Panigada S 《Marine pollution bulletin》2003,46(8):972-982

In the Mediterranean Sea, top predators, and particularly cetacean odontocetes, accumulate high concentrations of organochlorine contaminants and toxic metals, incurring high toxicological risk. In this paper we investigate the use of the skin biopsies as a non-lethal tool for evaluating toxicological hazard of organochlorines in Mediterranean cetaceans, presenting new data 10 years after the paper published by Fossi and co-workers [Mar. Poll. Bull. 24 (9) (1992) 459] in which this new methodology was first presented. Some organochlorine compounds, now with worldwide distribution, are known as endocrine disrupting chemicals (EDCs). Here the unexplored hypothesis that Mediterranean cetaceans are potentially at risk due to organochlorines with endocrine disrupting capacity is investigated. High concentrations of DDT metabolites and PCB congeners (known as EDCs) were found in the different Mediterranean species (Stenella coeruleoalba, Delphinus delphis, Tursiops truncatus and Balaenoptera physalus). In this paper we also propose benzo(a)pyrene monooxygenase (BPMO) activity in marine mammal skin biopsies (non-lethal biomarker) as a potential indicator of exposure to organochlorines, with special reference to the compounds with endocrine disrupting capacity. A statistically significant correlation was found between BPMO activity and organochlorine levels (DDTs, pp(')DDT, op(')DDT, PCBs and PCB99) in skin biopsies of males of B. physalus. Moreover a statistical correlation was also found between BPMO activity and DDT levels in skin biopsies of the endangered Mediterranean population of D. delphis. These results suggest that BPMO induction may be an early sign of exposure to organochlorine EDCs and can be used for periodic monitoring of Mediterranean marine mammal toxicological status.  相似文献