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201.
A numerical method is formulated for the solution of the advective Cahn–Hilliard (CH) equation with constant and degenerate mobility in three-dimensional porous media with non-vanishing velocity on the exterior boundary. The CH equation describes phase separation of an immiscible binary mixture at constant temperature in the presence of a conservation constraint and dissipation of free energy. Porous media / pore-scale problems specifically entail images of rocks in which the solid matrix and pore spaces are fully resolved. The interior penalty discontinuous Galerkin method is used for the spatial discretization of the CH equation in mixed form, while a semi-implicit convex–concave splitting is utilized for temporal discretization. The spatial approximation order is arbitrary, while it reduces to a finite volume scheme for the choice of element-wise constants. The resulting nonlinear systems of equations are reduced using the Schur complement and solved via inexact Newton’s method. The numerical scheme is first validated using numerical convergence tests and then applied to a number of fundamental problems for validation and numerical experimentation purposes including the case of degenerate mobility. First-order physical applicability and robustness of the numerical method are shown in a breakthrough scenario on a voxel set obtained from a micro-CT scan of a real sandstone rock sample.  相似文献   
202.
In this paper a constitutive model for soils incorporating small strain stiffness formulated in the multilaminate framework is presented. In the multilaminate framework, the stress–strain behaviour of a material is obtained by integrating the mechanical response of an infinite number of randomly oriented planes passing through a material point. Such a procedure leads to a number of advantages in describing soil behaviour, the most significant being capture of initial and induced anisotropy due to plastic flow in a physically meaningful manner. In the past, many soil models of varying degree of refinement in the multilaminate framework have been presented by various authors. However, the issue of high initial soil stiffness in the range of very small strains and its degradation with straining, commonly referred to as ‘small strain stiffness’, has not been addressed within the multilaminate framework. In this paper, we adopt a micromechanics‐based approach to derive small strain elastic stiffness of the soil mass. Comparison of laboratory test data with results obtained from numerical simulations based on the proposed constitutive model incorporating small strain stiffness is performed to demonstrate its predictive capabilities. The model is implemented in a finite element code and numerical simulations of a deep excavation are presented with and without incorporation of small strain stiffness to demonstrate its importance in predicting profiles of deformation. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
203.
Florida Bay is Florida’s (USA) largest estuary and has experienced harmful picocyanobacteria blooms for nearly two decades. While nutrient loading is the most commonly cited cause of algal blooms in Florida Bay, the role of zooplankton grazing pressure in bloom occurrence has not been considered. For this study, the spatial and temporal dynamics of cyanobacteria blooms, the microbial food web, microzooplankton and mesozooplankton grazing rates of picoplankton, and the effects of nutrients on plankton groups in Florida Bay were quantified. During the study, cyanobacteria blooms (>3 × 105 cells mL−1) persisted in the eastern and central regions of Florida Bay for more than a year. Locations with elevated abundance of cyanobacteria hosted microzooplankton grazing rates on cyanobacteria that were significantly lower (p < 0.001) and less frequently detectable compared to sites without blooms. Consistent with this observation, cyanobacteria abundances were significantly correlated with ciliates and heterotrophic nanoflagellates at low cyanobacteria densities (p < 0.001) but were not correlated during bloom events. The experimental enrichment of mesozooplankton abundance during blooms yielded a significant decrease in the net growth rate of picoplankton but had the opposite effect when blooms were absent, suggesting that the cascading effect of mesozooplankton grazing on the microbial food web was also altered during blooms. While inorganic nutrient enrichment significantly increased the net growth rates of eukaryotic phytoplankton and heterotrophic bacteria, such nutrient loading had no effect on the net growth rates of cyanobacteria. Hence, this study demonstrates that low rates of zooplankton grazing and low rates of inorganic nutrient loading contribute to the persistence of cyanobacteria blooms in Florida Bay.  相似文献   
204.
This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2009. During this period, 450 earthquakes and 68 quarry blasts were detected and located in the region under consideration. The three strongest events occurred about 15 km NW of Basel in southern Germany (ML 4.2), near Wildhaus in the Toggenburg (ML 4.0) and near Bivio in Graubünden (ML 3.5). Although felt by the population, they were not reported to have caused any damage. With a total of 24 events with ML ≥ 2.5, the seismic activity in the year 2009 was close to the average over the previous 34 years.  相似文献   
205.
Lithium concentration and isotope data (δ7Li) are reported for pore fluids from 18 cold seep locations together with reference fluids from shallow marine environments, a sediment-hosted hydrothermal system and two Mediterranean brine basins. The new reference data and literature data of hydrothermal fluids and pore fluids from the Ocean Drilling Program follow an empirical relationship between Li concentration and δ7Li (δ7Li = −6.0(±0.3) · ln[Li] + 51(±1.2)) reflecting Li release from sediment or rocks and/or uptake of Li during mineral authigenesis. Cold seep fluids display δ7Li values between +7.5‰ and +45.7‰, mostly in agreement with this general relationship. Ubiquitous diagenetic signals of clay dehydration in all cold seep fluids indicate that authigenic smectite-illite is the major sink for light pore water Li in deeply buried continental margin sediments. Deviations from the general relationship are attributed to the varying provenance and composition of sediments or to transport-related fractionation trends. Pore fluids on passive margins receive disproportionally high amounts of Li from intensely weathered and transported terrigenous matter. By contrast, on convergent margins and in other settings with strong volcanogenic input, Li concentrations in pore water are lower because of intense Li uptake by alteration minerals and, most notably, adsorption of Li onto smectite. The latter process is not accompanied by isotope fractionation, as revealed from a separate study on shallow sediments. A numerical transport-reaction model was applied to simulate Li isotope fractionation during upwelling of pore fluids. It is demonstrated that slow pore water advection (order of mm a−1) suffices to convey much of the deep-seated diagenetic Li signal into shallow sediments. If carefully applied, Li isotope systematics may, thus, provide a valuable record of fluid/mineral interaction that has been inherited several hundreds or thousands of meters below the actual seafloor fluid escape structure.  相似文献   
206.
The common appearance of hygroscopic brine (“sweating”) on ordinary chondrites (OCs) from Oman during storage under room conditions initiated a study on the role of water‐soluble salts on the weathering of OCs. Analyses of leachates from OCs and soils, combined with petrography of alteration features and a 11‐month record of in situ meteorite and soil temperatures, are used to evaluate the role of salts in OC weathering. Main soluble ions in soils are Ca2+, SO42?, HCO3?, Na+, and Cl?, while OC leachates are dominated by Mg2+ (from meteoritic olivine), Ca2+ (from soil), Cl? (from soil), SO42? (from meteoritic troilite and soil), and iron (meteoritic). “Sweating meteorites” mainly contain Mg2+ and Cl?. The median Na/Cl mass ratio of leachates changes from 0.65 in soils to 0.07 in meteorites, indicating the precipitation of a Na‐rich phase or loss of an efflorescent Na‐salt. The total concentrations of water‐soluble ions in bulk OCs ranges from 600 to 9000 μg g?1 (median 2500 μg g?1) as compared to 187–14140 μg g?1 in soils (median 1148 μg g?1). Soil salts dissolved by rain water are soaked up by meteorites by capillary forces. Daily heating (up to 66.3 °C) and cooling of the meteorites cause a pumping effect, resulting in a strong concentration of soluble ions in meteorites over time. The concentrations of water‐soluble ions in meteorites, which are complex mixtures of ions from the soil and from oxidation and hydrolysis of meteoritic material, depend on the degree of weathering and are highest at W3. Input of soil contaminants generally dominates over the ions mobilized from meteorites. Silicate hydrolysis preferentially affects olivine and is enhanced by sulfide oxidation, producing local acidic conditions as evidenced by jarosite. Plagioclase weathering is negligible. After completion of troilite oxidation, the rate of chemical weathering slows down with continuing Ca‐sulfate contamination.  相似文献   
207.
Retreating glaciers give way to new landscapes with lakes as an important element. In this study, we combined available data on lake outlines with historical orthoimagery and glacier outlines for six time periods since the end of the Little Ice Age (LIA; ~1850). We generated a glacial lake inventory for modern times (2016) and traced the evolution of glacial lakes that formed in the deglaciated area since the LIA. In this deglaciated area, a total of 1192 lakes formed over the period of almost 170 years, 987 of them still in existence in 2016. Their total water surface in 2016 was 6.22 ± 0.25 km2. The largest lakes are > 0.4 km2 (40 ha) in size, while the majority (> 90%) are smaller than 0.01 km2. Annual increase rates in area and number peaked in 1946–1973, decreased towards the end of the 20th century, and reached a new high in the latest period 2006–2016. For a period of 43 years (1973–2016), we compared modelled overdeepenings from previous studies to actual lake genesis. For a better prioritization of formation probability, we included glacier-morphological criteria such as glacier width and visible crevassing. About 40% of the modelled overdeepened area actually got covered by lakes. The inclusion of morphological aspects clearly aided in defining a lake formation probability to be linked to each modelled overdeepening. Additional morphological variables, namely dam material and type, surface runoff, and freeboard, were compiled for a subset of larger and ice-contact lakes in 2016, constituting a basis for future hazard assessment.  相似文献   
208.
Uncrewed aerial systems (UAS), combined with structure-from-motion photogrammetry, has already proven to be very powerful for a wide range of geoscience applications and different types of UAS are used for scientific and commercial purposes. However, the impact of the UAS used on the accuracy of the point clouds derived is not fully understood, especially for the quantitative analysis of geomorphic changes in complex terrain. Therefore, in this study, we aim to quantify the magnitude of systematic and random error in digital elevation models derived from four commonly used UAS (XR6/Sony α6000, Inspire 2/X4s, Phantom 4 Pro+, Mavic Pro) following different flight patterns. The vertical error of each elevation model is evaluated through comparison with 156 GNSS reference points and the normal distribution and spatial correlation of errors are analysed. Differences in mean errors (−0.4 to −1.8 cm) for the XR6, Inspire 2 and Phantom 4 Pro are significant but not relevant for most geomorphological applications. The Mavic Pro shows lower accuracies with mean errors up to 4.3 cm, thus showing a higher influence of random errors. QQ plots revealed a deviation of errors from a normal distribution in almost all data. All UAS data except Mavic Pro exhibit a pure nugget semivariogram, suggesting spatially uncorrelated errors. Compared to the other UAS, the Mavic Pro data show trends (i.e. differences increase with distance across the survey—doming) and the range of semivariances is 10 times greater. The lower accuracy of Mavic Pro can be attributed to the lower GSD at the same flight altitude and most likely, the rolling shutter sensor has an effect on the accuracy of the camera calibration. Overall, our study shows that accuracies depend highly on the chosen data sampling strategy and that the survey design used here is not suitable for calibrating all types of UAS camera equally.  相似文献   
209.
Marine silty clay deposited during the Late-Wisconsinian postglacial marine transgression of eastern Québec (Goldthwait Sea) is ubiquitous in the sedimentary column of intertidal zones of the St-Lawrence Estuary. This mud is very compact and limits the penetration of organisms composing the modern Macoma balthica community. In order to describe the characteristics of intertidal sediments containing Goldthwait Sea mud, axial tomography (CT-Scan) is used. CT-Scan is a non-destructive method that can be used to describe sediment characteristics (grain size, mineralogy, primary and secondary sedimentary structures, fabric, shape and roundness, bedding contact), and to obtain high resolution, 3D representations of structures within sediment cores. Based on differences in the densities of analysed materials, the different lithologies, lithofacies, and organisms within the core can be discriminated, and a quantification of the volume occupied by the different components of the material can be made. Here, CT-Scan images provide information on the distribution, orientation and interweaving of thanatocœnosis shell beds that alternate with massive or faintly laminated postglacial marine mud beds, as well as on ichnofacies characteristics. In addition, we show 3D images of bioturbation structures within the recent sediment layer, which is distinguished from the underlying Goldthwait Sea mud. When coupled with conventional sedimentary (grain size statistics) and radiochronological (14C) analyses, these data provide information which is valuable for identifying depositional processes within sedimentary environments.  相似文献   
210.
The chemical and isotopic composition of pore fluids is presented for five deep-rooted mud volcanoes aligned on a transect across the Gulf of Cadiz continental margin at water depths between 350 and 3860 m. Generally decreasing interstitial Li concentrations and 87Sr/86Sr ratios with increasing distance from shore are attributed to systematically changing fluid sources across the continental margin. Although highest Li concentrations at the near-shore mud volcanoes coincide with high salinities derived from dissolution of halite and late-stage evaporites, clayey, terrigenous sediments are identified as the ultimate Li source to all pore fluids investigated. Light δ7Li values, partly close to those of hydrothermal vent fluids (δ7Li: +11.9‰), indicate that Li has been mobilized during high-temperature fluid/sediment or fluid/rock interactions in the deep sub-surface. Intense leaching of terrigenous clay has led to radiogenic 87Sr/86Sr ratios (∼0.7106) in pore fluids of the near-shore mud volcanoes. In contrast, non-radiogenic 87Sr/86Sr ratios (∼0.7075) at the distal locations are attributed to admixing of a basement-derived fluid component, carrying an isotopic signature from interaction with the basaltic crust. This inference is substantiated by temperature constraints from Li isotope equilibrium calculations suggesting exchange processes at particularly high temperatures (>200 °C) for the least radiogenic pore fluids of the most distal location.Advective pore fluids in the off-shore reaches of the Gulf of Cadiz are influenced by successive exchange processes with both oceanic crust and terrigenous, fine-grained sediments, resulting in a chemical and isotopic signature similar to that of fluids in near-shore ridge flank hydrothermal systems. This suggests that deep-rooted mud volcanoes in the Gulf of Cadiz represent a fluid pathway intermediate between mid-ocean ridge hydrothermal vent and shallow, marginal cold seep. Due to the thicker sediment coverage and slower fluid advection rates, the overall geochemical signature is shifted towards the sediment-diagenetic signal compared to ridge flank hydrothermal environments.  相似文献   
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