Quantifying hydrogen‐deuterium exchange of meteoritic dicarboxylic acids during aqueous extraction     

Megan FULLER  Yongsong HUANG 《Meteoritics & planetary science》2003,38(3):357-363

Abstract— Hydrogen isotope ratios of organic compounds in carbonaceous chondrites provide critical information about their origins and evolutionary history. However, because many of these compounds are obtained by aqueous extraction, the degree of hydrogen‐deuterium (H/D) exchange that occurs during the process needs to be quantitatively evaluated. This study uses compound‐specific hydrogen isotopic analysis to quantify the H/D exchange during aqueous extraction. Three common meteoritic dicarboxylic acids (succinic, glutaric, and 2‐methyl glutaric acids) were refluxed under conditions simulating the extraction process. Changes in δD values of the dicarboxylic acids were measured following the reflux experiments. A pseudo‐first order rate law was used to model the H/D exchange rates which were then used to calculate the isotope exchange resulting from aqueous extraction. The degree of H/D exchange varies as a result of differences in molecular structure, the alkalinity of the extraction solution and presence/absence of meteorite powder. However, our model indicates that succinic, glutaric, and 2‐methyl glutaric acids with a δD of 1800%***_o would experience isotope changes of 38_o, 10_o, and 6_o, respectively during the extraction process. Therefore, the overall change in δD values of the dicarboxylic acids during the aqueous extraction process is negligible. We also demonstrate that H/D exchange occurs on the chiral α‐carbon in 2‐methyl glutaric acid. The results suggest that the racemic mixture of 2‐methyl glutaric acid in the Tagish Lake meteorite could result from post‐synthesis aqueous alteration. The approach employed in this study can also be used to quantify H/D exchange for other important meteoritic compounds such as amino acids.  相似文献   

CCD联合平差方法及其初步实例检验     

YU Yong LI Jinling TANG Zhenghong WANG Guangli ZHAO Ming 《中国科学院上海天文台年刊》2003,(1)

在常规照相天体测量工作中 ,对暗天体的定位是采用逐级定标星过渡的方法实现的。由于星表系统差和局部差的存在 ,最终定位结果可能包含难以把握的误差积累。在CCD小视场观测情况下时常难以找到足够数量的定标星。鉴于此 ,推导了CCD观测联合平差方法的严格矢量表达式 ,以期通过共同星的过渡 ,实现大天区统一平差。原理上此方法可实现相对于河外天体的定位 ,以削弱星表系统差和局部差对定位结果的影响。讨论了CCD联合平差方法实现中的问题 ,包括底片常数模型选择、切点位置改正、共同星的较差改正和法方程解算方法等 ,并分析了具体的处理措施。用实例初步检验了CCD联合平差方法的效果 ,表明通过对多张CCD观测的联合平差 ,可以削弱单张CCD观测参考星数目过少、单张CCD观测参考星分布不均、个别参考星存在位置偏差和局部区域参考星存在系统性位置偏差等不利因素对归算结果的影响 ,进而达到扩大视场和提高归算精度的目的  相似文献   

瓮安生物群与宽川铺生物群中球形类化石研究   总被引：2，自引：0，他引：2  

刘云焕  李勇  邵铁全  于波  付淑青  韩会平  李园园  李荣西 《地球科学与环境学报》2005,27(1):5-13

通过对获自瓮安生物群与宽川铺生物群中大量球形类化石的系统研究，建立了便于交流和深入讨论的球形类化石形态分类方案，对各种类型的球形类化石进行了属性探讨，并按形态属描述球形类化石4个新类型(相当于形态属)，8个新种类(相当于形态种)。研究表明球形类化石是一个多源的非正式生物类群，包括动物性和植物性球形类化石。具有丰富的研究内涵，对揭示早期生物的起源、演化、多样性及胚胎发育具有深远意义。  相似文献   

贵州织金煤矿区龙潭组岩石特征及其意义     

陶述平  谭西德  黄昔容 《国土资源导刊(湖南)》2001,20(4):247-249

织金矿区含煤地层为上二叠统龙潭组,含主要可采煤6层.煤系地层以含玄武岩屑、海绿石为特征的5类碎屑岩夹碳酸盐岩,水平、沙纹、波状层理发育,煤系中稳定的灰岩、硅铁质灰岩标志层较多,有利于煤层的划分与对比,并产丰富的动植物化石及碎块.属海、陆交替环境下的标型海陆交互相沉积.  相似文献   

广西森林旅游资源的特色及其开发意义     

傅中平  黄载环 《南方国土资源》2001,14(3):27-29

广西森林旅游资源多达 816 .7万hm2 ,景点 2 80个 ,内容丰富 ,前景广阔 ,加强广西森林旅游资源特色的开发 ,有利于促进广西旅游业可持续发展 ,有利于经济、社会、环境效益的提高及人们的文化素质和生活质量的提高。  相似文献   

冰雹云雷达回波自动识别系统   总被引：2，自引：0，他引：2  

段勇  贺敬安  谈曙青 《成都信息工程学院学报》2001,16(2):110-116

利用CAPPI资料对立体风暴进行识别，计算并提供出实用的风暴结构参数，采用矩心踊跃法和矩不变量法相结合对单体风暴和混合性风暴回波进行跟踪；最小二第线性外推预报；根据WSD－88D的冰雹算法，在风暴结构基础上本文建立了Windows98操作平台上冰雹识别系统，经单站1年11次强对流天气过程的资料检验，结果表明：雹云识别精度达82％。系统建立了大量人机对话框以方便用户，增加实用性及推广性。  相似文献   

企鹅珍珠贝人工苗生长的初步观察   总被引：3，自引：0，他引：3  

梁飞龙  毛勇  余祥勇 《广东海洋大学学报》2001,21(1):6-9

为了解企鹅珍珠贝生长规律，观察了壳高2.5～5.0mm的出池幼苗，按月测量其生长参数和成活率，以及环境因子。结果表明，企鹅珍珠贝生长最快的月份为7～11月和次年4～6月，壳长，壳高和壳宽月均增加量分别为3.8～13.0mm、4.7～11.2mm、2.3～3.8mm，月成活率97.8%～98.6%。企鹅珍珠贝生长最慢月份是11月至次年3月。  相似文献   

激变食变星PG0027+260的CCD光变曲线     

李泳  蒋兆基  陈建生  魏名智 《中国天文和天体物理学报》1990,(2)

我们于1989年11月30日晚对PG0027+260进行了时间分辨率为108秒的高速CCD测光,得到了一条完整的光变曲线,从而确认其为激变食变星系统,轨道周期0.146~d  相似文献   

Numerical prediction of blast‐induced stress wave from large‐scale underground explosion     

Chengqing Wu  Yong Lu  Hong Hao 《国际地质力学数值与分析法杂志》2004,28(1):93-109

This paper presents a numerical model for predicting the dynamic response of rock mass subjected to large‐scale underground explosion. The model is calibrated against data obtained from large‐scale field tests. The Hugoniot equation of state for rock mass is adopted to calculate the pressure as a function of mass density. A piecewise linear Drucker–Prager strength criterion including the strain rate effect is employed to model the rock mass behaviour subjected to blast loading. A double scalar damage model accounting for both the compression and tension damage is introduced to simulate the damage zone around the charge chamber caused by blast loading. The model is incorporated into Autodyn3D through its user subroutines. The numerical model is then used to predict the dynamic response of rock mass, in terms of the peak particle velocity (PPV) and peak particle acceleration (PPA) attenuation laws, the damage zone, the particle velocity time histories and their frequency contents for large‐scale underground explosion tests. The computed results are found in good agreement with the field measured data; hence, the proposed model is proven to be adequate for simulating the dynamic response of rock mass subjected to large‐scale underground explosion. Extended numerical analyses indicate that, apart from the charge loading density, the stress wave intensity is also affected, but to a lesser extent, by the charge weight and the charge chamber geometry for large‐scale underground explosions. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Using an adjoint model to improve an optimum interpolation-based data-assimilation system     

X.-Y. HUANG  N. GUSTAFSSON  E. R. KÄLLÉN 《地球，A辑:动力气象学与海洋学》1997,49(2):161-176

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