Compositional trends among IID irons; their possible formation from the P-rich lower magma in a two-layer core     

John T. Wasson  Heinz Huber 《Geochimica et cosmochimica acta》2006,70(24):6153-6167

Group IID is the fifth largest group of iron meteorites and the fourth largest magmatic group (i.e., that formed by fractional crystallization). We report neutron-activation data for 19 (of 21 known) IID irons. These confirm earlier studies showing that the group has a relatively limited range in Ir concentrations, a factor of 5. This limited range is not mainly due to incomplete sampling; Instead, it seems to indicate low solid/liquid distribution coefficients reflecting very low S contents of the parental magma, the same explanation responsible for the limited range in group IVA. Despite this similarity, these two groups have very different volatile patterns. Group IVA has very low abundances of the volatile elements Ga, Sb and Ge whereas in group IID Ga and Sb abundances are the highest known in a magmatic group of iron meteorites and Ge abundances are the second highest (after group IIAB). Group IID appears to be the only large magmatic group having high volatile abundances but low S. In the volatile-depleted groups IVA and IVB it is plausible that S was lost as a volatile from a chondritic precursor material. Because group IID seems to have experienced minimal loss of volatiles, we suggest that S was lost as an early melt having a composition near that of the Fe–FeS eutectic (315 mg/g S). When temperatures had risen 400–500 K higher P-rich melts formed, became gravitationally unstable, and drained through the first melt to form an inner core that was parental to the IID irons. As discussed by [Kracher, A., Wasson, J.T., 1982. The role of S in the evolution of the parental cores of the iron meteorites. Geochim. Cosmochim. Acta 46, 2419–2426], it is plausible that a metal-rich inner core and a S-rich outer core could coexist metastably because stratification near the interface permitted only diffusional mixing. The initial liquidus temperature of the inner, P-rich core is estimated to have been 1740 K; after >60% crystallization the increase in P and the decrease in temperature may have permitted immiscibility with the S-rich outer core. We have not recognized samples of the outer core.  相似文献   

Seasonal Diatom Variability and Paleolimnological Inferences – A Case Study     

Dörte Köster  Reinhard Pienitz 《Journal of Paleolimnology》2006,35(2):395-416

The seasonality of physical, chemical, and biological water variables is a major characteristic of temperate, dimictic lakes. Yet, few investigations have considered the potential information that is encoded in seasonal dynamics with respect to the paleolimnological record. We used a one-year sequence of diatoms obtained from sediment traps and water samples, as well as the sedimentary diatom record covering the past ca. 1000 years in Bates Pond, Connecticut (USA), to investigate which variables influence the seasonal distribution of diatoms and how this can be used for the interpretation of the fossil record. The seasonal patterns in diatom assemblages were related to stratification and, to a lesser extent, to nitrate, silica, and phosphorus. During mixing periods in spring and autumn, both planktonic and benthic species were collected in the traps, while few lightly silicified, spindle-shaped planktonic diatoms dominated during thermal stratification in summer. Changes in fossil diatom assemblages reflected human activity in the watershed after European settlement and subsequent recovery in the 20th century. A long-term trend in diatom assemblage change initiated before European settlement was probably related to increased length of mixing periods during the Little Ice Age, indicated by the increase of taxa that presently grow during mixing periods and by application of a preliminary seasonal temperature model. We argue that the analysis of seasonal diatom dynamics in temperate lakes may provide important information for the refinement of paleolimnological interpretations. However, investigations of several lakes and years would be desirable in order to establish a more robust seasonal data set for the enhancement of paleolimnological interpretations.  相似文献   

Evidence for compressionally induced high subsidence rates in the Kurile Basin (Okhotsk Sea)   总被引：1，自引：0，他引：1  

Boris V. Baranov  Reinhard Werner  Kaj A. Hoernle  Ira B. Tsoy  Paul van den Bogaard  Igor A. Tararin 《Tectonophysics》2002,350(1)

A combined volcanological, geochemical, paleo-oceanological, geochronological and geophysical study was undertaken on the Kurile Basin, in order to constrain the origin and evolution of this basin. Very high rates of subsidence were determined for the northeastern floor and margin of the Kurile Basin. Dredged volcanic samples from the Geophysicist Seamount, which were formed under subaerial or shallow water conditions but are presently located at depths in excess of 2300 m, were dated at 0.84±0.06 and 1.07±0.04 Ma with the laser ⁴⁰Ar/³⁹Ar single crystal method, yielding a minimum average subsidence rate of 1.6 mm/year for the northeast basin floor in the Quaternary. Trace element and Sr–Nd–Pb isotope data from the volcanic rocks show evidence for contamination within lower continental crust and/or the subcontinental lithospheric mantle, indicating that the basement presently at 6-km depth is likely to represent thinned continental crust. Average subsidence rates of 0.5–2.0 mm/year were estimated for the northeastern slope of the Kurile Basin during the Pliocene and Quaternary through the determination of the age and paleo-environment (depth) of formation of sediments from a canyon wall. Taken together, the data from the northeastern part of the Kurile Basin indicate that subsidence began in or prior to the Early Pliocene and that subsidence rates have increased in the Quaternary. Similar rates of subsidence have been obtained from published studies on the Sakhalin Shelf and Slope and from volcanoes in the rear of the Kurile Arc. The recent stress field of the Kurile Basin is inferred from the analysis of seismic activity, focal mechanism solutions and from the structure of the sedimentary cover and of the Alaid back-arc volcano. Integration of these results suggests that compression is responsible for the rapid subsidence of the Kurile Basin and that subsidence may be an important step in the transition from basin formation to its destruction. The compression of the Kurile Basin results from squeezing of the Okhotsk Plate between four major plates: the Pacific, North American, Eurasian and Amur. We predict that continued compression could lead to subduction of the Kurile Basin floor beneath Hokkaido and the Kurile Arc in the future and thus to basin closure.  相似文献   

Petrology and Geochemistry of the Volcanic Rocks Dredged from the Geophysicist Seamount in the Kurile Basin: Evidence for the Existence of Thinned Continental Crust     

Igor A. Tararin  Eugeniy P. Lelikov  Reinhard Werner 《Gondwana Research》2003,6(4):757-765

Dredged samples from the Geophysicist seamount volcano in the northeastern part of the Kurile Basin include volcanic and volcanoclastic rocks ranging from basalt to andesite. The rocks have geochemical features typical of high-K island-arc calc-alkaline volcanism. They are enriched in LILE and depleted in Zr, Ti, Nb, Ta and Y. The chondrite-normalized REE patterns are characterized by enrichment of LREE similar to those of island-arc lava from the submarine volcanoes of rear-arc zone of the Kurile Island Arc. The volcanic rocks have a wide range of ⁸⁷Sr/⁸⁶Sr ratios (0.70287-0.70652), varying ¹⁴³Nd/¹⁴⁴Nd and Pb isotopic ratios. Their trace-element compositions and Sr-Nd-Pb isotope signatures may be explained by a small addition of crustal continental component to mantle-derived magmas that suggest the existence of thinned continental basement under the eastern part of the Kurile Basin.  相似文献   

Environmental impact assessment in the Moradabad industrial area (rivers Ramganga-Ganga interfluve), Ganga Plain,India     

Maneesh Sharma  Heinz Tobschall  Indra Singh 《Environmental Geology》2003,43(8):957-967

Sediment samples collected in the Moradabad area, lying in the interfluve of the Ganga and Ramganga Rivers, were analysed for heavy metals, after studying the geomorphology of the area. Geomorphologically, the area can be divided into three terraces - the T₀, T₁ and T₂ surfaces. The rivers on these three surfaces show varying amounts of pollution depending upon the input from industries and urban settlements. The Ramganga River on the T₀ surface shows the highest amount of pollution. However, the pollution levels in all these rivers show a downstream dilution effect. The characteristic feature of the vast interfluve area (T₂ surface) is the presence of several, independent basins which are closed and rarely interact with each other or with any river. The sediments are redistributed and redeposited within the basin itself, and thus these basins serve as sinks. The sediments of one such basin in the study area show significant concentrations of arsenic, chromium, copper, nickel, lead, zinc and organic carbon. The concentrations of heavy metals in such a basin will show exponential increases with time, because there is no activity to funnel out the sediments and dilute the effect of pollution. This increase will pose more threats, as ultimately it will make its way laterally and vertically through the sediments, thereby polluting groundwater.  相似文献   

Strontium isotope evolution of Late Permian and Triassic seawater   总被引：7，自引：0，他引：7  

Christoph Korte  Heinz W Kozur  Ján Veizer 《Geochimica et cosmochimica acta》2003,67(1):47-62

The ⁸⁷Sr/⁸⁶Sr values based on brachiopods and conodonts define a nearly continuous record for the Late Permian and Triassic intervals. Minor gaps in measurements exist only for the uppermost Brahmanian, lower part of the Upper Olenekian, and Middle Norian, and only sparse data are available for the Late Permian. These 219 measurements include 67 brachiopods and 114 conodont samples from the Tethyan realm as well as 37 brachiopods and one conodont sample from the mid-European Middle Triassic Muschelkalk Sea. The Late Permian/Lower Triassic interval is characterized by a steep 1.3 × 10⁻³ rise, from 0.7070 at the base of the Dzhulfian to 0.7082 in the late Olenekian, a rate of change comparable to that in the Cenozoic. In the mid-Triassic (Anisian and Ladinian), the isotope values fall to 0.7075, followed again by a rise to 0.7081 in the Middle/Late Norian. The ⁸⁷Sr/⁸⁶Sr values decline again in the Late Norian (Sevatian) and Rhaetian to 0.7076.The sharp rise in the ⁸⁷Sr/⁸⁶Sr values during the Late Permian/Early Triassic was coincident with widespread clastic sedimentation. Because of the paucity of tectonic uplifts, the enhanced erosion may have been due to intermittent humid phases, during mainly an arid interval, coupled with the absence of a dense protective land plant cover following the mass extinction during the latest Permian. The apex of the ⁸⁷Sr/⁸⁶Sr curve at the Olenekian/Anisian boundary coincides with cessation of the large-scale clastic sedimentation and also marks the final recovery of land vegetation, as indicated by the renewed onset of coal formation in the Middle Triassic. The rising ⁸⁷Sr/⁸⁶Sr values from the Middle Carnian to the Late Norian coincide with the uplift and erosion of the Cimmeride-Indosinian orogens marking the closure of the Palaeotethys. The subsequent Rhaetian decline that continues into Jurassic (Pliensbachian/Toarcian boundary), on the other hand, coincides with the opening of the Vardar Ocean and its eastern continuation in the Izmir-Ankara Ophiolitic Belt.Samples from the Upper Muschelkalk are more radiogenic than the global trend. This may reflect separation of the basin from the open ocean. Due to strong meteoric influx from a large land mass in the north, the Germanic Basin became increasing brackish up section in the north and east, but because of the high evaporation rates, the salt content was not much reduced in the southern and central basin where a rich, but increasingly endemic, marine fauna survived.  相似文献   

Distribution and sources of pre-anthropogenic lead isotopes in deep ocean water from FeMn crusts   总被引：3，自引：0，他引：3  

F. von Blanckenburg  R.K. O'nions  J.R. Heinz 《Geochimica et cosmochimica acta》1996,60(24):4957-4963

The lead isotope composition of ocean water is not well constrained due to contamination by anthropogenic lead. Here the global distribution of lead isotopes in deep ocean water is presented as derived from dated (ca. 100 ka) surface layers of hydrogenetic Fe-Mn crusts. The results indicate that the radiogenic lead in North Atlantic deep water is probably supplied from the continents by river particulates, and that lead in Pacific deep water is similar to that characteristic of island and continental volcanic arcs. Despite a short residence time in deep water (80–100 a), the isotopes of lead appear to be exceedingly well mixed in the Pacific basin. There is no evidence for the import of North Atlantic deep water-derived lead into the Pacific ocean, nor into the North Indian Ocean. This implies that the short residence time of lead in deep water prohibits advection over such long distances. Consequently, any climate-induced changes in deep-water flow are not expected to result in major changes in the seawater Pb-isotope record of the Pacific Ocean.  相似文献   

Towards a long-term monitoring of Central European water mite faunas (Acari: Hydrachnidia and Halacaridae) – considerations on the background of data from 1900 to 2000     

Reinhard Gerecke  Erwin O. Lehmann 《Limnologica》2005,35(1-2):45-51

The state of knowledge of the Central European water mite fauna and the research history are briefly surveyed. Several areas for which we are provided with rich data sets are of high value for the monitoring of faunistic trends on the background of local and global environmental change. The need for a database combining historical and actual faunistic information is stressed. It should facilitate the access to all data from former times, give a survey on actual activities by regular updates, and help for a better organization of future research activities. On the base of an update of the Limnofauna Europaea (K.O. Viets 1978, Gerecke in www.watermite.org) a first attempt is made to (1) recognize changes in the Central European fauna during the past 100 years; (2) emphasize species which may be endangered or have disappeared during the past 100 years. At the present state of knowledge, the degree of threat to water mite species in this area is best calculated from their preference for particular habitat types which are rare and in danger to disappear in cultivated landscapes. Our knowledge concerning neozoic water mites in the study area is discussed.  相似文献   

MTBE in Drinking Water Production – Occurrence and Efficiency of Treatment Technologies     

Christine Baus  HsuWen Hung  Frank Sacher  Michael Fleig  Heinz‐Jürgen Brauch 《洁净——土壤、空气、水》2005,33(2):118-132

In Germany, the gasoline additive methyl tert‐butyl ether (MTBE) is almost constantly detected in measurable concentrations in surface waters and is not significantly removed during riverbank filtration. The removal of MTBE from water has been the focus of many studies that mostly were performed at high concentration levels and centred in understanding the mechanisms of elimination. In order to assess the performance of conventional and advanced water treatment technologies for MTBE removal in the low concentration range further studies were undertaken. Laboratory experiments included aeration, granulated activated carbon (GAC) adsorption, ozonation and advanced oxidation processes (AOP). The results show that the removal of MTBE by conventional technologies is not easily achieved. MTBE is only removed by aeration at high expense. Ozonation at neutral pH values did not prove to be effective in eliminating MTBE at all. The use of ozone/H₂O₂ (AOP) may lead to a partly elimination of MTBE. However, the ozone/H₂O₂ concentrations required for a complete removal of MTBE from natural waters is much higher than the ozone levels applied nowadays in waterworks. MTBE is only poorly adsorbed on activated carbon, thus GAC filtration is not efficient in eliminating MTBE. A comparison with real‐life data from German waterworks reveals that if MTBE is detected in the raw water it is most often found in the corresponding drinking water as well due to the poor removal efficiency of conventional treatment steps.  相似文献   

Relief-rejuvenation and topographic length scales in a fluvial drainage basin, Napf area, Central Switzerland   总被引：2，自引：2，他引：2  

Fritz Schlunegger  Heinz Schneider 《Geomorphology》2005,69(1-4):102-117

This paper explores how, and to what extent, a phase of relief-rejuvenation modifies the mode of surface erosion in an approximately 63 km² drainage basin located at the northern border of the Swiss Alps (Luzern area). In the study area, the retreat of the Alpine glaciers at the end of the Last Glacial Maximum (LGM) caused base level to lower by approximately 80 m. The fluvial system adapted to the lowered base level by headward erosion. This is indicated by knickzones in the longitudinal stream profiles and by the continuous upstream narrowing of the width of the valley floor towards these knickzones. In the headwaters above these knickzones, processes are still to a significant extent controlled by the higher base level of the LGM. There, frequent exposure of bedrock in channels and especially on hillslopes implies that sediment flux is to a large extent limited by weathering rates. In the knickzones, however, exposure of bedrock in channels implies that sediment flux is supply-limited, and that erosion rates are controlled by stream power.The morphometric analysis reveals the existence of length scales in the topography that result from distinct geomorphic processes. Along the tributaries where the upstream sizes of the drainage basins exceed 100,000–200,000 m², the mode of sediment transport and erosion changes from predominantly hillslope processes (i.e., landsliding, creep of regolith, rock avalanches and to some extent debris flows) to processes in channels (fluvial processes and debris flows). This length scale reflects the minimum size of the contributing area for channelized processes to take over in the geomorphic development (i.e., threshold size of drainage basin). This threshold size depends on the ratio between production rates of sediment on hillslopes, and export rates of sediment by processes in channels. Consequently, in the headwaters, erosion rates and sediment flux, and hence landscape evolution rates, are to a large extent limited by weathering processes. In contrast, in the lower portion of the drainage basin that adjusts to the lowered base-level, rates of channelized erosion and relief formation are controlled mainly by stream power. Hence, this paper shows that base-level lowering, headward erosion and establishment of knickzones separate drainage basins in two segments with different controls on rates of surface erosion, sediment flux and relief formation.  相似文献