Fracture control of ground water flow and water chemistry in a rock aquitard   总被引：1，自引：0，他引：1  

Eaton TT  Anderson MP  Bradbury KR 《Ground water》2007,45(5):601-615

There are few studies on the hydrogeology of sedimentary rock aquitards although they are important controls in regional ground water flow systems. We formulate and test a three-dimensional (3D) conceptual model of ground water flow and hydrochemistry in a fractured sedimentary rock aquitard to show that flow dynamics within the aquitard are more complex than previously believed. Similar conceptual models, based on regional observations and recently emerging principles of mechanical stratigraphy in heterogeneous sedimentary rocks, have previously been applied only to aquifers, but we show that they are potentially applicable to aquitards. The major elements of this conceptual model, which is based on detailed information from two sites in the Maquoketa Formation in southeastern Wisconsin, include orders of magnitude contrast between hydraulic diffusivity (K/S(s)) of fractured zones and relatively intact aquitard rock matrix, laterally extensive bedding-plane fracture zones extending over distances of over 10 km, very low vertical hydraulic conductivity of thick shale-rich intervals of the aquitard, and a vertical hydraulic head profile controlled by a lateral boundary at the aquitard subcrop, where numerous surface water bodies dominate the shallow aquifer system. Results from a 3D numerical flow model based on this conceptual model are consistent with field observations, which did not fit the typical conceptual model of strictly vertical flow through an aquitard. The 3D flow through an aquitard has implications for predicting ground water flow and for planning and protecting water supplies.  相似文献   

Precipitation of heavy metals in produced water: influence on contaminant transport and toxicity   总被引：1，自引：0，他引：1  

Azetsu-Scott K  Yeats P  Wohlgeschaffen G  Dalziel J  Niven S  Lee K 《Marine environmental research》2007,63(2):146-167

Produced water undergoes changes in its physical chemistry including precipitation of heavy metals after being discharged and mixed with ambient seawater. Potential impacts of the precipitation of heavy metals on their transport and toxicity were studied using samples from offshore oil production sites on the Scotian Shelf off eastern Canada. Concentrations of aluminum, cadmium, chromium, cobalt, copper, iron, lead, manganese, nickel and zinc were measured in total, particulate and dissolved fractions together with Microtox tests for assessment of toxicity. Heavy metals in produced water were transformed from dissolved to particulate phase in a period of hours under oxygenated conditions, and aggregated to larger particles that settle rapidly (>100 m/day) over a few days. In addition, there was production of buoyant particles comprised of heavy metal precipitates sequestered onto oil droplets that were transported to the surface. The particulate fraction was generally more toxic than the dissolved fraction. This was evident at the mixing interface between produced water and seawater where elevated particulate and toxicity levels were observed. Laboratory studies suggest an increase in the toxicity of discharged produced water over time. Time-series experiments showed a sustained toxic response for more than a week following the oxidation of freshly discharged produced water that initially elicited little or no toxic response in the Microtox test. Chemical processes identified in this study, namely precipitation of heavy metals and consequent settling and rising fluxes of particles, will influence the toxicity, the fate and the transport of potential contaminants in the produced water. Therefore, these processes need to be considered in assessment of the environmental impact associated with offshore oil and gas operations.  相似文献   

Habitat selection and quality for multiple cohorts of young-of-the-year bluefish (Pomatomus saltatrix): Comparisons between estuarine and ocean beaches in southern New Jersey   总被引：1，自引：0，他引：1  

David L. Taylor  Ryan S. Nichols  Kenneth W. Able 《Estuarine, Coastal and Shelf Science》2007,73(3-4):667-679

In this study, seasonal and annual variability in the use of estuarine and ocean beaches by young-of-the-year bluefish, Pomatomus saltatrix, was evaluated by indices of abundance in coastal areas of southern New Jersey (1998–2000). Biological and physical factors measured at specific sites were correlated with bluefish abundance to determine the mechanisms underlying habitat selection. In addition, integrative and discrete indicators of bluefish growth were used to examine spatio-temporal dynamics in habitat quality and its effect on habitat selection by multiple cohorts of bluefish. Intra-annual recruitment to coastal areas of southern New Jersey was episodic, and resulted from the ingress of spring-spawned bluefish (hatch-date April) to estuarine beaches in late May to early June, followed by the recruitment of summer-spawned fish (hatch-date early July) to ocean beaches from July to October. Bluefish utilized estuarine and ocean beaches in a facultative manner that was responsive to dynamics in prey composition and temperature conditions. The recruitment and residency of bluefish in the estuary (1998–1999) and ocean beaches (1998), for example, was coincidental with the presence of the Atlantic silverside Menidia menidia and bay anchovy Anchoa mitchilli, the principal prey species for bluefish occupying these respective habitat-types. Bluefish abundance in the estuary (2000) and ocean beaches (1999–2000) was also correlated with water temperature, with the greatest catches of juveniles coinciding with their optimal growth temperature (24 °C). Bluefish growth, estimated as the slope of age–length relationships and daily specific growth rates, equaled 1.27–2.63 mm fork length (FL) d⁻¹ and 3.8–8.7% body length increase d⁻¹, respectively. The growth of sagittal otoliths was also used as a proxy for changes in bluefish size during and shortly before their time of capture. Accordingly, otolith growth rates of summer-spawned bluefish were greater at ocean beaches relative to the estuary and were explained by the more suitable temperature conditions found at ocean beaches during the mid- to late summer. Notwithstanding the fast growth of oceanic summer-spawned bluefish, individuals spawned in the spring were still larger in absolute body size at the end of the summer growing season (240 and 50–200 mm FL for spring- and summer-spawned bluefish, respectively). The size discrepancy between spring- and summer-spawned bluefish at the onset of autumn migrations and during overwintering periods may account for the differential recruitment success of the respective cohorts.  相似文献   

Mineralization of contaminant uranium and leach rates in sediments from Hanford,Washington     

Christopher F. Brown  R. Jeffrey Serne  Jeffrey G. Catalano  Kenneth M. Krupka  Jonathan P. Icenhower 《Applied Geochemistry》2010

  相似文献   

Aquifer Storage Recovery (ASR) of chlorinated municipal drinking water in a confined aquifer     

John A. Izbicki  Christen E. Petersen  Kenneth J. Glotzbach  Loren F. Metzger  Allen H. Christensen  Gregory A. Smith  David O’Leary  Miranda S. Fram  Trevor Joseph  Heather Shannon 《Applied Geochemistry》2010

About 1.02 × 10⁶ m³ of chlorinated municipal drinking water was injected into a confined aquifer, 94–137 m below Roseville, California, between December 2005 and April 2006. The water was stored in the aquifer for 438 days, and 2.64 × 10⁶ m³ of water were extracted between July 2007 and February 2008. On the basis of Cl⁻ data, 35% of the injected water was recovered and 65% of the injected water and associated disinfection by-products (DBPs) remained in the aquifer at the end of extraction. About 46.3 kg of total trihalomethanes (TTHM) entered the aquifer with the injected water and 37.6 kg of TTHM were extracted. As much as 44 kg of TTHMs remained in the aquifer at the end of extraction because of incomplete recovery of injected water and formation of THMs within the aquifer by reactions with free-chlorine in the injected water. Well-bore velocity log data collected from the Aquifer Storage Recovery (ASR) well show as much as 60% of the injected water entered the aquifer through a 9 m thick, high-permeability layer within the confined aquifer near the top of the screened interval. Model simulations of ground-water flow near the ASR well indicate that (1) aquifer heterogeneity allowed injected water to move rapidly through the aquifer to nearby monitoring wells, (2) aquifer heterogeneity caused injected water to move further than expected assuming uniform aquifer properties, and (3) physical clogging of high-permeability layers is the probable cause for the observed change in the distribution of borehole flow. Aquifer heterogeneity also enhanced mixing of native anoxic ground water with oxic injected water, promoting removal of THMs primarily through sorption. A 3 to 4-fold reduction in TTHM concentrations was observed in the furthest monitoring well 427 m downgradient from the ASR well, and similar magnitude reductions were observed in depth-dependent water samples collected from the upper part of the screened interval in the ASR well near the end of the extraction phase. Haloacetic acids (HAAs) were completely sorbed or degraded within 10 months of injection.  相似文献   

Speciation and behavior of arsenic in evaporation basins,California, USA     

Ji-Hun Ryu  Suduan Gao  Kenneth K. Tanji 《Environmental Earth Sciences》2010,61(8):1599-1612

Disposal of saline subsurface drainage waters from croplands into evaporation basins (or ponds) in the San Joaquin Valley of California causes excessive accumulation of salts and elevated concentrations of arsenic (As), a potentially high risk element with little information about its fate, in the agricultural evaporation ponds. We examined dissolved As concentration, speciation, and distribution in waters as well as As fractionation in sediments in the 10-cell South Evaporation Basin for better understanding of processes and conditions affecting As transformations and fate in a specific drainage disposal facility. The increase of total dissolved As concentrations were observed with higher Cl⁻ and electric conductivity along flow path indicating that evaporation was an important factor regulating total dissolved As concentration. The increases of reduced As species such as arsenite [As(III)] and organic As (monomethylarsonic acid and dimethylarsinic acid) were found towards the terminal flow pathway. However, arsenate [As(V)], the oxidized species remained greater than 67% of total dissolved As in all cell waters. Sequential extractions of sediments indicated that reducing conditions may influence As behavior in sediments to be more soluble and exchangeable. Arsenic association with oxides was appreciable only under oxidizing condition. Carbonate minerals played an important role in immobilizing As into the sediments under alkaline condition and a broad range of redox conditions. However, these sink mechanisms did not significantly reduce As concentrations in the cell waters. The reducing condition facilitated by high concentration of organic matter might be a major factor for the increase in As mobility.  相似文献   

New 1982 — 1990 photometry of λ Andromedae and its 11-year cycle     

Douglas S. Hall  Gregory W. Henry  Dietmar Böhme  Peter A. Brooks  Sandy Chang  Ales Dolzan  George L. Fortier  Robert E. Fried  Russell M. Genet  Bruce S. Grim  James Hannon  Darrel B. Hoff  Kevin Krisciunas  Howard J. Landis  Howard P. Louth  Larry P. Lovell  Paul Nielsen  Bobby E. Powell  Harry D. Powell  Don Pray  Thomas R. Renner  Charles W. Rogers  Stephen Shervais  Douglas M. Slauson  Samuel Slote  Harold J. Stelzer  Arthur J. Stokes  Jack C. Troeger  Louis C. Turner  Norman F. Wasson  Kenneth W. Zeigler 《Journal of Astrophysics and Astronomy》1991,12(4):281-287

We present photoelectric photometry of λ And never before published, obtained between February 1982 and December 1990 at 29 different observatories. Then we combine it with all other photometry available to us (previously published, contained in the I.A.U. Commission 27 Archives, and obtained with the Vanderbilt 16-inch automatic telescope but not yet published), to yield a 14.8-year data base. Analysis reveals a long-term cycle in mean brightness, with a full range of 0^m.15 and a period of 11.4 ± 0.4 years. Because most of our new photometry was concentrated in the 1983-84 observing season, we analyze that one well-defined light curve with a two-spot model. Spot A keeps a 0^m.04 amplitude throughout four rotation cycles whereas the amplitude of spot B diminishes from 0^m.09 down almost to 0^m.03. The spot rotation periods were 55^d.9 ± 0^d.6 and 520^d.8 ± 1^d.0, respectively.  相似文献   

SOME OBSERVATIONS ON THE ENVIRONMENT OF THE FIRM: LOCATIONAL BEHAVIOR OF KRAFT PULP MILLS IN THE INTERIOR OF BRITISH COLUMBIA     

Brenton M. Barr  Kenneth J. Fairbairn 《The Professional geographer》1974,26(1):19-26

  相似文献   

Accessory silicate mineral assemblages in the Bilanga diogenite: A petrographic study     

Kenneth Domanik  Serena Kolar  Donald Musselwhite  Michael J. Drake 《Meteoritics & planetary science》2004,39(4):567-579

Abstract— The petrographic relationships in diogenites between orthopyroxene and minor phases such as chromite, troilite, diopside, plagioclase, and silica are often obscured by the intense brecciation that characterizes these meteorites. Although brecciated, Bilanga preserves numerous clasts displaying primary textural relations between orthopyroxene and these minor phases that are large enough to analyze by electron microprobe. In this study, we focus on the distribution, composition, and origin of the minor phases in Bilanga to provide new insights into the crystallization and metamorphic history of these rocks. The samples examined consist mainly of orthopyroxene grains plus five types of assemblages containing diopside + a Fe‐rich phase (chromite, troilite, and/or Fe‐Ni metal) ± plagioclase ± silica. We interpret type 1 assemblages as being remnants of intercumulus melt trapped in the interstices between orthopyroxene grains after crystal settling in a magma chamber. Type 2 assemblages appear to have formed by heterogeneous exsolution during thermal metamorphism. Type 3 assemblages are believed to be remnants of other assemblages that have been shocked, melted, and rapidly recrystallized by impact events. Type 4 assemblages consist of veins that also appear to have formed from trapped intercumulus melt. Regions of silica‐rich mesostasis (type 5) appear to be larger patches of more evolved intercumulus melt that have been significantly affected by late‐stage impact melting. Finally, large clasts containing plagioclase ± diopside are interpreted to be exotic fragments of a different but possibly related rock type incorporated in the Bilanga breccia.  相似文献   

Peat porewater chloride concentration profiles in the Everglades during wet/dry cycles from January 1996 to June 1998: field measurements and theoretical analysis     

Michael M. Reddy  Micaela B. Reddy  Kenneth L. Kipp  Aaron Burman  Paul Schuster  Peter S. Rawlik Jr. 《水文研究》2008,22(11):1713-1724

Water quality is a key aspect of the Everglades Restoration Project, the largest water reclamation and ecosystem management project proposed in the United States. Movement of nutrients and contaminants to and from Everglades peat porewater could have important consequences for Everglades water quality and ecosystem restoration activities. In a study of Everglades porewater, we observed complex, seasonally variable peat porewater chloride concentration profiles at several locations. Analyses and interpretation of these changing peat porewater chloride concentration profiles identifies processes controlling conservative solute movement at the peat–surface water interface, that is, solutes whose transport is minimally affected by chemical and biological reactions. We examine, with an advection–diffusion model, how alternating wet and dry climatic conditions in the Florida Everglades mediate movement of chloride between peat porewater and marsh surface water. Changing surface water–chloride concentrations alter gradients at the interface between peat and overlying water and hence alter chloride flux across that interface. Surface water chloride concentrations at two frequently monitored sites vary with marsh water depth, and a transfer function was developed to describe daily marsh surface water chloride concentration as a function of marsh water depth. Model results demonstrate that porewater chloride concentrations are driven by changing surface water chloride concentrations, and a sensitivity analysis suggests that inclusion of advective transport in the model improves the agreement between the calculated and the observed chloride concentration profiles. Published in 2007 by John Wiley & Sons, Ltd.  相似文献