Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2     

Irvine WM  Friberg P  Hjalmarson A  Ishikawa S  Kaifu N  Kawaguchi K  Madden SC  Matthews HE  Ohishi M  Saito S  Suzuki H  Thaddeus P  Turner BE  Yamamoto S  Ziurys LM 《The Astrophysical journal》1988,334(2):L107-L111

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.  相似文献   

贵州遵义牛蹄塘组黑色岩系的硒同位素变化及其环境指示初探   总被引：4，自引：0，他引：4  

朱建明  Johnson Thomas M  罗泰义  朱祥坤 《岩石矿物学杂志》2008,27(4):361-366

西南早寒武世牛蹄塘组是分布在中国南方扬子地台的一套黑色岩系,区域上发育有典型富集多金属元素的硫化物矿化层.选取遵义松林小竹牛蹄塘组下部富硒、钼、镍等元素的黑色岩系剖面,利用Se同位素初步探讨了该剖面岩石的沉积环境和硒的可能来源.结果表明,小竹牛蹄塘组下部剖面黑色岩系的δ82/76SeSRM3149比值变化较大,下部底层含碳斑脱岩与磷块岩的变化范围在-4.35‰～ 4.11‰之间;中间镍钼层及碳质页岩、碳质碳酸盐岩的δ82/76SeSRM3149变化范围窄,平均值为0.9‰±0.23‰(n=4);上层碳质页岩为-1.24‰.结合已发表的钼同位素数据,认为中间岩石沉积于缺氧/无氧环境,但存在盆地海水与热液或充氧水团的混合;下层的岩石曾一度位于充氧与贫氧环境的边界面,局部岩石曾暴露地表经历了较强的风化和蚀变作用,海水中硒有可能来自底部富硒斑脱岩的氧化淋滤或海底热液.据此推测遵义松林小竹牛蹄塘组下部岩石的沉积环境极可能处在局限盆地靠近陆地的边缘部分,经历了充氧→贫氧→缺氧/无氧→贫氧的演化阶段.  相似文献   

西北婆罗州深水区：活动褶皱冲断带中的烃类聚集     

G.  M.  Ingram  T.  J.  Chisholm  C.  J.  Grant  万玲 《海洋地质》2006,(2):71-80

在西北婆罗州深水区，一个活动的海上褶皱冲断带内拥有大量已经证实的烃类聚集，相信继续的勘探活动还会发现相当可观的油气。在新近纪大规模褶皱冲断带中发现典型的圈闭几何形态是上盘背斜、前陆褶皱及隆起和逆断层下盘错动断开处。商业性钻井目标位于变形的中新统和上新统沉积地层中，其中充满的油气来自现今仍然活跃的含油气系统。此处主要面临的问题是避免钻探活动变形和近期隆起期间烃类已经排出的圈闭。构造变形阶段研究列出了控制圈闭形成史和烃类保存史的一些关键要素。本文目的是提供一个有关西北婆罗州深水区褶皱冲断带的总体看法，为今后这一地区的油气勘探介绍一些重要结果。  相似文献   

制图教育在俄罗斯各综合大学的学术与教学课题     

A.M.伯兰  徐伟 《海洋测绘》1997,(1)

制图学教育在俄罗斯高等综合大学已有65年的历史(1929～1994),早在1929年制图专业就已在莫斯科大学地理系创建。当今在俄罗斯培养高技能制图员的综合大学有莫斯科大学、圣彼得堡大学、伊尔库茨克大学、伊热夫斯克大学、萨兰斯克大学、特维尔大学以及最近(1994年)刚刚获得工程技术综合大学地位的老牌国家测量制图高等学校——莫斯科测绘学院。  相似文献   

苏北盆地中古生代油气勘探发现与生储盖组合特征及现实意义     

许红  焦里力  蔡乾忠  钱中富  温珍河  郑绍贵  郭振轩  王运海  闫桂京  孙和清 《海洋地质前沿》2007,23(9):24-29,34

苏北盆地中古生代油气勘探具有50年的历史,在收集前人资料分析基础上,对苏北盆地和黄桥二氧化碳气田及朱家墩天然气田生储盖体系的地质特征及成藏要素分别进行了对比,分析了典型成藏模式;认为苏北盆地虽然只是苏北—南黄海盆地古、中、新生代盆地的一小部分,但其幔源"古生新储"二氧化碳气田和常规"古生新储"天然气田的发现对于海域南黄海盆地极具现实意义。  相似文献   

Observation of clouds and solar radiation over the Pacific Ocean as relation to global climate     

Farn Parungo  Clarence Nagamoto  Cecilia M. I. R. Girz  Jeff Torgerson  Zhou Mingyu 《海洋学报(英文版)》1995,14(2):201-207

ＯｂｓｅｒｖａｔｉｏｎｏｆｃｌｏｕｄｓａｎｄｓｏｌａｒｒａｄｉａｔｉｏｎｏｖｅｒｔｈｅＰａｃｉｆｉｃＯｃｅａｎａｓｒｅｌａｔｉｏｎｔｏｇｌｏｂａｌｃｌｉｍａｔｅ￥ＦａｒｎＰａｒｕｎｇｏ；ＣｌａｒｅｎｃｅＮａｇａｍｏｔｏ；ＣｅｃｉｌｉａＭ．Ｉ．Ｒ．Ｇｉ...  相似文献   

A quantitative analysis on the Egyptian Mediterranean waters     

M. A. Sai  F. M. Eid 《海洋学报(英文版)》1994,13(2):203-212

ＡｑｕａｎｔｉｔａｔｉｖｅａｎａｌｙｓｉｓｏｎｔｈｅＥｇｙｐｔｉａｎＭｅｄｉｔｅｒｒａｎｅａｎｗａｔｅｒｓ￥Ｍ．Ａ．ＳａｉｄａｎｄＦ．Ｍ．Ｅｉｄ（ＲｅｃｅｉｖｅｄＳｅｐｔｅｍｂｅｒ２１，１９９３１ａｃｃｆｅｐｔｅｄＪａｎｕａｒｙ１５，１９９４）Ａｂｓ...  相似文献   

Assessing degradation capability of aerobic indigenous microflora in PAH-contaminated brackish sediments     

Abbondanzi F  Campisi T  Focanti M  Guerra R  Iacondini A 《Marine environmental research》2005,59(5):419-434

A study was conducted to determine polycyclic aromatic hydrocarbons (PAHs) distribution and microbial population changes in brackish sediments from an Italian lagoon included in the Ramsar List of Wetlands of International Importance. The presence and level of PAH-degrading bacteria were estimated by the most probable number (MPN) enumeration technique, whereas degradation capability towards target compounds was checked against loss of spiked PAHs (Phenanthrene, Anthracene and Fluoranthene) in MPN tubes after incubation in optimal conditions. Chemical analyses and microbiological counts suggested a potential for PAHs biodegradation by natural occurring populations of sediment microorganisms, thus indicating an "optimal range" in sediment PAHs concentrations, outside of which the natural selection of the indigenous microflora did not occur. The MPN procedure here described, provided an effective and reliable way to simultaneously determine microbial population densities and subsequent confirmation of the biodegradation capability of sediment indigenous microflora when exposed to laboratory and environmental concentrations of PAHs.  相似文献   

CHARACTERISTICS ON INTERANNUAL VARIATIONS OF NORTH PACIFIC SST AND ITS RELATION TO EAST ASIA CLIMATE     

解思梅  TAKASHI AOKI  MASATOSHI M. YOSHINO 《海洋学报(英文版)》1987,6(1):68-79

The interannual variations of the monthly sea surface temperature (SST) in the North Pacific (including Equatorial East Pacific) during 1951-1980 are analysed by means of EOF method. The findings are:(1) In the cold and warm ocean current areas, such as the North Pacific Current, the California Current and the Equatorial East Pacific areas, the convergence speeds are the fastest, while in the Kuroshio and the western part of the North Equatorial Current areas they are fast only in winter.(2) The physical features of the first 3 eigenvectors are obvious. The first eigenvector shows that the SST values are high in the south and low in the north in the latitudinal distribution of the SST field. The warm current area, i.e. the northwestern part of the North Pacific is positive and the cold current area, i.e. the southeastern part of the North Pacific including the Eastern Equatorial Pacific is negative. The zero line of the 2nd eigenvector field runs from northeast to southwest, in the same direction as the  相似文献   

Sub-lethal effects of metal exposure: physiological and behavioural responses of the estuarine bivalve Macoma balthica     

Duquesne S  Liess M  Bird DJ 《Marine environmental research》2004,58(2-5):245-250

Variation in glycogen concentration, condition index (CI) and filtration activity were measured in the bivalve Macoma balthica buried in sediment and experimentally exposed to cadmium (Cd). The stress due to elevated but sub-lethal concentrations (300 ppb Cd) affected the overall fitness of the organism as all parameters monitored responded significantly. Lower concentrations tested (10, 30 and 100 ppb) only induced a significant decrease in filtration activity, which may play a protective role, enabling the organism to slow down its metabolic activity and preserving the integrity of its reserves (reflected by stable CI and glycogen levels). Hence, the various endpoints selected show different thresholds. Our results also demonstrate that under high exposure, small individuals loose proportionally more glycogen per unit of weight than larger ones, thus confirming the higher sensitivity of small individuals to metal contamination. Furthermore, exposure to intermediate concentration (30 ppb) seems to be beneficial to the small individuals as indicated by their high CI values compared to the control. These results showed thus that non-sigmoidal concentration-response relationship and sizes of individuals should be considered in monitoring programmes and risk assessment.  相似文献