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81.
On March 19, 1984, more than 170000 gallons of oil were spilled into the Columbia River. We had recently developed analytical methods for estimating the exposure of fish to aromatic compounds by measuring the concentrations of metabolites of these contaminants in fish bile. The oil spill provided an opportunity to field test our methods in assessing the exposure of fish to petroleum aromatic compounds from the spilled oil. Our findings indicated that, within 5 days after the spill, mean concentrations of metabolites of aromatic compounds in the bile of white sturgeon (Acipenser transmontanus) captured 57 miles downstream from the spill were significantly higher than those of sturgeon caught upriver.  相似文献   
82.
As part of the 2002 Western Arctic Shelf–Basin Interactions (SBI) project, spatio-temporal variability of dissolved inorganic carbon (DIC) was employed to determine rates of net community production (NCP) for the Chukchi and western Beaufort Sea shelf and slope, and Canada Basin of the Arctic Ocean. Seasonal and spatial distributions of DIC were characterized for all water masses (e.g., mixed layer, halocline waters, Atlantic layer, and deep Arctic Ocean) of the Chukchi Sea region during field investigations in spring (5 May–15 June 2002) and summer (15 July–25 August 2002). Between these periods, high rates of phytoplankton production resulted in large drawdown of inorganic nutrients and DIC in the Polar Mixed Layer (PML) and in the shallow depths of the Upper Halocline Layer (UHL). The highest rates of NCP (1000–2850 mg C m−2 d−1) occurred on the shelf in the Barrow Canyon region of the Chukchi Sea and east of Barrow in the western Beaufort Sea. A total NCP rate of 8.9–17.8×1012 g for the growing season was estimated for the eastern Chukchi Sea shelf and slope region. Very low inorganic nutrient concentrations and low rates of NCP (<15–25 mg C m−2 d−1) estimated for the mixed layer of the adjacent Arctic Ocean basin indicate that this area is perennially oligotrophic.  相似文献   
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The natural Australian landscape sustains a mosaic of wetlands that range from permanently wet to temporary. This diversity of wetland types and habitats provides for diverse biotic communities, many of which are specific to individual wetlands. This paper explores the prospects for southern Australian wetlands under modified water regime and salinity induced by climatic changes. Extended droughts predicted as a consequence of climate change (lower rainfall and higher temperatures) combined with human-induced changes to the natural hydrological regime will lead to reductions in the amount of water available for environmental and anthropogenic uses. Reduced runoff and river flows may cause the loss of some temporary wetland types that will no longer hold water long enough to support hydric communities. Species distributions will shift and species extinctions may result particularly across fragmented or vulnerable landscapes. Accumulation of salts in wetlands shift species-rich freshwater communities to species-poor salt tolerant communities. Wetlands will differ in ecological response to these changes as the salinity and drying history of each wetland will determine its resilience: in the short term some freshwater communities may recover but they are unlikely to survive and reproduce under long term increased salinity and altered hydrology. In the long term such salinized wetlands with altered hydrology will need to be colonized by salt tolerant species adapted for the new hydrological conditions if they are to persist as functional wetlands. As the landscape becomes more developed, to accommodate the need for water in a warmer drying climate, increasing human intervention will result in a net loss of wetlands and wetland diversity.  相似文献   
86.
Recent detection of methane (CH4) on Mars has generated interest in possible biological or geological sources, but the factors responsible for the reported variability are not understood. Here we explore one potential sink that might affect the seasonal cycling of CH4 on Mars - trapping in ices deposited on the surface. Our apparatus consisted of a high-vacuum chamber in which three different Mars ice analogs (water, carbon dioxide, and carbon dioxide clathrate hydrates) were deposited in the presence of CH4 gas. The ices were monitored for spectroscopic evidence of CH4 trapping using transmission Fourier-Transform Infrared (FT-IR) spectroscopy, and during subsequent sublimation of the ice films the vapor composition was measured using mass spectrometry (MS). Trapping of CH4 in water ice was confirmed at deposition temperatures <100 K which is consistent with previous work, thus validating the experimental methods. However, no trapping of CH4 was observed in the ice analogs studied at warmer temperatures (140 K for H2O and CO2 clathrate, 90 K for CO2 snow) with approximately 10 mTorr CH4 in the chamber. From experimental detection limits these results provide an upper limit of 0.02 for the atmosphere/ice trapping ratio of CH4. If it is assumed that the trapping mechanism is linear with CH4 partial pressure and can be extrapolated to Mars, this upper limit would indicate that less than 1% is expected to be trapped from the largest reported CH4 plume, and therefore does not represent a significant sink for CH4.  相似文献   
87.
Water resources, and in particular run-off, are significantly affected by climate variability. At present, there are few examples of how the water management sector integrates information about changing intra-annual climate conditions in a systematic manner in developing countries. This paper, using the case study of Cape Town in the Western Cape, South Africa, identifies processes and products to facilitate increased uptake of seasonal climate forecasts among water resource managers. Results suggest that existing seasonal forecasts do not focus enough on specific users’ needs. In order to increase uptake, forecasts need to include information on the likely impact of precipitation variability on runoff and water availability. More opportunities are also needed for those with climate knowledge to interact with water resource managers, particularly in the developing country context where municipal managers’ capacity is strained. Although there are challenges that need to be overcome in using probabilistic climate information, seasonal forecast information tailored to the needs of water resource planners has the potential to support annual planning and is therefore a means of adapting to climate change.  相似文献   
88.
The specter of climate change threatens fresh water resources along the U.S.–Mexico border. Water managers and planners on both sides of the border are promoting desalination—the conversion of seawater or brackish groundwater to fresh water—as an adaptation response that can help meet growing water demands and buffer against the negative impacts of climate change on regional water supplies. However, the uneven distribution of costs and benefits of this expensive, energy-intensive technology is likely to exacerbate existing social inequalities in the border zone. In this paper, we examine the discourses employed in the construction of the climate problem and proposed solutions. We focus our analysis on a proposed Arizona–Sonora binational desalination project and use insights from risk and hazards literature to analyze how, why, and to what effect desalination is emerging as a preferred climate change adaptation response. Our risk analysis shows that while desalination technology can reduce some vulnerabilities (e.g., future water supply), it can also introduce new vulnerabilities by compounding the water-energy nexus, increasing greenhouse gas emissions, inducing urban growth, producing brine discharge and chemical pollutants, shifting geopolitical relations of water security, and increasing water prices. Additionally, a high-tech and path-dependent response will likely result in increased reliance on technical expertise, less opportunity for participatory decision-making and reduced flexibility. The paper concludes by proposing alternative adaptation responses that can offer greater flexibility, are less path dependent, incorporate social learning, and target the poorest and most vulnerable members of the community. These alternatives can build greater adaptive capacity and ensure equity.  相似文献   
89.

Four meadows of turtle grass (Thalassia testudinum Banks ex Konig) in Sarasota Bay, Florida were sampled on a bimonthly basis from June 1992 to July 1993 to determine spatial and temporal variation in short shoot density, biomass, productivity, and epiphyte loads. Concurrent with the seagrass sampling, quarterly water-quality monitoring was undertaken at ≥3 sites in the vicinity of each studied seagrass meadow. Three months after termination of the seagrass sampling effort, a biweekly water-quality monitoring program was instituted at two of the seagrass sampling sites. In addition, a nitrogen loading model was calibrated for the various watersheds influencing the seagrass meadows. Substantial spatial and temporal differences in turtle grass parameters but smaller spatial variation in water quality parameters are indicated by data from both the concurrent quarterly monitoring program and the biweekly monitoring program instituted after termination of the seagrass study. Turtle grass biomass and productivity were negatively correlated with watershed nitrogen loads, while water quality parameters did not clearly reflect differences in watershed nutrient inputs. We suggest that traditional water-quality monitoring programs can fail to detect the onset or continuance of nutrient-induced declines in seagrass health. Consequently, seagrass meadows should be monitored directly as a part of any effort to determine status and/or trends in the health of estuarine environments. *** DIRECT SUPPORT *** A01BY074 00029

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90.
Mining operations in Palawan, Philippines, resulted in cinnabar (HgS) mine tailings being used to build a 600 m long peninsula in Honda Bay. Samples collected from the peninsula as well as sediments from the surrounding waters had elevated mercury levels as high as 570 ppm. Natural processes are transporting mercury as much as 10 km from the peninsula, mainly in a coastwise direction, and preferentially associated with fine-grained, organic-rich sediments. Depth of penetration into sediments exceeds 10 cm near the source. As the HgS is transported away from the peninsula, it is rapidly altered to more bioavailable forms; 50% conversion occurs within a distance of only 10–40 m.  相似文献   
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