Modelling the formation of H₂SO₄–H₂O particles in rural, urban and marine conditions     

Liisa Pirjola  Markku Kulmala 《Atmospheric Research》1998,46(3-4)

The factors which affect the formation of new sulphuric acid particles in different atmospheric conditions are investigated. An atmospheric chemistry gas phase box model coupled to a three mode integral aerosol dynamics model is used. The simulations show the dependence of the concentration of nucleation mode particles on initial pre-existing particles, the intensity of UV radiation, the emissions of dimethylsulphide (DMS) and the ratio of emissions of hydrocarbons (HC) and NO_x present in the atmosphere. Eight different basic cases are simulated in urban, rural and marine conditions. The effects of pre-existing particles as a sink of sulphuric acid are clearly seen. The increased UV radiation is also seen to enhance particle formation via sulphuric acid route significantly.  相似文献   

Particle Size Distribution and Gas-Particle Partition of Polycyclic Aromatic Hydrocarbons in Helsinki Urban Area     

Masahiko Shimmo  Karri Saarnio  Pasi Aalto  Kari Hartonen  Tuulia Hyötyläinen  Markku Kulmala  Marja-Liisa Riekkola 《Journal of Atmospheric Chemistry》2004,47(3):223-241

Ambient concentrations of polycyclic aromatic hydrocarbons (PAHs) were measured in Helsinki (Finland). Particle mass size distributions were obtained with a cascade impactor (12 stages) with glass fibre filters as substrates. Simultaneously with the impactor measurements, particulate and gaseous PAHs were collected on a quartz filter and XAD-2 adsorbent, respectively, for evaluation of gas-partition coefficients. Samples were analysed for PAHs by on-line coupled supercritical fluid extraction — liquid chromatography — gas chromatography — mass spectrometry. The impactor results showed that most of the PAHs in Helsinki urban area were concentrated in fine particles (<2.5 μm diameter) with unimode peak at about 1 μm. The results were comparable with the number distribution measured with a differential mobility particle sizer. Total amounts of PAHs (gas + particle) varied from 15 (acenaphthylene) to 1990 (fluorene) pg/m³. The PAHs lighter than 202 amu (pyrene and fluoranthene) were exclusively in gas phase, whereas those heavier than 202 amu were mostly associated with particles. A plot of the partition coefficients (logKp) versus the temperature dependent sub-cooled vapour pressures (logp _L ⁰ ) showed a gradient of −0.66, which deviated from equilibrium state (gradient = −1).  相似文献   

Geochemical Baselines of Nickel and Chromium in Various Surficial Materials in the Barents Region, NW Russia and Finland     

Reijo Salminen  Igor Bogatyrev  Victor Chekushin  Sergey P. Glavatskikh  Virgilija Gregorauskiene  Heikki Niskavaara  Lubov Selenok  Markku Tenhola  Olga Tomilina 《Geostandards and Geoanalytical Research》2004,28(2):333-341

The geochemical baselines of nickel and chromium were studied from the data produced by the Barents Ecogeochemistry project, a large international regional geochemical mapping exercise. The project surveyed major and trace element distributions in stream water, organic and mineralogically-modified soil horizons, and terrestrial moss in the northwestern part of Russia and in Finland. Other materials were collected during the pilot phase and later from thirty special sites. The results on respective materials by XRF, ICP-MS and ICP-AES showed that both geological and anthropogenic factors have an influence on the geochemical baseline concentrations of Ni and Cr in organic soil and stream water. The main explanation of the observed distribution patterns in terrestrial moss is human activity, but geological factors can also affect the baselines. The variation of geochemical baselines in the mineral-rich soil horizon depends only on variations in bedrock. The mineralogy of samples mainly controls the leachability properties of soil samples.  相似文献   

Optimization of photovoltaic solar power plant locations in northern Chile     

Anna Suuronen  Anssi Lensu  Markku Kuitunen  Rodrigo Andrade-Alvear  Natalia Guajardo Celis  Marcelo Miranda  Marcelo Perez  Jussi V. K. Kukkonen 《Environmental Earth Sciences》2017,76(24):824

The optimization of photovoltaic solar power plants location in Atacama Desert, Chile, is presented in this study. The study considers three objectives: (1) Find sites with the highest solar energy potential, (2) determine sites with the least impact on the environment, and (3) locate the areas which produce small social impact. To solve this task, multi-criteria decision analyses (MCDAs) such as analytical hierarchy process and ordered weighted averaging were applied in a GIS environment. In addition, survey results of social impacts were analyzed and included into the decision-making process, including landscape values. The most suitable sites for solar energy projects were found near roads and power lines throughout the study area. Large suitable areas were found also from central valley from Arica and Parinacota to the north edge of Atacama region. In Atacama region, most suitable sites were found in the Andes. On the contrary, Andes were also found to have high environmental values and scenically valuable landscapes. Moderate and low suitability were found on the coast, especially in Atacama region. Factors such as slope and distance to power lines and roads influenced largely the sensitivity analysis. Area of high suitability increased by 15% when distance to roads was excluded and 18% when distance to power lines or slope was removed. MCDA-GIS method was found to be useful and applicable to the optimization of solar power plant locations in northern Chile.  相似文献   

Spectral evolution of magnetic flares and time lags in accreting black hole sources   总被引：1，自引：0，他引：1  

Juri Poutanen  Andrew C. Fabian 《Monthly notices of the Royal Astronomical Society》1999,306(3):L31-L37

We present a model for the short time-scale spectral variability of accreting black holes. It describes the time-averaged spectra well, and also temporal characteristics such as the power-density spectrum, time/phase lags, and coherence function of Cygnus X-1. We assume that X/ γ -rays are produced in compact magnetic flares at radii ≲100 GM c ² from the central black hole. The tendency for magnetic loops to inflate and detach from the underlying accretion disc causes the spectrum of a flare to evolve from soft to hard because of the decrease of the feedback from the cold disc, so causing time delays between hard and soft photons. We identify the observed time lags with the evolution time-scales of the flares, which are of the order of the Keplerian time-scale. We model the overall temporal variability using a pulse avalanche model in which each flare has a certain probability of triggering a neighbouring flare, thus occasionally producing long avalanches. The duration of the avalanches determines the Fourier frequencies at which most of the power emerges.  相似文献   

Contributions of soil moisture interactions to climate change in the tropics in the GLACE–CMIP5 experiment     

Wilhelm May  Arndt Meier  Markku Rummukainen  Alexis Berg  Frederique Chéruy  Stefan Hagemann 《Climate Dynamics》2015,45(11-12):3275-3297

  相似文献   

Madam– a map-making method for CMB experiments     

E. Keihänen  H. Kurki-Suonio  T. Poutanen 《Monthly notices of the Royal Astronomical Society》2005,360(1):390-400

We present a new map-making method for cosmic microwave background (CMB) measurements. The method is based on the destriping technique, but it also utilizes information about the noise spectrum. The low-frequency component of the instrument noise stream is modelled as a superposition of a set of simple base functions, whose amplitudes are determined by means of maximum-likelihood analysis, involving the covariance matrix of the amplitudes. We present simulation results with  1/ f   noise and show a reduction in the residual noise with respect to ordinary destriping. This study is related to Planck Low Frequency Instrument (LFI) activities.  相似文献   

Spectra of the spreading layers on the neutron star surface and constraints on the neutron star equation of state     

Valery Suleimanov  Juri Poutanen 《Monthly notices of the Royal Astronomical Society》2006,369(4):2036-2048

Spectra of the spreading layers on the neutron star surface are calculated on the basis of the Inogamov–Sunyaev model taking into account general relativity correction to the surface gravity and considering various chemical composition of the accreting matter. Local (at a given latitude) spectra are similar to the X-ray burst spectra and are described by a diluted blackbody. Total spreading layer spectra are integrated accounting for the light bending, gravitational redshift and the relativistic Doppler effect and aberration. They depend slightly on the inclination angle and on the luminosity. These spectra also can be fitted by a diluted blackbody with the colour temperature depending mainly on a neutron star compactness. Owing to the fact that the flux from the spreading layer is close to the critical Eddington, we can put constraints on a neutron star radius without the need to know precisely the emitting region area or the distance to the source. The boundary layer spectra observed in the luminous low-mass X-ray binaries, and described by a blackbody of colour temperature   T _c= 2.4 ± 0.1 keV  , restrict the neutron star radii to   R = 14.8 ± 1.5 km  (for a  1.4-M_⊙  star and solar composition of the accreting matter), which corresponds to the hard equation of state.  相似文献   

X-ray spectra of accretion discs with dynamic coronae   总被引：1，自引：0，他引：1  

Julien Malzac  rei M. Beloborodov  Juri Poutanen 《Monthly notices of the Royal Astronomical Society》2001,326(2):417-427

We compute the X-ray spectra produced by non-static coronae atop accretion discs around black holes and neutron stars. The hot corona is radiatively coupled to the underlying disc (the reflector) and generates an X-ray spectrum which is sensitive to the bulk velocity of the coronal plasma, β = v / c . We show that an outflowing corona reproduces the hard-state spectrum of Cyg X-1 and similar objects. The dynamic model predicts a correlation between the observed amplitude of reflection R and the X-ray spectrum slope Γ since both strongly depend on β . A similar correlation was observed and its shape was well fitted by the dynamic model. The scattering of soft radiation in an outflowing corona can also account for the observed optical–UV polarization pattern in active galactic nuclei.  相似文献   

The ADV/ASV AATSR aerosol retrieval algorithm: current status and presentation of a full-mission AOD dataset     

Pekka Kolmonen  Larisa Sogacheva  Timo H. Virtanen  Markku Kulmala 《International Journal of Digital Earth》2016,9(6):545-561

An advanced along-track scanning radiometer (AATSR) global multi-year aerosol retrieval algorithm is described. Over land, the AATSR dual-view (ADV) algorithm utilizes the measured top of the atmosphere (TOA) reflectance in both the nadir and forward views to decouple the contributions of the atmosphere and the surface to retrieve aerosol properties. Over ocean, the AATSR single-view (ASV) algorithm minimizes the discrepancy between the measured and modelled TOA reflectances in one of the views to retrieve the aerosol information using an ocean reflectance model. Necessary steps to process global, multi-year aerosol information are presented. These include cloud screening, the averaging of measured reflectance, and post-processing. Limitations of the algorithms are also discussed. The main product of the aerosol retrieval is the aerosol optical depth (AOD) at visible/near-infrared wavelengths. The retrieved AOD is validated using data from the surface-based AERONET and maritime aerosol network (MAN) sun photometer networks as references. The validation shows good agreement with the reference (r?=?0.85, RMSE?=?0.09 over land; r?=?0.83, RMSE?=?0.09 at coasts and r?=?0.96, RMSE?=?0.06 over open ocean). The results of the aerosol retrievals are presented for the full AATSR mission years 2002–2012 with seasonally averaged time series for selected regions.  相似文献