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151.
Diatom abundances in the surface sediment samples of 41 mountain lakes in the central Austrian Alps (Niedere Tauern) were related to environmental variables using multi-variate techniques. Canonical correspondence analysis (CCA) revealed that the pH, date of autumn mixing (A mix), mean August water temperature (T Aug), dissolved organic carbon (DOC), and relative water depth (Z rel) made significant contributions to explain the diatom assemblage variation in the lakes of the training set. A weighted averaging partial least square regression and calibration model was used to establish Di-pH (R 2 boot= 0.72, RMSEPboot= 0.131), and a thermistor measurements-based PLS model for A mix (R 2 boot= 0.71, RMSEPboot= 0.006 log10 Julian days). The latter showed a better prediction than T Aug, and was used in terms of climate change. These transfer functions, together with analyses of loss on ignition (LOI), the total carbon/nitrogen (C/N)-ratios, and selected pollen, were applied to an early to mid-Holocene (11.5–4 cal. ky BP) sediment core section from an Austrian Alpine treeline lake on crystalline bedrock. Additionally, passive sample scores in the CCA of the diatom training set were used to show trends in the variables DOC and Z rel. During the early Holocene, diatoms indicative of increased pH, extended warm summers, and low water levels dominated. Between 10.2 and 7.6 cal. ky BP it was followed by diatom assemblages that indicated an increase in lake water depth and an earlier A mix. The multi-proxy data suggest that the A mix decline is the result of a series of snow-rich summer cool and wet climate fluctuations, which were divided by climate warming at ∼9 cal. ky BP. Increased A mix, LOI and DOC, and the correspondent decline in the C/N-ratios, show subsequent climate warming between 7.3 and 6 cal. ky BP. The long-term trend in Di-pH indicates the impact of catchment-related processes during the early-Holocene, that were superimposed by climate.  相似文献   
152.
Markus Weiler   《Journal of Hydrology》2005,310(1-4):294-315
Simulating infiltration in soils containing macropores still provides unsatisfactory results, as existing models seem not to capture all relevant processes. Recent studies of macropore flow initiation in natural soils containing earthworm channels revealed a distinct flow rate variability in the macropores depending on the initiation process. When macropore flow was initiated at the soil surface, most of the macropores received very little water while a few macropores received a large proportion of the total inflow. In contrast, when macropore flow was initiated from a saturated or nearly saturated soil layer, macropore flow rate variation was much lower. The objective of this study was to develop, evaluate, and test a model, which combines macropore flow variability with several established approaches to model dual permeability soils. We then evaluate the INfiltration–INitiation–INteraction Model (IN3M) to explore the influence of macropore flow variability on infiltration behavior by performing a sensitivity analysis and applying IN3M to sprinkling and dye tracer experiments at three field sites with different macropore and soil matrix properties. The sensitivity analysis showed that the flow variability in macropores reduces interaction between the macropores and the surrounding soil matrix and thus increases bypass flow, especially for surface initiation of macropore flow and at higher rainfall intensities. The model application shows reasonable agreement between IN3M simulations and field data in terms of water balance, water content change, and dye patterns. The influence of macropore flow variability on the hydrological response of the soil was considerable and especially pronounced for soils where initiation occurs at the soil surface. In future, the model could be applied to explore other types of preferential flow and hence to get a generally better understanding of macropore flow.  相似文献   
153.
A tree-ring proxy of summer temperature anomalies for northern Finland for the past 7500 yr was analyzed using Fourier spectrum and wavelet approaches. Multicentennial (250-450 yr) variability is present in the proxy record during most of the time range. This variability is suggested to reflect low-frequency variability in the North Atlantic Oscillation. Century-scale (90-130 yr) variation is another important feature of the tree-ring proxy data during the Holocene and may be attributed to Glessberg solar activity variations. In addition, an approximately 2000-yr quasi-period is found in this temperature proxy data, similar to the millennial-scale variability, present in many climate records from the North Atlantic region. The results point to the importance of multiple forcings underlying significant Holocene climatic fluctuations.  相似文献   
154.
The clothing industry is widely cited as an industrial sector that is embedded primarily in buyer-driven structures of global commodity chains in which retailers and brand-name companies, rather than manufacturers, are the key driving forces. Analysis of clothing production systems within the commodity chain literature, however, has been predominantly Western-centric, with little emphasis on similarities and/or differences between competitors in different institutional and societal contexts. Therefore, this paper explores the ways in which international and domestic clothing brand-owners compete for market shares within Indonesia. The analytical focus includes important issues such as the influence of the regulatory policy framework on firm-specific behaviour as well as applied marketing strategies within individual fashion segments.  相似文献   
155.
Rockfall is a major threat to settlements and transportation routes in large parts of the Alps. While protective forest stands in many locations undoubtedly reduce rockfall risk, little is known about the exact frequency and spatial distribution of rockfall activity in a given place or about how these parameters can be assessed. Therefore, the objective of the present study was to reconstruct rockfall events with dendrogeomorphological methods and to analyse the spatial and temporal rockfall activity in a subalpine forest stand. The study site is located in the transit zone of frequently passing, rather small rockfall fragments (mean diameter of 10 to 20 cm). In all, 33 stem discs from previously felled Picea abies trees found at the foot of Schwarzenberg in Diemtigtal (Swiss Prealps) were sampled, and a total number of 301 rockfall events were dated to between A.D. 1724 and 2002.Results showed that the spatial distribution of rockfall changed slightly with time, and that rockfall activity increased considerably over the last century. In contrast, rockfall magnitude presumably remained on a comparable level. The seasonal occurrence of rockfall showed a clear peak during the dormant season of trees, most probably in early spring. Furthermore, on a 10-year moving average basis, rockfall rates were positively correlated with mean annual as well as summer and winter temperatures. This means that higher temperatures resulted in increased rockfall activity. On the other hand, no correlation with annual or seasonal precipitation totals was revealed. Overall, this study provides an appropriate method for the detailed assessment of spatial and temporal variations in rockfall activity in a given place.  相似文献   
156.
A laboratory experiment with two sequenced columns was performed as a preliminary study for the installation of a permeable reactive barrier (PRB) at a site where a mixed ground water contamination exists. The first column contained granular zero valent iron (ZVI), the second column was filled with granular activated carbon (GAC). Trichloromethane (TCM, 930 μg/l) and chlorobenzene (MCB, 260 μg/l) were added to the ground water from the site as the main contaminants. Smaller amounts (<60 μg/l) of benzene, 1,2-dichloroethane, 1,1,2-trichloroethane (1,1,2-TCA), 1,1-dichloroethene (1,1-DCE), trichloroethene (TCE), tetrachloroethene (PCE), 1,2-dichloropropane (1,2-DCP), bromodichloromethane (BDCM), dibromochloromethane (DBCM), tribromomethane (TBM), vinyl chloride and chromate were also added to the water to simulate the complex contamination pattern at the site of interest. PCE, TCE, 1,1-DCE, DBCM, BDCM, TBM, MCB and chromate were remediated in contact with ZVI, while the remaining contaminants showed incomplete degradation. A fraction of 8–16.5% TCM was converted to dichloromethane (DCM). Remaining contaminant concentrations were efficiently sorbed by the GAC until breakthrough of DCM was observed after 1,230 exchanged pore volumes in the GAC. The results show that the complex mixture of contaminants can be remediated by a sequenced PRB consisting of ZVI and GAC and that DCM sorption capacity is the critical parameter for the dimensions of the GAC reactor.  相似文献   
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159.
The solar 0.5–8 soft X-ray flux was monitored by the NOAA Geostationary Operational Environmental Satellites (GOES) from 1974 to the present, providing a continuous record over two solar activity cycles. Attempts have been made to determine a soft X-ray (SXR) background flux by subtracting out solar flares (using the daily lowest flux level). The SXR background flux represents the quiescent SXR flux from heated plasma in active regions, and reflects similar (intermediate-term) variability and periodicities (e.g. 155-day period) as the SXR or hard X-ray (HXR) flare rate, although it is determined in non-flaring time intervals. The SXR background flux peaks late in Solar Cycle 21 (2–3 years after the sunspot maximum), similar to the flare rate measured in SXR, HXR, or gamma rays, possibly due the increasing complexity of coronal magnetic structures in the decay phase of the solar cycle. The SXR background flux appears to be dominated by postflare emission from the dominant active regions, while the contributions from the quiet Sun are appreciable in the Solar Minimum only (A1-level). Comparisons with full-disk integrated images from YOHKOH suggest that the presence of coronal holes can decrease the quietest SXR irradiance level by an additional order of magnitude, but only in the rare case of absence of active regions.Presented at IAU Colloquium No. 143, The Sun as a Variable Star: Solar and Stellar Irradiance Variations, Boulder, CO, June 20–25, 1993  相似文献   
160.
Extended X-ray absorption fine structure (EXAFS) spectroscopy and chemical analyses were combined to determine the Fe bearing minerals in recent lake sediments from Baldeggersee (Switzerland). The upper section of a laminated sediment core, deposited under eutrophic conditions, was compared to the lower part from an oligotrophic period. Qualitative analysis of FeK EXAFS agreed well with chemical data: In the oligotrophic section Fe(II)–O and Fe(III)–O specieswere present, whereas a significant fraction of Fe(II)–S sulfides was strongly indicated in the eutrophic part. A statistical analysis was performed by least square fitting of normalized reference spectra. The set of reference minerals included Fe(III) oxides and Fe(II) sulfides, carbonates and phosphates. In the oligotrophic regime no satisfying fit was obtained using the set of reference spectra, indicating that siderite (FeCO3) was not present in a significant amount in these carbonate-rich sediments. Simulated EXAFS spectra for a(Cax, Fe1-x)CO3solid solution allowed reconstructing the specificfeatures of the experimental spectra, suggesting that this phase was the dominant Fe carrier in the oligotrophic section of the core. In the eutrophic part, mackinawite was positively identified and represented the dominant Fe(II) sulfide phase. This finding agreed with chemical extraction, which indicated that18–40 mol% of Fe was contained in the acid volatile iron sulfide fraction. EXAFS spectra of the eutrophic section were best fitted by considering the admixture of mackinawite and the Fe–Ca carbonate phase inferred to be predominant in the oligotrophic regime.  相似文献   
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