Mobility of potentially harmful metals in latosols impacted by the municipal solid waste deposit of Londrina,Brazil     

Raquel Souza Teixeira  Philippe Cambier  Regina Davison Dias  José Paulo Peccinini Pinese  Anne Jaulin-Soubelet 《Applied Geochemistry》2010

The contamination of soils by metals issuing from municipal solid waste (MSW) disposal in tropical environments has hardly been studied with regard to the particular problems associated with them, i.e., generally a high permeability of soils despite the abundance of clay, and the role of reactive Fe compounds. From a previous geotechnical and chemical survey, three latosol profiles differently affected by MSW leachates in the region of Londrina (Paraná, Brazil) were selected. The aims were to evaluate the extent of their contamination, to better understand the fate of potentially harmful metals in tropical soils and rank the determining factors. Samples between 0.5 and 7 m depth were analyzed for their physical, mineralogical and chemical properties, and their micro-morphology was described by optical and transmission electron microscopy. Two steps of a sequential extraction procedure helped to assess the mobility of elements and to better discriminate between metals originating from pedogenesis and issued from MSW. These combined approaches showed that exposed soil profiles have been impacted at various depths, down to 7 m, through increased metal content, especially enhanced mobility of Zn, Co, Mn, Cu and Fe, and through increased salinity and organic matter. The mobility of potentially harmful metals should decrease with pH, which significantly increased in some impacted horizons, but other factors can reverse this trend.  相似文献   

Phytoplankton Interannual Variability at Cassino Beach, Southern Brazil (1992–2007), with Emphasis on the Surf Zone Diatom Asterionellopsis glacialis     

Clarisse Odebrecht  Marli Bergesch  Leonardo Rubi R?rig  Paulo C. Abreu 《Estuaries and Coasts》2010,33(2):570-583

A long-term study (monthly sampling, 1992 to 2007) was conducted in the surf zone of Cassino Beach, Southern Brazil, in order to detect possible natural and/or anthropogenic disturbances. Surface water temperature (6–29°C) was the only parameter with predictable seasonal variation; salinity (14–38) was inversely related to rainfall (3.1–485.2 mm month⁻¹) and low values followed extreme precipitation periods in 1997/1998 and 2002/2003 (El Ni?o years). Asterionellopsis glacialis and chlorophyll a presented high concentrations and peak frequency until 1998, when an intense mud deposition occurred with concomitant extreme rainfall. It affected the surf zone and beach, changing the hydrology and dissolved inorganic nutrient availability. Six phytoplankton species groups were recognized with distinct responses to this mud deposition. We conclude that large-scale climatic changes, like El Ni?o Southern Oscillation, in conjunction with human activities significantly altered the phytoplankton ecology of the highly dynamic Cassino Beach surf zone.  相似文献   

The freshwater lens of Benjamín Aceval,Chaco, Paraguay: a terrestrial analogue of an oceanic island lens     

Georg Houben  Ursula Noell  Sara Vassolo  Christoph Grissemann  Mebus Geyh  Susanne Stadler  Eduardo J. Dose  Sofia Vera 《Hydrogeology Journal》2014,22(8):1935-1952

The occurrence of a freshwater lens in the Paraguayan Chaco, 900 km away from the ocean, is reported. It is located underneath sandstone hills, surrounded by lowlands with predominantly saline groundwater. Its geometry was delineated using geoelectrical and electromagnetic investigations. The unusual height of the fresh groundwater level can be attributed to the presence of a confining layer at depth. The lens receives its recharge exclusively from rainfall during the hot and humid summer months. It predominantly contains water predating the atmospheric atomic bomb tests, some of it probably up to a thousand or more years old. The water balance shows that extraction currently does not exceed recharge in normal years. However, the available volume of groundwater leaves little room for a further increase of extraction in the future. Recharge is augmented by return flow from thousands of latrines and cess pits, and this has lead to widespread contamination of the groundwater by faecal bacteria.  相似文献   

Catastrophic,rainfall-induced debris flows in Andean villages of Tarapacá, Atacama Desert,northern Chile   总被引：1，自引：0，他引：1  

Sergio A. Sepúlveda  Sofía Rebolledo  James McPhee  Marisol Lara  Mauricio Cartes  Eduardo Rubio  David Silva  Nicolle Correia  Juan P. Vásquez 《Landslides》2014,11(3):481-491

In March 2012, during the rainy season in the Altiplano plateau, a >100-year return period rainfall event affected the deeply incised valleys of the Precordillera of the Tarapacá Region, northern Chile. This extreme event in a very arid region triggered a number of debris and mud flows that caused severe damage and destruction in several small villages along the Camiña and Tarapacá valleys. The highly vulnerable location of the villages on top of alluvial fans due to socioeconomic and cultural reasons is a key factor to explain the level of destruction in most villages. In this paper, this unusual, remarkable landslide event is described, and the hazard faced by these settlements for future rainfall episodes and possible mitigation measures are discussed.  相似文献   

Petrogenesis of a voluminous Quaternary adakitic volcano: the case of Baru volcano     

Paulo?J.?HidalgoEmail author  Tyrone?O.?Rooney 《Contributions to Mineralogy and Petrology》2014,168(3):1011

The origin of adakite magmas remains controversial because initially the term adakite had petrogenetic significance implying an origin by direct melting of the eclogitized subducting oceanic crust. Many models have been produced for their origin, and until now there has not been a straightforward method to discriminate between these models in a given adakite suite. Here, we use detailed chronological and geochemical studies of selected adakitic edifices that allows for the determination of the magmatic output rate parameter (Qe), which has been correlated with the rates of magma generation deep within subduction zones. By providing temporal and eruption rate estimates, we provide constraints on the possible petrogenetic processes involved in the generation of adakite-like signatures. Adakite magmas derived from the melting of the subducting slab should be volumetrically insignificant when compared to the adakite-like magmas produced by typical arc magma generation processes. In this study, we use this observation and the extraordinary stratigraphic exposure from Miocene to present in an adakitic volcano in Panama and to study the temporal and chemical variation in erupted magmas to estimate rates of magma generation. Detailed chemical and geochronological analyses of Baru volcano indicate that the volcanic edifice was constructed in its entirety during the Quaternary and magmas display adakite-like features such as steep rare earth elements patterns, pronounced depletions in the heavy rare earth elements, low Y, high Sr, and high Sr/Y. The magmatic output rates (Qe) that we have calculated show that compared to other typical adakitic volcanoes, most of the volcanic edifice of Baru volcano was constructed extremely rapidly (<~213 k.a.) and in time frames that are similar to typical arc volcanoes. The observed chemical and mineralogical variation, coupled with the high magma production rates, indicate that Baru volcano is more representative of a typical arc volcano than a small-volume melt of the subducting oceanic crust. The technique we outline may have broader application in determining the petrogenetic conditions of other adakite suites.  相似文献   

A Middle Miocene carbonate embankment on an active volcanic slope: Ilhéu de Baixo,Madeira Archipelago,Eastern Atlantic     

B. Gudveig Baarli  Mrio Cacho  Carlos M. da Silva  Markes E. Johnson  Eduardo J. Mayoral  Ana Santos 《Geological Journal》2014,49(1):90-106

Carbonate factories on insular oceanic islands in active volcanic settings are poorly explored. This case study illuminates marginal limestone deposits on a steep volcanic flank and their recurring interruption by deposits linked to volcaniclastic processes. Historically known as Ilhéu da Cal (Lime Island), Ilhéu de Baixo was separated from Porto Santo, in the Madeira Archipelago, during the course of the Quaternary. Here, extensive mines were tunnelled in the Miocene carbonate strata for the production of slaked lime. Approximately 10 000 m³ of calcarenite (−1 to 1ø) was removed by hand labour from the Blandy Brothers mine at the south end of the islet. Investigations of two stratigraphic sections at opposite ends of the mine reveal that the quarried material represents an incipient carbonate ramp developed from east to west and embanked against the flank of a volcanic island. A petrographic analysis of limestones from the mine shows that coralline red algae from crushed rhodoliths account for 51% of all identifiable bioclasts. This material was transported shoreward and deposited on the ramp between normal wave base and storm wave base at moderate depths. The mine's roof rocks are formed by Surtseyan deposits from a subsequent volcanic eruption. Volcaniclastic density flows also are a prevalent factor interrupting renewed carbonate deposition. These flows arrived downslope from the north and gradually steepened the debris apron westwards. Slope instability is further shown by a coral rudstone density flow that followed from growth of a coral reef dominated by Pocillopora madreporacea (Lamarck), partial reef collapse, and transport from a more easterly direction into a fore‐reef setting. The uppermost facies represents a soft bottom at moderate depths in a quiet, but shore‐proximal setting. Application of this study to a broader understanding of the relationship between carbonate and volcaniclastic deposition on oceanic islands emphasizes the susceptibility of carbonates to dilution and complete removal by density flows of various kinds, in contrast to the potential for preservation beneath less‐disruptive Surtseyan deposits. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Non-linear stability of the equilibria in the gravity field of a finite straight segment   总被引：1，自引：0，他引：1  

Andrés Riaguas  Antonio Elipe  Teodoro López-Moratalla 《Celestial Mechanics and Dynamical Astronomy》2001,81(3):235-248

We study the non-linear stability of the equilibria corresponding to the motion of a particle orbiting around a finite straight segment. The potential is a logarithmic function and may be considered as an approximation to the one generated by elongated celestial bodies. By means of the Arnold's theorem for non-definite quadratic forms we determine the orbital stability of the equilibria, for all values of the parameter k of the problem, resonant cases included.  相似文献   

High-resolution seismic stratigraphy of the late Neogene of the central sector of the Colombian Pacific continental shelf: A seismic expression of an active continental margin     

Jaime Orlando Martínez  Eduardo López Ramos 《Journal of South American Earth Sciences》2011,31(1):28-44

The sedimentary prism of the central Pacific continental shelf of Colombia was affected by regional folding and faulting, and probably later mud diapirism, from the Late Miocene to the Holocene. Interpretation of high-resolution seismic lines (2 s/dt) revealed that the prism consists of 13 high-resolution seismic units, that can be separated into 5 seismic groups.Deposition of the prism and the associated stacking pattern, are probably the response to variable uplift and subsidence in a fore-arc basin that underwent important tectonic events by the end of the Miocene. Throughout the Pliocene, the continental shelf sedimentation was affected by the growing of a dome structure probable due to mud diapirism. This fact caused peripheral faults both normal and reverse that controlled the distribution of some of the seismic units. During the Late Pleistocene (Wisconsin stage?) a eustatic sea level fall caused the shoreline to advance about 50 km westward of its present position. Because of this eustatic sea level change, a strong fluvial dissection took place and is interpreted as the probable extension of the San Juan River to the south of the present day river mouth. Within this framework it is believed that the Malaga and Buenaventura Bays were the passageways of branches of the old drainage system of the San Juan River. The inner branch circulated through the present Buenaventura Bay and runs southward leaving the mark of an apparent valley identified in the seismic information in the eastern sector of the study area. This old fluvial valley and its filling material located in the present day inner continental shelf front of Buenaventura are postulated as important targets to find placer minerals such as gold and platinum.  相似文献   

Two paleoecological histories spanning the period of human settlement in southeastern Brazil     

Marco F. Raczka  Paulo E. De Oliveira  Mark Bush  Crystal H. McMichael 《第四纪科学杂志》2013,28(2):144-151

The absence of human occupation sites in southeastern Brazil during the mid Holocene has been referred to as the 'Archaic Gap' (8970–1940 cal. a BP) and is predicted to have resulted from increased aridity. A ca. 14 000 cal. a pollen history from two well‐dated lake sediment cores located within the archeological district of Lagoa Santa, in the State of Minas Gerais, southeastern Brazil, was used to test this hypothesis. Our analyses indicated that the present cerrado and tropical semi‐deciduous forest mosaic persisted throughout the mid Holocene, until ca. 5500 cal. a BP, and the Lagoa Santa region did not experience especially dry conditions during the Holocene period. The early Holocene pollen spectra contained an assemblage of cold‐adapted taxa such as Podocarpus, Myrsine and Araucaria, co‐occurring with taxa from cerrado, e.g. Caryocar. A replacement of cold taxa by the modern cerrado–semi‐deciduous forest vegetation took place progressively, but appears to have been completed by the mid Holocene. No evidence of sustained drought was found in sedimentation or forest composition, nor any prolonged dry event in the study region. Holocene dryness as an explanation for the abandonment of Lagoa Santa region is not supported by the palynological analyses conducted in this study. Rather it is suggested that unpredictable climate may have underlain that abandonment. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Putative Meteoritic Craters in Río Cuarto (Central Argentina) Interpreted as Eolian Structures     

Cione  Alberto L.  Tonni  Eduardo P.  San Cristóbal  Jorge  Hernández  Pedro J.  Benítez  Adrián  Bordignon  Fernando  Perí  Jorge A. 《Earth, Moon, and Planets》2002,91(1):9-24

Ten oblong aligned depressions in the Río Cuarto area (provincia de Córdoba, Argentina) were supposed to be the result of very-low-angle Holocene meteoroid impacts. However, we consider that authors that studied the structures did not demonstrated their extraterrestrial origin. We suggest that an eolian origin for the structures of Río Cuarto is more likely. Actually, these landforms integrate large systems of similar deflation/accumulation geoforms aligned according to predominant winds during different periods.  相似文献