Natural Gradient Tracer Test to Evaluate Natural Attenuation of MTBE Under Anaerobic Conditions   总被引：1，自引：0，他引：1  

Illa Amerson  Richard L. Johnson 《Ground Water Monitoring & Remediation》2003,23(1):54-61

A natural gradient tracer test using perdeuterated MTBE was conducted in an anaerobic aquifer to determine the relative importance of dispersion and degradation in reducing MTBE concentrations in ground water. Preliminary ground water chemistry and hydraulic conductivity data were used to place the tracer within an existing dissolved MTBE plume at Port Hueneme, California. Following one year of transport, the tracer plume was characterized in detail.
Longitudinal dispersion was identified as the dominant mechanism for lowering the perdeuterated MTBE concentrations. The method of moments was used to determine the longitudinal and lateral dispersion coefficients (0.85 m²/day and 0.08 m²/day, respectively). A mass-balance analysis, carried out after one year of transport, accounted for 110% of the injected mass and indicated that no significant mass loss occurred. The plume structure created by zones of higher and lower hydraulic conductivity at the site was complex, consisting of several localized areas of high tracer concentration in a lower concentration plume. This is important because the aquifer has generally been characterized as exhibiting fairly minor heterogeneity. In addition, the tracer plume followed a curved flowpath that deviated from the more macroscopic direction of ground water flow inferred from local ground water elevation measurements and the behavior of the existing plume. Understanding the mass balance, plume structure, curvature of the tracer plume, and consequently natural attenuation behavior required the detailed sampling approach employed in this study. These data imply that a detailed understanding of site hydrogeology and an extensive sampling network may be critical for the correct interpretation of monitored natural attenuation of MTBE.  相似文献   

Risk-Based, Quota-Based, or Fund-Based LUST Closures? (Career-Limiting Editorial #1, Part 2)     

Paul C. Johnson 《Ground Water Monitoring & Remediation》2003,23(3):4-4

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Neoarchaean magmatism and metamorphism of the western granulites in the central domain of the Mozambique belt, Tanzania: U–Pb shrimp geochronology and PT estimates     

S. P. Johnson  H. N. C. Cutten  S. Muhongo  B. De Waele 《Tectonophysics》2003,375(1-4):125

U–Pb sensitive high resolution ion microprobe (SHRIMP) dating of zircons from charnockitic and garnet–biotite gneisses from the central portion of the Mozambique belt, central Tanzania indicate that the protolith granitoids were emplaced in a late Archaean, ca. 2.7 Ga, magmatic event. These ages are similar to other U–Pb and Pb–Pb ages obtained for other gneisses in this part of the belt. Zircon xenocrysts dated between 2.8 and 3.0 Ga indicate the presence of an older basement. Major and trace element geochemistry of these high-grade gneisses suggests that the granitoid protoliths may have formed in an active continental margin environment. Metamorphic zircon rims and multifaceted metamorphic zircons are dated at ca. 2.6 Ga indicating that these rocks were metamorphosed some 50–100 my after their emplacement. Pressure and temperature estimates on the charnockitic and garnet–biotite gneisses were obscured by post-peak metamorphic compositional homogenisation; however, these estimates combined with mineral textures suggest that these rocks underwent isobaric cooling to 800–850 °C at 12–14 kbar. It is considered likely that the granulite facies mineral assemblage developed during the ca. 2.6 Ga event, but it must be considered that it might instead represent a pervasive Neoproterozoic, Pan African, granulite facies overprint, similar to the ubiquitous eastern granulites further to the east.  相似文献   

The Global Distribution of Secondary Particulate Matter in a 3-D Lagrangian Chemistry Transport Model     

R. G. Derwent  W. J. Collins  M. E. Jenkin  C. E. Johnson  D. S. Stevenson 《Journal of Atmospheric Chemistry》2003,44(1):57-95

A global 3-D Lagrangian chemistry-transport model STOCHEM is used to describe the tropospheric distributions of four components of the secondary atmospheric aerosol: nitrate, sulphate, ammonium and organic compounds. The model describes the detailed chemistry of the formation of the acid precursors from the oxidation of SO₂, DMS, NO_x, NH₃ and terpenes and their uptake into the aerosol. Model results are compared in some detail with the available surface observations. Comparisons are made between the global budgets and burdens found in other modelling studies. The global distributions of the total mass of secondary aerosols have been estimated for the pre-industrial, present day and 2030 emissions and large changes have been estimated in the mass fractions of the different secondary aerosol components.  相似文献   

Tropospheric Ozone in a Global-Scale Three-Dimensional Lagrangian Model and Its Response to NOX Emission Controls     

W. J. Collins  D. S. Stevenson  C. E. Johnson  R. G. Derwent 《Journal of Atmospheric Chemistry》1997,26(3):223-274

A three-dimensional Lagrangian tropospheric chemistry modelis used toinvestigate the impact of human activities on the tropospheric distributionofozone and hydroxyl radicals. The model describes the behaviour of 50 speciesincluding methane, carbon monoxide, oxides of nitrogen, sulphur dioxide andnineorganic compounds emitted from human activities and a range of other sources.Thechemical mechanism involves about 100 chemical reactions of which 16 arephotochemical reactions whose diurnal dependence is treated in full. The modelutilises a five minute chemistry time step and a three hour advection timestepfor the 50,000 air parcels. Meteorological data for the winds, temperatures,clouds and so on are taken from the UK Meteorological Office global model for1994 onwards. The impacts of a 50% reduction in European NO_Xemissions onglobal ozone concentrations are assessed. Surface ozoneconcentrations decrease in summertime and rise in wintertime, but to differentextents.  相似文献   

An Assessment of Conventional In Situ Air Sparging Pilot Tests     

Paul C. Johnson  Richard L. Johnson  Christopher Neaville  Erik E. Hansen  Steve M. Stearns  Ira J. Dortch 《Ground water》1997,35(5):765-774

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The Effects of Climate Change on Water Resources in the West: Introduction and Overview     

Tim Barnett  Robert Malone  William Pennell  Detlet Stammer  Bert Semtner  Warren Washington 《Climatic change》2004,62(1-3):1-11

The results of an experimental `end to end' assessment of the effects of climate change on water resources in the western United States are described. The assessment focuses on the potential effects of climate change over the first half of the 21st century on the Columbia, Sacramento/San Joaquin, and Colorado river basins. The paper describes the methodology used for the assessment, and it summarizes the principal findings of the study. The strengths and weaknesses of this study are discussed, and suggestions are made for improving future climate change assessments.  相似文献   

Just When You Thought the Water Was Getting Safe to Drink…     

Paul C. Johnson 《Ground Water Monitoring & Remediation》2004,24(2):4-6

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Influence of landscape position and vegetation on long-term weathering rates at the Hubbard Brook Experimental Forest, New Hampshire, USA     

Carmen A. Nezat  Joel D. Blum  Chris E. Johnson 《Geochimica et cosmochimica acta》2004,68(14):3065-3078

The spatial variability of long-term chemical weathering in a small watershed was examined to determine the effect of landscape position and vegetation. We sampled soils from forty-five soil pits within an 11.8-hectare watershed at the Hubbard Brook Experimental Forest, New Hampshire. The soil parent material is a relatively homogeneous glacial till deposited ∼14,000 years ago and is derived predominantly from granodiorite and pelitic schist. Conifers are abundant in the upper third of the watershed while the remaining portion is dominated by hardwoods. The average long-term chemical weathering rate in the watershed, calculated by the loss of base cations integrated over the soil profile, is 35 meq m⁻² yr⁻¹—similar to rates in other ∼10 to 15 ka old soils developed on granitic till in temperate climates. The present-day loss of base cations from the watershed, calculated by watershed mass balance, exceeds the long-term weathering rate, suggesting that the pool of exchangeable base cations in the soil is being diminished. Despite the homogeneity of the soil parent material in the watershed, long-term weathering rates decrease by a factor of two over a 260 m decrease in elevation. Estimated weathering rates of plagioclase, potassium feldspar and apatite are greater in the upper part of the watershed where conifers are abundant and glacial till is thin. The intra-watershed variability across this small area demonstrates the need for extensive sampling to obtain accurate watershed-wide estimates of long-term weathering rates.  相似文献   

Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS   总被引：6，自引：1，他引：6  

Alistair B. Jeffcoate  Tim Elliott  Alex Thomas  Claudia Bouman 《Geostandards and Geoanalytical Research》2004,28(1):161-172

The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li.  相似文献