Geochemical and Sr–Nd–Pb isotopic investigation of Triassic granitoids and basement rocks in the northern Gyeongsang Basin, Korea: Implications for the young basement in the East Asian continental margin     

Chang-Sik Cheong  Sung-Tack Kwon  Hee Sagong 《Island Arc》2002,11(1):25-44

Abstract We present chemical and Sr–Nd–Pb isotopic compositions of three Triassic (226–241 Ma) calc‐alkaline granitoids (the Yeongdeok granite, Yeonghae diorite and Cheongsong granodiorite) and basement rocks in the northern Gyeongsang basin, south‐eastern Korea. These plutons exhibit typical geochemical characteristics of I‐type granitoids generated in a continental magmatic arc. The Yeongdeok and Yeonghae plutons have similar initial Sr, Nd and Pb isotope ratios (⁸⁷Sr/⁸⁶Sr_initial = 0.7041 ~ 0.7050, ?_Nd(t) = 2.3 ~ 4.0, ²⁰⁶Pb/²⁰⁴Pb_feldspar = 18.22 ~ 18.34), but distinct rare earth element patterns, suggesting that the two plutons formed from partial melting of a similar source material at different depths. The Cheongsong pluton has slightly more enriched Sr–Nd–Pb isotopic compositions (⁸⁷Sr/⁸⁶Sr_initial = 0.7047 ~ 0.7065, ?_Nd(t) = 3.9 ~ 2.8, ²⁰⁶Pb/²⁰⁴Pb_feldspar = 18.24 ~ 18.37) than the other two plutons. The Nd model ages of the basement rocks (1.1 ~ 1.4 Ga) are slightly older than those of the plutons (0.6 ~ 1.0 Ga). The initial Sr and Nd isotopic ratios of the plutons can be modeled by the mixing between the mid‐oceanic ridge basalt‐like depleted mantle component and the crustal component represented by basement rocks, which is also supported by Pb isotope data. The Sr and Nd isotope data from granitoids and basement rocks suggest that the Gyeongsang basin, the Hida belt and the inner zone of south‐western Japan share relatively young basement histories (middle Proterozoic), compared with those (early Proterozoic to Archean) of the Gyeonggi and Yeongnam massifs and the Okcheon belt. The Nd isotope data of basement rocks suggest that the Hida belt might be better correlated with the basement of the Gyeongsang basin than the Gyeonggi massif, the Okcheon belt or the Yeongnam massif, although it may represent an older continental margin of East Asia than the Gyeongsang basin considering its slightly older Nd model ages.  相似文献   

Multi-decadal scenario simulation over Korea using a one-way double-nested regional climate model system. Part 1: recent climate simulation (1971–2000)     

Eun-Soon Im  Won-Tae Kwon  Joong-Bae Ahn  Filippo Giorgi 《Climate Dynamics》2007,28(7-8):759-780

We present an analysis of a high resolution multi-decadal simulation of recent climate (1971–2000) over the Korean Peninsula with a regional climate model (RegCM3) using a one-way double-nested system. Mean climate state as well as frequency and intensity of extreme climate events are investigated at various temporal and spatial scales, with focus on surface air temperature and precipitation. The mother intermediate resolution model domain encompasses the eastern regions of Asia at 60 km grid spacing while the high resolution nested domain covers the Korean Peninsula at 20 km grid spacing. The simulation spans the 30-year period of January 1971 through December 2000, and initial and lateral boundary conditions for the mother domain are provided from ECHO-G fields based on the IPCC SRES B2 scenario. The model shows a good performance in reproducing the climatological and regional characteristics of surface variables, although some persistent biases are present. Main results are as follows: (1) The RegCM3 successfully simulates the fine-scale structure of the temperature field due to topographic forcing but it shows a systematic cold bias mostly due to an underestimate of maximum temperature. (2) The frequency distribution of simulated daily mean temperature agrees well with the observed seasonal and spatial patterns. In the summer season, however, daily variability is underestimated. (3) The RegCM3 simulation adequately captures the seasonal evolution of precipitation associated to the East Asia monsoon. In particular, the simulated winter precipitation is remarkably good, clearly showing typical precipitation patterns that occur on the northwestern areas of Japan during the winter monsoon. Although summer precipitation is underestimated, area-averaged time series of precipitation over Korea show that the RegCM3 agrees better with observations than ECHO-G both in terms of seasonal evolution and precipitation amounts. (4) Heavy rainfall phenomena exceeding 300 mm/day are simulated only at the high resolution of the double nested domain. (5) The model shows a tendency to overestimate the number of precipitation days and to underestimate the precipitation intensities. (6) A CSEOF analysis reveals that the model captures the strength of the annual cycle and the surface warming trend throughout the simulated period.  相似文献   

Characteristics of biomass burning aerosol and its impact on regional air quality in the summer of 2003 at Gwangju, Korea   总被引：1，自引：0，他引：1  

S.Y. Ryu  B.G. Kwon  Y.J. Kim  H.H. Kim  K.J. Chun 《Atmospheric Research》2007,84(4):362-373

The main objective of this study is to investigate the chemical characteristics of biomass burning aerosol and its impact on regional air quality during an agricultural waste burning period in early summer in the rural areas of Korea. A 12-h integrated intensive sampling of biomass burning aerosol in the fine and coarse modes was conducted on 2–20 June 2003 in Gwangju, Korea. The collected samples were analyzed for concentrations of mass, ionic, elemental, and carbonaceous species. Average concentrations of fine and coarse mass were measured to be 67.9 and 18.7 μg m^− 3 during the biomass burning period, 41.9 and 18.8 μg m^− 3 during the haze period, and 35.6 and 13.3 μg m^− 3 during the normal period, respectively. An exceptionally high PM_2.5 concentration of 110.3 μg m^− 3 with a PM_2.5/PM₁₀ ratio of 0.79 was observed on 6 June 2003 during the biomass burning period. The potassium ratio method was used to identify biomass burning samples. The average ratio of potassium in the fine mode to the coarse mode (FK/CK) was 23.8 during the biomass burning period, 6.0 during the haze period, and 4.7 during the normal period, respectively. A FK/CK ratio above 9.2 was considered a criterion for biomass burning event in this study. Particulate matter from the open field burning of agricultural waste has an adverse impact on visibility, human health, and regional air quality.  相似文献   

SHRIMP U–Pb zircon ages of pyroclastic rocks in the Bansong Group, Taebaeksan Basin, South Korea and their implication for the Mesozoic tectonics     

Raehee Han  Jin-Han Ree  Deung-Lyong Cho  Sung-Tack Kwon  Richard Armstrong 《Gondwana Research》2006,9(1-2):106

The Bansong Group (Daedong Supergroup) in the Korean peninsula has long been considered to be an important time marker for two well-known orogenies, in that it was deposited after the Songnim orogeny (Permian–Triassic collision of the North and South China blocks) but was deformed during the Early to Middle Jurassic Daebo tectonic event. Here we present a new interpretation on the origin of the Bansong Group and associated faults on the basis of structural and geochronological data. SHRIMP (Sensitive High-Resolution Ion MicroProbe) U–Pb zircon age determination of two felsic pyroclastic rocks from the Bansong Group formed in the foreland basin of the Gongsuweon thrust in the Taebaeksan Basin yielded ages of 186.3 ± 1.5 and 187.2 ± 1.5 Ma, respectively, indicating the deposition of the Bansong Group during the late Early Jurassic. Inherited zircon component indicates ca. 1.9 Ga source material for the volcanic rocks, agreeing with known basement ages.The Bansong Group represents syntectonic sedimentation during the late Early Jurassic in a compressional regime. During the Daebo tectonic event, the northeast-trending regional folds and thrusts including the Deokpori (Gakdong) and Gongsuweon thrusts with a southeast vergence developed in the Taebaeksan Basin. This is ascribed to deformation in a continental-arc setting due to the northwesterly orthogonal convergence of the Izanagi plate on the Asiatic margin, which occurred immediately after the juxtaposition of the Taebaeksan Basin against the Okcheon Basin in the late stage of the Songnim orogeny. Thus, the Deokpori thrust is not a continental transform fault between the North and South China blocks, but an “intracontinental” thrust that developed after their juxtaposition.  相似文献   

Interactions of biopolymers with silica surfaces: Force measurements and electronic structure calculation studies     

Kideok D. Kwon  Virginia Vadillo-Rodriguez  James D. Kubicki 《Geochimica et cosmochimica acta》2006,70(15):3803-3819

Pull-off forces were measured between a silica colloid attached to an atomic force microscope (AFM) cantilever and three homopolymer surfaces representing constituents of extracellular polymeric substances (EPS). The pull-off forces were −0.84 (±0.16), −0.68 (±0.15), and −2.37 (±0.31) nN as measured in water for dextran, phosphorylated dextran, and poly-l-lysine, respectively. Molecular orbital and density functional theory methods (DFT) were applied to analyze the measured pull-off forces using dimer clusters representing interactions between the three polymers and silica surfaces. Binding energies for each dimer were calculated with basis set superposition error (BSSE) and interpolated using corrections for silica surface hydroxyl density and silica charge density. The binding energies were compared with the normalized pull-off forces with the effective silica surface area contacting the polymer surfaces. The predicted binding energies at a −0.064 C/m² silica surface charge density corresponding to circum-neutral pH were −0.055, −0.029, and −0.338 × 10⁻¹⁸ J/nm² for the dimers corresponding to the silica surface with dextran, phosphorylated dextran, and poly-l-lysine, respectively. Polarizable continuum model (PCM) calculations with different solvents, silanol vibrational frequency calculations, and orbital interaction analysis based on natural bonding orbital (NBO) showed that phosphate groups formed stronger H-bonds with neutral silanols than hydroxyl and amino functional groups of polymers, implying that phosphate containing polymers would play important roles in EPS binding to silica surfaces.  相似文献   

Statistical Methods for Jointly Estimating the Decay Constant of ⁴⁰K and the Age of a Dating Standard     

Jaimyoung Kwon  Kyoungwon Min  Peter J. Bickel  Paul R. Renne 《Mathematical Geology》2002,34(4):457-474

To simultaneously evaluate the decay constant of ⁴⁰K () and the age of a standard (t _std) using isotopic data from geologic materials, we applied a series of statistical methods. The problem of estimating the most probable intercept of many nonlinear curves in and t _std space is formulated by an errors-in-variables nonlinear regression model. Then a maximum likelihood method is applied to the model for a point estimate, which is equivalent to the nonlinear least square method when measurement error distributions are Gaussian. Uncertainties and confidence regions of the estimates can be approximated using three methods: the asymptotic normal approximation, the parametric bootstrap method and Bonferroni confidence regions. Five pairs of published data for samples with ages from 2 ka to 4.5 Ga were used to estimate and the age of Fish Canyon sanidine (t _FCs). The statistical procedure yields most probable estimates of (5.4755 ± 0.0170 × 10^–10 (1)/year) and t _FCs (28.269 ± 0.0661 (1) Ma) which are in between previously published values. These results indicate the power of our approach to provide improved constraints on these parameters, although the preliminary nature of some of the input data require further review before the values can be adopted.  相似文献   

Origin and depositional environment of fine-grained sediments since the last glacial maximum in the southeastern Yellow Sea: evidence from rare earth elements     

In Kwon Um  Man Sik Choi  Gwang Soo Lee  Tae Soo Chang 《Geo-Marine Letters》2015,35(6):421-431

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Unexpected nationwide nitrate declines in groundwater of Korea          下载免费PDF全文

Jin‐Yong Lee  Kideok D. Kwon  Yu‐Chul Park  Woo‐Hyun Jeon 《水文研究》2017,31(26):4693-4704

Elevated levels of nitrate in groundwater are an important concern for health and the environment. The overapplication of nitrogen fertilizer to croplands is one of the major sources of high nitrate content in groundwater. In this study, we analyse the nitrate concentrations in Korean groundwater based on data from groundwater quality monitoring wells (n = 1,022–2,072), which were sampled twice annually over a recent 13‐year analysis period (2001–2013). We report that groundwater nitrate levels are decreasing, despite steadily increasing groundwater use. The maximum nitrate concentration decreased from 168.91 to 48.11 mg/L, whereas the mean values also show a gradual decreasing trend. Non‐parametric Mann–Kendall tests on nitrate concentrations also confirm the decreasing trend. The nitrate decrease is more clearly evident in agricultural groundwater as compared to domestic and drinking groundwaters. This decrease of nitrate in groundwater coincides with a large decline in nitrogen fertilizer application due to reduced cropland areas, more sustainable agricultural practices, and progressive improvement of sewage disposal services. This study proposes that the long‐term adoption of best practices in agriculture has had a positive impact on groundwater nitrate control.  相似文献   

Identification of groundwater recharge sources and processes in a heterogeneous alluvial aquifer: results from multi‐level monitoring of hydrochemistry and environmental isotopes in a riverside agricultural area in Korea     

Byoung‐Young Choi  Seong‐Taek Yun  Bernhard Mayer  Gi‐Tak Chae  Kyoung‐Ho Kim  Kangjoo Kim  Yong‐Kwon Koh 《水文研究》2010,24(3):317-330

We evaluated sources and pathways of groundwater recharge for a heterogeneous alluvial aquifer beneath an agricultural field, based on multi‐level monitoring of hydrochemistry and environmental isotopes of a riverside groundwater system at Buyeo, Korea. Two distinct groundwater zones were identified with depth: (1) a shallow oxic groundwater zone, characterized by elevated concentrations of NO₃^? and (2) a deeper (>10–14 m from the ground surface) sub‐oxic groundwater zone with high concentrations of dissolved Fe, silica, and HCO₃^?, but little nitrate. The change of redox zones occurred at a depth where the aquifer sediments change from an upper sandy stratum to a silty stratum with mud caps. The δ¹⁸O and δ²H values of groundwater were also different between the two zones. Hydrochemical and δ¹⁸O? δ²H data of oxic groundwater are similar to those of soil water. This illustrates that recharge of oxic groundwater mainly occurs through direct infiltration of rain and irrigation water in the sandy soil area where vegetable cropping with abundant fertilizer use is predominant. Oxic groundwater is therefore severely contaminated by agrochemical pollutants such as nitrate. In contrast, deeper sub‐oxic groundwater contains only small amounts of dissolved oxygen (DO) and NO₃^?. The ³H contents and elevated silica concentrations in sub‐oxic groundwater indicate a somewhat longer mean residence time of groundwater within this part of the aquifer. Sub‐oxic groundwater was also characterized by higher δ¹⁸O and δ²H values and lower d‐excess values, indicating significant evaporation during recharge. We suggest that recharge of sub‐oxic groundwater occurs in the areas of paddy rice fields where standing irrigation and rain water are affected by strong evaporation, and that reducing conditions develop during subsequent sub‐surface infiltration. This study illustrates the existence of two groundwater bodies with different recharge processes within an alluvial aquifer. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Uncertainty analysis for the integration of seismic and controlled source electro‐magnetic data     

Myoung Jae Kwon  Roel Snieder 《Geophysical Prospecting》2011,59(4):609-626

We study the appraisal problem for the joint inversion of seismic and controlled source electro‐magnetic (CSEM) data and utilize rock‐physics models to integrate these two disparate data sets. The appraisal problem is solved by adopting a Bayesian model and we incorporate four representative sources of uncertainty. These are uncertainties in 1) seismic wave velocity, 2) electric conductivity, 3) seismic data and 4) CSEM data. The uncertainties in porosity and water saturation are quantified by a posterior random sampling in the model space of porosity and water saturation in a marine one‐dimensional structure. We study the relative contributions from the four individual sources of uncertainty by performing several statistical experiments. The uncertainties in the seismic wave velocity and electric conductivity play a more significant role on the variation of posterior uncertainty than do the seismic and CSEM data noise. The numerical simulations also show that the uncertainty in porosity is most affected by the uncertainty in the seismic wave velocity and that the uncertainty in water saturation is most influenced by the uncertainty in electric conductivity. The framework of the uncertainty analysis presented in this study can be utilized to effectively reduce the uncertainty of the porosity and water saturation derived from the integration of seismic and CSEM data.  相似文献